Enhancing CO_(2) transport with plasma-functionalized ionic liquid membranes

The ionic liquid(IL) 1-butyl-3-methylimidazolium tetrafluoroborate treated with radiofrequency plasma is proposed for functionalization and immobilization on polyethersulfone supports to form supported ionic liquid membranes for CO_(2) separation.The effects of treatment time and transmembrane pressure difference on CO_(2) permeance were evaluated.The best gas permeation performance was obtained with a treatment time of 10 min and the transmembrane pressure difference was 0.25 MPa.Characterization of the materials by Fourier transform infrared spectroscopy,x-ray photoelectron spectroscopy and nuclear magnetic resonance spectroscopy demonstrates that the IL is grafted with carboxyl groups and deprotonated through plasma treatment.A preliminary mechanism for the plasma treatment and facilitated transport of CO_(2)has been proposed on this basis.

Perioperative Nursing Observation of Plasma Radiofrequency Ablation for Treatment of Lumbar Intervertebral Disc Herniation

Objective:To observe and analyze the perioperative nursing effect of plasma radiofrequency ablation for treatment of lumbar disc herniation.Methods:A total of 100 patients with lumbar intervertebral disc herniation received from October 2017 to October 2020 were selected and randomly divided into two groups with 50 cases in each group.The control group received the conventional nursing model and the experimental group received the comprehensive nursing model.The two groups of nursing care were compared on satisfaction,SDS and SAS scores before and after treatment,VAS score and JOA score before and after treatment,and treatment effect.Results:The nursing satisfaction of the experimental group,SDS and SAS scores before and after treatment,VAS score and JOA score before and after treatment,and the treatment effect were better than those of the control group.The difference was statistically significant(P<0.05).Conclusion:The comprehensive nursing model has a significant effect on the perioperative nursing of the treatment of lumbar intervertebral disc herniation by plasma radiofrequency ablation.More popularization and application will help improve the treatment effect.

Synthesis of Ag-decorated vertical graphene nanosheets and their electrocatalytic efficiencies

Herein we report the successful preparation of silver(Ag)-decorated vertically oriented graphene sheets(Ag/VGs)via helicon wave plasma chemical vapor deposition(HWP-CVD)and radiofrequency plasma magnetron sputtering(RF-PMS).VGs were synthesized in a mixture of argon and methane(Ar/CH_(4))by HWP-CVD and then the Ag nanoparticles on the prepared VGs were modified using the RF-PMS system for different sputtering times and RF power levels.The morphology and structure of the Ag nanoparticles were characterized by scanning electron microscopy and the results revealed that Ag nanoparticles were evenly dispersed on the mesoporous wall of the VGs.X-ray diffraction results showed that the diameter of the Ag particles increased with the increase in Ag loading,and the average size was between 10.49 nm and 25.9 nm,consistent with the transmission electron microscopy results.Ag/VGs were investigated as effective electrocatalysts for use in an alkaline aqueous system.Due to the uniquely ordered and interconnected wall structure of VGs,the area of active sites increased with the Ag loading,giving the Ag/VGs a good performance in the oxygen evolution reaction.The double-layer capacitance(C_(dl))of the Ag/VGs under different Ag loadings were studied,and the results showed that the highest Ag content gave the best C_(dl)(1.04 mF cm^(-2)).Our results show that Ag/VGs are likely to be credible electrocatalytic materials.

Effects of RFTVR and CO2 laser on symptoms improvement, QOL and vas of patients with early laryngeal cancer

Objective: To study the effect of RFTVR and CO2 laser on the improvement of symptoms, QOL and vas of patients with early laryngeal cancer. Methods: In this study, 120 patients with laryngeal cancer diagnosed and treated from January 2015 to December 2016 were taken as research objects. All patients were randomly divided into observation group and control group, 60 patients in each group. Patients in observation group were treated with RFTVR, and patients in control group were treated with new-type fiber-optic CO2 laser. The patients in the two groups were treated with cisplatin injection. The differences of perioperative indexes, swallowing function, pronunciation function, survival period, QOL score and VAS score between the two groups were compared. Results: There was no significant difference in the amount of intraoperative bleeding, operation time and hospitalization time between the two groups (P > 0.05);the correct swallowing of the observation group was significantly higher than that of the control group. After treatment, jitter, shimmer and HNR of the two groups were significantly improved, and jitter and shimmer of the observation group were significantly lower than that of the control group, and HNR was significantly higher than that of the control group (P < 0.05) The QOL score and VAS score of the two groups were significantly improved, and the QOL score of the observation group was significantly higher than that of the control group and the VAS score was significantly lower than that of the control group (P < 0.05);the total survival period and tumor free survival period of the observation group were significantly higher than that of the control group. Conclusion: Compared with CO2 laser treatment, the swallowing function and voice function of patients treated by low temperature plasma radiofrequency ablation were significantly improved, and the life quality of patients was significantly improved by prolonging the survival period of patients..

Determination of gaseous semi- and low-volatile organic halogen compounds by barrier-discharge atomic emission spectrometry

A group parameter approach using ＂total organic halogen＂ is effective for monitoring gaseous organic halogen compounds, including fluorine, chlorine, and bromine compounds, generated from combustion. We described the use of barrier-discharge radiofrequency- helium-plasma/atomic emission spectrometry, for the detection of semi- and low-volatile organic halogen compounds （SLVOXs）, which can be collected by CarbotrapTM adsorbents and analyzed using thermal desorpfion. The optimal carder gas flow rates at the injection and desorption lines were established to be 100 mL/min. The detection range for SLVOXs in the gaseous samples was from 10 ng to tens of micrograms. Measuring F was more difficult than measuring C1 or Br, because the wavelength of F is close to that of air. The barrier- discharge radiofrequency-helium-plasma/atomic emission spectrometry measured from 85% to 103% of the SLVOXs in the gas sample. It has been found that Carbotrap B is appropriate for high-boiling-point compounds, and Carbotrap C is suitable for the determination of organic halogen compounds with lower boiling points, in the range 200-230℃. Under optimal analysis conditions, a chlorine- containing plastic was destroyed using different oxygen concentrations. Lower oxygen concentrations resulted in the production of lower amounts of organic halogen compounds.