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中国农业源非CO_(2)温室气体排放核算 被引量:1
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作者 秦硕璞 李婷 +6 位作者 张雅京 杨淼 郝一涵 汪明明 马欣悦 王辰星 严岩 《生态学报》 CAS CSCD 北大核心 2024年第17期7536-7551,共16页
中国作为传统的农业大国,高消耗、高投入、高需求的农业发展模式推动着中国农业非CO_(2)温室气体排放总量持续增长。农业源非CO_(2)气体以极具增温潜势的CH_(4)和N_(2)O为主,控制农业源非CO_(2)温室气体排放是我国实现农业绿色发展和“... 中国作为传统的农业大国,高消耗、高投入、高需求的农业发展模式推动着中国农业非CO_(2)温室气体排放总量持续增长。农业源非CO_(2)气体以极具增温潜势的CH_(4)和N_(2)O为主,控制农业源非CO_(2)温室气体排放是我国实现农业绿色发展和“双碳”目标的重要环节。我国农业系统非CO_(2)温室气体核算尚处于不断探索完善的过程之中,在估算方法、模型参数等方面还未形成一套完整和公认的体系。研究参考IPCC分类法建立了适用于中国农业系统的,包括种植业、畜牧业和农业废弃物的农业非CO_(2)温室气体排放核算体系。以2020年为基准对中国农业温室气体排放情况进行了核算。结果显示,我国农业系统非CO_(2)温室气体排放总量为62801.68万t CO_(2)-e,CH_(4)是农业系统排放贡献最大的温室气体。我国农业系统温室气体排放类型具有明显的空间分异特征;西北、华北、西南以畜牧业温室气体为主导,华东、华南地区以种植业为主导,东北、华中地区较为特殊,主导类型相对复杂;农业废弃物排放主要分布在东北、华东地区。研究所构建的温室气体核算体系可充分体现我国农业温室气体排放现状,体现各省域农业温室气体排放结构,有利于各区域制定有针对性的农业规划政策,可为降低我国农业温室气体核算研究中的不确定性、为碳中和实现过程中明确农业系统的温室气体贡献提供方法支持与数据基础。 展开更多
关键词 非CO_(2)温室气体 农业系统 温室气体排放核算 气候变化
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Exploring catalytic behaviors of CoS_(2)-ReS_(2) heterojunction by interfacial engineering
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作者 Jianmin Yu Yongteng Qian +12 位作者 Sohyeon Seo Yang Liu Huong T.D.Bui Ngoc Quang Tran Jinsun Lee Ashwani Kumar Hongdan Wang Yongguang Luo Xiaodong Shao Yunhee Cho Xinghui Liu Min Gyu Kim Hyoyoung Lee 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第10期11-18,I0002,共9页
Herein, a stable and efficient CoS_(2)-ReS_(2) electrocatalyst is successfully constructed by using the different molar ratios of CoS_(2) on ReS_(2). The size and morphology of the catalysts are significantly changed ... Herein, a stable and efficient CoS_(2)-ReS_(2) electrocatalyst is successfully constructed by using the different molar ratios of CoS_(2) on ReS_(2). The size and morphology of the catalysts are significantly changed after the CoS_(2) is grown on ReS_(2), providing regulation of the catalytic activity of ReS_(2). Particularly, the optimized CoS_(2)-ReS_(2) shows superior electrocatalytic properties with a low voltage of 1.48 V at 20 mA cm^(-2) for overall water splitting in 1.0 M KOH, which is smaller than the noble metal-based catalysts(1.77 V at 20 mA cm^(-2)). The XPS, XAS, and theoretical data confirm that the interfacial regulation of ReS_(2) by CoS_(2) can provide rich edge catalytic sites, which greatly optimizes the catalytic kinetics and drop the energy barrier for oxygen/hydrogen evolution reactions. Our results demonstrated that interfacial engineering is an efficient route for fabricating high-performance water splitting electrocatalysts. 展开更多
关键词 CoS_(2) res_(2) Interfacial engineering Catalytic kinetics Water splitting
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Ultra-high photoresponsive photodetector based on ReS_(2)/SnS_(2)heterostructure
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作者 王冰辉 邢艳辉 +7 位作者 董晟园 李嘉豪 韩军 涂华垚 雷挺 贺雯馨 张宝顺 曾中明 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第9期545-551,共7页
Photodetectors based on two-dimensional materials have attracted much attention because of their unique structure and outstanding performance.The response speed of single ReS_(2)photodetector is slow exceptionally,the... Photodetectors based on two-dimensional materials have attracted much attention because of their unique structure and outstanding performance.The response speed of single ReS_(2)photodetector is slow exceptionally,the heterostructure could improves the response speed of ReS_(2)-based photodetector,but the photodetectors responsivity is reduced greatly,which restricts the development of ReS_(2).In this paper,a vertically structured ReS_(2)/SnS_(2)van der Waals heterostructure photodetectors is prepared,using ReS_(2)as the transport layer and SnS_(2)as the light absorbing layer to regulate the channel current.The device has an ultra-high photoconductive gain of 10^(10),which exhibits an ultra-high responsivity of4706 A/W under 365-nm illumination and response speed in seconds,and has an ultra-high external quantum efficiency of1.602×10^(6)%and a high detectivity of 5.29×10^(12)jones.The study for ReS_(2)-based photodetector displays great potential for developing future optoelectronic devices. 展开更多
关键词 two-dimensional material res_(2) HETEROSTRUCTURE PHOTODETECTOR
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Ti_(3)C_(2)T_(x) MXene/ReS_(2)复合吸波材料的制备及性能调控
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作者 高家林 张新慈 李林 《哈尔滨师范大学自然科学学报》 CAS 2023年第6期46-53,共8页
采用冰模板法成功制备了Ti_(3)C_(2)T_(x)MXene/ReS_(2)复合吸波材料.利用X射线衍射仪(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)和矢量网络分析仪(VNA)对复合材料的组成、形貌和电磁性能进行了表征.结构表征结果表明,所制备的Ti... 采用冰模板法成功制备了Ti_(3)C_(2)T_(x)MXene/ReS_(2)复合吸波材料.利用X射线衍射仪(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)和矢量网络分析仪(VNA)对复合材料的组成、形貌和电磁性能进行了表征.结构表征结果表明,所制备的Ti_(3)C_(2)T_(x)MXene/ReS_(2)复合材料具有三维层级有序多孔结构.材料的电磁参数测试表明,ReS_(2)的引入可以有效地调节复合材料的介电损耗特性.与ReS_(2)和Ti_(3)C_(2)T_(x)MXene材料相比,Ti_(3)C_(2)T_(x)MXene/ReS_(2)复合材料表现出良好的电磁波吸收性能和阻抗匹配特性:在频率为17 GHz处,该复合材料的最小反射损耗可达到-36 dB;在1.5 mm匹配厚度下,其有效吸收带宽可以达到4.0 GHz.Ti_(3)C_(2)T_(x)MXene/ReS_(2)复合材料的成功制备为高性能电磁波吸收材料的设计和开发提供新的策略. 展开更多
关键词 电磁波吸收 MXene res_(2) 介电损耗 阻抗匹配
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Processes involving soil CO_(2)dynamic in a sector of Chaco-Pampean plain,Argentina:An isotope geochemical approach
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作者 Sanci Romina Panarello Héctor 《Acta Geochimica》 EI CAS CSCD 2024年第5期947-958,共12页
The magnitude and spatial variability of CO_(2)surface emissions and processes involving CO_(2)released to the atmosphere from the soils are relevant issues in the context of climate change.This work evaluated CO_(2)f... The magnitude and spatial variability of CO_(2)surface emissions and processes involving CO_(2)released to the atmosphere from the soils are relevant issues in the context of climate change.This work evaluated CO_(2)fluxes and^(13)C/^(12)C ratio of vegetation,organic matter,and soil gases from no disturbed soils of Chaco Pampean Plain(Argentina)with different soil properties and environmental conditions(PL and PA units).Soil organic decomposition from individual layers was accompanied byδ^(13)C of total organic carbon(δ^(13)C-TOC)values more enriched to depth.δ^(13)C-TOC values in the upper soil profile~ca.0–15 cm were like the plant community of this area(~−33 to−29‰)whileδ^(13)CTOC varied stronger bellow horizon A,till~−24‰.Bothδ^(13)C-TOC and soilδ^(13)C-CO_(2)were similar(~−24 to 26‰)at deeper horizons(~50–60 cm).Toward the superficial layers,δ^(13)C-TOC andδ^(13)C-CO_(2)showed more differences(till~4‰),due influence of the diffusion process.Horizon A layer(~0–20 cm)from both PL and PA units contained the most enrichedδ^(13)C-CO_(2)values(~−15–17‰)because atmospheric CO_(2)permeated the soil air.A simple two-component mixing model between sources(atmosphericδ^(13)C-CO_(2)and soil CO_(2))confirmed that process.Isotopically,CO_(2)fluxes reflected the biodegradation of C3 plants(source),diffusive transport,and CO_(2)exchange(atmosphere/soil).Soil moisture content appeared as a determining factor in the diffusion process and the magnitude of CO_(2)surface emissions(12–60 g·m^(−2)·d^(−1)).That condition was confirmed by CO_(2)diffusion coefficients estimated by air-filled porosity parameters and soil radon gradient model. 展开更多
关键词 Soil CO_(2) Carbon isotopes Isotope fractionation Radon gases
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Decoupling CO2 from Climate Change
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作者 Michael Nelson David B. Nelson 《International Journal of Geosciences》 CAS 2024年第3期246-269,共24页
This study determines if there is a correlation between rising carbon dioxide levels and global warming. Historical data were reviewed from three different time periods spanning 500 million years. It showed that the c... This study determines if there is a correlation between rising carbon dioxide levels and global warming. Historical data were reviewed from three different time periods spanning 500 million years. It showed that the curves and trends were too dissimilar to establish a connection. Observations from CO<sub>2</sub>/temp ratios showed that the CO<sub>2</sub> and the temperature moved in opposite directions 42% of the time. Many ratios displayed zero or near zero values, reflecting a lack of response. As much as 87% of the ratios revealed negative or near zero values, which strongly negate a correlation. The infrared spectra showed the Greenhouse Gases had an exceptionally low absorption band between 11.67 μm to 9.1 μm, which is a zone called the infrared atmospheric window. Most of the Greenhouse Gases absorb little infrared inside that zone. And that zone is where the Earth’s surface emits almost all infrared radiation. Even with minimal absorbance, water vapor captures the most infrared radiation. It absorbs 84 times more than CO<sub>2</sub>, 407 thousand times more than methane, 452 thousand times more than ozone and 2.3 million times more than nitrous oxide. The Intergovernmental Panel on Climate Change (IPCC) and the United States EPA excluded water vapor because it was not associated with man-made activities. They reported that water vapor and clouds were simply feedback mechanisms from CO<sub>2</sub>. Clouds reflect radiation from the sun. The Northern Hemisphere is 2.7°F warmer than the Southern Hemisphere because of clouds. The world cloud cover has gone down 4.1% from 1982 to 2018. Calculations show that this could be responsible for 2.4°F of the 2.7°F. The research shows that most of the recent increase in temperature (89.9%) is because of fewer clouds. 展开更多
关键词 Climate Change Greenhouse Effect Greenhouse gases CO2 Water Vapor CLOUDS
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CO2 Back-Radiation Sensitivity Studies under Laboratory and Field Conditions
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作者 Ernst Hammel Martin Steiner +4 位作者 Christoph Marvan Matthias Marvan Klaus Retzlaff Werner Bergholz Axel Jacquine 《Atmospheric and Climate Sciences》 2024年第4期407-428,共22页
We measured the IR back radiation using a relatively low-cost experimental setup and a test chamber with increasing CO2 concentrations starting with a pure N2 atmosphere against a temperature-controlled black referenc... We measured the IR back radiation using a relatively low-cost experimental setup and a test chamber with increasing CO2 concentrations starting with a pure N2 atmosphere against a temperature-controlled black reference background. The results confirm estimations within this work and previous finding about CO2-induced infrared radiation saturation within realistic atmospheric conditions. We used this setup also to study thermal forcing effects with stronger and rare greenhouse gases against a clear night sky. Our results and their interpretation are another indication for having a more critical approach in climate modelling and against monocausal interpretation of climate indices only caused by anthropogenic greenhouse gas emissions. Basic physics combined with measurements and data taken from the literature allow us to conclude that CO2 induced infrared back-radiation must follow an asymptotic logarithmic-like behavior, which is also widely accepted in the climate-change community. The important question of climate sensitivity by doubling current CO2 concentrations is estimated to be below 1˚C. This value is important when the United Nations consider climate change as an existential threat and many governments intend rigorously to reduce net greenhouse gas emissions, led by an ambitious European Union inspired by IPCC assessments is targeting for more than 55% in 2030 and up to 100% in 2050 [1]. But probably they should also listen to experts [2] [3] who found that all these predictions have considerable flaws in basic models, data and impact scenarios. 展开更多
关键词 Climate Change Greenhouse gases CO2 Backscatter IR Radiation
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CO_2激光差频GaSe晶体产生太赫兹波的数值计算 被引量:2
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作者 姜可 谢冀江 +1 位作者 张来明 骆聪 《红外与激光工程》 EI CSCD 北大核心 2013年第5期1223-1227,共5页
以可调谐CO2激光差频非线性GaSe晶体为例,在共线相位匹配方式下,计算了oe—e和oe—o两种相位匹配方式下的角度调谐特性、有效非线性系数、走离角和允许角。结果表明:GaSe晶体可产生73.84~3000μm的太赫兹波,且有效非线性系数为4l-... 以可调谐CO2激光差频非线性GaSe晶体为例,在共线相位匹配方式下,计算了oe—e和oe—o两种相位匹配方式下的角度调谐特性、有效非线性系数、走离角和允许角。结果表明:GaSe晶体可产生73.84~3000μm的太赫兹波,且有效非线性系数为4l-54pm/V;走离角在1.771°~10.63°之间;所允许的最大发散角为13.95~94.7μm·rad,对入射光的方向性要求较高。对于500μm以上的太赫兹波,两种匹配方式除有效非线性系数外没有大的区别。模拟结果对于开展基于激光差频技术产生太赫兹的研究具有重要的指导意义。 展开更多
关键词 差频 太赫兹 CO2激光 gase晶体 相位匹配
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GaSe:AgGaSe_2晶体的光学性能及应用(英文) 被引量:5
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作者 古新安 朱韦臻 +9 位作者 罗志伟 ANGELUTS A A EVDOKIMOV M G NAZAROV M M SHKURINOV A P ANDREEV Y M LANSKII G V SHAIDUKO A V KOKH K A SVETLICHNYI V A 《中国光学》 CAS 2012年第1期57-63,共7页
从GaSe:AgGaSe2熔体(质量掺杂浓度为10%)中生长的非线性光学晶体ε-GaSe:Ag晶体(质量掺杂浓度≤0.04%)是一种非中心对称晶体,可用于相位匹配频率转换。Ag的掺入使GaSe晶体的显微硬度提高了30%,从而使其可以在任意方向上进行切割和抛光... 从GaSe:AgGaSe2熔体(质量掺杂浓度为10%)中生长的非线性光学晶体ε-GaSe:Ag晶体(质量掺杂浓度≤0.04%)是一种非中心对称晶体,可用于相位匹配频率转换。Ag的掺入使GaSe晶体的显微硬度提高了30%,从而使其可以在任意方向上进行切割和抛光。本文研究了GaSe:AgGaSe2晶体在可见、中红外及太赫兹波段的光学性能。实验证明:GaSe:AgGaSe2晶体的吸收系数是纯GaSe晶体的2倍,其CO2激光倍频效率是ZnGeP2晶体的1.7倍。 展开更多
关键词 gase:Aggase2晶体 光学特性 中红外波段 THZ波段 二次谐波振荡
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CO激光在非线性晶体ZnGeP_2和GaSe中的混频效应(英文) 被引量:1
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作者 张来明 谢冀江 +10 位作者 郭劲 陈飞 姜可 ANDREEV YU M IONIN A A KINYAEVSKIY I O KLIMACHEV YU M KOZLOV A YU KOTKOV A A LANSKII G V SHAIDUKO A V 《光学精密工程》 EI CAS CSCD 北大核心 2012年第2期277-286,共10页
为了获得2.15~1 500μm的相干光源,研究了CO激光在高质量非线性晶体ZnGeP2和GaSe中的混频效应。为了提高转换效率,在激光锁模方式下对CO激光器的二次谐波、和频和差频的产生进行了研究。结果显示,利用GaSe晶体和ZnGeP2晶体,调Q多谱线C... 为了获得2.15~1 500μm的相干光源,研究了CO激光在高质量非线性晶体ZnGeP2和GaSe中的混频效应。为了提高转换效率,在激光锁模方式下对CO激光器的二次谐波、和频和差频的产生进行了研究。结果显示,利用GaSe晶体和ZnGeP2晶体,调Q多谱线CO激光辐射的谱线内倍频效率分别大于0.3%和1.1%。采用ZnGeP2晶体进行倍频时,可调谐锁膜CO激光器的转换效率为12.5%。模拟结果显示,二次谐波与和频产生的输出光谱相同。相邻谱线下,和频和差频的产生过程中,基波和一次谐波可以分别在4.0~5.0μm和100~≥1 200μm(太赫兹范围)形成振荡。利用锁模CO激光器在ZnGeP2晶体中的混频效应,可以得到2.15~≥1 500μm的相干光源,同时转换效率可达到甚至高于12.5%。 展开更多
关键词 非线性晶体 ZnGeP2晶体 gase晶体 混频效应 脉冲CO激光 锁模
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基于GaSe和GaSe_(0.7)S_(0.3)单晶的单脉冲CO_2激光倍频器(英文) 被引量:1
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作者 TARASENKO V F SITNIKOV A G +10 位作者 PANCHENKO A N TEL'MINOV A E GENIN D E 李殿军 张来明 姜可 谢冀江 SARKISOV S Yu BEREZNAYA S A KOROTCHENKO Z V KAZAKOV A V 《中国光学》 EI CAS 2011年第4期397-403,共7页
描述了使用电感储能发生器和半导体转换开关泵浦的工作波长为10.6μm的高效CO2激光器。给出了激光泵浦的非线性晶体GaSe和GaSe0.7S0.3的二次谐波振荡的实验数据和理论估算结果。结果显示,GaSe晶体在输入能量为180mJ时,最大能量转换效率... 描述了使用电感储能发生器和半导体转换开关泵浦的工作波长为10.6μm的高效CO2激光器。给出了激光泵浦的非线性晶体GaSe和GaSe0.7S0.3的二次谐波振荡的实验数据和理论估算结果。结果显示,GaSe晶体在输入能量为180mJ时,最大能量转换效率为0.38%,倍频激光的峰值功率为8 kW。 展开更多
关键词 gase gase0.7S0.3 单脉冲CO2激光 倍频器
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Air-stable,all-dry transferred ReS_(2)/GaSe heterostructure-based NO_(2)gas sensor
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作者 A.Venkatesan Hyeyoon Ryu +2 位作者 Anupom Devnath Hyungyu Yoo Seunghyun Lee 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2024年第1期79-87,共9页
Two-dimensional(2D)materials have gained considerable attention in chemical sensing owing to their naturally high surface-to-volume ratio.However,the poor response time and incomplete recovery re-strict their applicat... Two-dimensional(2D)materials have gained considerable attention in chemical sensing owing to their naturally high surface-to-volume ratio.However,the poor response time and incomplete recovery re-strict their application in practical,high performance gas sensors.In this work,we fabricated air-stable ReS_(2)/GaSe heterostructure-based NO_(2)gas sensors with excellent gas sensing response,recovery,selectiv-ity and a low limit of detection(LOD)toward nitrogen dioxide(NO_(2)).The ReS_(2)/GaSe heterostructure was prepared via mechanical exfoliation and an all-dry transfer method.Before the sensing measurements,temperature-dependant transport measurements were carried out.The Schottky Barrier Height(SBH)of the ReS_(2)/GaSe heterostructure was calculated and the corresponding transport mechanisms were dis-cussed.The fabricated gas sensors showed a significant response enhancement with full reversibility to-ward ppm-level NO_(2)(response of∼17%at 3 ppm,a LOD of∼556 ppb)at an operating temperature of(33°C).In particular,the total response and recovery time of the ReS_(2)/GaSe was revealed to be less than 4 min(∼38 s and∼174 s,respectively)for the 250 ppm concentration,which is one of the best response and recovery time toward ppm-level NO_(2).The excellent sensing performances and recovery characteris-tics of the ReS_(2)/GaSe structure are attributed to its efficient charge separation,unique interlayer coupling and desirable band alignments.This atomically thin,ultrasensitive gas sensor that operates at room tem-perature is a strong technological contender to conventional metal oxide gas sensors,which often require elevated temperatures. 展开更多
关键词 2D materials All-dry transfer Gas sensor Van der Waals heterostructure res_(2)/gase Gas sensing response Transition metal dichalcogenide
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二维ReS_(2)/TiO_(2)异质结薄膜的制备及其光电催化性能 被引量:1
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作者 曾升 周子文 +1 位作者 胡佳齐 吕斌 《材料科学与工程学报》 CAS CSCD 北大核心 2021年第5期731-735,共5页
本研究利用TiO_(2)的前驱体在FTO上旋涂一层种子溶液,退火后用水热法使TiO_(2)籽晶垂直生长成纳米棒阵列。随后采用液相剥离法(LPE)制得二维ReS2材料,并用滴涂法将二维ReS2滴涂到TiO_(2)纳米棒阵列形成ReS_(2)/TiO_(2)异质结。通过X射... 本研究利用TiO_(2)的前驱体在FTO上旋涂一层种子溶液,退火后用水热法使TiO_(2)籽晶垂直生长成纳米棒阵列。随后采用液相剥离法(LPE)制得二维ReS2材料,并用滴涂法将二维ReS2滴涂到TiO_(2)纳米棒阵列形成ReS_(2)/TiO_(2)异质结。通过X射线衍射仪(XRD)、扫描电子显微镜(SEM)和光电催化测试等分析表征了所制备材料和结构的晶型,形貌及其光电化学性能。结果表明,当负载量在约0.1 mg/cm^(2)时,ReS_(2)/TiO_(2)异质结有着最强的光电流1.5 mA/cm^(2),是纯TiO_(2)纳米棒(0.03mA/cm^(2))的50倍,强烈的增强来源于ReS_(2)/TiO_(2)异质结构形成能可有效地拓宽TiO_(2)的吸光范围,并且促进光生载流子的有效分离和提高光电催化性能。 展开更多
关键词 液相剥离法 res_(2) TiO_(2) 异质结 光电催化
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Selective catalytic methanation of CO in hydrogen-rich gases over Ni/ZrO_2 catalyst 被引量:23
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作者 Qihai Liu Xinfa Dong Xinman Mo Weiming Lin 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2008年第3期268-272,共5页
Ni/ZrO2 catalysts were prepared by the incipient-wetness impregnation method and were investigated in activity and selectivity for the selective catalytic methanation of CO in hydrogen-rich gases with more than 20 vol... Ni/ZrO2 catalysts were prepared by the incipient-wetness impregnation method and were investigated in activity and selectivity for the selective catalytic methanation of CO in hydrogen-rich gases with more than 20 vol% CO2. The result showed that Ni loadings significantly influenced the performance of Ni/ZrO2 catalyst. The 1.6 wt% Ni loading catalyst exhibited the highest catalytic activity among all the catalysts in the selective methanation of CO in hydrogen-rich gas. The outlet concentration of CO was less than 20 ppm with the hydrogen consumption below 7%, at a gas-hourly-space velocity as high as 10000 h-1 and a temperature range of 260 °C to 280 °C. The X-ray diffraction (XRD) and temperature programmed reduction (TPR) measurements showed that NiO was dispersed thoroughly on the surface of ZrO2 support if Ni loading was under 1.6 wt%. When Ni loading was increased to 3 wt% or above, the free bulk NiO species began to assemble, which was not favorable to increase the selectivity of the catalyst. 展开更多
关键词 selective methanation CO removal Ni/ZrO2 catalyst hydrogen-rich gases fuel cell
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Effect of CO_2 on explosion limits of flammable gases in goafs 被引量:9
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作者 MA, Li XIAO, Yang +1 位作者 DENG, Jun WANG, Qiuhong 《Mining Science and Technology》 EI CAS 2010年第2期193-197,共5页
In order to reduce the number of accidents due to explosions of flammable gases in the goaf of coalmines,the conditions for explosion of flammable gases and their explosion limits,affected to a considerable extent by ... In order to reduce the number of accidents due to explosions of flammable gases in the goaf of coalmines,the conditions for explosion of flammable gases and their explosion limits,affected to a considerable extent by CO2,are explored.With the use of our experimental equipment suitable for the study of explosion of polybasic explosive gas mixtures,we investigated the effect of CH4/H2=10/1 and CH4/C2H4=10/1 gases mixed with CO2 on their explosion limits.The results indicate that after adding CO2,the explosion limit of the CH4/H2(or C2H4) =10/1 gas mixtures decreased markedly with increasing amounts of CO2.When the amount of CO2 exceeded 25%,the CH4/C2H4=10/1 flammable gas mixture did not lead to explosions.Similar results were obtained when the amount of CO2 exceeded 23% in the CH4/H2=10/1 flammable gas mixture.We also compared the explosion limits and the explosion suppression effect of N2 or CO2 on the explosion limits of the CH4+CO and CH4+C2H4 dual explosive gas mixtures.Along with the increases in the amounts of CO2 or N2,the area of the explosion limits of gas mixtures decreased.Under the same conditions,the explosion suppression effect of CO2 was greater than that of N2.CO2 has clearly the better suppression effect on the explosion of flammable gases in goafs. 展开更多
关键词 CO2 flammable gases explosion limits
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五种吸附剂与C_(4)F_(7)N气体及CF_(3)SO_(2)F气体的相容性试验研究 被引量:3
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作者 吕浥尘 郑宇 +2 位作者 朱太云 周文俊 李涵 《电工技术学报》 EI CSCD 北大核心 2023年第S01期196-203,共8页
全氟异丁腈(C_(4)F_(7)N)和三氟甲基磺酰氟(CF_(3)SO_(2)F)是两种具有应用前景的SF_(6)替代气体,有必要研究其与设备中常见吸附剂的相容性。该文通过试验研究了五种常用的吸附剂(3A分子筛、4A分子筛、5A分子筛、13X分子筛及活性氧化铝)... 全氟异丁腈(C_(4)F_(7)N)和三氟甲基磺酰氟(CF_(3)SO_(2)F)是两种具有应用前景的SF_(6)替代气体,有必要研究其与设备中常见吸附剂的相容性。该文通过试验研究了五种常用的吸附剂(3A分子筛、4A分子筛、5A分子筛、13X分子筛及活性氧化铝)与C_(4)F_(7)N气体、CF_(3)SO_(2)F气体的相容性,采用C_(4)F_(7)N/CO_(2)、CF_(3)SO_(2)F/N_(2)混合气体进行试验,检测试验前后混合气体的比例及成分,发现活性氧化铝会使C_(4)F_(7)N气体体积分数下降,但不会使CF_(3)SO_(2)F气体体积分数下降;其他几种吸附剂均不会使两种气体体积分数下降。分析表明,C_(4)F_(7)N气体分子的CN基团会与活性氧化铝发生弱相互作用,从而导致其被活性氧化铝吸附,因此活性氧化铝不适合作为C_(4)F_(7)N气体设备中的吸附剂。该文涉及的五种吸附剂均与CF_(3)SO_(2)F气体相容。 展开更多
关键词 吸附剂 C_(4)F_(7)N CF_(3)SO_(2)F SF_(6)替代气体 相容性
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The Emission Reduction Potential of Non-CO_2 Greenhouse Gases in China and Its Policy Implications 被引量:1
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作者 Delin HUANG Songfeng CAI Zhen WANG 《Asian Agricultural Research》 2013年第4期87-92,共6页
Using the improved Energy-Environmental Version of the GTAP Model (GTAP-E) and the sixth version of emission database of non-CO2 greenhouse gases, we simulate the emission reduction potential of non-CO2 greenhouse gas... Using the improved Energy-Environmental Version of the GTAP Model (GTAP-E) and the sixth version of emission database of non-CO2 greenhouse gases, we simulate the emission reduction potential of non-CO2 greenhouse gases in China and its policy implications. The results show that at present, China is a country with the greatest emission of non-CO2 greenhouse gases in the world, and the emission will account for about 20% of the world's total emission in 2020. The proportion of emission of non-CO2 greenhouse gases from the agricultural sector reaches 73%. In the next 10 years, the emission of non-CO2 gases from cattle and sheep, industry and service industry will experience the highest growth rate; the growth rate of emission from service industry will be higher than that of emission from industry, and the emission from service industry will exceed that from industry after 2010. China can implement emission reduction policy of non-CO2 greenhouse gases to ease the international pressure of CO2 emission reduction. Although the high carbon tax collected can reduce considerable non-CO2 emission, there is little difference in policy efficiency between high carbon tax and low carbon tax. So, in the implementation of emission reduction carbon tax policy of non-CO2 gases, it is necessary to control the carbon tax at a low level. 展开更多
关键词 Non-CO2 GREENHOUSE gaseS EMISSION reduction POTENT
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锂硫电池中ReS_(2)修饰碳纤维布复合正极的设计与制备
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作者 周雨琼 许俊 《电子元件与材料》 CAS CSCD 北大核心 2022年第9期902-907,932,共7页
锂硫电池因具有高理论容量和高能量密度被认为是最具前景的储能技术之一。然而,锂硫电池因硫电导率低、多硫化物穿梭效应、电极体积膨胀等问题限制了其实际应用。为了探究ReS_(2)纳米片对锂硫电池性能的影响,采用简单的水热法实现ReS_(2... 锂硫电池因具有高理论容量和高能量密度被认为是最具前景的储能技术之一。然而,锂硫电池因硫电导率低、多硫化物穿梭效应、电极体积膨胀等问题限制了其实际应用。为了探究ReS_(2)纳米片对锂硫电池性能的影响,采用简单的水热法实现ReS_(2)纳米片在碳纤维布(CFC)上均匀生长,形成ReS_(2)-CFC复合材料;并通过熔融扩散法,将活性物质硫分散在ReS_(2)-CFC中作为锂硫电池正极(S/ReS_(2)-CFC)。借助扫描电子显微镜(SEM)、X射线衍射仪(XRD)和电化学技术等表征测试手段分析了S/ReS_(2)-CFC的形貌和电化学性能。结果表明,CFC和ReS_(2)通过物理和化学协同作用能够很好地抑制多硫化物的穿梭,提高电池倍率性能和循环稳定性。S/ReS_(2)-CFC正极电池在0.2C(1C=1675 mAh·g)倍率下有1522 mAh·g的高放电比容量;在4C倍率下放电比容量能够达到768 mAh·g,经过500圈循环后保持在548 mAh·g,每圈衰减率为0.058%。 展开更多
关键词 锂硫电池 res_(2)纳米片 碳纤维布 复合材料 正极
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2009-2019年黑龙江龙凤山区域大气本底站CO_(2)浓度变化特征
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作者 谢桐川 赵胡笳 +6 位作者 王鹏 代家庚 孙敬敏 侯续丽 吕明佳 马文博 刘宁微 《气象与环境学报》 2023年第5期44-52,共9页
利用2009—2019年黑龙江龙凤山区域大气本底站CO_(2)浓度长期监测数据,分析了中国东北区域大气本底站CO_(2)浓度的日变化、月变化以及年际变化趋势,探讨了影响龙凤山区域大气本底站CO_(2)浓度的气象驱动因子。结果表明:龙凤山大气本底站... 利用2009—2019年黑龙江龙凤山区域大气本底站CO_(2)浓度长期监测数据,分析了中国东北区域大气本底站CO_(2)浓度的日变化、月变化以及年际变化趋势,探讨了影响龙凤山区域大气本底站CO_(2)浓度的气象驱动因子。结果表明:龙凤山大气本底站CO_(2)浓度日变化表现为在夏季变化幅度最大,其次是秋季,春季次之,冬季变化幅度最小,每日峰值出现在08:00之前,16:00左右出现最低值。CO_(2)浓度月变化表现为最大值出现在1月,平均值约为416.1×10^(-6),最小值出现在7月,平均值为391.1×10^(-6)。CO_(2)浓度季节变化表现为冬季CO_(2)浓度明显高于其他季节,平均值为415.4×10^(-6),夏季出现最低值,其平均值为395.8×10^(-6)。研究期内龙凤山区域大气本底站CO_(2)平均浓度呈现增长趋势,增长率为2.45×10^(-6)/a。龙凤山区域大气本底站春季最大频率风向出现在SSW方向(21.0%),夏季最大频率风向出现在SSW和S方向(23.1%和22.7%),秋季最大频率风向出现在SSW方向(23.4%),冬季风向频率最大值出现在SW方向(31.6%),不同季节CO_(2)浓度高值均出现在北风主导条件下。龙凤山区域大气本底站CO_(2)浓度与温度呈负相关(-0.54),相对湿度与CO_(2)浓度在春季和秋季呈显著负相关(-0.44和-0.55),CO_(2)浓度与风速相关性较小,可能与较高浓度CO_(2)源输送有关。 展开更多
关键词 温室气体 CO_(2) 气象要素 区域大气本底站
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CO–15%CO_(2)混合气体还原碳化MoO_(2)制备Mo_(2)C的动力学机理分析
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作者 王璐 李红肖 +1 位作者 阙标华 薛正良 《工程科学学报》 EI CSCD 北大核心 2023年第4期551-559,共9页
对CO–15%CO_(2)混合气体还原碳化MoO_(2)制备Mo_(2)C的反应机理及其动力学展开研究并采用热力学软件FactSage 7.3、场发射扫描电子显微镜(FE-SEM)、X射线衍射(XRD)、热重(TG)、比表面积测试(BET)和模型拟合等手段和方法对实验数据进行... 对CO–15%CO_(2)混合气体还原碳化MoO_(2)制备Mo_(2)C的反应机理及其动力学展开研究并采用热力学软件FactSage 7.3、场发射扫描电子显微镜(FE-SEM)、X射线衍射(XRD)、热重(TG)、比表面积测试(BET)和模型拟合等手段和方法对实验数据进行分析.结果表明:变温实验中,升温速率越快,MoO_(2)的开始反应温度和完全还原温度越高;恒温实验中,温度越高,MoO_(2)的还原碳化速率越快;反应前后物相组成表明MoO_(2)是经一步反应直接生成Mo_(2)C,没有中间产物金属Mo的生成,并且还发现所得Mo_(2)C基本与MoO_(2)具有一致的片状形貌,但是由于气体的进入与逸出、产物摩尔体积的缩小以及沉积碳的减少,Mo_(2)C颗粒表面会产生微孔和裂纹导致比表面积增长近20倍;动力学分析结果表明该还原碳化过程由形核长大与界面化学反应共同控制,其中形核长大过程占比68.9%,表观活化能为80.651 kJ·mol^(–1);界面化学反应占比31.1%,表观活化能为121.002 kJ·mol^(–1). 展开更多
关键词 CO–15%CO_(2)混合气体 二氧化钼 碳化钼 反应机理 动力学
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