1,3‐Dienes are a class of easily accessible and versatile feedstock chemicals that can participate in a wide range of reactions to facilitate the synthesis of various valuable allylic compounds.In the past decades,ra...1,3‐Dienes are a class of easily accessible and versatile feedstock chemicals that can participate in a wide range of reactions to facilitate the synthesis of various valuable allylic compounds.In the past decades,radical methodology has emerged as a powerful tool for organic synthesis by virtue of the fact that diverse highly reactive radical species can usually be generated under mild,neutral and controlled conditions,and allow for rapid generation of molecular complexity.In this review,we critically illustrate the recent advances in the field of radical‐mediated transformations of 1,3‐dienes based on the different radical precursors and working modes.Wherever possible,particular emphasis is also put on the related mechanistic studies and synthetic applications.展开更多
ON December 25, 1919, a French ocean liner set off for Marseilles from Yangshupu Pier in Shanghai. Among the passengers were 30 people from Hunan, who were heading for a work-study program in France. Most of them were...ON December 25, 1919, a French ocean liner set off for Marseilles from Yangshupu Pier in Shanghai. Among the passengers were 30 people from Hunan, who were heading for a work-study program in France. Most of them were progressive youth; six of them were women, including: Xiang Jingyu, Cai Chang, Ge Jianhao, Li Zhixin, Xiong Jiguang and Xiao Shuliang. Cai Hesen, the展开更多
文摘1,3‐Dienes are a class of easily accessible and versatile feedstock chemicals that can participate in a wide range of reactions to facilitate the synthesis of various valuable allylic compounds.In the past decades,radical methodology has emerged as a powerful tool for organic synthesis by virtue of the fact that diverse highly reactive radical species can usually be generated under mild,neutral and controlled conditions,and allow for rapid generation of molecular complexity.In this review,we critically illustrate the recent advances in the field of radical‐mediated transformations of 1,3‐dienes based on the different radical precursors and working modes.Wherever possible,particular emphasis is also put on the related mechanistic studies and synthetic applications.
文摘ON December 25, 1919, a French ocean liner set off for Marseilles from Yangshupu Pier in Shanghai. Among the passengers were 30 people from Hunan, who were heading for a work-study program in France. Most of them were progressive youth; six of them were women, including: Xiang Jingyu, Cai Chang, Ge Jianhao, Li Zhixin, Xiong Jiguang and Xiao Shuliang. Cai Hesen, the
