A Probe into C-E Translation of Publicity Materials of Red Tourism in Hu.nan Province

Hunan Province is rich in red tourism resources, and many scenic spots in the region proudly echo the glory of China's revolutionary history. Publicity materials of red tourism in Hunan Province play the role of publicizing and promoting historical sites and places linked with China's revolutionary history. However, at present the C-E translation of publicity materials of red tourism in Hunan province is far from satisfaction. Reasonable application of eco-translatology in C-E translation of publicity materials of red tourism in Hunan Province will allow the translator to enjoy a much greater degree of flexibility in translating and produce appropriate translation which produce functionally the same effect on the target readers as the original on the readers.

Hydration kinetics of cementitious materials composed of red mud and coal gangue

To elucidate the intrinsic reaction mechanism of cementitious materials composed of red mud and coal gangue（RGC）, the hydration kinetics of these cementitious materials at 20°C was investigated on the basis of the Krstulovi？-Dabi？ model. An isothermal calorimeter was used to characterize the hydration heat evolution. The results show that the hydration of RGC is controlled by the processes of nucleation and crystal growth（NG）, interaction at phase boundaries（I）, and diffusion（D） in order, and the pozzolanic reactions of slag and compound-activated red mud-coal gangue are mainly controlled by the I process. Slag accelerates the clinker hydration during NG process, whereas the compound-activated red mud-coal gangue retards the hydration of RGC and the time required for I process increases with increasing dosage of red mud-coal gangue in RGC.

Durability and microstructure analysis of the road base material prepared from red mud and flue gas desulfurization fly ash

The present study aimed to investigate the durability and microstructure evolution of road base materials(RBM)prepared from red mud and flue gas desulfurization fly ash.The durability testing showed that the strength of RBM with the blast furnace slag addition of 1wt%,3wt%and 5wt%reached 3.81,4.87,and 5.84 MPa after 5 freezing–thawing(F–T)cycles and reached 5.21,5.75,and 6.98 MPa after 20 weting–drying(W–D)cycles,respectively.The results also indicated that hydration products were continuously formed even during W–D and F–T exposures,resulting in an increase of the strength and durability of RBM.The observed increase of macropores(>1μm)after F–T and W–D exposures suggested that the mechanism of RBM deterioration is pore enlargement due to cracks that develop inside their matrix.Moreover,the F–T exposure showed a greater negative effect on the durability of RBM compared to the W–D exposure.The leaching tests showed that sodium and heavy metals were solidified below the minimum requirement,which indicates that these wastes are suitable for use as a natural material replacement in road base construction.

Controlled low-strength material incorporating recycled fine aggregate from urban red brick based construction waste

Sixteen controlled low-strength material( CLSM)mixtures with various cement-to-sand( C/Sa) ratios and water-to-solid( W/So) ratios were prepared using recycled fine aggregate from urban red brick based construction waste.The fluidity and bleeding of the fresh CLSM mixtures were measured via the modified test methods, and the hardened CLSM mixtures were then molded to evaluate their compressive strength and durability. The results showthat the fluidity of the fresh CLSM mixtures is 105 to 227 mm with the corresponding bleeding rate of 3. 7% to 15. 5%, which increases with the increase in fluidity. After aging for 28 d,the compressive strength of the hardened CLSM mixtures reaches 1. 15 to 13. 96 M Pa, and their strength can be further enhanced with longer curing ages. Additionally, the strength increases with the increase of the C/Sa ratio, and decreases with the increase of the W/So ratio under the same curing age. Based on the obtained compressive strength, a fitting model for accurately predicting the compressive strength of the CLSM mixtures was established, which takes into account the above two independent variables( C/Sa and W/So ratios).M oreover, the durability of the hardened CLSM mixtures is enhanced for samples with higher C/Sa ratios.

Sustainable materials in Fujian vernacular residential architecture

Cases abound in Fujian province of applying sustainable materials in the construction of traditional residential buildings, which demonstrate the skills and creative techniques of local builders, reflecting their wisdom in molding and adapting to the environment. This paper probes into the utilization of locally available resources in Fujian traditional residential architecture from the perspective of the characteristics of "reduction, recycling and reuse" of sustainable materials, and puts forward the view that sustainability study of contemporary architecture should be approached from the relationship between man and environment and that inspiration can be drawn from the creative and innovative ideas of the folk residential builders.

Properties of Rapid Hardening Controlled Low Strength Material Made of Recycled Fine Aggregate from Urban Red Brick Construction Waste

In some cases of emergency backfill engineering projects, traditional backfill materials cannot meet the requirements of fast construction due to their long curing time. This study presents a new kind of rapid hardening controlled low strength material, which utilizes both rapid hardening sulphoaluminate cement and recycled fine aggregate from urban red brick construction waste. Totally, sixteen mixtures were prepared for the experiment with different cement-to-sand ratios and water-to-solid ratios. The flowability and bleeding rate of fresh mixture were measured to evaluate its workability, and the compressive strength of hardened mixture was tested to evaluate its rapid hardening and mechanical properties. Test results indicate that rapid hardening controlled low strength material containing recycled fine aggregate from urban red brick construction waste can achieve the desirable flowability, but the bleeding rate increases with the increase of flowability. In addition, 2-hour compressive strength can reach 0.08 - 0.12 MPa, and 4-hour compressive strength is 0.32 - 1.54 MPa, which can meet the requirements of emergency backfill construction. At last, based on the derived compressive strength, a fitting model for predicting compressive strength evolution of this new rapid hardening backfill material is developed, which fits accurately with these experimental data.

Revealing the Pressure-Induced Softening/Weakening Mechanism in Representative Covalent Materials

Diamond, cubic boron nitride(c-BN), silicon(Si), and germanium(Ge), as examples of typical strong covalent materials, have been extensively investigated in recent decades, owing to their fundamental importance in material science and industry. However, an in-depth analysis of the character of these materials' mechanical behaviors under harsh service environments, such as high pressure, has yet to be conducted. Based on several mechanical criteria, the effect of pressure on the mechanical properties of these materials is comprehensively investigated.It is demonstrated that, with respect to their intrinsic brittleness/ductile nature, all these materials exhibit ubiquitous pressure-enhanced ductility. By analyzing the strength variation under uniform deformation, together with the corresponding electronic structures, we reveal for the first time that the pressure-induced mechanical softening/weakening exhibits distinct characteristics between diamond and c-BN, owing to the differences in their abnormal charge-depletion evolution under applied strain, whereas a monotonous weakening phenomenon is observed in Si and Ge. Further investigation into dislocation-mediated plastic resistance indicates that the pressure-induced shuffle-set plane softening in diamond(c-BN), and weakening in Si(Ge), can be attributed to the reduction of antibonding states below the Fermi level, and an enhanced metallization, corresponding to the weakening of the bonds around the slipped plane with increasing pressure, respectively. These findings not only reveal the physical mechanism of pressure-induced softening/weakening in covalent materials, but also highlights the necessity of exploring strain-tunable electronic structures to emphasize the mechanical response in such covalent materials.

Effect of distortion degree on the hydration of red mud base cementitious material

The interaction of Si anions with Al sites during the hydration process was observed by NMR, IR and SEM to understand the reaction mechanism of the hydrates formation mixed with oil shale calcined at different temperatures. As the reaction progressed, the coordination of Al （Ⅳ, Ⅴ, and Ⅵ） changed almost completely to Ⅳ, when mixed with oil shale calcined at 700 ℃. However, when mixed with oil shale calcined at 400 ℃, some 6-coordination of Al still remained in the hydrates. Under the function of alkaline solutions, which were produced with the hydration of clinker, a certain amount of Si and Al atoms dissolved or hydrolyzed from aluminosilicate, formed geomonomers in solutions, and then polycondensed to form networks.

Synthesis and Characterization of a Red Clay Based New Composite Ceramic Material

In this study, a new composite ceramic material using a red clay matrix with different amount of clinker from the cement industry has been developed. The aim is to valorize some natural resources such as red clay and sub-products from the cement industry as clinker in order to develop new materials for industrial and/or catalytic uses. Raw materials were grounded in order to reduce the particle size and obtain a homogeneous slip. The samples were mixed and compressed into pellets and undergo a heat treatment up to 1100℃. Geotechnical characterization has been carried out. Firing proprieties (shrinkage, water absorption, and mechanical resistance to the inflection) were measured. The composition of the ceramic material was investigated by X-ray diffraction, XRF, SEM and EDS methods. The incorporation of clinker in the ceramic composite material up to 50 wt% exhibits good behaviors (physical and mechanical proprieties) and can be used as a ceramic product.

赤泥脱碱活化及在胶凝材料中的应用

总结了目前赤泥在脱碱、活化方面的研究现状,分析对比了各方法的优势以及存在的问题,综述了国内外赤泥在胶凝材料中的应用研究,在赤泥资源化应用方面具有积极引导意义。

含水率对红层泥岩填料刚度劣化特性及微观结构影响研究

为研究含水率对红层泥岩填料刚度劣化规律和微观结构的影响,开展了不同含水率下三轴不排水剪切试验、压汞试验和扫描电镜试验,基于能量守恒定律推导了填料刚度劣化与弹塑性应变能增量间的关系。结果表明:填料黏聚力随含水率增加而降低,内摩擦角则随含水率增加先增加后降低。填料结构损伤由应变能转化引起,从宏观上表现为刚度劣化。归一化刚度比值随塑性应变能增量占比增加而线性降低,随应力发展呈非线性衰减。以最优含水率为界,当试样在干侧时,填料有较好的荷载抵抗能力;湿侧填料荷载抵抗能力远低于干侧。损伤应力等值线与等含水率线构成上下界为对数曲线的状态面。填料孔隙分布在干侧为单峰形态,粒间接触较为紧密,结构稳定性好。在湿侧呈双峰结构,团聚体排列定向性程度较低。填料应在干侧压实填筑,推荐采用5%~7%作为填筑目标含水率。

广西大新红黏土工程地质特性及路基处治措施

研究目的:红黏土因其特殊的工程性质,容易引起边坡出现裂隙、垮塌、不均匀沉降等病害,对工程质量、安全、造价造成极大影响。本文对红黏土进行详细室内土工试验,分析研究红黏土的物理力学性特征,从而为红黏土边坡防护及填料利用提供相应的处治措施建议,以指导工程实践。研究结论:(1)该地区红黏土显示出高含水率、高饱和度、高孔隙比、高液限、高塑性、压缩性较小、黏聚力高、弱~中膨胀性的特征;(2)随深度增加,含水率、液限、孔隙比、液性指数、压缩系数逐渐增大,而黏聚力、压缩模量逐步降低,形成上硬下软的特征;(3)对红黏土路堑,提出采用“缓边坡、宽平台、固坡脚”的设计原则;(4)针对红黏土填料,提出根据击实后50 kPa下膨胀总率判定填料膨胀性,采取包边、加筋、设置垫层、无机结合料改良处治后用于路基填料;(5)本研究成果对广西红黏土地区勘察设计具有一定的参考价值。

共价有机框架材料的制备及其对水体中刚果红的吸附性能研究

为了降低水体中刚果红(CR)的污染水平,采用溶剂法在室温常压下合成了一种巯基修饰的共价有机框架材料(COFs-TFB),以不同的反应条件为考察对象进行吸附实验,研究其吸附CR的性能。通过现代化技术手段对所合成的材料进行表征。实验结果表明,COFs-TFB材料对CR的吸附速度快,适于在酸性条件下进行;COFs-TFB材料对CR的吸附表现出优先选择吸附性,且重复利用性较好;在CR初始浓度为900 mg/L时,对CR的饱和吸附量为2124.6 mg/g;对CR的吸附过程符合准二级动力学模型和Langmuir等温吸附线模型,为单层化学吸附过程。因此,合成的COFs-TFB材料在吸附水体中刚果红领域具有良好的应用前景。

红层泥岩填料的力学特性及本构模型研究

在红层泥岩地区进行道路工程施工时,考虑到材料短缺和成本问题,常常采用就地取材的方式作为路基填料。为了研究红层泥岩填料的适用性,选取甘肃省永登县某工点的风化红层泥岩填料为研究对象,在室内开展一系列三轴CU剪切试验,探究含水率、围压和压实度对应力-应变曲线、峰值(残余)强度、抗剪强度指标的影响,并对不同类型的应力-应变曲线,分别采用相应的模型进行拟合。研究结果表明:含水率、围压和压实度对其物理力学特性具有显著影响;对符合应变软化型规律的曲线,采用沈珠江的双曲线模型拟合的规律一般;对符合应变硬化型规律的曲线,采用Duncan-Chang模型拟合的规律较好。研究结果可以为甘肃省红层泥岩路基的病害处治与维修提供参考依据。

铟基配合物材料的刚果红吸附性能及其机理研究

含有机染料的废水会导致严重环境污染,有效去除废水中有机染料污染物的研究广受关注。本研究利用均苯四甲酸和四水合硝酸铟作为原料,通过直接沉淀法和溶剂热法成功组装了两个铟基配合物材料(In-CP#1和In-CP#2),并对其进行了表面形貌、红外光谱、X-射线粉末衍射、比表面积以及热重表征。同时,将两化合物作为吸附剂,系统研究了吸附时间和有机染料初始浓度对其吸附性能的影响及其吸附机理。结果表明,两化合物的吸附机理主要是化学作用,且吸附过程符合准二级动力学特征,但并不符合Langmuir单分子层吸附模型。

赤泥用于酸性含锰废水中锰的净化研究

采用还原焙烧-磁选预处理赤泥,得到非磁性物;非磁性物经煅烧、盐酸溶出后加入饱和偏铝酸钠聚合剂聚合后过滤、熟化制备聚合氯化铝(PAC)基液;使用该PAC基液,在沉降时间5 h、PAC基液与废水体积比1∶120、搅拌转速140 r/min、pH值8、反应温度30℃、聚丙烯酰胺(PAM)投加量20 mg/L条件下处理含锰酸性废水,处理后液中锰质量浓度由325.3 mg/L降至1.5 mg/L,锰去除率达99.5%,净化后液中锰质量浓度达到国家一级排放标准。

双羟基染料改性有色水性聚氨酯的制备与性能

为了探究双羟基染料不同引入方式对水性聚氨酯(WPU)乳液及其成膜性能的影响,采用异佛尔酮二异氰酸酯、聚四氢呋喃(PTMG)、2,2-二羟甲基丙酸和1,4-丁二醇(BDO)合成了WPU乳液。将酸性红87作为扩链剂部分替代BDO制备了有色化学共聚聚氨酯(ARWPUA-1~3)乳液;将酸性红87作为软段部分替代PTMG制备了有色化学共聚聚氨酯(ARWPUB-1~3)乳液;将酸性红87与WPU共混制备了WPU/AR。采用FTIR、1HNMR和UV-Vis对样品的结构进行了表征;考察了不同有色WPU的贮存稳定性、耐溶剂性、颜色特征值、耐干/湿摩擦色牢度以及力学性能,并对其进行了分子动力学模拟。结果表明,由n(酸性红87)∶n(BDO)=1∶4制备的ARWPUA-2具有优异的贮存稳定性;在不同溶剂中均不会发生溶解脱色现象;具有良好的耐干/湿摩擦色牢度和较高的力学性能,其拉伸强度22.6MPa,断裂伸长率为810%。

赤泥基路用材料中主要金属的浸出行为及其路用固化效果

赤泥高碱高氟和多金属含量等污染特性会影响其资源化利用。针对赤泥路用存在潜在环境风险的主要金属,重点研究赤泥基路用材料制备过程对主要金属污染物的浸出环境行为与固化效果的影响。结果表明,不同赤泥基路用材料金属总量大小与浸出含量水平受铝土矿产地、氧化铝生产工艺以及制备过程添加的材料等的影响,赤泥基路用材料的制备过程对Al、As、V、Se、Mo有显著固化效果,使其浸出含量分别降低了10.97%~75.77%、97.84%~99.90%、98.16%~100.00%、90.62%~99.34%、61.60%~87.66%,但对Na、Fe、K、Ba、Cr的固化效果不明显反而会使其浸出含量增加,应注重材料制备过程的质量控制。在实际道路应用过程中长期风险评估应重点关注但不限于赤泥基路用材料中Na、总Cr、Cr^(6+)、V、Se、Mo的迁移转化等环境行为。

活化赤泥基胶凝材料的抗冻融性能研究

赤泥资源化利用对氧化铝行业可持续发展和环境保护具有重要意义。本文以赤泥和热活化赤泥为主要原料与钢渣等多种固废协同制备赤泥基胶凝材料,并对其抗冻融性能进行了研究。分别对养护14和28 d的胶凝材料试样进行冻融试验,用万能试验机、XRD、SEM、工业CT等检测方法对试样冻融前后的强度、物相、显微结构、孔隙率等进行表征,并对冻融损伤机理进行了探究。结果表明,赤泥基胶凝材料冻融前后的质量损失、强度损失、显微结构差异显著。其中,赤泥-普通硅酸盐水泥胶凝材料较其他赤泥基胶凝材料的抗冻性能优异,其养护14 d试件冻融前后的质量损失和强度损失分别为23.68%和50.75%;用热活化赤泥制备的赤泥-钢渣胶凝材料冻融后的质量损失率较冻融前降低了16.30%。

赤泥-聚丙烯酸-羧甲基纤维素水凝胶对水中Pb^(2+)吸附研究

为解决环境中重金属铅的污染问题,并对氧化铝冶炼中产生的工业固体废弃物赤泥进行妥当处置,本文以赤泥为原材料,通过聚合交联反应引入羧甲基纤维素钠(CMC)和丙烯酸(AA),制备得到吸附性能好、稳定性强和回收利用率高的赤泥-聚丙烯酸-羧甲基纤维素(RMAAC)复合水凝胶材料,将其作为吸附剂应用于水中Pb2+的吸附去除。结果表明,RMAAC对Pb2+的吸附主要归因于单分子层化学吸附,同时存在物理吸附,涉及的吸附机理有离子交换、官能团络合、阳离子-π和配位螯合作用。Langmuir模型计算得到的最大吸附量为730.16 mg/g,在pH为3~6时均具有较好的吸附性能。在多元重金属离子污染中,RMAAC展现出对Pb2+较高的选择性吸附能力。