Evaluating the biosignature potential of ammonium in Proterozoic red beds and implications for the search for life on Mars

Over the past two decades,it has become increasingly apparent that early Mars may once have been warmer,wetter and more habitable for microbial life than it is today,which has spurred discussions about potential biosignatures that may be preserved in Martian sediments.An impediment to this line of research is the pervasive oxidation of Mars’surface due to photochemical oxidants that have likely destroyed remnants of organic matter.Here,we investigate whether nitrogen(N)transferred from biomass to phyllosilicate minerals during diagenesis can be preserved in oxidized mudrocks.We investigate two sequences of terrestrial Proterozoic red beds,namely the Sibley Group(1.4 Ga)in Canada and the Stoer Group(1.2 Ga)in Scotland,and we find enrichments in authigenic N in the range of several tens of ppm in both units.The highest concentrations(ca.100 ppm on average)are found in the most desiccated red beds of the Stoer Group,concurrent with enrichments in potassium(K).We discuss similarities and differences between the two sets of rocks with regards to salinity,pH,biological productivity and K-metasomatism,and we conclude that the ideal mechanism for the preservation of biogenic N in red beds may be in-situ release of ammonium from microbial mats into the clay substrate,possibly facilitated by early diagenetic,biologically induced illitization.Illite and smectite have been observed on Mars,and experiments suggest that Martian waters contained moderate amounts of dissolved K.Hence,it is conceivable that a similar K and N enrichment process could have occurred as to what we document for the Proterozoic,preserving evidence of life that may have survived to the modern day.

Planktic Foraminiferal Biostratigraphy of the Cretaceous Oceanic Red Beds in Kangmar,Southern Tibet,China

The planktic foraminifera of the Chuangde Formation （Upper Cretaceous Oceanic Red Beds, CORBs） as exposed at Tianbadong section, Kangmar, southern Tibet has been firstly studied for a detailed for a detailed biostratigraphy elaboration. A rich and well-preserved planktic foraminifera were recovered from the Chuangde Formation of the Tianbadong section and the Globotruncanita elevata, Globotruncana ventricosa, Radotruncana calcarata, Globotruncanella havanensis, Globotruncana aegyptiaca, Gansserina gansseri and Abathomphalus mayaroensis zones have been recognized. The planktic foraminiferal assemblage points to an early Campanian to Maastrichitian age for the CORBs of the eastern North Tethyan Himalayan sub-belt, which also provides a better understanding of the shifting progress of the Indian Plate to the north and the evolution of the Neotethyan ocean. The lithostratigraphy of the Chuangde Formation of the Tianbadong section comprises two lithological sequences observed in ascending succession： a lower unit （the Shale Member） mainly composed of purple （cherry-red, violet-red） shales with interbedded siltstones and siliceous rocks; and an upper unit （the Limestone Member） of variegated limestones. The strata of the Chuangde Formation in the Tianbadong section are similar to CORBs in other parts of the northern Tethyan Himalaya area of Asia （Gyangze, Sa＇gya, Sangdanlin, northern Zanskar, etc.）. The fossil contents of the Chuangde Formation in the sections （CORBs） studied provide a means of correlation with the zonation schemes for those of the northern Tethyan Himalayan sub-belt and the Upper Cretaceous of the southern Tethyan Himalayan sub-belt. Paleogeographic reconstruction for the Late Cretaceous indicates that the Upper Cretaceous Chuangde Formation （CORBs） and correlatable strata in northern Zanskar were representative of slope to basinal deposits, which were situated in the northern Tethyan Belt. Correlatable Cretaceous strata in Spiti and Gamba situated in the southern Tethyan Belt in contrast were deposited in shelf environments along the Tethyan Himalayan passive margin. CORBs are most likely formed by the oxidation of Fe（II）-enriched, anoxic deep ocean water near the chemocline that separated the oxic oceanic surface from the anoxic.

Burial Records of Reactive Iron in Cretaceous Black Shales and Oceanic Red Beds from Southern Tibet

One of the new directions in the field of Cretaceous research is to elucidate the mechanism of the sedimentary transition from the Cretaceous black shales to oceanic red beds. A chemical sequential extraction method was applied to these two types of rocks from southern Tibet to investigate the burial records of reactive iron. Results indicate that carbonate-associated iron and pyrite are relatively enriched in the black shales, but depleted or absent in red beds. The main feature of the reactive iron in the red beds is relative enrichment of iron oxides （largely hematite）, which occurred during syn-depostion or early diagenesis. The ratio between iron oxides and the total iron indicates an oxygen-enriched environment for red bed deposition. A comparison between the reactive iron burial records and proxies of paleo-productivity suggests that paleo-productivity decreases when the ratio between iron oxides and the total iron increases in the red beds. This phenomenon could imply that the relationship between marine redox and productivity might be one of the reasons for the sedimentary transition from Cretaceous black shale to oceanic red bed deposition.

Response of Reactive Phosphorus Burial to the Sedimentary Transition from Cretaceous Black Shales to Oceanic Red Beds in Southern Tibet

The mechanism of sedimentary transition from the Cretaceous black shales to the oceanic red beds is a new and important direction of Cretaceous research. Chemical sequential extraction is applied to study the burial records of reactive phosphorus in the black shale of the Gyabula Formation and oceanic red beds of the Chuangde Formation, Southern Tibet. Results indicate that the principal reactive phosphorus species is the authigenic and carbonate-associated phosphorus （CAP） in the Gyabula Formation and iron oxides-associated phosphorus （FeP） in the Chuangde Formation which accounts for more than half of their own total phosphorus content. While the authigenic and carbonate-associated phosphorus （CAP） is almost equal in the two Formations; the iron oxidesassociated phosphorus is about 1.6 times higher in the Chuangde Formation than that in the Gyabula Formation resulting in a higher content of the total phosphorus in the Chuangde Formation. According to the observations on the marine phosphorus cyde in Modern Ocean, it is found that preferential burial and regeneration of reactive phosphorus corresponds to highly oxic and reducing conditions, respectively, leading to the different distribution of phosphorus in these two distinct type of marine sediments. It is the redox-sensitive behavior of phosphorus cycle to the different redox conditions in the ocean and the controlling effects of phosphorus to the marine production that stimulate the local sedimentary transition from the Cretaceous black shale to the oceanic red beds.

Cretaceous Oceanic Red Beds:Distribution,Lithostratigraphy and Paleoenvironments

Cretaceous oceanic red beds （CORBs） represented by red shales and marls, were deposited during the Cretaceous and early Paleocene, predominantly in the Tethyan realm, in lower slope and abyssal basin environments. Detailed studies of CORBs are rare; therefore, we compiled CORBs data from deep sea ocean drilling cores and outcrops of Cretaceous rocks subaerially exposed in southern Europe, northwestern Germany, Asia and New Zealand. In the Tethyan realm, CORBs mainly consist of reddish or pink shales, limestones and marlstones. By contrast, marlstones and chalks are rare in deep-ocean drilling cores. Upper Cretaceous marine sediments in cores from the Atlantic Ocean are predominantly various shades of brown, reddish brown, yellowish brown and pale brown in color. A few red, pink, yellow and orange Cretaceous sediments are also present. The commonest age of CORBs is early Campanian to Maastrichtian, with the onset mostly of oxic deposition often after Oceanic Anoxic Events （OAEs）, during the early Aptian, late Albian-early Turonian and Campanian. This suggests an indicated and previously not recognized relationship between OAEs, black shales deposition and CORBs. CORBs even though globally distributed, are most common in the North Atlantic and Tethyan realms, in low to mid latitudes of the northern hemisphere; in the South Atlantic and Indian Ocean in the mid to high latitudes of the southern hemisphere; and are less frequent in the central Pacific Ocean. Their widespread occurrence during the late Cretaceous might have been the result of establishing a connection for deep oceanic current circulation between the Pacific and the evolving connection between South and North Atlantic and changes in oceanic basins ventilation.

Identifying the spatiotemporal characteristics of individual red bed landslides: a case study in Western Yunnan, China

Strata in red bed areas have typical characteristics of soft-hard interbedding and high sensitivity to water. Under the comprehensive action of internal stratigraphic structure and external hydrological factors, red bed landslides have highly complex spatiotemporal characteristics, presenting significant challenges to the prevention and control of landslide disasters in red bed areas, especially for slope and tunnel engineering projects. In this study, we applied an interdisciplinary approach combining small baseline subset interferometric synthetic aperture radar(SBAS-InSAR), deep displacement monitoring, and engineering geological surveying to identify the deformation mechanisms and spatiotemporal characteristics of the Abi landslide, an individual landslide that occurred in the red bed area of Western Yunnan, China. Surface deformation time series indicated that a basic deformation range developed by March 2020. Based on In SAR results and engineering geological analysis, the landslide surface could be divided into three zones: an upper sliding zone(US), a lower uplifted zone(LU), and a toe zone(Toe). LU was affected by the structure of the sliding bed with variable inclination. Using deep displacement curves combined with the geological profile, a set of sliding surfaces were identified between different lithology. The groundwater level standardization index(GLSI) and deformation normalization index(DNI) showed different quadratic relationships between US and LU. Verification using the Pearson correlation analysis shows that the correlation coefficients between model calculated results and measured data are 0.7933 and 0.7577, respectively, indicating that the DNI-GLSI models are applicable. A fast and short-lived deformation sub stage(ID-Fast) in the initial deformation stage was observed, and ID-Fast was driven by concentrated rainfall.

Discovery of Pseudofrenelopsis gansuensis from the Lower Cretaceous of Wangqing,Jilin Province,and Its Significance in Correlation of Cretaceous Red Beds in China

New data from abundant vegetative shoots and cuticular analysis are provided for the Cretaceous cheirolepidiaceous conifer Pseudofrenelopsis gansuensis Deng, Yang et Lu. The material was found from a new locality of the Lower Cretaceous strata in the Luozigou Basin, Wangqing, Jilin Province, northeastern China. Pseudofrenelopsis is a common plant in the Dalazi Formation of the Yanji Basin about 150 km from Wangqing, but there exists different species, Pseudofrenelopsis dalatzensis only. Both P. dalatzensis and P. gansuensis have been recorded from the Lower Cretaceous of Jiuquan, Gansu Province, but they are in different stratigraphic horizons. The Lower Cretaceous plant-bearing strata in Luozigou have used to correlate with the Dalazi Formation of the Yanji Basin. The discovery of P. gansuensis, which is lower in horizon than P. dalatzensis in Jiuquan, may indicate that they are also different in horizon in Jilin. Cheirolepidiaceous conifers are among the few fossils of red beds of the Early Cretaceous in China. The present discovery of Pseudofrenelopsis gansuensis provides important evidence for classification, correlation and determination of geological ages of the Early Cretaceous non-marine red deposits of the two separate basins in remote areas of North China.

A Preliminary Study on the Red Beds in the Northern Heyuan Basin, Guangdong Province, China

The red beds of the northern Heyuan Basin （Guangdong Province, China） are more than 4,000 m thick. Based on the lithological characters, in ascending order these beds are divided into the Dafeng Formation, Zhutian Formation, and Zhenshui Formation of the Nanxiong Group, Shanghu Formation and Danxia Formation. The Nanxiong Group with relatively mature coarse clastic rocks attains about 2940 m in thickness. The Dafeng Formation is 837 m thick, consisting of conglomerates and sandy conglomerates; the Zhutian Formation, which is 1.200 m thick, consists of purplish red sandstone with gravels, poorly sorted sandstone, feldspathic quartzose sandstone banded granular conglomerate, siltstone, and sandy mudstone. The Zhutian Formation is rich in calcareous concretions. Heyuannia （Oviraptoridae） and turtle fossils were found in this formation. The Zhenshui Formation deposited to a thickness of 900 m consists of coarse sediments, including granular conglomerate, and gravelly sandstone with well developed cross-beddings; the Shanghu Formation, which is 820 m thick, consists of purplish red granular conglomerate coarse sandstone intercalated with fine si^tstone; the Danxia Formation characterized by the Danxia ~andform is composed of coarse c^astic gravels and sandy gravels. The lower part of the Nanxiong Group whence dinosaur eggs and derived oviraptorosaurs come, belongs to the Late Cretaceous. No fossils are found in the Shanghu Formation or the Danxia Formation, but their stratigraphic order of superposition on the Nanxiong Group clearly shows their younger age.

Variation on Foraminiferal Composition in Cretaceous Black-Gray-Red Bed Sequence of Southern Tibet, China

An Upper Cretaceous black-gray-red bed sequence was deposited in the Tethys-Himalayan Sea where abundant foraminifera,especially planktons,were yielded. In the shallow shelf to the upper slope on the north margin of Indian plate was recorded an extinction-recovery-radiation cycle of foraminiferal fauna highly sensitive to paleoceanographical changes. The black unit, consisting of the Late Cenomanian-earliest Turonian beds, displays a major extinction, with keeled planktonic and many benthic species as the principal victims at the end of the Cenomanian when existed only low diversity, surface water-dwelling foraminifera. The gray unit spans a long-term recovery interval from the Turonian to the early Santonian with keeled planktonic foraminifera returning stepwise to the water column. The planktonic biota in the red unit, extremely abundant, indicate a biotic radiation during the Late Santonian and the Early Campanian, implying that the high oxygen levels had returned to all the oceanic depth levels, and that the water stratification disappeared, followed by the radiation of all depth-dwellers. The variation on foraminiferal faunas from the whole sequence refers to the extreme warm climate that appeared in the Middle Cretaceous and to the declined temperature toward the late epoch. Substantial deposits for this warming and cooling zones represent the black shales in the Middle Cretaceous and the red beds in the later period of the southern Tibet. The change in the foraminiferal composition corresponded to the formation of dysaerobic facies and to the development of high-oxidized circumstances.

Magnetostratieraphy of the Red Beds in the Hengyang Basin

This paper discusses the Cretaceous-Tertiary magnetic polarity sequence of the the Hengyang Basin on the basis of magnetostratigraphic study. The age of each stratigraphic unit has been determined with the magnetic polarity time scale combined with 39Ar/40Ar dating, thus providing evidence for determining the geological ages of different formations. The authors assign the age of the Dongjing Formation of the Hengyang Basin to Early Cretaceous, the Shenhuangshan Formation to Early-Late Cretaceous, the Daijiaping Formation to Late Cretaceous, and the Dongtang and Xialiushi formations to Palaeocene.

Field, Mega- and Microscopic Description of the Volcaniclastic Red Beds and the Associated Scoriaceous Basalt of Wadi Al Roaian, Ablah Area, Assir Terrain

The study area is located in the entrance of Wadi Girshah in Ablah area, Assir terrain, southwestern Saudi Arabia. The present study aims to shed light on the field, mega- and microscopic description of the volcaniclastic red beds and the associated scoriaceous basalts of Wadi Al Roaian. It is based mainly up on the field works augmented by petrographic description. The present study revealed that, the succession of the upper part of Girshah Formation comprises three main horizons: 1) lower unit of epidotized and silicified basaltic and andesitic tuffs;2) middle unit of volcaniclastic red beds-scoriaceous basalts of successive cycles (each of these cycles begins by reddish tuffaceous mudstone and sandstone and is terminated by the calcite-bearing scoriaceous basalt). This unit indicated the deposition in lacustrine environments and the red iron oxyhydroxides minerals were formed either by the direct hematitization of the deposited tuffs or by the diagenetic hematitization of the green clays formed instead of the precursor tuffaceous materials;3) upper scoriaceous basalt unit composed from hematitized and calcitized basalt. The unit was formed by basic volcanic eruptions in subaerial condition which was predominated by the formation of calcium carbonate lakes associated with the progressive and subsequent calcitization of the Ca-plagioclase minerals of the basalt and the associated glassy tuffaceous material. The scoriaceous basalts of Wadi Al Roaian area represent subaerial basic volcanic eruption in continental situation and are associated with subsequent events of mineral alteration and formation of secondary minerals i.e. calcite, hematite and goethite.

Mesozoic “Red Beds” and its Evolution in the Hefei Basin

The Hefei Basin is the largest basin in the North China landmass with complete and well-preserved Mesozoic and Cenozoic strata. In the basin there developed a suite of extremely thick ＂red beds＂ in the Mesozoic. Owing to complex evolution processes and a lack of paleontological traces, there have been controversies regarding the division and correlation of this suite of red beds. Based on results obtained in recent years in drilling, seismic and surface geological investigations and in consideration of relationships between seismic sequences and regional tectonic events, as well as evidence in paleontology, petrology and isotopic dating, this paper preliminarily puts forward the following ideas about the sequence stratigraphic framework of the continental ＂red beds＂ in the Hefei Basin. （1） The Zhougongshan Formation and the Yuantongshan Formation have similar lithologic, geophysical and paleontological characteristics, so we incorporate them into a single formation, called the Yuantongshan Formation, and the original Zhougongshan and Yuantongshan Formations are regarded as the upper and the lower parts of the newly defined Yuantongshan Formation. Its age is the Middle Jurassic; （2） the Zhuxiang Formation belongs to the Upper Jurassic Series and （3） the age of the Xiangdaopu Formation is the Lower Cretaceous. Furthermore, signatures of depositional evolution are analyzed in the paper based on features of seismic reflection, outcrops and drilling data. The Early and Middle Jurassic is characterized by a foreland basin, which is influenced mainly by uplift and longitudinal compression of the Dabieshan Mountains; the Lower Jurassic System has a relatively small depositional area; the Middle Jurassic strata are distributed extensively over the whole basin, marking the summit of basin development; a flexure basin is characteristic of the Late Jurassic, manifesting a joint effect of the Dabieshan and Zhangbaling Mountains with the former being more significant. In the Early Cretaceous, the Xiangdaopu Formation was distributed in the Daqiao depression, evidently affected by extension of the Tanlu fault; in the Late Cretaceous, the Hefei Basin was subjected to dismembering and the Zhangqiao Formation was distributed in the east-west direction along the downthrown side of the fault.

Land degradation and management of red beds in China:Two case studies

Red beds cover approximately 9.5%of China,and are home to approximately 144 million people.In total,83%of these lands are distributed in humid regions making it an important part of research on red bed soil erosion in China in these areas.This paper presents the main types of land degradation in red bed landscapes and the status of current soil erosion in a typical red bed basin,the Nanxiong Basin located in the north of Guangdong Province,China,and establishes the connection between management strategies and regional economic development in humid red bed regions of China.The soil erosive modulus was calculated in the Nanxiong Basin by using RUSLE(The Revised Universal Soil Loss Equation).The results of overlapping analyses demonstrated that appropriate measures,such as the Return Farmland to Forests initiative,should be taken at the junction of central red bed areas and mountainous areas in order to mitigate current soil erosion.Two examples are presented to demonstrate this:the tourism development in Mt.Danxiashan,a noted scenic mountainous area near Nanxiong Basin,and the land degradation mitigation in the Nanxiong Basin.Both examples promote local economic growth while simultaneously protecting the environment.A‘stakeholder'strategy is pursued at Mt.Danxiashan,which can help residents to understand their positive effects on the environment as well as increase their income.The second example,in Nanxiong City,showcases how local farmers became stakeholders by implementing contract responsibility and self-support systems for economic forests and terraced land in the 1980s.

THE ANALYSIS METHODOLOGY OF POLLEN FROM THE MESOZOIC—CENOZOIC RED BEDS IN NORTHERN TIBET

A group of red interbedded sandstone, siltstone and clay\|stone occur in the inland of northern Tibet. During the last 50 years, a lot of researches have been done at this group of beds along the Qinghai\|Xizang highway in the Kekexili area.. According to the lithological characters, the strata have been divided into tow parts, the lower part named as the Feng huoshan group, and the upper part the Yaxicuo group. It is obscure to the age of the strata. For example, Yi jixiang et al. (1990) put them in early Pliocene in the light of the microfossils which they found at the foot of Feng huoshan mountain. The fossils include (1) Charophyta: Rhabdochara? sp ., Peckichara subsphecrica?, Cyrogoniae; (2) Ostracoda: Cypris sp .; (3) Gastropod: Sinoplanorbis sp ., Amnicola sp ., Bithynia sp .; and (4) Sporopollen: Tricoporopollenites nactonodus ?, Polypodiceoisporites, Cyathidites, Schizosporis, Pediastrum. Based on different species of Charophyta, Ostracoda, Gastropod, Bivalve, Sporopollen, Zhang Yifu et al. (1994) refer the strata to Cretaceous. The lower abundance of the fossils from previous research gave lower precision of fossil identification. Thus, the age of the strata was confusion.

Formation Mechanism of Reduction Spheroids with Dark Cores in Cretaceous Red Beds in Jiaolai Basin, China

Red beds are not entirely red sometimes, in which grey-green spheroids or irregular spots can be found. However, the formation mechanism of grey-green spheroids or irregular spots in red beds is not clear so far. Samples taken from well JK1 in Jiaozhou area of Jiaolai Basin displayed that the reduction spheroids have more Vanadium (V) element, less TFe3O4 and Lead (Pb) element, almost the same content of other elements such as FeO and so on, comparing the red parts of the samples. The existence of organisms can explain the existence of green reductive spheres in the red beds formed under the oxidation environment.

Tracking shallow marine red beds through geological time as exemplified by the lower Telychian (Silurian) in the Upper Yangtze Region,South China

Marine red beds occur frequently in China through geological time.Despite their complex environments,the red beds are found in three depositional settings:1) oceanic,deep water,as in the Upper Cretaceous of southern Tibet;2) outer shelf,deeper water,as in the Lower-Middle Ordovician of South China;and 3) inner shelf,shallow water,as in the Silurian and Triassic in South China.The Silurian marine red beds are recurrent in the lower Telychian,upper Telychian,and upper Ludlow.This paper is to document the marine nature of the lower Telychian red beds (LRBs) in the Upper Yangtze Region and to discuss the spatial and temporal distribution of the LRBs and their depositional environments.The LRBs are best developed on the north side of the Cathaysian Oldland,which can be interpreted as the source area.It is inferred that they were deposited during a marine regression,characterized by the lack of upwelling,low nutrition and organic productivity with a decrease of biodiversity and a high rate of sedimentation.The iron-rich sediments may have been transported by rivers on the oldland into the Upper Yangtze Sea,as rates of deposition were rapid enough to counteract normal reducing effect around sediment-water interface.The LRBs are different from the off-shore,deeper water red beds of lower Telychian in Avalonia and Baltica and further from the oceanic,deep water red beds of Upper Cretaceous in southern Tibet chiefly in palaeogeographic settings,biotic assemblages and marine environments.

Paleosols in an outcrop of red beds from the Upper Cretaceous Yaojia Formation,southern Songliao Basin, Jilin Province, NE China

Paleosols in an outcrop of fluvial–lacustrine red beds have been recognized in the Upper Cretaceous Yaojia Formation in southern Songliao Basin, Songyuan City, Jilin Province, NE China. They are recognized in the field by pedogenic features, including root traces and burrows, soil horizons and soil structures. Root traces are remnants of small herbaceous plants, elongating and branching downwards in the red paleosols. They are filled by calcite,analcime, and clay minerals in spaces created by the decay of the plant roots. Burrows are found near the root traces with backfilled cells made by soil-dwelling insects. Soil horizons include calcic horizons(Bk horizon) with continuous calcareous layers, argillic horizons(Bt horizon) with clay films and dark brown to black iron-manganese cutans, vertic horizons(Bw horizon) with slickensided claystone, and deformed soil structure and gleyed horizons(Bg horizon) with mottles and reticulate mottles. Soil structures of the paleosols include pseudo-anticlinal structures,subangular blocky structures, and angular blocky structures. The micro-pedogenesis characteristics are also observed, including micrite pedogenic minerals and clay skins. Based on the pedogenic features above, paleosols types including Aridisol, Alfisol, and Vertisol are interpreted in the red beds of the Yaojia Formation. Forming in the Late Cretaceous, the paleosols can provide more details about the seasonal climate conditions and terrestrial sedimentary system in lacustrine basin.

Age of the Silurian Lower Red Beds in South China:Stratigraphical Evidence from the Sanbaiti Section

The age of the Silurian Lower Red Beds in the Upper Yangtze region remains debatable.Twenty-four samples were collected for conodont biostratigraphical studies from the Paiyunan Formation in the Sanbaiti Section,Huaying,Sichuan Province.The conodont fauna from the Paiyunan Formation,together with the graptolites from the underlying Lungmachi Formation,indicates that the Lower Red Beds at Sanbaiti correspond to the lower Telychian.Comparative analysis indicates that most exposures of the Lower Red Beds in the Upper Yangtze region can be assigned,in general,to the Telychian Stage,except for several localities,where the Lower Red Beds can be roughly dated as an interval between the upper Aeronian and lower Telychian.

Clay mineral assemblages of the oceanic red beds in the northern South China Sea and their responses to the Middle Miocene Climate Transition

The Middle Miocene Climate Transition(MMCT,~14 Ma)is the largest cooling event in the Cenozoic“Coolhouse”,which significantly impacts the global chemical weathering pattern.In this paper,the responses of the MMCT global cooling event in the deep South China Sea were studied by clay mineral assemblages analysis of the oceanic red beds(ORB)at International Ocean Discovery Program(IODP)Expedition 368 Site U1502.The results show that the clay mineral assemblages of the ORB at Site U1502 are mainly composed of smectite(56–88%),illite(7–29%),and kaolinite(6–20%),without chlorite.The contents of these clay minerals and illite crystallinity show a four-stage variation pattern during early-middle Miocene(22.8–10.8 Ma).Smectite decreased from average 81%during 22.8–16.2 Ma and 16.2–14.4 Ma to average 67%during 13.8–10.8 Ma,with a rapid decrease of~14%during 14.4–13.8 Ma.On the contrary,illite and kaolinite increased rapidly by~8%and~6%,respectively,during 14.4–13.8 Ma.Illite crystallinity increased from average 0.18°Δ2θduring 22.8–16.2 Ma to average 0.19°Δ2θduring 16.2–14.4 Ma,and then decreased rapidly by~0.02°Δ2θduring 14.4–13.8 Ma.The provenance analysis of clay minerals shows that illite and kaolinite mainly originated from South China landmass due to physical erosion,while smectite mainly came from the Luzon arc as the product of chemical weathering.Therefore,smectite/illite ratio and illite crystallinity are used as proxies of chemical weathering intensity in the early-middle Miocene.High values of the ratio and the crystallinity represent the enhanced chemical weathering,whereas low values indicate the weakened chemical weathering or the strengthened physical erosion process.The smectite/illite ratio and illite crystallinity both decreased rapidly during 14.4–13.8 Ma,indicating the chemical weathering in the surrounding area of the South China Sea weakened rapidly,which we believe is the result of the MMCT event forcing.In addition,their values increased slightly during 16.2–14.4 Ma,which is in response to the relatively enhanced chemical weathering during the Middle Miocene Climate Optimum(MMCO).The variation pattern of clay mineral assemblages of the early-middle Miocene ORB in the South China Sea and its rapid transformation during the MMCT reveal that the Cenozoic cooling played a specific role in controlling the chemical weathering of the Earth’s surface.

Upper Cretaceous oceanic red beds in southern Tibet:Lithofacies,environments and colour origin

Application of mineralogy, geochemistry, sedimentary petrology, and sedimentology methods result in better understanding of the genesis and paleoenvironmens of the Upper Cretaceous oceanic red beds exposed in southern Tibet. The red beds comprise the Chungde Formation. Nine lithofacies recognized within this formation are: red foraminiferal packstone/grainstone, red microfos- sils wackestone, red marlstone with microfossils, red marlstone, red to variegated floatstone and rud- stone (debris flow), red shale, red radiolarite, red chert with radiolaria, and red chert. Sedimentary structures and textures, microfossils, and carbonate content show that the Chuangde Fm was depos- ited near the base of a continental slope in a deep oceanic basin environment, with the basin floor below the carbonate compensation depth (CCD). Red marlstones and limestones intercalated within red shales represent slides and slumps from the upper part of the continental margin. Debris flow and turbidity deposits consist of volcaniclastic, fossilliferous rudstone and floatstone, and very thin cal- careous mudstone, intercalated with red shales. The Upper Cretaceous oceanic red beds in southern Tibet are characterized by high Fe2O3, low FeO, which indicates an oxic diagenetic environment, resulting in precipitation of hematite. The latter occurs as finely, disseminated ferric oxide giving the red color to the rocks. It is concluded that the red beds in southern Tibet were deposited under highly oxygenated bottom conditions in the deep ocean basin. Such conditions not only occurred in a deep ocean basin as indicated by the occurrence of pelagic red shale deposited below the CCD, but also extended up the continental margin as indicated by the presence of red colored marlstones and limestones embedded in the Chuangde Fm. The latter were deposited above CCD, most probably on the continental slope. The oxic bottom conditions are interpreted to be a result of a combination of climate cooling, active bottom ocean circulation, and change in the ocean-atmosphere oxygen budget.