A novel way to extract the reaction plane dispersion by combining azimuthal distribu-tion constructed using the experimental measured reaction plane which contains reaction planedispersion and two-particle azimuthal c...A novel way to extract the reaction plane dispersion by combining azimuthal distribu-tion constructed using the experimental measured reaction plane which contains reaction planedispersion and two-particle azimuthal correlation which is free of reaction plane dispersion is de-scribed.This method is applied to the low energy fission reaction <sup>84</sup>Kr+<sup>27</sup>Al at 10.6 MeV/u forlight particles p and a with success.展开更多
The collective flow for <sup>64</sup>Zn+<sup>27</sup>Al system is measured at intermediate energyby using a 4π multidetector array in conjunction with an array of Si telescopes.Theevents have ...The collective flow for <sup>64</sup>Zn+<sup>27</sup>Al system is measured at intermediate energyby using a 4π multidetector array in conjunction with an array of Si telescopes.Theevents have been sorted versus the impact parameter by means of global variables.Three methods of reaction plane determination are compared:sphericity tensor method,transverse momentum analysis,and azimuthal correlation method.For this system,thetransverse momentum analysis method is the best one.展开更多
The Cooling Storage Ring external-target experiment(CEE)spectrometer is used to study the nuclear matter created in heavy-ion collisions at√sNN=2.1-2.4 GeV with the aim to reveal the quantum chromodynamics phase stru...The Cooling Storage Ring external-target experiment(CEE)spectrometer is used to study the nuclear matter created in heavy-ion collisions at√sNN=2.1-2.4 GeV with the aim to reveal the quantum chromodynamics phase structure in the high-baryon-density region.Collective flow is considered an effective probe for evaluating the properties of media during high-energy nuclear collisions.One of the main functions of the zero-degree calorimeter(ZDC),a subdetector system in the CEE,is to determine the reaction plane in heavy-ion collisions.This step is crucial for measuring the collective flow and other reaction-plane-related analyses.In this paper,we illustrate the procedures for event plane determination using the ZDC.Finally,isospin-dependent quantum molecular dynamics model-based predictions of the rapidity dependence of the directed and elliptical flows for p,d,t,3He,and 4He,produced in 2.1 GeV U+U collisions,are presented.展开更多
开发经济高效的析氧反应电催化剂对于推进可充电金属-空气电池和电解水技术的发展至关重要.一般来说,具有完整蜂窝结构的石墨碳基面是电化学惰性的,需要依赖缺陷或者掺杂结构诱导的电荷极化效应来提升催化活性.相比于基面,边缘位点具有...开发经济高效的析氧反应电催化剂对于推进可充电金属-空气电池和电解水技术的发展至关重要.一般来说,具有完整蜂窝结构的石墨碳基面是电化学惰性的,需要依赖缺陷或者掺杂结构诱导的电荷极化效应来提升催化活性.相比于基面,边缘位点具有特殊的局域电子态,为提升石墨碳电极的本征催化活性开辟了新的思路,然而其结构精准构筑目前仍面临极大挑战.本文以“人字形”多壁碳纳米管(H-MWCNTs)作为研究切入点,利用高温熔盐介质主导的插层剥离和截断效应,实现“边缘-平面位点”结构可控构筑,为实现高效电解水析氧反应(OER)提供了重要的结构基础.通过熔盐辅助热解方法可控制备了具有完全暴露的内外边缘平面的目标催化剂H-MWCNTs-MS,并研究其OER催化性能.在碱性介质中10 mA cm^(-2)电流密度所需过电位仅为236 mV,是目前报道的较好的非金属电催化剂.同时,H-MWCNTs-MS在10,50和100 mA cm^(-2)电流密度下均表现出较好的电化学稳定性.利用原位衰减全反射-表面增强红外吸收光谱(ATR-SEIRAS)技术研究了“边缘-平面位点”在OER过程中的结构重构过程,与理论计算分析的高能“边缘态”结果一致,并确定酮氧官能化位点为真实催化活性中心.理论计算结果表明,氧官能团修饰结构能够显著促进电荷的再分配,增强层间耦合作用,降低关键含氧中间体*OOH的形成能垒,加速OER反应动力学.此外,H-MWCNTs-MS的开放式结构极大程度提高了“边缘-平面位点”的利用率,减小的纳米管壁厚促进了层间电荷迁移,也是增强OER活性的关键要素.综上,精准构筑“边缘-平面位点”为开发高效石墨碳电极开辟了新的思路,通过原位谱学技术揭示边缘位点催化结构重构,能够进一步丰富研究者对于电催化协同效应的科学认识.展开更多
Au nanostructures were prepared on uniform Cu2O octahedra and rhombic dodecahedra via the galvanic replacement reaction between HAuCl 4 and Cu2O. The compositions and structures were studied by Scanning Electron Micro...Au nanostructures were prepared on uniform Cu2O octahedra and rhombic dodecahedra via the galvanic replacement reaction between HAuCl 4 and Cu2O. The compositions and structures were studied by Scanning Electron Microscope (SEM), Transmission Electron Microscope (TEM), High-Resolution Transmission Electron Microscope (HRTEM), X-Ray Diffraction (XRD), X-Ray Absorption Spectroscopy (XAS), X-ray Photoelectron Spectroscopy (XPS) and in-situ DRIFTS spectroscopy of CO adsorption. Different from the formation of Au-Cu alloys on Cu2O cubes by the galvanic replacement reaction (ChemNanoMat 2 (2016) 861-865), metallic Au particles and positively-charged Au clusters form on Cu2O octahedra and rhombic dodecahedra at very small Au loadings and only metallic Au particles form at large Au loadings. Metallic Au particles on Cu2O octahedra and rhombic dodecahedra are more active in catalyzing the liquid phase aerobic oxidation reaction of benzyl alcohol than positively-charged Au clusters. These results demonstrate an obvious morphology effect of Cu2O nanocrystals on the liquid-solid interfacial reactions and prove oxide morphology as an effective strategy to tune the surface reactivity and catalytic performance. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.展开更多
目的探讨腹横肌平面(TAP)阻滞复合全身麻醉在剖宫产麻醉镇痛中的应用效果。方法选取2019年9月至2020年9月于本院行择期剖宫产的100例孕妇作为研究对象,按照随机数字表法分为对照组与观察组,每组50例。两组均予以相同的麻醉诱导及后续麻...目的探讨腹横肌平面(TAP)阻滞复合全身麻醉在剖宫产麻醉镇痛中的应用效果。方法选取2019年9月至2020年9月于本院行择期剖宫产的100例孕妇作为研究对象,按照随机数字表法分为对照组与观察组,每组50例。两组均予以相同的麻醉诱导及后续麻醉镇痛方案,观察组于麻醉诱导前行超声引导下TAP阻滞,TAP双侧予以20 ml 0.375%罗哌卡因注射,比较两组手术情况、术中瑞芬太尼用量、术后48 h内自控静脉镇痛(PCIA)给药总量、曲马多补救镇痛情况、镇痛满意度评分、新生儿Apgar评分及术后不良反应情况。结果两组手术时间、术中出血量、自主呼吸恢复时间比较差异无统计学意义。观察组瑞芬太尼用量、PCIA给药总量均少于对照组,曲马多补救镇痛率低于对照组,镇痛满意度评分高于对照组,差异有统计学意义(P<0.05)。观察组新生儿1 min Apgar评分高于对照组,差异有统计学意义(P<0.05);两组5、10 min新生儿Apgar评分比较差异无统计学意义。两组头晕、嗜睡发生率比较差异无统计学意义;观察组术后恶心呕吐、皮肤瘙痒发生率均低于对照组,差异有统计学意义(P<0.05)。结论TAP阻滞复合全麻用于剖宫产术中,能减少术中瑞芬太尼用量,增强术后镇痛效果,减少不良反应发生。展开更多
基金The project supported in part by the National Natural Science Foundation of ChinaShanghai Science Technology Development Foundation
文摘A novel way to extract the reaction plane dispersion by combining azimuthal distribu-tion constructed using the experimental measured reaction plane which contains reaction planedispersion and two-particle azimuthal correlation which is free of reaction plane dispersion is de-scribed.This method is applied to the low energy fission reaction <sup>84</sup>Kr+<sup>27</sup>Al at 10.6 MeV/u forlight particles p and a with success.
文摘The collective flow for <sup>64</sup>Zn+<sup>27</sup>Al system is measured at intermediate energyby using a 4π multidetector array in conjunction with an array of Si telescopes.Theevents have been sorted versus the impact parameter by means of global variables.Three methods of reaction plane determination are compared:sphericity tensor method,transverse momentum analysis,and azimuthal correlation method.For this system,thetransverse momentum analysis method is the best one.
基金the National Key Research and Development Program of China(Nos.2022YFA1604900 and 2020YFE0202002)the National Natural Science Foundation of China(Nos.12175084,11890710,11890711,11927901)+1 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB34030000)Fundamental Research Funds for Central Universities(No.CCNU220N003).
文摘The Cooling Storage Ring external-target experiment(CEE)spectrometer is used to study the nuclear matter created in heavy-ion collisions at√sNN=2.1-2.4 GeV with the aim to reveal the quantum chromodynamics phase structure in the high-baryon-density region.Collective flow is considered an effective probe for evaluating the properties of media during high-energy nuclear collisions.One of the main functions of the zero-degree calorimeter(ZDC),a subdetector system in the CEE,is to determine the reaction plane in heavy-ion collisions.This step is crucial for measuring the collective flow and other reaction-plane-related analyses.In this paper,we illustrate the procedures for event plane determination using the ZDC.Finally,isospin-dependent quantum molecular dynamics model-based predictions of the rapidity dependence of the directed and elliptical flows for p,d,t,3He,and 4He,produced in 2.1 GeV U+U collisions,are presented.
文摘开发经济高效的析氧反应电催化剂对于推进可充电金属-空气电池和电解水技术的发展至关重要.一般来说,具有完整蜂窝结构的石墨碳基面是电化学惰性的,需要依赖缺陷或者掺杂结构诱导的电荷极化效应来提升催化活性.相比于基面,边缘位点具有特殊的局域电子态,为提升石墨碳电极的本征催化活性开辟了新的思路,然而其结构精准构筑目前仍面临极大挑战.本文以“人字形”多壁碳纳米管(H-MWCNTs)作为研究切入点,利用高温熔盐介质主导的插层剥离和截断效应,实现“边缘-平面位点”结构可控构筑,为实现高效电解水析氧反应(OER)提供了重要的结构基础.通过熔盐辅助热解方法可控制备了具有完全暴露的内外边缘平面的目标催化剂H-MWCNTs-MS,并研究其OER催化性能.在碱性介质中10 mA cm^(-2)电流密度所需过电位仅为236 mV,是目前报道的较好的非金属电催化剂.同时,H-MWCNTs-MS在10,50和100 mA cm^(-2)电流密度下均表现出较好的电化学稳定性.利用原位衰减全反射-表面增强红外吸收光谱(ATR-SEIRAS)技术研究了“边缘-平面位点”在OER过程中的结构重构过程,与理论计算分析的高能“边缘态”结果一致,并确定酮氧官能化位点为真实催化活性中心.理论计算结果表明,氧官能团修饰结构能够显著促进电荷的再分配,增强层间耦合作用,降低关键含氧中间体*OOH的形成能垒,加速OER反应动力学.此外,H-MWCNTs-MS的开放式结构极大程度提高了“边缘-平面位点”的利用率,减小的纳米管壁厚促进了层间电荷迁移,也是增强OER活性的关键要素.综上,精准构筑“边缘-平面位点”为开发高效石墨碳电极开辟了新的思路,通过原位谱学技术揭示边缘位点催化结构重构,能够进一步丰富研究者对于电催化协同效应的科学认识.
基金supported by the National Basic Research Program of China(2013CB933104)the National Natural Science Foundation of China(21525313,21173204,21373192,U1332113)+1 种基金MOE Fundamental Research Funds for the Central Universities(WK2060030017)Collaborative Innovation Center of Suzhou Nano Science and Technology
文摘Au nanostructures were prepared on uniform Cu2O octahedra and rhombic dodecahedra via the galvanic replacement reaction between HAuCl 4 and Cu2O. The compositions and structures were studied by Scanning Electron Microscope (SEM), Transmission Electron Microscope (TEM), High-Resolution Transmission Electron Microscope (HRTEM), X-Ray Diffraction (XRD), X-Ray Absorption Spectroscopy (XAS), X-ray Photoelectron Spectroscopy (XPS) and in-situ DRIFTS spectroscopy of CO adsorption. Different from the formation of Au-Cu alloys on Cu2O cubes by the galvanic replacement reaction (ChemNanoMat 2 (2016) 861-865), metallic Au particles and positively-charged Au clusters form on Cu2O octahedra and rhombic dodecahedra at very small Au loadings and only metallic Au particles form at large Au loadings. Metallic Au particles on Cu2O octahedra and rhombic dodecahedra are more active in catalyzing the liquid phase aerobic oxidation reaction of benzyl alcohol than positively-charged Au clusters. These results demonstrate an obvious morphology effect of Cu2O nanocrystals on the liquid-solid interfacial reactions and prove oxide morphology as an effective strategy to tune the surface reactivity and catalytic performance. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
文摘目的探讨腹横肌平面(TAP)阻滞复合全身麻醉在剖宫产麻醉镇痛中的应用效果。方法选取2019年9月至2020年9月于本院行择期剖宫产的100例孕妇作为研究对象,按照随机数字表法分为对照组与观察组,每组50例。两组均予以相同的麻醉诱导及后续麻醉镇痛方案,观察组于麻醉诱导前行超声引导下TAP阻滞,TAP双侧予以20 ml 0.375%罗哌卡因注射,比较两组手术情况、术中瑞芬太尼用量、术后48 h内自控静脉镇痛(PCIA)给药总量、曲马多补救镇痛情况、镇痛满意度评分、新生儿Apgar评分及术后不良反应情况。结果两组手术时间、术中出血量、自主呼吸恢复时间比较差异无统计学意义。观察组瑞芬太尼用量、PCIA给药总量均少于对照组,曲马多补救镇痛率低于对照组,镇痛满意度评分高于对照组,差异有统计学意义(P<0.05)。观察组新生儿1 min Apgar评分高于对照组,差异有统计学意义(P<0.05);两组5、10 min新生儿Apgar评分比较差异无统计学意义。两组头晕、嗜睡发生率比较差异无统计学意义;观察组术后恶心呕吐、皮肤瘙痒发生率均低于对照组,差异有统计学意义(P<0.05)。结论TAP阻滞复合全麻用于剖宫产术中,能减少术中瑞芬太尼用量,增强术后镇痛效果,减少不良反应发生。