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Changes in Sediment Sources in the Southern Muddy Area of Weihai,China,Since the Late Pleistocene:A Record from Rare Earth Elements
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作者 ZHANG Zhichao LIU Jinqing +3 位作者 YIN Ping CAO Ke FENG Xiaokun WANG Shengyu 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第5期1221-1232,共12页
The small muddy areas developed in the southern Shandong Peninsula have attracted increasing attention from researchers because of complex changes in sediment sources driven by sea-level fluctuations and land-sea inte... The small muddy areas developed in the southern Shandong Peninsula have attracted increasing attention from researchers because of complex changes in sediment sources driven by sea-level fluctuations and land-sea interactions since the late Pleistocene.This study investigates the evolution of sediment sources and their responses to environmental changes since the late Pleistocene,using core WHZK01 collected from the nearshore muddy area in southern Weihai for rare earth element(REE)analysis.In doing so,this work highlights the changing patterns of material sources and the primary control factors.The results reveal that the sedimentary deposits in core WHZK01 exhibit distinct terrestrial characteristics.Discriminant function analysis(F_(D))and source discrimination dia-grams both suggest that the primary sources of these deposits are the Yellow River and adjacent small and medium-sized rivers,although the sources vary among different sedimentary units.Furthermore,the DU3 layer(17.82-25.10 m)displays typical riverine sedimentation,dominated by terrestrial detrital input,primarily from the local rivers,namely the Huanglei and Muzhu Rivers.The material in the DU2 layer(14.91-17.82 m)is mainly influenced by a mixture of the Qinglong and Yellow Rivers.The DU1 layer(0-14.91 m)is influenced by sea-level changes during the Holocene,with the Yellow River being the primary source,although there is also some input from local rivers.The changes in sea level during the Holocene and the input of Yellow River material carried by the coastal currents of the Yellow Sea are identified as the main controlling factors for the changes in material sources in the study area since the late Pleistocene,with small and mediumsized rivers also exerting some influence on the material sources.The above mentioned findings not only contribute to a better understanding of the source-sink systems of the Yellow River and adjacent small and mediumsized rivers but also deepen our understanding of the late Quaternary land-sea interactions in the Shandong Peninsula. 展开更多
关键词 rare earth element source identification environmental evolution muddy area southern Weihai
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Rare Earth Elements(La,Ce,Pr)Modified Co/NC Catalyst for Efficient and Stable Ammonia Decomposition to Hydrogen Production
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作者 ZHU Yi PAN Hongfei 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第6期1372-1378,共7页
Co/NC catalysts modified with rare earth elements(La,Ce,Pr)were prepared by pyrolysis of rare earth elements doped ZIF-67.The experimental results show that the modification of rare earth elements significantly improv... Co/NC catalysts modified with rare earth elements(La,Ce,Pr)were prepared by pyrolysis of rare earth elements doped ZIF-67.The experimental results show that the modification of rare earth elements significantly improves the ammonia decomposition activity and stability of the Co/NC catalyst.The La-Co/NC catalyst can achieve an 82.3%ammonia decomposition and 18.4 mmol hydrogen production rate at 550℃with a GHSV of 20000 cm^(3)·h^(-1).Furthermore,no obvious performance degradation is observed after 72 hours of reaction for all rare earth elements modified catalysts.It is shown that the modification of rare earth elements significantly improves the surface alkalinity and surface chemical state of the catalyst,and thus improves the ammonia decomposition activity of the catalyst.A new type of high-performance ammonia decomposition Co-based catalyst is proposed,and the promoting effect of rare earth elements on the activity of ammonia decomposition is revealed. 展开更多
关键词 hydrogen carrier hydrogen production ammonia decomposition rare earth elements cobalt-based catalysts
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Association between Exposure of Rare Earth Elements and Outcomes of In Vitro Fertilization-Embryo Transfer in Beijing
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作者 Yutong Wang Jing Li +9 位作者 Shirong Xu Shengli Lin Zhenchen Hou Linlin Wang Yali Huang Yue Sun Wei Guo Lailai Yan Ying Wang Chan Tian 《Biomedical and Environmental Sciences》 SCIE CAS CSCD 2024年第8期876-886,共11页
Objective The study aimed to investigate the impact of rare earth elements(REEs)exposure on pregnancy outcomes of in vitro fertilization-embryo transfer(IVF-ET)by analyzing samples from spouses.Methods A total of 141 ... Objective The study aimed to investigate the impact of rare earth elements(REEs)exposure on pregnancy outcomes of in vitro fertilization-embryo transfer(IVF-ET)by analyzing samples from spouses.Methods A total of 141 couples were included.Blood and follicular fluid from the wives and semen plasma from the husbands,were analyzed for REEs using inductively coupled plasma mass spectrometry(ICP-MS).Spearman's correlation coefficients and the Mann–Whitney U test were used to assess correlations and compare REE concentrations among three types of samples,respectively.Logistic models were utilized to estimate the individual REE effect on IVF-ET outcomes,while BKMR and WQS models explored the mixture of REE interaction effects on IVF-ET outcomes.Results Higher La concentration in semen(median 0.089 ng/mL,P=0.03)was associated with a lower fertilization rate.However,this effect was not observed after artificial selection intervention through intracytoplasmic sperm injection(ICSI)(P=0.27).In semen,the REEs mixture did not exhibit any significant association with clinical pregnancy.Conclusion Our study revealed a potential association between high La exposure in semen and a decline in fertilization rate,but not clinical pregnancy rate.This is the first to report REEs concentrations in follicular fluid with La,Ce,Pr,and Nd found at significantly lower concentrations than in serum,suggesting that these four REEs may not accumulate in the female reproductive system.However,at the current exposure levels,mixed REEs exposure did not exhibit reproductive toxicity. 展开更多
关键词 rare earth elements In vitro fertilization Pregnancy outcomes Mixture exposure analysis
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Biomedical rare-earth magnesium alloy:Current status and future prospects 被引量:1
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作者 Mingli Yang Cheng Chen +5 位作者 Dongsheng Wang Yinjin Shao Wenhao Zhou Cijun Shuai Youwen Yang Xinghai Ning 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第4期1260-1282,共23页
Biomedical magnesium(Mg)alloys have garnered significant attention because of their unique biodegradability,favorable biocompatibility,and suitable mechanical properties.The incorporation of rare earth(RE)elements,wit... Biomedical magnesium(Mg)alloys have garnered significant attention because of their unique biodegradability,favorable biocompatibility,and suitable mechanical properties.The incorporation of rare earth(RE)elements,with their distinct physical and chemical properties,has greatly contributed to enhancing the mechanical performance,degradation behavior,and biological performance of biomedical Mg alloys.Currently,a series of RE-Mg alloys are being designed and investigated for orthopedic implants and cardiovascular stents,achieving substantial and encouraging research progress.In this work,a comprehensive summary of the state-of-the-art in biomedical RE-Mg alloys is provided.The physiological effects and design standards of RE elements in biomedical Mg alloys are discussed.Particularly,the degradation behavior and mechanical properties,including their underlying action are studied in-depth.Furthermore,the preparation techniques and current application status of RE-Mg alloys are reviewed.Finally,we address the ongoing challenges and propose future prospects to guide the development of high-performance biomedical Mg-RE alloys. 展开更多
关键词 Magnesium alloy rare earth elements Biodegradation behavior Mechanical performance Biological properties
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Effects of Rare-earth and Microalloying Elements on the Microstructure Characteristics of Hypereutectoid Rails
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作者 戴宇恒 ZHAO Wenqian +1 位作者 包喜荣 陈林 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第3期682-688,共7页
We performed thermal simulation experiments of double-pass deformation of hypereutectoid rails with different microalloying elements at a cooling rate of 1℃/s and deformation of 80%to explore the influence of rare-ea... We performed thermal simulation experiments of double-pass deformation of hypereutectoid rails with different microalloying elements at a cooling rate of 1℃/s and deformation of 80%to explore the influence of rare-earth and microalloying elements on the structure of hypereutectoid rails and optimize the composition design of hypereutectoid rails.Scanning electron microscopy,transmission electron microscopy,X-ray diffraction,and other characterization techniques were employed to quantitatively analyzed the effects of different microalloying elements,including rare-earth elements,on pearlite lamellar spacing,cementite characteristics,and dislocation density.It was found that the lamellar spacing was reduced by adding various microalloying elements.Cementite lamellar thickness decreased with the refinement of pearlite lamellar spacing while the cementite content per unit volume increased.Local cementite spheroidization,dispersed in the ferrite matrix in granular form and thus playing the role of dispersion strengthening,was observed upon adding cerium(Ce).The contributions of dislocation density to the alloy strength of four steel sheet samples with and without the addition of nickel,Ce,and Ce–copper(Cu)composite were 26,27,32,and 37 MPa,respectively,indicating that the Ce–Cu composite had the highest dislocation strengthening effect.The Ce–Cu composite has played a meaningful role in the cementite characteristics and dislocation strengthening,which provides a theoretical basis for optimizing the composition design of hypereutectoid rails in actual production conditions. 展开更多
关键词 microalloying elements rare earth hypereutectoid rail CEMENTITE DISLOCATION
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Geochemical characterization of rare earth elements in sediment profiles from the Oualida lagoon(Morocco)
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作者 Nezha Mejjad Abdelmourhit Laissaoui +2 位作者 Ouafa El Hammoumi Ahmed Fekri Hamid Amsil 《Acta Geochimica》 EI CAS CSCD 2023年第6期1051-1064,共14页
The present work assesses the temporal distribution pattern and geochemical changes of rare earth elements and Yttrium, Scandium, Thorium, and Uranium delivery into the Oualidia lagoon. Two sediment cores were retriev... The present work assesses the temporal distribution pattern and geochemical changes of rare earth elements and Yttrium, Scandium, Thorium, and Uranium delivery into the Oualidia lagoon. Two sediment cores were retrieved from the Oualidia lagoon and analyzed using neutron activation analysis. The results indicated that heavy rare earth elements are slightly enriched the sediment cores over light rare earth elements. The highest values of REEs were recorded in the top layers of the cores and depleted with depth, suggesting a possible change in factors controlling their accumulation, including mechanical, chemical, and environmental parameters such as weathering intensity, grain size, and Fe-Mn oxides. The sediments display positive Ce anomalies, which are probably related to the submarine weathering process and detrital input. Noting also the variation of hydrodynamics conditions and confinement of the upstream part of the lagoon played a key role in changing the sediment origins.Thus, further investigation of REEs origin in the Oualidia lagoon sediment is required to identify their sources,provenances, and the factors controlling their spatial and vertical distributions. However, these results provide baseline data of occurring changes in REEs geochemical composition and constitute a typical study case to understand the link between sedimentary and geochemistry processes in a lagoonal ecosystem. 展开更多
关键词 Geochemical characterization rare earth elements SEDIMENT Oualidia lagoon
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Geochemical Characteristics of the Trace and Rare Earth Elements in Reef Carbonates from the Xisha Islands(South China Sea): Implications for Sediment Provenance and Paleoenvironment 被引量:2
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作者 BI Dongjie ZHAI Shikui +5 位作者 ZHANG Daojun XIU Chun LIU Xinyu LIU Xiaofeng JIANG Longjie ZHANG Aibin 《Journal of Ocean University of China》 SCIE CAS CSCD 2019年第6期1291-1301,共11页
Based on the concentrations of the trace elements,rare earth elements(REE),and Sr isotopic compositions in reef carbonates from the well‘Xike-1’reef core of the Xisha Islands,the constraints on sediment provenance a... Based on the concentrations of the trace elements,rare earth elements(REE),and Sr isotopic compositions in reef carbonates from the well‘Xike-1’reef core of the Xisha Islands,the constraints on sediment provenance and paleoenvironment were defined.Variations of the terrigenous input into the paleoseawater were traced in detail and the paleoenvironment and sediment provenance were further investigated.The results show that the HREE/LREE values in the reef carbonates are negatively associated with their Th and Al concentrations;however,their Al and Th concentrations show positive correlation.The lowest 87 Sr/86 Sr values in the reef carbonates generally coincide with the lowest values of Al,Th concentrations and the highest values of HREE/LREE.These data indicate that the HREE/LREE,Al concentrations,and Th concentrations of the reef carbonates are useful indexes for evaluating the influence of the terrigenous inputs on the seawater composition in the study area.From top to bottom,the changing process of the HREE/LREE values and Al,Th concentrations can be divided into 6 intervals;they are H1(0–89.30 m,about 0–0.11 Myr),L1(89.30–198.30 m,about 0.11–2.2 Myr),H2(198.30–374.95 m,about 2.2–5.3 Myr),D(374.95–758.40 m,about 5.3–13.6 Myr),L2(758.40–976.86 m,about 13.6–15.5 Myr),and H3(976.86–1200.00 m,about 15.5–21.5 Myr).Moreover,the changing trend of the HREE/LREE values coincides with that of the seawater δ^13C values recorded by benthonic foraminiferal skeletons from the drill core of ODP site 1148 in the South China Sea(SCS),but not with that of the seawaterδ18O values.The high uplifting rates of the Qinghai-Tibet Plateau coincide with the high Th and Al concentrations and the low HREE/LREE values in the reef carbonates.These data indicate that the main factors controlling the changes of terrigenous flux in the SCS are the tectonic activities associated with Qinghai-Tibet Plateau uplifting and the variations of uplifting rates rather than paleoclimatic changes. 展开更多
关键词 TRACE and rare earth elements paleoenvironmental and sediment provenance reeF CARBONATES the South China Sea(SCS) the UPLIFT of Qinghai-Tibet Plateau
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Geochemistry of the Rare Earth Elements (REE) Distribution in Terengganu Coastal Waters: A Study Case from Redang Island Marine Sediment 被引量:3
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作者 A. Nor Antonina N. A. M. Shazili +3 位作者 B. Y. Kamaruzzaman M. C. Ong Y. Rosnan F. N. Sharifah 《Open Journal of Marine Science》 2013年第3期154-159,共6页
A study on the rare earth elements (REEs) of Redang Island marine sediments was conducted in August 2011 during the premonsoon season. Bottom sediments were collected from 27 sampling stations on board UMT Discovery I... A study on the rare earth elements (REEs) of Redang Island marine sediments was conducted in August 2011 during the premonsoon season. Bottom sediments were collected from 27 sampling stations on board UMT Discovery II vessel using a Smith McIntyre grab and analyzed for rare earth elements (REEs) using inductively coupled plasma mass spectrometry (ICP-MS). Results showed that the REEs patterns in sediments reflected the source rock patterns with an overall order of abundance such as: light rare earth elements (LREE) > middle rare earth element (MREE) > high rare earth elements (HREE). The chondrite normalized patterns of REEs showed enrichment of LREEs over HREEs with La/Yb of 13.6 while the chondrite normalized value showed low (Gd/Yb)N ratios (2.12) which was illustrated in the flat HREE pattern. The chondrite normalized REE patterns of sediments showed the enrichment of LREE and depletion of HREE. From our findings, REEs concentrations in the study area were found to be of geogenic origins and the distributions were not influenced by anthropogenic sources. 展开更多
关键词 rare earth elements Marine SEDIMENTS Redang ISLAND MALAYSIA
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Sources of rare earth elements REE+Y(REY)in Bayili Coal Mine from Wensu County of Xinjiang,China 被引量:2
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作者 Jian-qiang XUE Jian-xin LIU +4 位作者 De-zhi HUANG Wei-jian ZHOU Chun-ming LIU Yu-sen CAO Chuang-hua CAO 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第10期3105-3115,共11页
By analyses on the trace elements of coals,host-rocks and wall-rocks,this study aims to trace the sources and evaluate the utilization prospects of REE+Y(REY)in coals from Bayili Coal Mine(Wensu,Xinjiang,China).The di... By analyses on the trace elements of coals,host-rocks and wall-rocks,this study aims to trace the sources and evaluate the utilization prospects of REE+Y(REY)in coals from Bayili Coal Mine(Wensu,Xinjiang,China).The distribution patterns of REY in the coals are divided into two groups,flat-type and heavy REE-enrichment type(H-type).The REY of the former was mainly from the gneisses of the basement of the coal-bearing basin,and that of the later was partly from hydrothermal solution.The host-rocks show two types of REY patterns,middle REE-enrichment type(M-type)and H-type,which are due to the injection of REY from acid terrestrial water and hydrothermal solution,respectively.Almost all the coal samples are plotted into the promising area on the diagram of percentage of critical elements(REY_(def,rel))vs ratio of sum of critical elements to the sum of excessive elements(C_(outl))and half of the coal samples have high contents of Ga closing to the cut-off grade of Ga deposit as by-product,which indicate that the REY and Ga in Bayili Coal Mine are of utilization prospects as by-product. 展开更多
关键词 source rare earth elements distribution pattern COAL Wensu County(Xinjiang)
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Enhancement Effects of Three Rare Earth Elements on the Growth of Chaetoceros Mulleri 被引量:1
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作者 Qu Keming(曲克明) +1 位作者 Xin Fuyan(辛福言) 《Marine Science Bulletin》 CAS 2001年第2期83-88,共6页
Enhancement effects of rare earth elements on the growth of Chaetoceros mulleri is studied in this paper. The results show that all of the light, middle and heavy rare earth elements have similar enhancement effect on... Enhancement effects of rare earth elements on the growth of Chaetoceros mulleri is studied in this paper. The results show that all of the light, middle and heavy rare earth elements have similar enhancement effect on the growth of Chaetoceros mulleri, with the beneficial concentrations of La, Gd and Yb being 7.28~87.40 μ mol/L, 6.36~57.23 μ mol/L and 5.78~17.34 μ mol/L. The optimum concentrations of La, Gd and Yb are 7.28 ~50.98 μ mol/L,31.80~44.52 μ m ol/L and 5.78~17.34 1μ mol/L, respectively. When the concentrations of La, Gd and Yb are 7.28~87.40 μ mol/L, 6.36~57.23 μ mol/L and 5.78~ 17,34 μ mol/L, the concentrations of chlorophyll have increased by 9.3~47.0%, 33.4~44.3%, and 36.5~40.3%, respectively as compared with the control group. The mechanism of enhancement of rare earth elements on the growth ot Chaetoceros mulleri is also discussed in this paper. 展开更多
关键词 rare earth element CHAETOCEROS mulleri ENHANCEMENT
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Correlations between Light Rare Earth Elements in Soil and Navel Orange Tree System in Gannan Area 被引量:1
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作者 Xiaoling WANG Xiaojuan TIAN Zhu GAO 《Asian Agricultural Research》 2018年第6期75-80,共6页
The total content of light rare earth elements( LREEs) in the soil of navel orange orchards of Gannan area is greater than that of heavy rare earth elements( HREEs). Appropriate content of LREE can not only promote th... The total content of light rare earth elements( LREEs) in the soil of navel orange orchards of Gannan area is greater than that of heavy rare earth elements( HREEs). Appropriate content of LREE can not only promote the growth of navel oranges,and it is also conducive to human health. On the basis of exploring the correlations between the content of LREE in the soil of navel orange orchards of Gannan area and the contents of LREE in navel orange leaves and fruit,the influence mechanism of LREEs on the quality of navel oranges was revealed. In this study,with two Newhall navel orange orchards with different soil LREEs background levels in Xinfeng County as the research object,the changes in the content of LREE( lanthanum,La; cerium,Ce; praseodymium,Pr; neodymium,Nd) in leaves and fruit of navel orange at different growth stages were analyzed using Inductively Coupled Plasma-Mass Spectrometry( ICP-MS),and the correlations between the content of LREE in the soil,navel orange leaves and navel orange fruit were studied. The results showed that the contents of the four kinds of LREEs in the soil ranked as Ce > La > Nd > Pr,and there were significant differences among them( P < 0. 01). Navel orange leaves and fruit have selective and heterogenic absorption for LREEs. At different growth stages,La showed the highest accumulation amount in the leaves and fruit of navel orange; and the content of LREE in the leaves of navel orange increased first and then decreased,while that in the fruit of navel orange showed continuous decrease. During the migration of LREEs from soil to leaves to fruit,the content of LREE decreased rapidly as the migration distance increased. The accumulation amount of LREE in navel orange was positively correlated with the content of LREE in the soil. The correlation between the content of LREE in the leaves and fruit of navel orange was greatest. Among the four kinds of LREEs,the correlation of La was greatest,followed by Ce,indicating that the accumulation amount of LREE in the navel orange body was affected by the element types. 展开更多
关键词 Light rare earth element Navel orange SOIL CORRELATION
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Distribution of Rare Earth Elements in Early Permian Reef-Island Ocean Sediments in Eastern Kunlun
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作者 WANG Yongbiao XU Guirong +1 位作者 LIN Qixiang GONG Shuyun 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2000年第1期68-73,共6页
Abstract: Based on the study of stratigraphy and fossils, the Early Permian ocean in eastern Kunlun is recognized as a kind of reef-island ocean, in which there exist many different kinds of sediment, including patch ... Abstract: Based on the study of stratigraphy and fossils, the Early Permian ocean in eastern Kunlun is recognized as a kind of reef-island ocean, in which there exist many different kinds of sediment, including patch carbonate platform, reef facies, transitional facies and deep basin sediments. It has been found that the total contents of REEs increase gradually from carbonate platform facies to deep basin facies. Meanwhile, sediments of different facies have different REE distribution patterns and different Ce anomalies. Most of the sediments of patch carbonate platform facies or reef facies are characterized by extremely negative Ce anomalies or moderately negative Ce anomalies (Ce/Ce*=0.33 to 0.55), and medium or thin-bedded limestones of transitional facies by moderately negative Ce anomalies (Ce/Ce*=0.49 to 0.60). However, sediments of deep basin facies show weak or no negative Ce anomalies (Ce/Ce*=0.69 to 1.47), among which the value of Ce/Ce* in the radiolarian chert is 1.47. 展开更多
关键词 rare earth elements reef-island ocean Early Permian eastern Kunlun
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Rare Earth Elements and Yttrium(REY) Geochemistry of Reefal Limestones in the Ordovician, Tarim Basin, NW China and their Paleoenvironment Implications
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作者 MENG Miaomiao LIU Xinxing +1 位作者 FAN Tailiang Ian JDUNCAN 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2019年第4期928-942,共15页
This study examines the rare earth elements and yttrium(REY)concentrations of twenty-five samples from the reef outcrop exposed along the Lianglitage Mountain in the Ordovician,Tarim Basin in China.The concentration a... This study examines the rare earth elements and yttrium(REY)concentrations of twenty-five samples from the reef outcrop exposed along the Lianglitage Mountain in the Ordovician,Tarim Basin in China.The concentration analysis provides constraints on the paleoenvironment during reef deposition.Based on the detailed sedimentology and petrographic work,we divide the reef facies into four sub-facies:the base facies,reef-core facies,reef-flank facies,and sealing facies.The geochemical data(such as major and trace elements,carbon and oxygen isotopes,and REYs)are further used to study the coeval seawater characteristics as well as potential diagenesis overprints.The result indicated that the diagenesis has little effect on the REY patterns of the reefal limestones.The REY concentrations of the reefal limestones are overall low(ranging from 3.69 to 19.60 ppm,arithmetic mean=10.22 ppm,SD=5.4).The PAAS-normalized REY patterns are consistently flat compared to the typical well-oxidized,shallow marine water patterns.However,the light REE(LREE)depletions,positive La anomalies,negative Ce anomalies and positive Y anomalies,suggest that these reefal limestones are likely an indicative of contemporaneous seawater REY signals.The seawater-like Y/Ho ratios(average at 37.51)further support that REY signals in these limestones are likely a reflection of seawater with little diagenetic modifications.The low Y/Ho ratios presented only in the reef-flank facies and sealing facies are likely a suggestion of detrital contamination.Hence,this study confirms that REY patterns of the limestones at the base facies and reef-core facies can record ancient seawater information,and reefs can be used as a potential geochemical proxy for paleoenvironment studies throughout the Earth’s history. 展开更多
关键词 rare earth elements and yttrium(REY) LIMESTONES depositional environment ORDOVICIAN Tarim Basin
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Investigation of Environmental and Biological Effects of Rare Earth Elements (REEs) with a Special Focus on Industrial and Mining Pollutions in Iran:A Review 被引量:1
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作者 Aref Shirazi Adel Shirazy +2 位作者 Amin Beiranvand Pour Ardeshir Hezarkhani Shayan Khakmardan 《Advances in Geological and Geotechnical Engineering Research》 2022年第1期1-10,共10页
The present article is a review study on the types of rare earth elements(REEs),environmental and biological effects as well as the sources of emission of these elements as pollution in nature.The purpose of this stud... The present article is a review study on the types of rare earth elements(REEs),environmental and biological effects as well as the sources of emission of these elements as pollution in nature.The purpose of this study is to provide a vision in environmental planning and control of pollution caused by REEs.The evaluation of rare earth elements was studied in human life and its environmental and biological effects,which have particular importance and are entering the life cycle through industrial and mining pollution sources.Since mining activities intensify the dispersion of these elements in the environment and the existence of industrial factories located around urban drainage system plays a unique role in creating and spreading pollution caused by rare earth elements;As a result,two case studies were conducted on two mining and industrial areas.The first case is the Choghart mine in Yazd province as an example of mining pollution,and the second case study is performed on the Kor river as an example of industrial pollution which is caused by industrial activities around it,Then the results are well explained to show both two environments of litho and hydro.Due to this fact that produced environmental pollution can cause exchange pollutant compounds with the surrounding environment besides its long-lasting destructive effects;It can cause irreversible biological effects on living organisms.By targeting this evaluation,several techniques can be proposed to prevent the entry and dispersal of rare earth elements from pollution sources besides methods to reduce the damage of these elements to the ecosystem. 展开更多
关键词 Environment rare earth elements POLLUTION Disease Kor river Choghart mine Life cycle
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Fractionation characteristics of rare earth elements(REEs) linked with secondary Fe, Mn, and Al minerals in soils 被引量:5
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作者 Chunying Chang Fangbai Li +3 位作者 Chengshuai Liu Jianfeng Gao Hui Tong Manjia Chen 《Acta Geochimica》 EI CAS CSCD 2016年第4期329-339,共11页
Soil secondary minerals are important scavengers of rare earth elements(REEs) in soils and thus affect geochemical behavior and occurrence of REEs. The fractionation of REEs is a common geochemical phenomenon in soils... Soil secondary minerals are important scavengers of rare earth elements(REEs) in soils and thus affect geochemical behavior and occurrence of REEs. The fractionation of REEs is a common geochemical phenomenon in soils but has received little attention, especially fractionation induced by secondary minerals. In this study, REEs(La to Lu and Y) associated with soil-abundant secondary minerals Fe-, Al-, and Mn-oxides in 196 soil samples were investigated to explore the fractionation and anomalies of REEs related to the minerals. The results show right-inclined chondrite-normalized REE patterns for La–Lu in soils subjected to total soil digestion and partial soil extraction. Light REEs(LREEs) enrichment features were negatively correlated with a Eu anomaly and positively correlated with a Ce anomaly. The fractionation between LREEs and heavy REEs(HREEs) was attributed to the high adsorption affinity of LREEs to secondary minerals and the preferred activation/leaching of HREEs.The substantial fractions of REEs in soils extracted byoxalate and Dithionite-Citrate-Bicarbonate buffer solutions were labile(10 %–30 %), which were similar to the mass fraction of Fe(10 %–20 %). Furthermore, Eu was found to be more mobile than the other REEs in the soils, whereas Ce was less mobile. These results add to our understanding of the distribution and geochemical behavior of REEs in soils, and also help to deduce the conditions of soil formation from REE fractionation. 展开更多
关键词 rare earth elements FRACTIONATION Secondary minerals Geochemical process - Europium anomaly Cerium anomaly
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Determination of 16 Rare Earth Elements in Banana by Microwave Digestion and ICP-MS 被引量:1
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作者 范稚莉 范稚莲 +5 位作者 闫飞燕 莫磊兴 王天顺 廖洁 牙禹 范业赓 《Agricultural Science & Technology》 CAS 2013年第11期1583-1586,共4页
[Objective] This study aimed to investigate the residues of rare earth ele-ments in Guangxi banana from banana-producing area with application of rare earth fertilizers and evaluate the safety of using rare earth fert... [Objective] This study aimed to investigate the residues of rare earth ele-ments in Guangxi banana from banana-producing area with application of rare earth fertilizers and evaluate the safety of using rare earth fertilizers in banana production. [Method] HNO3+H2O2 mixed acid system with high pressure airtight microwave di-gestion sample pretreatment method and ICP-MS technology were used, to establish a determination method of 16 rare earth elements in banana samples, including Sc45, Y89, La139, Ce140, Pr141, Sm147, Eu153, Gb157, Tb159, Nd144, Dy163, Ho165, Er166, Tm169, Yb172 and Lu175. [Result] Different standard curves present-ed good linearity. Detection limit of the instrument was 0.002-0.01 μg/L; detection limit of the method was 0.1-0.6 μg/kg; recovery rate of standard addition was 94.5%-116%; relative standard deviation was 2.02%-14.21%. [Conclusion] This method has many advantages, such as simple mass spectrogram, high sensitivity and high selectivity, accurate quantification, high precision and accuracy, simple operation, high reproducibility and high recovery rate, which is suitable for the detection of rare earth elements in banana and other fruits, with certain theoretical and applicable val-ue for guiding banana production and high-efficient planting. 展开更多
关键词 rare earth elements BANANA ICP-MS
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Some New Results from the Electron Theory on the Elastical of Alkahoe Earth Metals and Rare Earth Elements
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作者 崔秀山 邢胜娣 《Journal of Beijing Institute of Technology》 EI CAS 1994年第1期31+26-32,共8页
With the introduction of Poisson's ratio in the expression of Young's modulus,nearly all the theoretical values of the various elastic moduli for the alkaline earth metals and rare earth elements can be greatl... With the introduction of Poisson's ratio in the expression of Young's modulus,nearly all the theoretical values of the various elastic moduli for the alkaline earth metals and rare earth elements can be greatly refined, with the single exception of the theoreticalvalue of Young's modulus for Pr which is slightly increased This points to the validityof the new theory, that the bulk modulus is independent of the Poisson's ratio, and further that the valency electron structures of solids as determined by Yu's theory are correct. 展开更多
关键词 alkaline earth metals rare earth elements/electron theory of elasticity
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Influence of rare earth Ce on hot deformation behavior of as-cast Mn18Cr18N high nitrogen austenitic stainless steel 被引量:4
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作者 Yushuo Li Yanwu Dong +3 位作者 Zhouhua Jiang Qingfei Tang Shuyang Du Zhiwen Hou 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第2期324-334,共11页
The hot deformation behavior of Mn18Cr18N and Mn18Cr18N+Ce high nitrogen austenitic stainless steels at 1173-1473 K and 0.01-1 s^(-1) were investigated by thermal compression tests.The influence mechanism of Ce on the... The hot deformation behavior of Mn18Cr18N and Mn18Cr18N+Ce high nitrogen austenitic stainless steels at 1173-1473 K and 0.01-1 s^(-1) were investigated by thermal compression tests.The influence mechanism of Ce on the hot deformation behavior was analyzed by Ce-containing inclusions and segregation of Ce.The results show that after the addition of Ce,large,angular,hard,and brittle inclusions(TiN-Al_(2)O_(3),TiN,and Al_(2)O_(3)) can be modified to fine and dispersed Ce-containing inclusions(Ce-Al-O-S and TiN-Ce-Al-O-S).During the solidification,Ce-containing inclusions can be used as heterogeneous nucleation particles to refine as-cast grains.During the hot deformation,Ce-containing inclusions can pin dislocation movement and grain boundary migration,induce dynamic recrystallization(DRX)nucleation,and avoid the formation and propagation of micro cracks and gaps.In addition,during the solidification,Ce atoms enrich at the front of solid-li-quid interface,resulting in composition supercooling and refining the secondary dendrites.Similarly,during the hot deformation,Ce atoms tend to segregate at the boundaries of DRX grains,inhibiting the growth of grains.Under the synergistic effect of Ce-containing inclusions and Ce segregation,although the hot deformation resistance and hot deformation activation energy are improved,DRX is more likely to occur and the size of DRX grains is significantly refined,and the problem of hot deformation cracking can be alleviated.Finally,the microhardness of the samples was measured.The results show that compared with as-cast samples,the microhardness of hot-deformed samples increases signific-antly,and with the increase of DRX degree,the microhardness decreases continuously.In addition,Ce can affect the microhardness of Mn18Cr18N steel by affecting as-cast and hot deformation microstructures. 展开更多
关键词 rare earth hot deformation Mn18Cr18N steel non-metallic inclusions element segregation MICROHARDNESS
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Rare earth elemental and Sr isotopic evidence for seawater intrusion event of the Songliao Basin 91 million years ago 被引量:1
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作者 Yu-Ke Liu Hua-jian Wang +5 位作者 Jin-You Zhang Zhen-Wu Liu Fa-Zi Chen Xiao-Mei Wang Shui-Chang Zhang He Liu 《Petroleum Science》 SCIE EI CAS CSCD 2023年第3期1347-1362,共16页
Petrogenesis of lacustrine dolostone is closely related with paleo-lake water conditions.Here we report the high spatial-resolution petrographic and geochemical results of a lacustrine dolomite nodule from the Qingsha... Petrogenesis of lacustrine dolostone is closely related with paleo-lake water conditions.Here we report the high spatial-resolution petrographic and geochemical results of a lacustrine dolomite nodule from the Qingshankou Formation,the Songliao Basin.Sedimentary and elemental signatures confirm the protogenetic origin of this nodule and its effectiveness in recording geochemical characteristics of paleo-lake water during dolomitization.The low Y/Ho ratios,middle rare earth element(MREE)enrichment and subtle positive Eu anomalies within the nodule indicate a fresh water source.However,the Sr isotope values in the core of the nodule(0.7076-0.7080)are close to contemporaneous seawater(0.7074),yet different from the modern river(0.7120)and the host black shale(0.7100).On the premise of excluding the influence of hydrothermal fluids,the significantly low strontium isotope values of the lacustrine dolomite might be caused by seawater interference during dolomitization.Our findings demonstrate that lacustrine dolomite within black shales is not only a faithful tracer of diagenetic water environment,but also a novel and easily identified mineralogical evidence for episodic seawater intrusion event(91 Ma)in the Songliao Basin,which supplements other paleontological and geochemical evidence. 展开更多
关键词 Songliao Basin Lacustrine dolostone Seawater intrusion rare earth elements Strontium isotope
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基于REE示踪法的工程堆积体坡面泥沙来源研究 被引量:1
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作者 魏育超 陈姿宇 +5 位作者 王子吟 魏宇航 张一博 王达未 谢永生 骆汉 《水土保持研究》 CSCD 北大核心 2024年第5期9-17,共9页
[目的]探究生产建设项目工程堆积体坡面侵蚀的泥沙来源,更有针对性地布设水土流失防治措施,减少人为扰动造成的水土流失。[方法]结合室内人工模拟降雨试验与REE(Rare Earth Elements)示踪技术,研究90 mm/h雨强下不同砾石含量[0(纯土),10... [目的]探究生产建设项目工程堆积体坡面侵蚀的泥沙来源,更有针对性地布设水土流失防治措施,减少人为扰动造成的水土流失。[方法]结合室内人工模拟降雨试验与REE(Rare Earth Elements)示踪技术,研究90 mm/h雨强下不同砾石含量[0(纯土),10%,20%,30%]工程堆积体坡面不同坡位的侵蚀特征及侵蚀贡献率。[结果](1)不同砾石含量堆积体各坡位侵蚀量均为下坡位最大,同时下坡位平均侵蚀贡献率(57.40%)大于上坡位和中坡位,表明下坡位是坡面泥沙的主要来源。(2)含砾石堆积体坡面中坡位和下坡位的侵蚀量显著小于纯土堆积体。含砾石堆积体坡面上坡位和中坡位的侵蚀贡献率显著+大于纯土堆积体坡面,下坡位侵蚀贡献率显著小于纯土堆积体坡面。(3)砾石含量对下坡位侵蚀量和贡献率的影响更显著(p<0.05)。含砾石堆积体中,20%砾石含量堆积体坡面上坡位和下坡位的侵蚀量显著大于10%,30%砾石含量堆积体。10%砾石含量堆积体坡面上坡位侵蚀贡献率显著大于20%,30%砾石含量堆积体坡面,下坡位侵蚀贡献率显著小于20%,30%砾石含量堆积体坡面。[结论]各砾石含量工程堆积体坡面中,下坡位侵蚀贡献率均最大,表明下坡位是工程堆积体坡面泥沙的主要来源,要加强工程堆积体下坡位的防护和治理。 展开更多
关键词 土壤侵蚀 ree 砾石含量 贡献率 坡位
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