The compositions, structures and properties of envi- ronmental-friendly ramming materials for mud package and taphole of large-scaled blast furnaces were studied. The results show that the formation of silica fibers m...The compositions, structures and properties of envi- ronmental-friendly ramming materials for mud package and taphole of large-scaled blast furnaces were studied. The results show that the formation of silica fibers makes structure of ramming materials dense. During the process of extruding mud and ramming materials, SiC is partly oxidized ; CaO , F% 03 and carbon penetrate towards the outer wall. The improvement of ramming materials can inhibit the penetration of molten slag, iron and carbon. The bulk density of environmental-friendly ramming ma- terials dried at 200 ℃ is 2.90 g · cm-3, the cold com- pressive strength of this kind of ramming materials dried at 200 ℃ is about 17. 0 MPa and fired at I 450 ℃ is about 39. 2 MPa.展开更多
Silicon fines, boron acid solid powders and microfine SiO 2 as sintering agents were incorporated into Al 2O 3-SiC-C ramming mix in order to investigated their effects on the microstructure, mechanical properties a...Silicon fines, boron acid solid powders and microfine SiO 2 as sintering agents were incorporated into Al 2O 3-SiC-C ramming mix in order to investigated their effects on the microstructure, mechanical properties and sintering behavior of the ramming mix. Results show that all the three agents could improved both densification and mehanical properties markedly, compared to that of non-agent specimens and the effect of the composite of boron acid solid powders and microfine SiO 2 is the best. The oxidation resistance increased with the addition of agents, which is supported by densification. Microstructures showed that agent powders could fill pores or produce liquid phases at high temperature, therefore, improve the sintering of the ramming mix.展开更多
Mg0-Al2O3-Cr2O3 ramming mixes made of different raw materials have different mineral structure and different physical properties though with the identical particle size distribution, the same amount of binder and chem...Mg0-Al2O3-Cr2O3 ramming mixes made of different raw materials have different mineral structure and different physical properties though with the identical particle size distribution, the same amount of binder and chemical composition . The residual carbon content of the fused magnesia-chrome material made in reducing atmosphere is very high, if this material is used in the MgO-Al203-Cr2O3 ramming mix , it would cause spalling of the furnace lining during drying-out.展开更多
Fused materials from ZrO2 stabilized by CaO or MgO, or the combined additive consisting of CaO and MgO are made. With using chemical, petrographic, X-ray phase and electron microscopic researches the main characterist...Fused materials from ZrO2 stabilized by CaO or MgO, or the combined additive consisting of CaO and MgO are made. With using chemical, petrographic, X-ray phase and electron microscopic researches the main characteristics of these materials are determined. It is shown that, the materials of all compositions have low water absorption; they are characterized by equal struc-ture. The materials stabilized by the combined additive consisting of CaO and MgO are presented by generally the cubic phase and a small amount of tetragonal and monoclinic ZrO2 phases. Depending on CaO: MgO ratio in the materials the tetragonal ZrO2 phase settles down in a cubic matrix in the form of separate grains, and sites of net like structure in the form of a "woven" interlacing (2.9% of CaO and 2. 6% of MgO ). An influence of the above mentioned fused stabilized ZrO2 materials and quantity of monoclinic zirconia, on the forming of zirconia mix on a phosphate bond and properties of" .fired samples is studied. The samples from mix based on ZrO2 stabilized by the combined additive consisting of 2.9% CaO and 2.6% MgO with 20% of monoclinic Zr02 are characterized by the highest properties: after .firing at 1 580 ~C open porosity of 14. 3% - 14. 8%, apparent density of 4. 67 -4. 69 g · cm^-5, cold crushing strength of 62 - 68 MPa, thermal shock resistance ( 1 300℃←→air) of 15 thermal cycles, linear growth of 0. 2%. The manufacturing technology of powders mix-ture for ramming mix based on the new fused material .from ZrO2 stabilized by the combined additive is developed and its production is mastered. From this mixture the large-size, shaped products on the phosphate bond are made at one carbon black production plant, which are installed in the combustion chamber of the carbon black production reactor.展开更多
Aluminium powders were introduced to Al2O3-SiC-C dry ramming mixes in order to improve sintering properties and oxidation resistance according to their service conditions and installation methods. Properties such as b...Aluminium powders were introduced to Al2O3-SiC-C dry ramming mixes in order to improve sintering properties and oxidation resistance according to their service conditions and installation methods. Properties such as bulk density, porosity, modulus of rupture, crushing strength and hot modulus of rupture as a function of aluminium addition were investigated in the present work. The microstructure and thermodynamics for the heat treated specimens were also analyzed. The results show that as aluminium addition increasing, the bulk density of the specimen treated at 220℃ tends to decrease and the apparent porosity increases, the strength of the specimens treated at 1100℃ and 1450℃ increases markedly, the bulk density tends to increase, apparent porosity and linear shrinkage decrease. The HMOR at 1400℃ is enhanced from 1.0 MPa to 3.5 MPa with 3% aluminium. Aluminium is served as sintering agent and anti-oxidant and it will react with CO and CO2 forming Al2O3 , which is helpful to enhance the strength, densify the structure and improve the overall properties.展开更多
1 Scope This standard specifies the definition, classifica- tion, technical requirements, test methods, quality ap- praisal procedure, packing, marking, transportation, stroage and quality certificate of carbon rammi...1 Scope This standard specifies the definition, classifica- tion, technical requirements, test methods, quality ap- praisal procedure, packing, marking, transportation, stroage and quality certificate of carbon ramming mate- rials for blast furnace construction. This standard is applicable to carbon ramming materials for construction in leveling layer of blast furnace bottom, ramming layer upper or lower the cen- tral line of water cooling pipes, joints between carbon bricks, or joints between carbon bricks and cooling equipment.展开更多
A series of ballistic experiments were performed to investigate the damage behavior of high velocity reactive material projectiles(RMPs) impacting liquid-filled tanks,and the corresponding hydrodynamic ram(HRAM) was s...A series of ballistic experiments were performed to investigate the damage behavior of high velocity reactive material projectiles(RMPs) impacting liquid-filled tanks,and the corresponding hydrodynamic ram(HRAM) was studied in detail.PTFE/Al/W RMPs with steel-like and aluminum-like densities were prepared by a pressing/sintering process.The projectiles impacted a liquid-filled steel tank with front aluminum panel at approximately 1250 m/s.The corresponding cavity evolution characteristics and HRAM pressure were recorded by high-speed camera and pressure acquisition system,and further compared to those of steel and aluminum projectiles.Significantly different from the conical cavity formed by the inert metal projectile,the cavity formed by the RMP appeared as an ellipsoid with a conical front.The RMPs were demonstrated to enhance the radial growth velocity of cavity,the global HRAM pressure amplitude and the front panel damage,indicating the enhanced HRAM and structural damage behavior.Furthermore,combining the impact-induced fragmentation and deflagration characteristics,the cavity evolution of RMPs under the combined effect of kinetic energy impact and chemical energy release was analyzed.The mechanism of enhanced HRAM pressure induced by the RMPs was further revealed based on the theoretical model of the initial impact wave and the impulse analysis.Finally,the linear correlation between the deformation-thickness ratio and the non-dimensional impulse for the front panel was obtained and analyzed.It was determined that the enhanced near-field impulse induced by the RMPs was the dominant reason for the enhanced structural damage behavior.展开更多
Ramming system is the key device to guarantee the firing speed of self-propelled gun. Based on traditional reliability enhancement testing method, a new kind of reliability enhancement testing simulation method of ram...Ramming system is the key device to guarantee the firing speed of self-propelled gun. Based on traditional reliability enhancement testing method, a new kind of reliability enhancement testing simulation method of ramming system is put forward firstly. In CAD software Pro/E and dynamic simulation software ADAMS, the virtual prototype of ramming system is established. In EASY5 software, the corresponding hydraulic system and control system models are built. The reliability enhancement testing virtual environment of ramming system is developed using the mechanical-electrical-hydraulic co-simulation technology. Based on the load spectra provided by virtual prototype, and the stress distribution provided by finite element analysis and material's S-N curve(S is fatigue strength, N is fatigue life), a model of fatigue enhancement coefficient is established through the failure mechanism analysis. The simulation processes and simulation results show the feasibility of reliability enhancement testing based on virtual prototype, and provide sufficient theory reference for structure improvement and optimization of ramming system.展开更多
文摘The compositions, structures and properties of envi- ronmental-friendly ramming materials for mud package and taphole of large-scaled blast furnaces were studied. The results show that the formation of silica fibers makes structure of ramming materials dense. During the process of extruding mud and ramming materials, SiC is partly oxidized ; CaO , F% 03 and carbon penetrate towards the outer wall. The improvement of ramming materials can inhibit the penetration of molten slag, iron and carbon. The bulk density of environmental-friendly ramming ma- terials dried at 200 ℃ is 2.90 g · cm-3, the cold com- pressive strength of this kind of ramming materials dried at 200 ℃ is about 17. 0 MPa and fired at I 450 ℃ is about 39. 2 MPa.
文摘Silicon fines, boron acid solid powders and microfine SiO 2 as sintering agents were incorporated into Al 2O 3-SiC-C ramming mix in order to investigated their effects on the microstructure, mechanical properties and sintering behavior of the ramming mix. Results show that all the three agents could improved both densification and mehanical properties markedly, compared to that of non-agent specimens and the effect of the composite of boron acid solid powders and microfine SiO 2 is the best. The oxidation resistance increased with the addition of agents, which is supported by densification. Microstructures showed that agent powders could fill pores or produce liquid phases at high temperature, therefore, improve the sintering of the ramming mix.
文摘Mg0-Al2O3-Cr2O3 ramming mixes made of different raw materials have different mineral structure and different physical properties though with the identical particle size distribution, the same amount of binder and chemical composition . The residual carbon content of the fused magnesia-chrome material made in reducing atmosphere is very high, if this material is used in the MgO-Al203-Cr2O3 ramming mix , it would cause spalling of the furnace lining during drying-out.
文摘Fused materials from ZrO2 stabilized by CaO or MgO, or the combined additive consisting of CaO and MgO are made. With using chemical, petrographic, X-ray phase and electron microscopic researches the main characteristics of these materials are determined. It is shown that, the materials of all compositions have low water absorption; they are characterized by equal struc-ture. The materials stabilized by the combined additive consisting of CaO and MgO are presented by generally the cubic phase and a small amount of tetragonal and monoclinic ZrO2 phases. Depending on CaO: MgO ratio in the materials the tetragonal ZrO2 phase settles down in a cubic matrix in the form of separate grains, and sites of net like structure in the form of a "woven" interlacing (2.9% of CaO and 2. 6% of MgO ). An influence of the above mentioned fused stabilized ZrO2 materials and quantity of monoclinic zirconia, on the forming of zirconia mix on a phosphate bond and properties of" .fired samples is studied. The samples from mix based on ZrO2 stabilized by the combined additive consisting of 2.9% CaO and 2.6% MgO with 20% of monoclinic Zr02 are characterized by the highest properties: after .firing at 1 580 ~C open porosity of 14. 3% - 14. 8%, apparent density of 4. 67 -4. 69 g · cm^-5, cold crushing strength of 62 - 68 MPa, thermal shock resistance ( 1 300℃←→air) of 15 thermal cycles, linear growth of 0. 2%. The manufacturing technology of powders mix-ture for ramming mix based on the new fused material .from ZrO2 stabilized by the combined additive is developed and its production is mastered. From this mixture the large-size, shaped products on the phosphate bond are made at one carbon black production plant, which are installed in the combustion chamber of the carbon black production reactor.
文摘Aluminium powders were introduced to Al2O3-SiC-C dry ramming mixes in order to improve sintering properties and oxidation resistance according to their service conditions and installation methods. Properties such as bulk density, porosity, modulus of rupture, crushing strength and hot modulus of rupture as a function of aluminium addition were investigated in the present work. The microstructure and thermodynamics for the heat treated specimens were also analyzed. The results show that as aluminium addition increasing, the bulk density of the specimen treated at 220℃ tends to decrease and the apparent porosity increases, the strength of the specimens treated at 1100℃ and 1450℃ increases markedly, the bulk density tends to increase, apparent porosity and linear shrinkage decrease. The HMOR at 1400℃ is enhanced from 1.0 MPa to 3.5 MPa with 3% aluminium. Aluminium is served as sintering agent and anti-oxidant and it will react with CO and CO2 forming Al2O3 , which is helpful to enhance the strength, densify the structure and improve the overall properties.
文摘1 Scope This standard specifies the definition, classifica- tion, technical requirements, test methods, quality ap- praisal procedure, packing, marking, transportation, stroage and quality certificate of carbon ramming mate- rials for blast furnace construction. This standard is applicable to carbon ramming materials for construction in leveling layer of blast furnace bottom, ramming layer upper or lower the cen- tral line of water cooling pipes, joints between carbon bricks, or joints between carbon bricks and cooling equipment.
基金supported by the Youth Foundation of State Key Laboratory of Explosion Science and Technology (Grant No.QNKT22-12)the State Key Program of National Natural Science Foundation of China (Grant No.12132003)。
文摘A series of ballistic experiments were performed to investigate the damage behavior of high velocity reactive material projectiles(RMPs) impacting liquid-filled tanks,and the corresponding hydrodynamic ram(HRAM) was studied in detail.PTFE/Al/W RMPs with steel-like and aluminum-like densities were prepared by a pressing/sintering process.The projectiles impacted a liquid-filled steel tank with front aluminum panel at approximately 1250 m/s.The corresponding cavity evolution characteristics and HRAM pressure were recorded by high-speed camera and pressure acquisition system,and further compared to those of steel and aluminum projectiles.Significantly different from the conical cavity formed by the inert metal projectile,the cavity formed by the RMP appeared as an ellipsoid with a conical front.The RMPs were demonstrated to enhance the radial growth velocity of cavity,the global HRAM pressure amplitude and the front panel damage,indicating the enhanced HRAM and structural damage behavior.Furthermore,combining the impact-induced fragmentation and deflagration characteristics,the cavity evolution of RMPs under the combined effect of kinetic energy impact and chemical energy release was analyzed.The mechanism of enhanced HRAM pressure induced by the RMPs was further revealed based on the theoretical model of the initial impact wave and the impulse analysis.Finally,the linear correlation between the deformation-thickness ratio and the non-dimensional impulse for the front panel was obtained and analyzed.It was determined that the enhanced near-field impulse induced by the RMPs was the dominant reason for the enhanced structural damage behavior.
基金the National Natural Science Foundation of China(No.51175508)
文摘Ramming system is the key device to guarantee the firing speed of self-propelled gun. Based on traditional reliability enhancement testing method, a new kind of reliability enhancement testing simulation method of ramming system is put forward firstly. In CAD software Pro/E and dynamic simulation software ADAMS, the virtual prototype of ramming system is established. In EASY5 software, the corresponding hydraulic system and control system models are built. The reliability enhancement testing virtual environment of ramming system is developed using the mechanical-electrical-hydraulic co-simulation technology. Based on the load spectra provided by virtual prototype, and the stress distribution provided by finite element analysis and material's S-N curve(S is fatigue strength, N is fatigue life), a model of fatigue enhancement coefficient is established through the failure mechanism analysis. The simulation processes and simulation results show the feasibility of reliability enhancement testing based on virtual prototype, and provide sufficient theory reference for structure improvement and optimization of ramming system.