Bulk geochemistry,Sr,Nd,and O-H isotope systematics are reported for the first time on banded iron formation(BIF)-hosted high-grade iron ore at the northwestern segment of Congo Craton(CC).Located in Mbalam iron ore d...Bulk geochemistry,Sr,Nd,and O-H isotope systematics are reported for the first time on banded iron formation(BIF)-hosted high-grade iron ore at the northwestern segment of Congo Craton(CC).Located in Mbalam iron ore district,Southern Cameroon,Metzimevin iron ore deposit is a hematite-magnetite BIF system,dominated by SiO_(2)+Fe_(2)O_(3)(97.1 to 99.84 wt%),with low concentrations of clastic elements e.g.,Al_(2)O_(3),TiO_(2),and HFSE,depicting a nearly pure chemical precipitate.The REE+Y signature of the iron deposit displays strong positive Eu anomaly,strong negative Ce anomaly,and chondritic to superchondritic Y/Ho ratios,suggestive of formation by mixed seawater-high temperature hydrothermal fluids in oxidising environment.The^(87)Sr/^(86)Sr ratios of the BIF are higher than the maximum^(87)Sr/^(86)Sr evolution curves for all Archean reservoirs(bulk silicate earth,Archean crust and Archean seawater),indicating involvement of continentally-derived components during BIF formation and alteration.TheƐ_(Nd)(t)(+2.26 to+3.77)and Nd model age indicate that chemical constituents for the BIF were derived from undifferentiated crustal source,between 3.002 and 2.88 Ga.The variable and diverse O and H isotope data(−1.9‰to 17.3‰and−57‰to 136‰respectively)indicate that the Metzimevin iron ore formed initially from magmatic plumes and later enriched by magmatic-metamorphic-modified meteoric fluids.Mass balance calculations indicate mineralisation by combined leaching and precipitation,with an average iron enrichment factor of>2.67 and SiO_(2)depletion factor of>0.99.This is associated with an overall volume reduction of 28.27%,reflecting net leaching and volume collapse of the BIF protholith.展开更多
The Banian sediment-hosted antimony deposit is a medium-scale deposit located in the Dushan County,South Guizhou,China.Calcite as the dominant gangue mineral can be divided into two types: white and pink,the later is ...The Banian sediment-hosted antimony deposit is a medium-scale deposit located in the Dushan County,South Guizhou,China.Calcite as the dominant gangue mineral can be divided into two types: white and pink,the later is more intimate with mineralization.It is interesting that the REE characteristics are展开更多
Located on the northeast margin of the Qiangtang terrane between the Jinshajiang suture zone and Bangonghu-Nujiang suture zone,the Dongmozhazhua and Mohailaheng Pb-Zn deposits in the Yushu area of Qinghai Province are...Located on the northeast margin of the Qiangtang terrane between the Jinshajiang suture zone and Bangonghu-Nujiang suture zone,the Dongmozhazhua and Mohailaheng Pb-Zn deposits in the Yushu area of Qinghai Province are representative Pb-Zn deposits of the Pb-Zn-Cu polymetallic mineralization belt in the northern part of the Nujiang-Lancangjiang-Jinshajiang area,which are in the front belt of the Yushu thrust nappe system.The formed environments of these two deposits are different from those of sediment-hosted base metal deposits elsewhere in the world.The authors hold that they were formed during the Indian-Asian continental collision and developed within the fold-thrust belt combined with thrust and strike-slip-related Cenozoic basins in the interior of the collisional zone.Studying on the metallogenic epochs of these two deposits is helpful to the understanding of ore-forming regularity of the regional Pb-Zn-Cu mineralization belt and also to the search for new deposits in this region.The age of the Dongmozhazhua deposit has been determined by the Rb-Sr isochron method for sphalerite residues,whereas the age of the Mohailaheng deposit has been determined by the Rb-Sr isochron method for sphalerite residues and the Sm-Nd isochron method for fluorite.The age of the Dongmozhazhua deposit is 35.0-±0.0 Ma ((87Sr/86Sr)0=0.708807) for sphalerite residues.The age of the Mohailaheng deposit is 32.2±0.4 Ma ((87Sr/86Sr)o=0.708514) for sphalerite residues and 31.8±0.3 Ma ((143Nd/144Nd)o=0.512362) for fluorite with an average of 32.0 Ma.Together with the regional geological setting during mineralization,a possible tectonic model for metallogeny of the Dongmozhazhua and Mohailaheng Pb-Zn deposits has been established.These two ages are close to the ages of the Pb-Zn deposits in the Lanping and Tuotuohe basins,indicating that it is possible that the narrow 1000-kilometer-long belt controlled by a thrust nappe system on the eastern and northern margins of the Tibetan plateau could be a giant Pb-Zn mineralized belt.展开更多
The combined petrographic,petrological,geochemical and geochronological study of the Neoproterozoic gneisses of the Sarychabyn and Baskan complexes of the Junggar Alataw of South Kazakhstan elucidate the Precambrian t...The combined petrographic,petrological,geochemical and geochronological study of the Neoproterozoic gneisses of the Sarychabyn and Baskan complexes of the Junggar Alataw of South Kazakhstan elucidate the Precambrian tectonic evolution of the Aktau–Yili terrane.It is one of the largest Precambrian crustal blocks in the western Central Asian orogenic belt.The U-Pb single-grain zircon ages indicate that granite-gneisses formed from the same source and crystallised in the early Neoproterozoic ca.930–920 Ma.The chemical composition of gneisses corresponds to A2-type granites.The whole-rock Nd isotopic characteristics(εNd(t)=−4.9 to−1.0 and TNd(DM-2st)=1.9 to 1.7 Ga)indicate the involvement of Paleoproterozoic crustal rocks in magma generation.Early Neoproterozoic ca.930–920 Ma A-type granitoids in the Aktau–Yili terrane of South and Central Kazakhstan might reflect within-plate magmatism adjacent to the collisional belt or a local extension setting in back-arc areas of the continental arc.展开更多
1 Geologic setting The Xilin Gol Complex outcrops in the Bayan Gol area about 100 km to the northeast of Xilinhot City, Inner Mongolia (fig.1). Shao considered that the Xilin Gol Complex was an old tcrrane in the Pale...1 Geologic setting The Xilin Gol Complex outcrops in the Bayan Gol area about 100 km to the northeast of Xilinhot City, Inner Mongolia (fig.1). Shao considered that the Xilin Gol Complex was an old tcrrane in the Paleozoic展开更多
文摘Bulk geochemistry,Sr,Nd,and O-H isotope systematics are reported for the first time on banded iron formation(BIF)-hosted high-grade iron ore at the northwestern segment of Congo Craton(CC).Located in Mbalam iron ore district,Southern Cameroon,Metzimevin iron ore deposit is a hematite-magnetite BIF system,dominated by SiO_(2)+Fe_(2)O_(3)(97.1 to 99.84 wt%),with low concentrations of clastic elements e.g.,Al_(2)O_(3),TiO_(2),and HFSE,depicting a nearly pure chemical precipitate.The REE+Y signature of the iron deposit displays strong positive Eu anomaly,strong negative Ce anomaly,and chondritic to superchondritic Y/Ho ratios,suggestive of formation by mixed seawater-high temperature hydrothermal fluids in oxidising environment.The^(87)Sr/^(86)Sr ratios of the BIF are higher than the maximum^(87)Sr/^(86)Sr evolution curves for all Archean reservoirs(bulk silicate earth,Archean crust and Archean seawater),indicating involvement of continentally-derived components during BIF formation and alteration.TheƐ_(Nd)(t)(+2.26 to+3.77)and Nd model age indicate that chemical constituents for the BIF were derived from undifferentiated crustal source,between 3.002 and 2.88 Ga.The variable and diverse O and H isotope data(−1.9‰to 17.3‰and−57‰to 136‰respectively)indicate that the Metzimevin iron ore formed initially from magmatic plumes and later enriched by magmatic-metamorphic-modified meteoric fluids.Mass balance calculations indicate mineralisation by combined leaching and precipitation,with an average iron enrichment factor of>2.67 and SiO_(2)depletion factor of>0.99.This is associated with an overall volume reduction of 28.27%,reflecting net leaching and volume collapse of the BIF protholith.
文摘The Banian sediment-hosted antimony deposit is a medium-scale deposit located in the Dushan County,South Guizhou,China.Calcite as the dominant gangue mineral can be divided into two types: white and pink,the later is more intimate with mineralization.It is interesting that the REE characteristics are
文摘Located on the northeast margin of the Qiangtang terrane between the Jinshajiang suture zone and Bangonghu-Nujiang suture zone,the Dongmozhazhua and Mohailaheng Pb-Zn deposits in the Yushu area of Qinghai Province are representative Pb-Zn deposits of the Pb-Zn-Cu polymetallic mineralization belt in the northern part of the Nujiang-Lancangjiang-Jinshajiang area,which are in the front belt of the Yushu thrust nappe system.The formed environments of these two deposits are different from those of sediment-hosted base metal deposits elsewhere in the world.The authors hold that they were formed during the Indian-Asian continental collision and developed within the fold-thrust belt combined with thrust and strike-slip-related Cenozoic basins in the interior of the collisional zone.Studying on the metallogenic epochs of these two deposits is helpful to the understanding of ore-forming regularity of the regional Pb-Zn-Cu mineralization belt and also to the search for new deposits in this region.The age of the Dongmozhazhua deposit has been determined by the Rb-Sr isochron method for sphalerite residues,whereas the age of the Mohailaheng deposit has been determined by the Rb-Sr isochron method for sphalerite residues and the Sm-Nd isochron method for fluorite.The age of the Dongmozhazhua deposit is 35.0-±0.0 Ma ((87Sr/86Sr)0=0.708807) for sphalerite residues.The age of the Mohailaheng deposit is 32.2±0.4 Ma ((87Sr/86Sr)o=0.708514) for sphalerite residues and 31.8±0.3 Ma ((143Nd/144Nd)o=0.512362) for fluorite with an average of 32.0 Ma.Together with the regional geological setting during mineralization,a possible tectonic model for metallogeny of the Dongmozhazhua and Mohailaheng Pb-Zn deposits has been established.These two ages are close to the ages of the Pb-Zn deposits in the Lanping and Tuotuohe basins,indicating that it is possible that the narrow 1000-kilometer-long belt controlled by a thrust nappe system on the eastern and northern margins of the Tibetan plateau could be a giant Pb-Zn mineralized belt.
基金financially supported by the Russian Science Foundation (RSF) (Grant No. 22-77-00082)financially supported of grant 075-15-2021-680 of the Ministry of Science and Higher Education of the Russian Federation
文摘The combined petrographic,petrological,geochemical and geochronological study of the Neoproterozoic gneisses of the Sarychabyn and Baskan complexes of the Junggar Alataw of South Kazakhstan elucidate the Precambrian tectonic evolution of the Aktau–Yili terrane.It is one of the largest Precambrian crustal blocks in the western Central Asian orogenic belt.The U-Pb single-grain zircon ages indicate that granite-gneisses formed from the same source and crystallised in the early Neoproterozoic ca.930–920 Ma.The chemical composition of gneisses corresponds to A2-type granites.The whole-rock Nd isotopic characteristics(εNd(t)=−4.9 to−1.0 and TNd(DM-2st)=1.9 to 1.7 Ga)indicate the involvement of Paleoproterozoic crustal rocks in magma generation.Early Neoproterozoic ca.930–920 Ma A-type granitoids in the Aktau–Yili terrane of South and Central Kazakhstan might reflect within-plate magmatism adjacent to the collisional belt or a local extension setting in back-arc areas of the continental arc.
基金Project supported by Fok Ying Tung Education Foundation.
文摘1 Geologic setting The Xilin Gol Complex outcrops in the Bayan Gol area about 100 km to the northeast of Xilinhot City, Inner Mongolia (fig.1). Shao considered that the Xilin Gol Complex was an old tcrrane in the Paleozoic