Pt-based nanoframes represent a class of promising catalysts towards oxygen reduction reaction. Herein, we, for the first time, successfully prepared Pt-Pd octahedral nanoframes with ultrathin ridges less than 2 nm in...Pt-based nanoframes represent a class of promising catalysts towards oxygen reduction reaction. Herein, we, for the first time, successfully prepared Pt-Pd octahedral nanoframes with ultrathin ridges less than 2 nm in thickness. The Pt-Pd octahedral nanoframes were obtained through site-selected deposition of Pt atoms onto the edge sites of Pd octahedral seeds, followed by selective removal of the Pd octahedral cores via chemical etching. Due to that a combination of three-dimensional opens geometrical structure and Pt-skin surface compositional structure, the Pt-Pd octahedral nanoframes/C catalyst shows a mass activity of 1.15 A/mgPt towards oxygen reduction reaction, 5.8 times enhancement in mass activity relative to commercial Pt/C catalyst (0.20 A/mgPt). Moreover, even after 8000 cycles of accelerated durability test, the Pt-Pd octahedral nanoframes/C catalyst still exhibits a mass activity which is more than three times higher than that of pristine Pt/C catalyst.展开更多
In this paper, a low-dimensional multiple-input and multiple-output (MIMO) model predictive control (MPC) configuration is presented for partial differential equation (PDE) unknown spatially-distributed systems ...In this paper, a low-dimensional multiple-input and multiple-output (MIMO) model predictive control (MPC) configuration is presented for partial differential equation (PDE) unknown spatially-distributed systems (SDSs). First, the dimension reduction with principal component analysis (PCA) is used to transform the high-dimensional spatio-temporal data into a low-dimensional time domain. The MPC strategy is proposed based on the online correction low-dimensional models, where the state of the system at a previous time is used to correct the output of low-dimensional models. Sufficient conditions for closed-loop stability are presented and proven. Simulations demonstrate the accuracy and efficiency of the proposed methodologies.展开更多
In this paper, we consider a class of high-order nonlinear systems with unmodelled dynamics from the viewpoint of maintaining the desired control performance (e,g., asymptotical stability) and reducing the control e...In this paper, we consider a class of high-order nonlinear systems with unmodelled dynamics from the viewpoint of maintaining the desired control performance (e,g., asymptotical stability) and reducing the control effort. By introducing a new reseating transformation, adopting an effective reduced-order observer, and choosing an ingenious Lyapunov function and appropriate design parameters, this paper designs all improved output-feedback controller. The output-feedback controller guarantees the globally asymptotieal stability of the closed-loop system. Subsequently, taking a concrete system for an example, the smaller critical values for gain parameter and resealing transformation parameter are obtained to effectively reduce the control effort.展开更多
The uncertainty disturbance is one of the main disturbances that seriously influences the stabilization precision of an aerial inertially stabilized platform(ISP)system.In this paper,to improve the stabilization preci...The uncertainty disturbance is one of the main disturbances that seriously influences the stabilization precision of an aerial inertially stabilized platform(ISP)system.In this paper,to improve the stabilization precision of the ISP under disturbance uncertainty,a robust H∞controller is designed in this paper.Then,the reduction order is carried out for high-order controllers generated by the robust H∞loop shaping control method.The application of the minimum implementation and balanced truncation algorithm in controller reduction is discussed.First,the principle of reduced order of minimum implementation and balanced truncation are analyzed.Then,the method is used to reduce the order of the high-order robust H∞loop shaping controller.Finally,the method is analyzed and verified by the simulations and experiments.The results show that by the reduced-order method of minimum implementation and balanced truncation,the stabilization precision of the robust H∞loop shaping controller is increased by about 10%.展开更多
There are significant effects of process parameters on internal qualities of bloom, and these process parameters are as follows. position and reduction amount, reduction distribution, reduction rate, and so on. Develo...There are significant effects of process parameters on internal qualities of bloom, and these process parameters are as follows. position and reduction amount, reduction distribution, reduction rate, and so on. Developing a control model is the key to apply soft reduction technology successfully. As the research object, 360 mm ×450 mm bloom caster in PISCO (Panzhihua Iron and Steel Co. ) has been studied, and the research method for control model of dynamic soft reduction has been proposed. On the basis of solidification and heat transfer model, the position of soft reduction and reduction distribution of each frame are determined according to the bloom temperature distribution and solid fraction in bloom center calculated. Production practice shows that the ratio of center porosity which is less than or equal to 1.0, increased to 97.27%, ratio of central segregation which is less than or equal to 0.5, increased to 80.91%, and ratio of central carbon segregation index which is more than or equal to 1.10, decreased to 4% with the applying model of dynamic soft reduction.展开更多
This paper introduced domestic and overseas status, the historical evolution and the development history of earthquake disaster reduction planning. The urgencies and realistic significance were analyzed to carry out e...This paper introduced domestic and overseas status, the historical evolution and the development history of earthquake disaster reduction planning. The urgencies and realistic significance were analyzed to carry out earthquake disaster reduction planning for districts or countries in the northwest. With Hongsibao District in Wuzhong City, Ningxia Province as an example, this article analyzed in detail the present situation and the special problems of earthquake disaster reduction planning in Northwest China. The relevant solving measures were put forward in order to offer a reference for the scientific establishment and effective implementation of earth- quake disaster reduction planning in Northwest China. The foundation of earthquake disaster reduction in the Hongsibao District is still very weak, there is a single earthquake monitoring means, the emergency rescue system is not complete, the working mechanism is not perfect, and the lack of funding for the work of earthquake disaster reduction.展开更多
Nature has shown us that the microstructure of the skin of fast-swimming sharks in the ocean can reduce the skin friction drag due to the well-known shark-skin effect.In the present study,the effect of shark-skin-insp...Nature has shown us that the microstructure of the skin of fast-swimming sharks in the ocean can reduce the skin friction drag due to the well-known shark-skin effect.In the present study,the effect of shark-skin-inspired riblets on coherent vortex structures in a turbulent boundary layer(TBL) is investigated.This is done by means of tomographic particle image velocimetry(TPIV) measurements in channel fl ws over an acrylic plate of drag-reducing riblets at a friction Reynolds number of 190.The turbulent fl ws over drag-reducing riblets are verifie by a planar time-resolved particle image velocimetry(TRPIV) system initially,and then the TPIV measurements are performed.Two-dimensional(2D) experimental results with a dragreduction rate of around 4.81% are clearly visible over triangle riblets with a peak-to-peak spacing s+of 14,indicating from the drag-reducing performance that the buffer layer within the TBL has thickened;the logarithmic law region has shifted upward and the Reynolds shear stress decreased.A comparison of the spatial topological distributions of the spanwise vorticity of coherent vortex structures extracted at different wall-normal heights through the improved quadrant splitting method shows that riblets weaken the amplitudesof the spanwise vorticity when ejection(Q2) and sweep(Q4) events occur at the near wall,having the greatest effect on Q4 events in particular.The so-called quadrupole statistical model for coherent structures in the whole TBL is verified Meanwhile,their spatial conditional-averaged topological shapes and the spatial scales of quadrupole coherent vortex structures as a whole in the overlying turbulent fl w over riblets are changed,suggesting that the riblets dampen the momentum and energy exchange between the regions of near-wall and outer portion of the TBL by depressing the bursting events(Q2 and Q4),thereby reducing the skin friction drag.展开更多
We have demonstrated polarization insensitive AWGs by controlling the doping concentration of Boron in overcladding and the etching depth of waveguide. The proposed method uses the conventional fabrication process and...We have demonstrated polarization insensitive AWGs by controlling the doping concentration of Boron in overcladding and the etching depth of waveguide. The proposed method uses the conventional fabrication process and does not degrade optical properties and reliability characteristics.展开更多
Two examples of the use of vortex control to reduce noise and enhance the stable operating range of a centrifugal compressor are presented in this paper.In the case of high-flow operation of a centrifugal compressor w...Two examples of the use of vortex control to reduce noise and enhance the stable operating range of a centrifugal compressor are presented in this paper.In the case of high-flow operation of a centrifugal compressor with a vaned diffuser,a discrete frequency noise induced by interaction between the impeller-discharge flow and the diffuser vane,which appears most notably in the power spectra of the radiated noise,can be reduced using a tapered diffuser vane(TDV) without affecting the performance of the compressor.Twin longitudinal vortices produced by leakage flow passing through the tapered portion of the diffuser vane induce secondary flow in the direction of the blade surface and prevent flow separation from the leading edge of the diffuser.The use of a TDV can effectively reduce both the discrete frequency noise generated by the interaction between the impeller-discharge flow and the diffuser surface and the broadband turbulent noise component.In the case of low-flow operation,a leading-edge vortex(LEV) that forms on the shroud side of the suction surface near the leading edge of the diffuser increases significantly in size and blocks flow in the diffuser passage.The formation of an LEV may adversely affect the performance of the compressor and may cause the diffuser to stall.Using a one-side tapered diffuser vane to suppress the evolution of an LEV,the stable operating range of the compressor can be increased by more than 12 percent,and the pressure-rise characteristics of the compressor can be improved.The results of a supplementary examination of the structure and unsteady behavior of LEVs,conducted by means of detailed numerical simulations,are also presented.展开更多
基金This work is supported by Collaborative Innovation Center of Suzhou Nano Science and Technology, Ministry of Science and Technology of China (No.2014CB932700), the National Natural Science Foundation of China (No.21603208, No.21573206, and No.51371164), the China Postdoctoral Science Foundation (No.2015M580536, No.2016T90569), Key Research Program of Frontier Sciences, CAS (QYZDBSSW- SLH017), Strategic Priority Research Program B of the CAS (No.XDB01020000), Hefei Science Center, CAS (No.2015HSC-UP016), and Fundamental Research Funds for the Central Universities.
文摘Pt-based nanoframes represent a class of promising catalysts towards oxygen reduction reaction. Herein, we, for the first time, successfully prepared Pt-Pd octahedral nanoframes with ultrathin ridges less than 2 nm in thickness. The Pt-Pd octahedral nanoframes were obtained through site-selected deposition of Pt atoms onto the edge sites of Pd octahedral seeds, followed by selective removal of the Pd octahedral cores via chemical etching. Due to that a combination of three-dimensional opens geometrical structure and Pt-skin surface compositional structure, the Pt-Pd octahedral nanoframes/C catalyst shows a mass activity of 1.15 A/mgPt towards oxygen reduction reaction, 5.8 times enhancement in mass activity relative to commercial Pt/C catalyst (0.20 A/mgPt). Moreover, even after 8000 cycles of accelerated durability test, the Pt-Pd octahedral nanoframes/C catalyst still exhibits a mass activity which is more than three times higher than that of pristine Pt/C catalyst.
基金supported by National High Technology Research and Development Program of China (863 Program)(No. 2009AA04Z162)National Nature Science Foundation of China(No. 60825302, No. 60934007, No. 61074061)+1 种基金Program of Shanghai Subject Chief Scientist,"Shu Guang" project supported by Shang-hai Municipal Education Commission and Shanghai Education Development FoundationKey Project of Shanghai Science and Technology Commission, China (No. 10JC1403400)
文摘In this paper, a low-dimensional multiple-input and multiple-output (MIMO) model predictive control (MPC) configuration is presented for partial differential equation (PDE) unknown spatially-distributed systems (SDSs). First, the dimension reduction with principal component analysis (PCA) is used to transform the high-dimensional spatio-temporal data into a low-dimensional time domain. The MPC strategy is proposed based on the online correction low-dimensional models, where the state of the system at a previous time is used to correct the output of low-dimensional models. Sufficient conditions for closed-loop stability are presented and proven. Simulations demonstrate the accuracy and efficiency of the proposed methodologies.
基金supported by National Natural Science Founda-tion of China (No. 60774010)Natural Science Foundation of JiangsuProvince, Jiangsu "Six Top Talents" (No. 07-A-020)+1 种基金Program for Fundamental Research of Natural Sciences in Universities of JiangsuProvince (No. 07KJB510114)Natural Science Foundation ofXuzhou Normal University (No. 08XLB20)
文摘In this paper, we consider a class of high-order nonlinear systems with unmodelled dynamics from the viewpoint of maintaining the desired control performance (e,g., asymptotical stability) and reducing the control effort. By introducing a new reseating transformation, adopting an effective reduced-order observer, and choosing an ingenious Lyapunov function and appropriate design parameters, this paper designs all improved output-feedback controller. The output-feedback controller guarantees the globally asymptotieal stability of the closed-loop system. Subsequently, taking a concrete system for an example, the smaller critical values for gain parameter and resealing transformation parameter are obtained to effectively reduce the control effort.
基金supported in part by the Beijing Natural Science Foundation(Grant No.3182021)National Natural Science Foundation of China(Grant No.51775017)+1 种基金Research Project of Beijing Academy of Quantum Information Sciences(Grant No.Y18G30)the Open Research Fund of the State Key Laboratory for Manufacturing Systems Engineering(Grant No.sklms2018005)
文摘The uncertainty disturbance is one of the main disturbances that seriously influences the stabilization precision of an aerial inertially stabilized platform(ISP)system.In this paper,to improve the stabilization precision of the ISP under disturbance uncertainty,a robust H∞controller is designed in this paper.Then,the reduction order is carried out for high-order controllers generated by the robust H∞loop shaping control method.The application of the minimum implementation and balanced truncation algorithm in controller reduction is discussed.First,the principle of reduced order of minimum implementation and balanced truncation are analyzed.Then,the method is used to reduce the order of the high-order robust H∞loop shaping controller.Finally,the method is analyzed and verified by the simulations and experiments.The results show that by the reduced-order method of minimum implementation and balanced truncation,the stabilization precision of the robust H∞loop shaping controller is increased by about 10%.
文摘There are significant effects of process parameters on internal qualities of bloom, and these process parameters are as follows. position and reduction amount, reduction distribution, reduction rate, and so on. Developing a control model is the key to apply soft reduction technology successfully. As the research object, 360 mm ×450 mm bloom caster in PISCO (Panzhihua Iron and Steel Co. ) has been studied, and the research method for control model of dynamic soft reduction has been proposed. On the basis of solidification and heat transfer model, the position of soft reduction and reduction distribution of each frame are determined according to the bloom temperature distribution and solid fraction in bloom center calculated. Production practice shows that the ratio of center porosity which is less than or equal to 1.0, increased to 97.27%, ratio of central segregation which is less than or equal to 0.5, increased to 80.91%, and ratio of central carbon segregation index which is more than or equal to 1.10, decreased to 4% with the applying model of dynamic soft reduction.
基金Supported by State Key Laboratory of Loess and Quaternary Geology Open-end Fund(SKLLQG1426)Post-doctoral Foundation and National Natural Science Foundation of China(41102107)~~
文摘This paper introduced domestic and overseas status, the historical evolution and the development history of earthquake disaster reduction planning. The urgencies and realistic significance were analyzed to carry out earthquake disaster reduction planning for districts or countries in the northwest. With Hongsibao District in Wuzhong City, Ningxia Province as an example, this article analyzed in detail the present situation and the special problems of earthquake disaster reduction planning in Northwest China. The relevant solving measures were put forward in order to offer a reference for the scientific establishment and effective implementation of earth- quake disaster reduction planning in Northwest China. The foundation of earthquake disaster reduction in the Hongsibao District is still very weak, there is a single earthquake monitoring means, the emergency rescue system is not complete, the working mechanism is not perfect, and the lack of funding for the work of earthquake disaster reduction.
基金supported by the National Natural Science Foundation of China (Grants 11332006,11272233,and 11411130150)the foundation from the China Scholarship Council (CSC) (Grant 201306250092)the Foundation Project for Outstanding Doctoral Dissertations of Tianjin University
文摘Nature has shown us that the microstructure of the skin of fast-swimming sharks in the ocean can reduce the skin friction drag due to the well-known shark-skin effect.In the present study,the effect of shark-skin-inspired riblets on coherent vortex structures in a turbulent boundary layer(TBL) is investigated.This is done by means of tomographic particle image velocimetry(TPIV) measurements in channel fl ws over an acrylic plate of drag-reducing riblets at a friction Reynolds number of 190.The turbulent fl ws over drag-reducing riblets are verifie by a planar time-resolved particle image velocimetry(TRPIV) system initially,and then the TPIV measurements are performed.Two-dimensional(2D) experimental results with a dragreduction rate of around 4.81% are clearly visible over triangle riblets with a peak-to-peak spacing s+of 14,indicating from the drag-reducing performance that the buffer layer within the TBL has thickened;the logarithmic law region has shifted upward and the Reynolds shear stress decreased.A comparison of the spatial topological distributions of the spanwise vorticity of coherent vortex structures extracted at different wall-normal heights through the improved quadrant splitting method shows that riblets weaken the amplitudesof the spanwise vorticity when ejection(Q2) and sweep(Q4) events occur at the near wall,having the greatest effect on Q4 events in particular.The so-called quadrupole statistical model for coherent structures in the whole TBL is verified Meanwhile,their spatial conditional-averaged topological shapes and the spatial scales of quadrupole coherent vortex structures as a whole in the overlying turbulent fl w over riblets are changed,suggesting that the riblets dampen the momentum and energy exchange between the regions of near-wall and outer portion of the TBL by depressing the bursting events(Q2 and Q4),thereby reducing the skin friction drag.
文摘We have demonstrated polarization insensitive AWGs by controlling the doping concentration of Boron in overcladding and the etching depth of waveguide. The proposed method uses the conventional fabrication process and does not degrade optical properties and reliability characteristics.
文摘Two examples of the use of vortex control to reduce noise and enhance the stable operating range of a centrifugal compressor are presented in this paper.In the case of high-flow operation of a centrifugal compressor with a vaned diffuser,a discrete frequency noise induced by interaction between the impeller-discharge flow and the diffuser vane,which appears most notably in the power spectra of the radiated noise,can be reduced using a tapered diffuser vane(TDV) without affecting the performance of the compressor.Twin longitudinal vortices produced by leakage flow passing through the tapered portion of the diffuser vane induce secondary flow in the direction of the blade surface and prevent flow separation from the leading edge of the diffuser.The use of a TDV can effectively reduce both the discrete frequency noise generated by the interaction between the impeller-discharge flow and the diffuser surface and the broadband turbulent noise component.In the case of low-flow operation,a leading-edge vortex(LEV) that forms on the shroud side of the suction surface near the leading edge of the diffuser increases significantly in size and blocks flow in the diffuser passage.The formation of an LEV may adversely affect the performance of the compressor and may cause the diffuser to stall.Using a one-side tapered diffuser vane to suppress the evolution of an LEV,the stable operating range of the compressor can be increased by more than 12 percent,and the pressure-rise characteristics of the compressor can be improved.The results of a supplementary examination of the structure and unsteady behavior of LEVs,conducted by means of detailed numerical simulations,are also presented.