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THE CRYSTAL STRUCTURE OF RARE EARTH COMPLEX WITH AMINO ACIDS Ⅱ The Crystal Structure of Gtutamate Comptex of Erbium Perchtorate
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作者 Zeng Lin WANG~(※※), Ning Hai HU, Chun Li NIU, Kui Yue YANG, Jia Zan NI (Changchun Institute of Applied Chemistry, Chinese Acadimia Sinica, Changchun, 130022) 《Chinese Chemical Letters》 SCIE CAS CSCD 1991年第12期961-962,共2页
The crystat structure of {[Er;(L—Glu);(H;O);](ClO;);·3H;O);has been studied by X-ray diffraction. The crystal is monoctinic with space group P2;and cell parameters a=19.987(3) , b=16.505(3) , c=11.040... The crystat structure of {[Er;(L—Glu);(H;O);](ClO;);·3H;O);has been studied by X-ray diffraction. The crystal is monoctinic with space group P2;and cell parameters a=19.987(3) , b=16.505(3) , c=11.040(2) , β=104.69(1);, V=3538(1) , Z=2, Dc=2.29 g. cm;, μ=53.2 cm;, F(000)=2384. The asymmetric unit contains two complex motecules and four centre ions. Each erbium (Ⅲ) is coordinated by five oxygen donors from four different glutamates and four oxygen donors from the aqua ligand to form a nine coordination potyhedron. The mean distances of Er—0 (carboxylate) and Er—Ow are 2.439 and 2.41 respectivety. The finat R and Rw are 0.043 and 0. 058, respectivety. 展开更多
关键词 CI The Crystal Structure of Gtutamate Comptex of Erbium Perchtorate THE CRYSTAL STRUCTURE OF rare earth complex WITH amino acidS
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Syntheses aod Crystal Structures of Rare Earth Complexes with Adamantanecarboxylic Acid, [LnL_3(HL)(H_2O)]_2·2EtOH·2H_2O (Ln=Nd (1), La (2))
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作者 Zhu Zhili Feng Yunlong Lin Hong 《Journal of Rare Earths》 SCIE EI CAS CSCD 2005年第5期647-647,共1页
The title complexes (LnL3 (HL) (H2O) ]2· 2EtOH·2H2O (Ln= Nd (1), La (2), HL=adamantanecarboxylic acid) were prepared and determined by single-crystal X-ray diffraction. Both complexes crystallize ... The title complexes (LnL3 (HL) (H2O) ]2· 2EtOH·2H2O (Ln= Nd (1), La (2), HL=adamantanecarboxylic acid) were prepared and determined by single-crystal X-ray diffraction. Both complexes crystallize in triclinic system with space group P 1^-, cell parameters are: complex (1) a = 1.0556(2) nm, b =1.4913(3) nm, c = 1.4920(3) nm, a = 106.26 (3)°, β=93.51(3)°, γ=97.23(3)°, V=2.2253 (5) nm^3, Dcal=1.409 g · cm^-3, Z = I , F ( 000 ) = 990, μ(Mo Kα) = 1. 225 mm^-1, M, = 1884.50; complex (2) a = 1.0453(2) nm, b = 1.4971(3)nm, c = 1.5052(3) nm, α = 106.07(3)°, β =93.58 (3)°, γ=97.56(3)°, V=2.2391(5)nm^3, Dcal= 1.397 g·cm^-3, Z = 1, F(000) =984, μ(Mo Kα) = 1.015 mm^-1, Mr= 1877.88. The final R and wR are 0. 0396 and 0. 1062 for 8589 (1 ≥ 2σ (I)) observed reflections for complex (1), 0.0505 and 0. 1344 for 8417 ( 1 ≥ 2σ (1) ) observed reflections for complex (2), respectively. The crystals are consisted of a binuelear molecule. The coordination geometry of the Ln( Ⅲ ) ion can be described as trieapped trigonal prism. 展开更多
关键词 Nd( Ⅲ) complex Nd( complex adamantanecarboxylic acid crystal structure rare earths
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Synthesis and Characterization of Rare Earth Solid Complexes with Sodium 5-Aminosalicylate
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作者 张秀英 李书静 +1 位作者 雷雪峰 马君现 《Journal of Rare Earths》 SCIE EI CAS CSCD 2005年第2期143-147,共5页
Ten new rare earth solid complexes were synthesized by the reaction of sodium 5-aminosalicyliate with rare earth chloride. The structure character, physical and chemical properties of these complexes were studied by I... Ten new rare earth solid complexes were synthesized by the reaction of sodium 5-aminosalicyliate with rare earth chloride. The structure character, physical and chemical properties of these complexes were studied by IR, UV, ()~1H NMR spectra, TG-DTA, fluorescence, elemental analyses, molar conductance and magnetic susceptibility. The ten rare earth complexes exist in dimeric form probably and the coordination number is seven. The antibacterial activity of the ligand and six complexes was also tested against Staphylococcus aureus, Escherichia coli and Bacillus subtilis, and the effect of Yb complex at 20 mg·ml^(-1) against Staphylococcus aureus is most significant. 展开更多
关键词 rare earth complexes 5-amino salicylic acid antibacterial activity
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Study of Complexes of Lanthanum with Amino Acids by Titration Calorimeter 被引量:2
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作者 Ye Gang, Wang Cun-xin, Qu Song-sheng College of Chemistry and Environment Science, Wuhan University, Wuhan 430072, China 《Wuhan University Journal of Natural Sciences》 EI CAS 2000年第4期479-484,共6页
The stability constants and thermodynamic functions for complexes of lanthanum with eight kind of amino acids according to 1∶1 and 1∶2 in proportion have been determined by titration calorimeter at 298.15 K. The ent... The stability constants and thermodynamic functions for complexes of lanthanum with eight kind of amino acids according to 1∶1 and 1∶2 in proportion have been determined by titration calorimeter at 298.15 K. The enthalpy change makes a predominant contribution to the stability of these complexes. The ring in amino acid associated with lanthanum ion helps to enhance the stability of complexes. Steric effects between rings in complexes leads to that the equilibrium constants of reaction of the complexes (1∶2) is much less than that of the complexes (1∶1). 展开更多
关键词 titration calorimeter rare earth amino acid complexES steric effects
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Synthesis and Characterization of Lanthanum Complexes with Amino Acid Schiff Base
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作者 张秀英 张有娟 杨林 《Journal of Rare Earths》 SCIE EI CAS CSCD 2001年第3期177-180,共4页
Six new complexes of lanthanum with amino acid Schiff base ligands, A-F, were prepared in methanol-aqueous solution. The composition and properties of the title complexes were characterized by elemental analysis, mola... Six new complexes of lanthanum with amino acid Schiff base ligands, A-F, were prepared in methanol-aqueous solution. The composition and properties of the title complexes were characterized by elemental analysis, molar conductance, infrared, electronic spectra, H-1 NMR, thermogravimetric and differential thermal analysis. 展开更多
关键词 rare earths LANTHANUM amino acid Schiff base complex SYNTHESIS
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Investigation on the Coordinate Structures of the Rare Earth Metal Complexes with Edta and Cydta Ligands
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作者 Wang Jun, Zhang Xiang-dong, Zhang Yang, Liu Zhen-rong Department of Chemistry, Liaoning University, Shenyang 110036, Liaoning, China 《Wuhan University Journal of Natural Sciences》 CAS 2003年第04A期1131-1137,共7页
The crystal and molecular structures of cydta (trans-1, 2-cyclohexanediaminetetraacetic acid) have been determined by single\|crystal X-ray structure analyses. The reasons that RE Ⅲ -edta and RE Ⅲ -cydta compl... The crystal and molecular structures of cydta (trans-1, 2-cyclohexanediaminetetraacetic acid) have been determined by single\|crystal X-ray structure analyses. The reasons that RE Ⅲ -edta and RE Ⅲ -cydta complexes select different coordinate structures were discussed and illustrated through the comparison of the molecular and crystal structures between edta and cydta, (NH_ 4 )\[Y Ⅲ (edta)(H_ 2 O)_ 3 \]\55H_ 2 O and (NH_ 4 )\[Y Ⅲ (cydta)(H_ 2 O)_ 2 \]\55H_ 2 O as well as (NH_ 4 )\[Gd Ⅲ (edta)(H_ 2 O)_ 3 \]\55H_ 2 O and (NH_ 4 )\[Gd Ⅲ (cydta) (H_ 2 O) _ 2 \]\55H_ 2 O complexes. 展开更多
关键词 rare earth edta (ethylenediaminetetraacetic acid) cydta (trans-1 2-cyclohexanediaminetetraacetic acid) complexES coordinate structures
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Synthesis, Structure and Luminescent Properties of Three 1D Chain Rare Earth Complexes
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作者 CHEN Yan-Mei LI Lian +2 位作者 QIU Lei LI Qing ZHANG Wan-Ju 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2019年第6期977-984,共8页
Three 1 D chain coordination polymers [Ln(pydc)2(H2 O)2]n·n Him(Ln = Dy(1), Gd(2), Sm(3), H2 pydc = pyridine-2,5-dicarboxylic acid, Im = imidazole), were solvothermally synthesized by the reaction of pyridine-2,5... Three 1 D chain coordination polymers [Ln(pydc)2(H2 O)2]n·n Him(Ln = Dy(1), Gd(2), Sm(3), H2 pydc = pyridine-2,5-dicarboxylic acid, Im = imidazole), were solvothermally synthesized by the reaction of pyridine-2,5-dicarboxylic acid(H2 pydc), Ln(Ⅲ) salts and imidazole. They have been characterized by X-ray single-crystal diffraction, IR spectra, TGA analysis and elemental analysis. Structural analyses revealed that complexes 1~3 have similar 1 D chain structures and belong to P1 space group. It is noteworthy that complexes 1~3 exhibited excellent thermal stability and no weightlessness below 117 ℃. Meanwhile, 1 and 3 show characteristic fluorescence of corresponding lanthanide metal ions in solid state at room temperature. 展开更多
关键词 rare earth complexES LUMINESCENT property pyridine-2 5-dicarboxyllic acid crystal STRUCTURE
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Crystal Structure and Luminescence Property of Lanthanide Complexes with 2-Fluorobenzoic Acid and 2,2′-Bipyridine 被引量:4
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作者 李夏 张卓勇 宋海斌 《Journal of Rare Earths》 SCIE EI CAS CSCD 2005年第5期615-618,共4页
The two compounds of [Ln(2-FBA)3·2,2'-bpy ]2(2-FBA = 2-fluorobenzoato, 2,2'-bpy = 2,2'-bipyridine, Ln = Eu(1 ), Dy(2)) were synthesized and their structures were determined by X-ray diffraction method.... The two compounds of [Ln(2-FBA)3·2,2'-bpy ]2(2-FBA = 2-fluorobenzoato, 2,2'-bpy = 2,2'-bipyridine, Ln = Eu(1 ), Dy(2)) were synthesized and their structures were determined by X-ray diffraction method. Crystallized complexes 1 and 2 are isomorphous, monoelinie system with P21/n space group. The two complexes are binuclear molecule with an inversion center. The two lanthanide ions are linked by four bridged 2-FBA ligands and each lanthanide ion is further bonded to one chelated bidentate 2-FBA ligand and one 2,2'-bipyridine molecule. The coordination number of metal ion is eight. The europium complex exhibits strong red fluorescence. ^5D0→^7Fj(j = 1 - 4) transition emission of Eu^3+ ion was observed. 展开更多
关键词 lanthanide complexes 2-fluorobenzoic acid crystal structure rare earths
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Synthesis and Crystul Structure of Lutetium Complex with Triethylenetetraaminehexaacetic Acid (H_6ttha):{[Lu_2 (ttha) (H_2O)_6Lu_2 (ttha) (H_2O)_4]·21H_2O}_n 被引量:2
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作者 马宝清 高松 +3 位作者 金天柱 王哲明 严纯华 徐光宪 《Journal of Rare Earths》 SCIE EI CAS CSCD 1999年第4期250-254,共5页
The title complex was synthesized in an aqueous solution and its crystal structure was determined by X-raydiffraction method. It crystalizes in triclinic crystal system, space group P1, formula C36H110N8O55Lu4, Mr=223... The title complex was synthesized in an aqueous solution and its crystal structure was determined by X-raydiffraction method. It crystalizes in triclinic crystal system, space group P1, formula C36H110N8O55Lu4, Mr=2235.2,a=1.09787(7) nm, b=1.27603(10) nm, c=1.45903(10) nm; α=75.769(6)°, β=85.288(5)°, γ=71.577(6)°, V=1.8797(2) nm3,Z=1, Dc= 1.975 g·cm-3, F(000)=1106, μ=5.312 mm-1; R1=0.0239, wR2=0.0527 for 7156 reflections with I>2σ (I). In the complex, the lutetium ion is coordinated by two nitrogen atoms andsix oxygen atoms and the coordination number is 8. Its coordination polyhedron can be described as a distorted squareantiprism. The complex is of an infinite chain structure. The complex was characterized by elemental analysis, IR spectra and thermal analysis. 展开更多
关键词 rare earths Lutetium complex Crystal structure Triethylenetetraaminehexaacetic acid
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Hydrothermal synthesis, crystal structure and luminescence of a europium complex with phenylmalonic acid and 1, 10-phenanthroline
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作者 王春燕 鞠艳玲 +2 位作者 李艳秋 张艳斌 李夏 《Journal of Rare Earths》 SCIE EI CAS CSCD 2008年第1期22-25,共4页
A new complex Eu2(PA)6(phen)2 was prepared with hydrothermal reaction using EuCl3.6H2O, phenylmalonic acid (H2phma), and 1, 10-phenanthroline (phen), where PA was the decarboxylated product of HEphma, phenylac... A new complex Eu2(PA)6(phen)2 was prepared with hydrothermal reaction using EuCl3.6H2O, phenylmalonic acid (H2phma), and 1, 10-phenanthroline (phen), where PA was the decarboxylated product of HEphma, phenylacetate. The crystal structure of the title complex was determined with the X-ray diffraction. The title complex was a binuclear molecule with an inversion center. Each Eu^3+ ion was nine-coordinated with two nitrogen atoms from one phen molecule and seven oxygen atoms from five PA ligands. The carboxylic groups were bonded to the Eu^3+ ion in three modes, the chelating bidentate, the bridging bidentate, and the bridging-chelating tridentate. The complex emits intense red fluorescence under ultraviolet light. The luminescence peaks correspond to the characteristic emission 5D0→7FJ (J=0-4) transitions of the Eu^3+ ion. 展开更多
关键词 europium complex phenylmalonic acid crystal structure LUMINESCENCE rare earths
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Structure and Bonding in Some Gd(Ⅲ) Metal Complexes Studied by Three-Dimensional X-Ray Analysis and ^(155)Gd Mssbauer Spectroscopy
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作者 王军虎 Takahashi Masashi +1 位作者 Kitazawa Takafumi Takeda Masuo 《Journal of Rare Earths》 SCIE EI CAS CSCD 2007年第6期647-653,共7页
Some functional lanthanide metal complexes, such as acetylacetonato complexes, ethylenediaminetetraacetato complexes, were successfully applied for diagnostic technique. The authors are interested in investigating the... Some functional lanthanide metal complexes, such as acetylacetonato complexes, ethylenediaminetetraacetato complexes, were successfully applied for diagnostic technique. The authors are interested in investigating the structure and bonding in lanthanide and actinide metal complexes using 166Er, t55Gd, and 237Np Mtissbauer spectroscopies in connection with single-crystal and/or powder X-ray diffraction, making clear the differences on their structures as well as the differences in the participation of 4f and 5f orbitals in the chemical bonds. In this article, the crystal structures of two novel Gd(Ⅲ) acetylacetonato complexes, Gd(pta)3 · 2H2O (pta = 1,1,1 -trifluoro-5,5-dimethy 1-2,4-hexanedione) and Gd(bfa)3 · 2H2O (bfa = 1, 1, 1 -trifluoro-4-phenyl-2-4-butanedione) were reported. Though both of them were dihydrate and had distorted square antiprismatical structure, Gd(pta)3 · 2H2O crystallizes in the P 2 1/n (#14) monoclinic space group and its lattice parameters are a = 1.4141(6) nm, b = 1.0708(3) nm, c =2.2344(4) nm, β =952.4(2)°, and Gd(bfa)3· 2H2O crystallizes in P 212121 orthorhombic space group and its lattice parameters were a = 1.322 (1) nm, b = 2.295 (1) nm, c = 1. 0786(8) nm. In the meantime, the authors had finished a systematic investigation on the ^155Gd Mossbauer isomer shift (δ) of various Gd(Ⅲ) metal complexes having a different coordination number (C.N.) and different ratios coordinating oxygen to nitrogen. A tendency for the 6 value to decrease with an increase in the C.N, and the number of the nitrogen atom coordinating to Gd was confirmed. This indicated that the Gd-O and/or Gd-N bond in the investigated Gd(Ⅲ) metal complexes had a small covalent contribution, which was possible to be deduced from the O and/or N atoms of the lisands donating electrons to 6s, 5d, and 4f orbitals of Gd. 展开更多
关键词 Gd(Ⅲ) metal complex crystal structure bonding ^155Gd Mossbauer spectroscopy three-dimensional X-ray analysis covalent contribution rare earths
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Crystal Structure of Praseodymium Complex with L-proline,Pr_2(L-Pro)_6(H_2O)_4·6ClO_4
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作者 Wang Zeng-Lin Hu Ning-Hai +1 位作者 Niu Chun-Ji Ni Jia-Zuan(Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022) 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 1994年第1期5-8,共4页
Pr2(L-Pro)6(H2O)4]·6ClO4(Pro= proline), Mr=1641.4, monoclinic, P21,α=9. 879(3),b=21. 883(4),c=13. 393(2) A, β=91. 23(2) A, V=2895(1) A3, Z=2,Dc=1. 88g/cm3,μ( MoKα)=20. 5cm ̄(-1) . F(000)=1648, R =0. 035 for 5... Pr2(L-Pro)6(H2O)4]·6ClO4(Pro= proline), Mr=1641.4, monoclinic, P21,α=9. 879(3),b=21. 883(4),c=13. 393(2) A, β=91. 23(2) A, V=2895(1) A3, Z=2,Dc=1. 88g/cm3,μ( MoKα)=20. 5cm ̄(-1) . F(000)=1648, R =0. 035 for 5032 observed reflections. The coordination polyhedron of Pr( Ⅲ) ion comprises six oxygen atoms from the L-Pro molecules and two from the water molecules, Each L-Pro molecule coordinates to two Pr(Ⅲ) ions through the carboxyl oxygens in a bidentate bridging mode, thus creating one-dimensional chain structure. 展开更多
关键词 crystal structure praseodymium complex rare earth amino acid complex
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Syntheses, characterization, and luminescence of two lanthanide complexes [Ln_2(acetate)_6(H_2O)_4]·4H_2O (Ln=Tb(1), Sm(2)) 被引量:1
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作者 于琼燕 周秀霞 +4 位作者 刘茂胜 陈键侨 周正元 殷霞 蔡跃鹏 《Journal of Rare Earths》 SCIE EI CAS CSCD 2008年第2期178-184,共7页
Two dinuclear compounds [Ln2(acetate)6(H2O)4]-4H2O (Ln=Tb(1), Sm(2)) were obtained by the hydrothermal reaction of Ln2O3 with malonic acid at 150 ℃. Both compounds were characterized by elemental analyses, ... Two dinuclear compounds [Ln2(acetate)6(H2O)4]-4H2O (Ln=Tb(1), Sm(2)) were obtained by the hydrothermal reaction of Ln2O3 with malonic acid at 150 ℃. Both compounds were characterized by elemental analyses, infrared spectra, and single crystal X-ray diffraction. The results showed that complexes 1 and 2 were isomorphous and crystallize in triclinic space group P 1. The coordination geometry around Ln(Ⅲ) ions in the complexes 1 and 2 was a distorted tricapped trigonal prism with a nine coordination. In the crystal, the molecular organization was further stabilized by well-defined weak hydrogen bonding interactions between the neutral dinuclear molecular units that led to the formation of a three-dimensional network. The fluorescence properties of the two complexes 1 and 2 in organic solvents were also studied. The results show that the ligand acetate favored energy transfer to the emitting energy level of Tb(Ⅲ) in complex 1. Some factors that influence the fluorescent intensity were also discussed in the article. 展开更多
关键词 rare earth dinuclear complexes X-ray crystal structure malonic acid fluorescence rare earths
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Crystal Structure of Praseodymium Complex with L-proline,Pr2(L-Pro)6(H2O)4·6ClO4
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《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 1994年第1期5-8,共页
Pr2(L-Pro)6(H2O)4]·6ClO4(Pro= proline), Mr=1641.4, monoclinic, P21,α=9. 879(3),b=21. 883(4),c=13. 393(2) A, β=91. 23(2) A, V=2895(1) A3, Z=2,Dc=1. 88g/cm3,μ( MoKα)=20. 5cm ̄(-1) . F(000)=1648, R =0. 035 for 5... Pr2(L-Pro)6(H2O)4]·6ClO4(Pro= proline), Mr=1641.4, monoclinic, P21,α=9. 879(3),b=21. 883(4),c=13. 393(2) A, β=91. 23(2) A, V=2895(1) A3, Z=2,Dc=1. 88g/cm3,μ( MoKα)=20. 5cm ̄(-1) . F(000)=1648, R =0. 035 for 5032 observed reflections. The coordination polyhedron of Pr( Ⅲ) ion comprises six oxygen atoms from the L-Pro molecules and two from the water molecules, Each L-Pro molecule coordinates to two Pr(Ⅲ) ions through the carboxyl oxygens in a bidentate bridging mode, thus creating one-dimensional chain structure. 展开更多
关键词 crystal structure praseodymium complex rare earth amino acid complex
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Synthesis,crystal structure and fluorescence of a new europium complex with 2-bromobenzoate and 2,2'-bipyridine 被引量:3
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作者 邱晓 张艳斌 李夏 《Journal of Rare Earths》 SCIE EI CAS CSCD 2009年第5期797-800,共4页
A new complex of {[Eu2(2-BrBA)6(2,2’-bpy)2]2·CH3CH2OH·H2O} (2-BrBA=2-bromobenzoate; 2,2’-bpy=2,2’-bipyridine) was prepared by solvent method and characterized with X-ray single-crystal diffraction, IR spe... A new complex of {[Eu2(2-BrBA)6(2,2’-bpy)2]2·CH3CH2OH·H2O} (2-BrBA=2-bromobenzoate; 2,2’-bpy=2,2’-bipyridine) was prepared by solvent method and characterized with X-ray single-crystal diffraction, IR spectroscopy, UV spectroscopy, and fluorescence spectroscopy. The complex crystallized in triclinic crystal system, Pī space group, with a=1.17196(4) nm, b=2.36142(9) nm, c=2.59151(9) nm, α=113.266(2)°, β=101.100(2)°, and γ=94.400(2)°. Two independent dinuclear molecules were contained in the asymmetric unit. The two molecules were similar to each other. Each Eu(Ⅲ) ion was nine-coordinated with seven oxygen atoms from five 2-BrBA ligands and two nitrogen atoms from 2,2’-bpy molecule. The carboxylate groups acted as bidentate-chelating, bidentate-bridging and chelating-bridging coordination modes. The complex adopted a distorted monocapped square-antiprism coordination geometry. Five peaks at 579, 591, 613, 652, and 697 nm appeared in the fluorescence spectrum, corresponding to 5D0→7F0, 5D0→7F1, 5D0→7F2, 5D0→7F3, and 5D0→7F4 transition emissions of the Eu(Ⅲ) ion, respectively. 展开更多
关键词 europium complex 2-bromobenzoic acid crystal structure FLUORESCENCE rare earths
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Synthesis,crystal structure and characterization of one-dimension complex constructed by terbium(Ⅲ) and 2-iodobenzoate 被引量:1
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作者 许丽娟 李艳秋 李夏 《Journal of Rare Earths》 SCIE EI CAS CSCD 2009年第3期373-376,共4页
The complex of [Tb(2-IBA)3(H2O)2]n (2-IBA=2-iodobenzoate) was prepared by solvent method from TbCl3-6H2O and 2-iodobenzoic acid. The crystal structure was determined with X-ray single-crystal diffraction. The X-... The complex of [Tb(2-IBA)3(H2O)2]n (2-IBA=2-iodobenzoate) was prepared by solvent method from TbCl3-6H2O and 2-iodobenzoic acid. The crystal structure was determined with X-ray single-crystal diffraction. The X-ray diffraction analysis indicated that the title complex crystallized in triclinic crystal system and Pi space group. The Tb^3+ ion was coordinated by six oxygen atoms from five 2-IBA ligands and two oxygen atoms from two water molecules, giving a distorted square-antiprism polyhedral geometry. The carboxyl groups were bonded to the Tb^3+ ions with bidentate-bridging and bidentate-chelating coordination modes. The adjacent Tb^3+ ions were linked by two bidentate-bridging 2-IBA ligands, forming 1-D chain structure. The fluorescence spectrum of the complex showed four main peaks at 489, 543, 587, and 618 nm, corresponding to ^5D4→^7Fj(J=6-3) transition emissions of the Tb^3+ ion, respectively. 展开更多
关键词 terbium complex 2-iodobenzoic acid crystal structure fluorescence rare earths
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Synthesis, crystal structure, and fluorescence of two dimeric europium(III) complexes with 2-(trifluoromethyl)benzoate 被引量:1
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作者 李艳秋 李培洲 李夏 《Journal of Rare Earths》 SCIE EI CAS CSCD 2008年第6期804-808,共5页
Two complexes [Eu2(2-TFMBA)6(2,2′-bipy)2]·2H2O (1) and Eu2(2-TFMBA)6(1,10-phen)2 (2) (2-TFMBA=2-(Trifluoromethyl) benzoate; 2,2′-bipy=2,2′-bipyridine; 1,10-phen= 1,10-phenanthroline) were synth... Two complexes [Eu2(2-TFMBA)6(2,2′-bipy)2]·2H2O (1) and Eu2(2-TFMBA)6(1,10-phen)2 (2) (2-TFMBA=2-(Trifluoromethyl) benzoate; 2,2′-bipy=2,2′-bipyridine; 1,10-phen= 1,10-phenanthroline) were synthesized by solvent method and determined by X-ray diffraction analysis. Complex 1 crystallizes in monoclinic system with space group P21/c, whereas complex 2 crystallizes in triclinic system with space group Pi. Both are binuclear molecules with an inversion center. In complex 1, two center Eu^3+ ions are linked together by four 2-TFMBA ligands in bidentate-bridging mode. Each Eu^3+ ion is eight-coordinated with six O atoms from five 2-TFMBA ligands and two N atoms from one 2,2′-bipy molecule. In complex 2, two center Eu^3+ ions are linked together by four 2-TFMBA ligands in two modes, namely, bidentate-bridging and tridentate-bridging. Each Eu^3+ ion is nine-coordinated with seven O atoms from five 2-TFMBA ligands and two N atoms from one 1,10-phen molecule. The two complexes both exhibited strong red fluorescence under ultraviolet light, and the ^5D0→^7Fj (j=0-4) transition emissions of Eu^3+ ion were observed in their emission spectra. 展开更多
关键词 europium complex 2-(Trifluoromethyl) benzoic acid crystal structure FLUORESCENCE rare earths
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Synthesis,crystal structure and fluorescence property of 1-D europium complex with 2,3-difluorobenzoate
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作者 宋金浩 吴小说 李夏 《Journal of Rare Earths》 SCIE EI CAS CSCD 2009年第6期1092-1095,共4页
A new chain europium complex [Eu(2,3-DFBA)3·(H2O)2]n(2,3-DFBA=2,3-difluorobenzoate) was synthesized by solvent method.X-ray single-crystal diffraction analysis revealed that Eu3+ ions were linked through 2,3-DFBA... A new chain europium complex [Eu(2,3-DFBA)3·(H2O)2]n(2,3-DFBA=2,3-difluorobenzoate) was synthesized by solvent method.X-ray single-crystal diffraction analysis revealed that Eu3+ ions were linked through 2,3-DFBA groups via alternate bidentate-bridging and tridentate chelating-bridging coordination modes to form a one-dimensional(1-D) polymeric chain.Each Eu3+ ion is eight-coordinated by six O atoms of five 2,3-DFBA ligands and two water molecules.The abundant hydrogen bonds between chains resulted in a two... 展开更多
关键词 europium complex 2 3-difluorobenzoic acid crystal structure fluorescence rare earths
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Nitrilotriacetate Bridged 3d-4f Heteronuclear Complex: Synthesis and Crystal Structure of {[GdCu(NTA)(H_2O)_6Cl]ClO_4·H_2O}_n
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作者 刘沁德 李俊然 +3 位作者 马宝清 高松 周晴中 郁开北 《Journal of Rare Earths》 SCIE EI CAS CSCD 2000年第3期161-164,共4页
The heteronuclear gadolinium copper complex was synthesized. Its crystal structure was determined by single crystal diffraction. The crystal crystallizes in triclinic, space group P 1, a=0 8483(1) nm, b =0 ... The heteronuclear gadolinium copper complex was synthesized. Its crystal structure was determined by single crystal diffraction. The crystal crystallizes in triclinic, space group P 1, a=0 8483(1) nm, b =0 9642(2) nm, c =1 2838(2) nm, α =111 17(1)°, β = 93 52(1)°, γ =100 89(1)°, Z =2, D c=2 335 g·cm -3 . The complex appears as a zigzag 1D chain. Each gadolinium ion is coordinated by three carboxylic oxygen atoms and six oxygen atoms from H 2O. Each copper ion is chelated by NTA with its nitrogen atom and three oxygen atoms of three carboxyl groups, and coordinated by a chlorine ion. The ClO 4 - is located between the chains as a counter ion. 展开更多
关键词 rare earths GADOLINIUM nitrilotriacetic acid crystal structure heteronuclear complex
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Synthesis and luminescent properties of terbium complex with 2-amino-4-chlorobenzoic acid 被引量:3
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作者 陈永杰 邢贞方 +1 位作者 曹爽 王莹 《Journal of Rare Earths》 SCIE EI CAS CSCD 2016年第3期240-244,共5页
A novel complex [Tb(L)_2(H_2O)_3·H_2O](where L=2-amino-4-chlorobenzoic acid) was synthesized and characterized by a series of analysis. The molecular formula of complex was confirmed by Fourier transform in... A novel complex [Tb(L)_2(H_2O)_3·H_2O](where L=2-amino-4-chlorobenzoic acid) was synthesized and characterized by a series of analysis. The molecular formula of complex was confirmed by Fourier transform infrared(FT-IR) spectroscopy and thermogravimetric/differential thermogravimetric(TG-DTG) measurements. The optical properties of complex was measured by ultraviolet spectroscopy(UV) and fluorescence spectroscopy(FS). The results indicated that Tb^(3+) in the complex was coordinated by ligand, and the complex emitted bright yellow-green luminescence with main peak at 548.8 nm with excitation at 369.4 nm. 展开更多
关键词 rare earth complex 2-amino-4-chlorobenzoic acid solvothermal synthesis luminescent properties rare earths
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