The distribution characteristics of rare earth elements (REE) in bottomsediments are influenced by many factors. Hence, conducting a quantitative analysis isdifficult. A qualitative analysis of the relationships bet...The distribution characteristics of rare earth elements (REE) in bottomsediments are influenced by many factors. Hence, conducting a quantitative analysis isdifficult. A qualitative analysis of the relationships between ΣREE content andprovenance, hydrodynamics, grain size and mineral distribution in the Beibu Gulf showsthat terrestrial rocks control the ΣREE composition. Both weaker hydrodynamics andfiner grain size lead to a higher ΣREE content. Relative curves revealing therelationships between individual impact factors and ΣREE content were obtained fromthe combination of qualitative and quantitative analyses of the BP neural network,which trained the position of samples, gravel content, sand content, silt content, claycontent and clay mineral content. The results are consistent with those of thequantitative analysis. The self-learning algorithm is automatically determined andcalculated quantitatively. The impact of each factor on REEs and how each factorcontrols the ΣREE distribution is identified. Thus, environmental changes and thegeological evolution of the region can be inferred based on curve variation and the geological evolution of the region can be inferred based on curve variation and theactual situation. This method also provides useful theoretical guidance for the analysisof REE enrichment and dispersion.展开更多
The rare earth elements(REE)content of the coal in the Erlian Basin was determined by inductively coupled plasma mass spectrometry(ICP-MS),and it turns out that the REE content from different geological age shows a si...The rare earth elements(REE)content of the coal in the Erlian Basin was determined by inductively coupled plasma mass spectrometry(ICP-MS),and it turns out that the REE content from different geological age shows a significant difference:The REE content of the coal in the Jurassic Alatanheli Group is from 152.05×10^(−6) to 1416.21×10^(−6),with an average value of 397.31×10^(−6),and the relative concentration factor shows enriched;the REE content of the coal in Early Cretaceous Baiyanhua Group is from 20.65×10^(−6) to 102.53×10^(−6),the mean value is 49.06×10^(−6),and the relative concentration factor shows normally.The REE distribution patterns samples in Jurassic and Cretaceous shows the difference:The REE pattern in Jurassic coal mainly manifests as H-type distribution,with the Y,Lu positive anomaly,it is speculated that the fluid carried REE ions into the coal-bearing basin,and the heavy REE gather in the coal due to the different chemical properties of each REE.The REE occurrence mode is presumed to be mainly organic.Flat type is the REE main distribution pattern in Cretaceous coal.The REE patterns in clastic rocks of the roof,parting and floor of coal seam are similar to the REE patterns in the coal and the most possible reason is that the REE main source is from the clastic rock.It showed that the coal of the Early Jurassic,especially of Amugulen coalfield has resource value.展开更多
The material sources and control factors of rare earth elemems (REEs) for 25 borehole bulk samples from the Late Permian Longtan Formation in Mount Huaying (borehole number: ZK10-6), Sichuan Province, South China...The material sources and control factors of rare earth elemems (REEs) for 25 borehole bulk samples from the Late Permian Longtan Formation in Mount Huaying (borehole number: ZK10-6), Sichuan Province, South China, were investigated. All samples were determined by inductively coupled plasma mass spectrometry (ICP-MS). The chondrite-normalized distribution patterns of mudstone samples are uniform. All samples belong to the light rare earth element (LREE)-rich type and are enriched in LREEs relative to heavy rare earth elements (HREEs). The distribution curves of REEs in mudstone are highly similar to Mount Emei basalt and the three periods of REEs enrichment correspond to three Mount Emei basalt eruption cycles in Longtan period. The results indicate that REE patterns are not controlled by materials from the seawater or land plants. The predominant sources of REEs are from terrigenous material as indicated by negative Eu anomaly. So, the sources of REEs are controlled by terrigenous material, and the Mount Emei basalt is the predominant source of terrigenous material. Thus, transgression-regression is another control factor of REEs enrichment.展开更多
文摘The distribution characteristics of rare earth elements (REE) in bottomsediments are influenced by many factors. Hence, conducting a quantitative analysis isdifficult. A qualitative analysis of the relationships between ΣREE content andprovenance, hydrodynamics, grain size and mineral distribution in the Beibu Gulf showsthat terrestrial rocks control the ΣREE composition. Both weaker hydrodynamics andfiner grain size lead to a higher ΣREE content. Relative curves revealing therelationships between individual impact factors and ΣREE content were obtained fromthe combination of qualitative and quantitative analyses of the BP neural network,which trained the position of samples, gravel content, sand content, silt content, claycontent and clay mineral content. The results are consistent with those of thequantitative analysis. The self-learning algorithm is automatically determined andcalculated quantitatively. The impact of each factor on REEs and how each factorcontrols the ΣREE distribution is identified. Thus, environmental changes and thegeological evolution of the region can be inferred based on curve variation and the geological evolution of the region can be inferred based on curve variation and theactual situation. This method also provides useful theoretical guidance for the analysisof REE enrichment and dispersion.
基金This study was supported by the project of the China Geological Survey(DD20160187)the Science and Technology Special Project of the China National Administration of Coal Geology(ZMKJ-2019-J02).
文摘The rare earth elements(REE)content of the coal in the Erlian Basin was determined by inductively coupled plasma mass spectrometry(ICP-MS),and it turns out that the REE content from different geological age shows a significant difference:The REE content of the coal in the Jurassic Alatanheli Group is from 152.05×10^(−6) to 1416.21×10^(−6),with an average value of 397.31×10^(−6),and the relative concentration factor shows enriched;the REE content of the coal in Early Cretaceous Baiyanhua Group is from 20.65×10^(−6) to 102.53×10^(−6),the mean value is 49.06×10^(−6),and the relative concentration factor shows normally.The REE distribution patterns samples in Jurassic and Cretaceous shows the difference:The REE pattern in Jurassic coal mainly manifests as H-type distribution,with the Y,Lu positive anomaly,it is speculated that the fluid carried REE ions into the coal-bearing basin,and the heavy REE gather in the coal due to the different chemical properties of each REE.The REE occurrence mode is presumed to be mainly organic.Flat type is the REE main distribution pattern in Cretaceous coal.The REE patterns in clastic rocks of the roof,parting and floor of coal seam are similar to the REE patterns in the coal and the most possible reason is that the REE main source is from the clastic rock.It showed that the coal of the Early Jurassic,especially of Amugulen coalfield has resource value.
基金Project(40839910) supported by the National Natural Science Foundation of China
文摘The material sources and control factors of rare earth elemems (REEs) for 25 borehole bulk samples from the Late Permian Longtan Formation in Mount Huaying (borehole number: ZK10-6), Sichuan Province, South China, were investigated. All samples were determined by inductively coupled plasma mass spectrometry (ICP-MS). The chondrite-normalized distribution patterns of mudstone samples are uniform. All samples belong to the light rare earth element (LREE)-rich type and are enriched in LREEs relative to heavy rare earth elements (HREEs). The distribution curves of REEs in mudstone are highly similar to Mount Emei basalt and the three periods of REEs enrichment correspond to three Mount Emei basalt eruption cycles in Longtan period. The results indicate that REE patterns are not controlled by materials from the seawater or land plants. The predominant sources of REEs are from terrigenous material as indicated by negative Eu anomaly. So, the sources of REEs are controlled by terrigenous material, and the Mount Emei basalt is the predominant source of terrigenous material. Thus, transgression-regression is another control factor of REEs enrichment.