Developing high-performance anodes for potassium ion batteries(KIBs) is of paramount significance but remains challenging.In the normal sense,electrode materials are prepared by ubiquitous wet chemical routes,which ot...Developing high-performance anodes for potassium ion batteries(KIBs) is of paramount significance but remains challenging.In the normal sense,electrode materials are prepared by ubiquitous wet chemical routes,which otherwise might not be versatile enough to create desired heterostructures and/or form clean interfacial areas for fast transport of K-ions and electrons.Along this line,rate capability/cycling stability of resulting KIBs are greatly handicapped.Herein we present an all-chemical vapor deposition approach to harness the direct synthesis of nitrogen-doped graphene(NG)/rhenium diselenide(ReSe_2)hybrids over three-dimensional MXene supports as superior heterostructure anode material for KIBs.In such an innovative design,1 T'-ReSe2 nanoparticles are sandwiched in between the NG coatings and MXene frameworks via strong interfacial interactions,thereby affording facile K~+ diffusion,enhancing overall conductivity,boosting high-power performance and reinforcing structural stability of electrodes.Thus-constructed anode delivers an excellent rate performance of 138 mAh g^(-1) at 10.0 A g^(-1) and a high reversible capacity of 90 mAh g^(-1) at 5 A g^(-1) after 300 cycles.Furthermore,the potassium storage mechanism has been systematically probed by advanced in situlex situ characterization techniques in combination with first principles computations.展开更多
Polarization-resolved photodetectors,a significant branch of photodetection,can more effectively distinguish the target from the background by exploiting polarization-sensitive characteristics.However,due to the absen...Polarization-resolved photodetectors,a significant branch of photodetection,can more effectively distinguish the target from the background by exploiting polarization-sensitive characteristics.However,due to the absence of intrinsic polarized absorption properties of many materials,there is still a great challenge to develop the high-performance polarization-resolved photodetectors.Here,we report a van der Waals heterojunction(vdWH)ReSe_(2)/WSe_(2)photodetector,which performs a high responsivity of~0.28 A/W and a high detectivity of 1.1×10^(12)Jones under the illumination of 520 nm laser at room temperature.Remarkably,scanning photocurrent mapping(SPCM)measurements demonstrate the photoresponse of devices closely depend on the polarized angle of the incident light,indicating the effective polarized light detection.This work paves the way to develop high-performance polarization-resolved photodetectors based on two-dimensional(2D)materials.展开更多
Recently,van der Waals heterostructures(vdWHs)constructed by transition-metal dichalcogenides(TMDCs)have come under the research spotlight owing to their excellent capabilities,multiple functionalities,and innovative ...Recently,van der Waals heterostructures(vdWHs)constructed by transition-metal dichalcogenides(TMDCs)have come under the research spotlight owing to their excellent capabilities,multiple functionalities,and innovative architecture for advanced optoelectronic devices.Herein,novel heterojunction photodetectors composed of monolayer molybdenum disulfide(MoS2)and few-layer rhenium selenide(ReSe_(2))are explored for ultra-fast and polarization detection.Owing to the enhanced light-matter interactions and type-II band alignment of the ReSe_(2)/MoS_(2) heterostructure,the photodetector exhibits impressive performances at 638 nm in terms of a high on/off ratio~104,large photoresponsivity~3.52 A/W,high specific detectivity~1011 Jones,and large 3 dB frequency of 65.7 kHz.In addition,ultrafast rise/decay times(5.0/9.1 ms)are obtained under pulsed incident light contributed to the built-in electric field at the heterointerface,demonstrating a result one or two orders of magnitude faster than the currently reported values of group VII-TMDCs based photodetectors.Beyond the conventional photodetection,this photodetector also displays polarization detection capability with sensitivity 1.35.Such Re-based vdWHs provide superior platforms for the realization of ultra-fast and polarization-sensitive photodetection in broadband spectrum.展开更多
基金supported by the National Natural Science Foundation of China (51702225)the National Key Research and Development Program (2016YFA0200103)+2 种基金the Natural Science Foundation of Jiangsu Province (BK20170336)the support from Suzhou Key Laboratory for Advanced Carbon MaterialsWearable Energy Technologies, Suzhou, China。
文摘Developing high-performance anodes for potassium ion batteries(KIBs) is of paramount significance but remains challenging.In the normal sense,electrode materials are prepared by ubiquitous wet chemical routes,which otherwise might not be versatile enough to create desired heterostructures and/or form clean interfacial areas for fast transport of K-ions and electrons.Along this line,rate capability/cycling stability of resulting KIBs are greatly handicapped.Herein we present an all-chemical vapor deposition approach to harness the direct synthesis of nitrogen-doped graphene(NG)/rhenium diselenide(ReSe_2)hybrids over three-dimensional MXene supports as superior heterostructure anode material for KIBs.In such an innovative design,1 T'-ReSe2 nanoparticles are sandwiched in between the NG coatings and MXene frameworks via strong interfacial interactions,thereby affording facile K~+ diffusion,enhancing overall conductivity,boosting high-power performance and reinforcing structural stability of electrodes.Thus-constructed anode delivers an excellent rate performance of 138 mAh g^(-1) at 10.0 A g^(-1) and a high reversible capacity of 90 mAh g^(-1) at 5 A g^(-1) after 300 cycles.Furthermore,the potassium storage mechanism has been systematically probed by advanced in situlex situ characterization techniques in combination with first principles computations.
文摘Polarization-resolved photodetectors,a significant branch of photodetection,can more effectively distinguish the target from the background by exploiting polarization-sensitive characteristics.However,due to the absence of intrinsic polarized absorption properties of many materials,there is still a great challenge to develop the high-performance polarization-resolved photodetectors.Here,we report a van der Waals heterojunction(vdWH)ReSe_(2)/WSe_(2)photodetector,which performs a high responsivity of~0.28 A/W and a high detectivity of 1.1×10^(12)Jones under the illumination of 520 nm laser at room temperature.Remarkably,scanning photocurrent mapping(SPCM)measurements demonstrate the photoresponse of devices closely depend on the polarized angle of the incident light,indicating the effective polarized light detection.This work paves the way to develop high-performance polarization-resolved photodetectors based on two-dimensional(2D)materials.
基金supported by the National Natural Science Foundation of China(61804086)National Natural Science Foundation of Shandong Province(ZR2021MA033).
文摘Recently,van der Waals heterostructures(vdWHs)constructed by transition-metal dichalcogenides(TMDCs)have come under the research spotlight owing to their excellent capabilities,multiple functionalities,and innovative architecture for advanced optoelectronic devices.Herein,novel heterojunction photodetectors composed of monolayer molybdenum disulfide(MoS2)and few-layer rhenium selenide(ReSe_(2))are explored for ultra-fast and polarization detection.Owing to the enhanced light-matter interactions and type-II band alignment of the ReSe_(2)/MoS_(2) heterostructure,the photodetector exhibits impressive performances at 638 nm in terms of a high on/off ratio~104,large photoresponsivity~3.52 A/W,high specific detectivity~1011 Jones,and large 3 dB frequency of 65.7 kHz.In addition,ultrafast rise/decay times(5.0/9.1 ms)are obtained under pulsed incident light contributed to the built-in electric field at the heterointerface,demonstrating a result one or two orders of magnitude faster than the currently reported values of group VII-TMDCs based photodetectors.Beyond the conventional photodetection,this photodetector also displays polarization detection capability with sensitivity 1.35.Such Re-based vdWHs provide superior platforms for the realization of ultra-fast and polarization-sensitive photodetection in broadband spectrum.
