Gas-Water Production of a Continental Tight-Sandstone Gas Reservoir under Different Fracturing Conditions

A numerical model of hydraulic fracture propagation is introduced for a representative reservoir(Yuanba continental tight sandstone gas reservoir in Northeast Sichuan).Different parameters are considered,i.e.,the interlayer stress difference,the fracturing discharge rate and the fracturing fluid viscosity.The results show that these factors affect the gas and water production by influencing the fracture size.The interlayer stress difference can effectively control the fracture height.The greater the stress difference,the smaller the dimensionless reconstruction volume of the reservoir,while the flowback rate and gas production are lower.A large displacement fracturing construction increases the fracture-forming efficiency and expands the fracture size.The larger the displacement of fracturing construction,the larger the dimensionless reconstruction volume of the reservoir,and the higher the fracture-forming efficiency of fracturing fluid,the flowback rate,and the gas production.Low viscosity fracturing fluid is suitable for long fractures,while high viscosity fracturing fluid is suitable for wide fractures.With an increase in the fracturing fluid viscosity,the dimensionless reconstruction volume and flowback rate of the reservoir display a non-monotonic behavior,however,their changes are relatively small.

Adaptability of Development Methods for Offshore Gas Cap Edge Water Reservoirs under Different Permeability Levels

The BZ 34-1 oilfield is a typical gas cap edge water reservoir in the Bohai oilfield. The main characteristics of the oilfield were multi-phase sand body stacking and the sand body was composed of three parts: gas cap, oil reservoir, and edge water. The actual production site results show that the permeability difference of multi-layer sand bodies has a serious impact on the development effect. This article establishes a typical reservoir model numerical model based on the total recovery degree of the reservoir and the recovery degree of each layer, and analyzes the impact of permeability gradient. As the permeability gradient increases, the total recovery degree of all four well patterns decreases, and the total recovery degree gradually decreases. The recovery degree of low permeability layers gradually decreases, and the recovery degree of high permeability layers gradually increases. As the permeability gradient increases, the degree of recovery gradually decreases under different water contents. As the permeability gradient increases, the reduction rate of remaining oil saturation in low permeability layers is slower, while the reduction rate of remaining oil saturation in high permeability layers was faster. By analyzing the impact of permeability gradient on the development effect of oil fields, we could further deepen our understanding of gas cap edge water reservoirs and guide the development of this type of oil field.

Remaining Oil Distribution Law and Potential Tapping Strategy of Horizontal Well Pattern in Narrow Oil Rim Reservoir with Gas Cap and Edge Water

For thin oil rim reservoir with gas cap and edge water, it is helpful to improve the development effect to find out the distribution law of remaining oil in this kind of reservoirs. For this reason, taking the narrow oil rim reservoir with gas cap and edge water of Oilfield A in Bohai Sea as a case, the main controlling factors, including reservoir structure, fault, gas cap energy, edge water energy and well pattern, affecting the distribution of residual oil in this kind of reservoir were analyzed by using the data of core, logging, paleogeomorphology and production. Then, the distribution law of remaining oil was summarized. Generally, the remaining oil distribution is mainly potato-shaped or strip-shaped in plane. Vertically, it depends on the energy of gas cap and edge water. For the reservoir with big gas gap and weak edge water, the remaining oil mainly lies in the bottom of oil column. And for the reservoir with small gas gap and strong edge water, the remaining oil mainly locates at the top of oil column. Aiming at different distribution modes of remaining oil, the corresponding potential tapping strategies of horizontal wells are put forward: in the late stage of development, for the reservoir with big gas gap and weak edge water, the remaining oil concentrates at the bottom of the oil column, and the position of horizontal well should be placed at the lower 1/3 to the lower 1/5 of the oil column;for the reservoir with small gas cap and strong edge water, the remaining oil locates at the top of the oil column, and the position of horizontal well should be put at the upper 1/5 to the upper 1/3 of the oil column height, vertically. Based on the study on remaining oil of Oilfield A, a potential tapping strategy of well pattern thickening and vertical position optimization of horizontal well was proposed. This strategy guided the efficient implementation of the comprehensive adjustment plan of the oilfield. Moreover, 18 infill development wells were implemented in Oilfield A, and the average production of the infill wells is 2.1 times that of the surrounding old wells. It is estimated that the ultimate recovery factor of the oilfield will reach 33.9%, which is 2.3% higher than that before infilling wells. This study can be used for reference in the development of similar reservoirs.

A novel steady-state productivity equation for horizontal wells in bottom water drive gas reservoirs

It is known that there is a discrepancy between field data and the results predicted from the previous equations derived by simplifying three-dimensional（3-D） flow into two-dimensions（2-D）.This paper presents a new steady-state productivity equation for horizontal wells in bottom water drive gas reservoirs.Firstly,the fundamental solution to the 3-D steady-state Laplace equation is derived with the philosophy of source and the Green function for a horizontal well located at the center of the laterally infinite gas reservoir.Then,using the fundamental solution and the Simpson integral formula,the average pseudo-pressure equation and the steady-state productivity equation are achieved for the horizontal section.Two case-studies are given in the paper,the results calculated from the newly-derived formula are very close to the numerical simulation performed with the Canadian software CMG and the real production data,indicating that the new formula can be used to predict the steady-state productivity of such horizontal gas wells.

Study on the Critical Production Calculation Method of the Water-Flooding Reservoir with Gas Cap

The aim of this paper is to solve the problems that the existing method of critical production of gas cap reservoir is only suitable for single-phase flow, and the method of critical production of gas cap reservoir under water-flooding is still blank. In this paper, the relationships between dynamic and static equilibrium, plane radial flow theory, oil-water infiltration method and three-dimensional seepage field decomposition theory, were applied to study a calculation method for critical production of directional wells and horizontal wells. Furthermore, the effects of different factors on critical output were studied, such as horizontal permeability, ratio of horizontal permeability to vertical permeability, length of horizontal section, effective thickness, viscosity of crude oil and water content etc. Results show that the critical production increases with the increment of the horizontal permeability, the ratio of the vertical permeability to the horizontal permeability, the reservoir thickness and the horizontal well length;when the viscosity of crude oil is small, the critical production decreases first and then increases with the increase of water content;when the viscosity of crude oil is high, the critical production increases continuously with the increase of water content. This study could provide theoretical and technical guidance for changing of the working system of oil wells. It can avoid gas channeling and improve the development effect.

Progress and prospects of EOR technology in deep,massive sandstone reservoirs with a strong bottom-water drive

The Triassic massive sandstone reservoir in the Tahe oilfield has a strong bottom-water drive and is characterized by great burial depth,high temperature and salinity,a thin pay zone,and strong heterogeneity.At present,the water-cut is high in each block within the reservoir;some wells are at an ultrahigh water-cut stage.A lack of effective measures to control water-cut rise and stabilize oil production have necessitated the application of enhanced oil recovery(EOR)technology.This paper investigates the development and technological advances for oil reservoirs with strong edge/bottom-water drive globally,and compares their application to reservoirs with characteristics similar to the Tahe oilfield.Among the technological advances,gas injection from the top and along the direction of structural dip has been used to optimize the flow field in a typical bottom-water drive reservoir.Bottom-water coning is restrained by gas injection-assisted water control.In addition,increasing the lateral driving pressure differential improves the plane sweep efficiency which enhances oil recovery in turn.Gas injection technology in combination with technological measures like channeling prevention and blocking,and water plugging and profile control,can achieve better results in reservoir development.Gas flooding tests in the Tahe oilfield are of great significance to identifying which EOR technology is the most effective and has the potential of large-scale application for improving development of deep reservoirs with a strong bottomwater drive.

A new model for predicting irreducible water saturation in tight gas reservoirs

The irreducible water saturation(Swir) is a significant parameter for relative permeability prediction and initial hydrocarbon reserves estimation.However,the complex pore structures of the tight rocks and multiple factors of the formation conditions make the parameter difficult to be accurately predicted by the conventional methods in tight gas reservoirs.In this study,a new model was derived to calculate Swir based on the capillary model and the fractal theory.The model incorporated different types of immobile water and considered the stress effect.The dead or stationary water(DSW) was considered in this model,which described the phenomena of water trapped in the dead-end pores due to detour flow and complex pore structures.The water film,stress effect and formation temperature were also considered in the proposed model.The results calculated by the proposed model are in a good agreement with the experimental data.This proves that for tight sandstone gas reservoirs the Swir calculated from the new model is more accurate.The irreducible water saturation calculated from the new model reveals that Swir is controlled by the critical capillary radius,DSW coefficient,effective stress and formation temperature.

Geological characteristics and high production control factors of shale gas reservoirs in Silurian Longmaxi Formation, southern Sichuan Basin, SW China

Marine shale gas resources have great potential in the south of the Sichuan Basin in China.At present,the high-quality shale gas resources at depth of 2000–3500 m are under effective development,and strategic breakthroughs have been made in deeper shale gas resources at depth of 3500–4500 m.To promote the effective production of shale gas in this area,this study examines key factors controlling high shale gas production and presents the next exploration direction in the southern Sichuan Basin based on summarizing the geological understandings from the Lower Silurian Longmaxi Formation shale gas exploration combined with the latest results of geological evaluation.The results show that:(1)The relative sea depth in marine shelf sedimentary environment controls the development and distribution of reservoirs.In the relatively deep water area in deep-water shelf,grade-I reservoirs with a larger continuous thickness develop.The relative depth of sea in marine shelf sedimentary environment can be determined by redox conditions.The research shows that the uranium to thorium mass ratio greater than 1.25 indicates relatively deep water in anoxic reduction environment,and the uranium to thorium mass ratio of 0.75–1.25 indicates semi-deep water in weak reduction and weak oxidation environment,and the uranium to thorium mass ratio less than 0.75 indicates relatively shallow water in strong oxidation environment.(2)The propped fractures in shale reservoirs subject to fracturing treatment are generally 10–12 m high,if grade-I reservoirs are more than 10 m in continuous thickness,then all the propped section would be high-quality reserves;in this case,the longer the continuous thickness of penetrated grade-I reservoirs,the higher the production will be.(3)The shale gas reservoirs at 3500–4500 m depth in southern Sichuan are characterized by high formation pressure,high pressure coefficient,well preserved pores,good pore structure and high proportion of free gas,making them the most favorable new field for shale gas exploration;and the pressure coefficient greater than 1.2 is a necessary condition for shale gas wells to obtain high production.(4)High production wells in the deep shale gas reservoirs are those in areas where Long11-Long13 sub-beds are more than 10 m thick,with 1500 m long horizontal section,grade-I reservoirs penetration rate of over 90%,and fractured by dense cutting+high intensity sand injection+large displacement+large liquid volume.(5)The relatively deep-water area in the deep-water shelf and the area at depth of 3500–4500 m well overlap in the southern Sichuan,and the overlapping area is the most favorable shale gas exploration and development zones in the southern Sichuan in the future.With advancement in theory and technology,annual shale gas production in the southern Sichuan is expected to reach 450×108 m3.

A New Method for the Dynamic Reserves of Gas Condensate Reservoir Using Cyclic Gas Injection Based on the Effects of Reinjection Ratio and Water Influx

As we all know, cyclic gas injection is one of the most effective development methods to improve condensate oil recovery. When dealing with the calculation of the reserves, the injection-production differences and water influx create great influence on the accuracy. Based on the existing research, we proposed a new material balance equation which considered the differences of composition between produced and injected fluids and the effect of water influx, and a solution was provided in this paper. The results of the method are closer to the actual situation because they are built on the law of conservation of mass, and the using of curve fitting method can not only avoid the use of water influx coefficient but also obtain the water influx rate and reserves at the same time. The YH-23 gas condensate reservoir is taking as a typical subject to do the research, which has been exploited by cycle gas injection for 14 years. Three different methods are used to calculate the reserves, and the results show that the method proposed in this paper has minimum error of 2.96%.

Rate transient analysis methods for water-producing gas wells in tight reservoirs with mobile water

Tight gas reservoirs with mobile water exhibit multi-phase flow and high stress sensitivity.Accurately analyzing the reservoir and well parameters using conventional single-phase rate transient analysis methods proves challenging.This study introduces novel rate transient analysis methods incorporating evaluation processes based on the conventional flowing material balance method and the Blasingame type-curve method to examine fractured gas wells producing water.By positing a gas-water two-phase equivalent homogenous phase that considers characteristics of mobile water,gas,and high stress sensitivity,the conventional single-phase rate transient analysis methods can be applied by integrating the phase's characteristics and defining the phase's normalized parameters and material balance pseudotime.The rate transient analysis methods based on the equivalent homogenous phase can be used to quantitatively assess the parameters of wells and gas reservoirs,such as original gas-in-place,fracture half-length,reservoir permeability,and well drainage radius.This facilitates the analysis of production dynamics of fractured wells and well-controlled areas,subsequently aiding in locating residual gas and guiding the configuration of well patterns.The specific evaluation processes are detailed.Additionally,a numerical simulation mechanism model was constructed to verify the reliability of the developed methods.The methods introduced have been successfully implemented in field water-producing gas wells within tight gas reservoirs containing mobile water.

Characteristics and influencing factors of greenhouse gas emissions from reservoirs in the Yellow River Basin:A Meta-analysis

Reservoir construction and operation profoundly alter the hydrological,hydrodynamic,and carbon and nitrogen cycling processes of rivers.However,current research still lacks a systematic understanding of the characteristics of greenhouse gas(GHG)emissions from reservoirs in arid/semi-arid regions.This study integrates existing monitoring data to discuss the characteristics of GHG emissions from reservoirs in the Yellow River Basin and illustrate the controlling factors and underlying mechanism of these processes.The results indicate that while CO_(2) emission flux from reservoirs is lower than that from river channels,the emission fluxes of CH_(4) and N_(2)O are 1.9 times and 10 times those from rivers,respectively,indicating that the emission of GHG with stronger radiative effect is significantly enhanced in reservoirs.Compared to the reservoirs in humid climates(e.g.,the Three Gorges Reservoir),reservoirs in the Yellow River Basin exhibit relatively lower emissions of CO_(2) and CH_4 due to lower organic matter concentrations,but significantly higher N_(2)O emissions due to higher nitrogen loads.Monte Carlo simulations for 237 reservoirs in the Yellow River Basin showed that total emission of the three GHGs is 3.05 Tg CO_(2)-eq yr^(-1),accounting for 0.39% of the total emission from global reservoirs and lower than the area percentage of the basin(0.53%).This study has important implications on revealing the GHG emission characteristics and control mechanisms of reservoirs in arid/semi-arid regions.

Theory, technology and prospects of conventional and unconventional natural gas

The development of natural gas in China has entered a golden and leap-forward stage, which is a necessary bridge to clean energy. This in-depth study on the status quo, theory, technology and prospect of natural gas development shows:(1) The global remaining proven recoverable reserves of natural gas are 186×1012 m3, and the reserves-production ratio is 52.4, indicating a solid resource base for long-term and rapid development.(2) Ten formation and distribution laws of conventional and unconventional natural gas reservoirs have been proposed. In terms of exploration geology, the theory of conventional "monolithic" giant gas fields with different gas sources, and an unconventional gas accumulation theory with continuous distribution of "sweet areas" in different lithologic reservoirs have been established; in terms of development geology, a development theory of conventional structural gas reservoirs is oriented to "controlling water intrusion", while a development theory of unconventional gas is concentrated on man-made gas reservoirs.(3) With the geological resources(excluding hydrates) of 210×1012 m3 and the total proven rate of the resources less than 2% at present, the natural gas in China will see a constant increase in reserve and production; by 2030, the proven geological reserves of natural gas are expected to reach about(6 000-7 000)×108 m3, the production of conventional and unconventional natural gas each will reach about 1 000×108 m3, and the gas consumption will reach 5 500×108 m3. The dependence on imported natural gas may be 64% by 2030, and 70% by 2050.(4) Ten measures for future development of natural gas have been proposed, including strengthening exploration in large-scale resource areas, increasing the development benefits of unconventional gas, and enhancing the peak adjusting capacity of gas storage and scale construction of liquified natural gas.

ORIGIN ANALYSIS OF GEOTHERMAL WATER AND EVALUATION OF GEOTHERMAL RESERVOIR TEMPERATURE IN THE HENJING AREA, SOUTH JIANGXI PROVINCE, CHINA

The studies of water, gas and isotope chemistry indicate that the formation of geothermal water in the Henjing area is not related to the magmatic and volcanic sources. The geothermal water mainly derives from the meteoric source, and the gas components originate from the mixing of meteoric, crustal and mantle sources. Moreover, the geothermal water is in a low to moderate temperature geothermal reservoir. The results calculated by the quartz geothermometer and the silicaenthalpy diagram demonstrate that the lowest temperature of geothermal reservoir is in the range 78℃ to 134 ℃ and the highest temperature is in the range 95℃C to 155℃. Based on isotopic data, the possible elevation of recharge water is about 337. 5 m to 743. 6 m, which corresponds to the Wunizhang area.

Large-scale gas accumulation mechanisms and reservoir-forming geological effects in sandstones of Central and Western China

Large-scale gas accumulation areas in large oil-gas basins in central and Western China have multiple special accumulation mechanisms and different accumulation effects.Based on the geological theory and method of natural gas reservoir formation,this study examined the regional geological and structural background,formation burial evolution,basic characteristics of gas reservoirs,and fluid geology and geochemistry of typical petroliferous basins.The results show that the geological processes such as structural pumping,mudstone water absorption,water-soluble gas degasification and fluid sequestration caused by uplift and denudation since Himalayan stage all can form large-scale gas accumulation and different geological effects of gas accumulation.For example,the large-scale structural pumping effect and fluid sequestration effect are conducive to the occurrence of regional ultra-high pressure fluid and the formation of large-scale ultra-high pressure gas field;mudstone water absorption effect in the formation with low thickness ratio of sandstone to formation is conducive to the development of regional low-pressure and water free gas reservoir;the water-soluble gas degasification effect in large-scale thick sandstone can not only form large-scale natural gas accumulation;moreover,the degasification of water-soluble gas produced by the lateral migration of formation water will produce regional and regular isotopic fractionation effect of natural gas,that is,the farther the migration distance of water-soluble gas is,the heavier the carbon isotopic composition of methane formed by the accumulation.

Theories and practices of carbonate reservoirs development in China

Carbonate reservoirs in China have the characteristics of diversified accumulation pattern, complex structure and varying reservoir conditions. Concerning these characteristics, this article tracks the technical breakthroughs and related practices since the 1950 s, summarizes the developed theory and technologies of carbonate reservoir development, analyzes their adaptability and problems, and proposes their development trend. The following theory and technologies have come into being:(1) carbonate reservoir formation mechanisms and compound flow mechanisms in complex medium;(2) reservoir identification and description technologies based on geophysics and discrete fracture-vuggy modeling method;(3) well testing analysis technology and numerical simulation method of coupling free flow and porous media flow;(4) enhanced oil recovery techniques for nitrogen single well huff and puff, and water flooding development techniques with well pattern design in spatial structure, changed intensity water injection, water plugging and channel blocking as the core;(5) drilling and completion techniques, acid fracturing techniques and its production increasing techniques. To realize the efficient development of carbonate oil and gas reservoirs, researches in four aspects need to be done:(1) complex reservoir description technology with higher accuracy;(2) various enhanced oil recovery techniques;(3) improving the drilling method and acid fracturing method for ultra-deep carbonate reservoir and significantly cutting engineering cost;(4) strengthening the technological integration of information, big data, cloud computation, and artificial intelligence in oilfield development to realize the smart development of oilfield.

Field Scale Simulation Study of Miscible Water Alternating CO₂Injection Process in Fractured Reservoirs

Vast amounts of world oil reservoirs are in natural fractured reservoirs. There are different methods for increasing recovery from fractured reservoirs. Miscible injection of water alternating CO2?is a good choice among EOR methods. In this method, water and CO2?slugs are injected alternatively in reservoir as miscible agent into reservoir. This paper studies water injection scenario and miscible injection of water and CO2?in a two dimensional, inhomogeneous fractured reservoir. The results show that miscible water alternating CO2?gas injection leads to 3.95% increase in final oil recovery and total water production decrease of 3.89% comparing to water injection scenario.

Evaluation of reservoir environment by chemical properties of reservoir water‒A case study of Chang 6 reservoir in Ansai oilfield,Ordos Basin,China

The Ordos Basin is the largest continental multi-energy mineral basin in China,which is rich in coal,oil and gas,and uranium resources.The exploitation of mineral resources is closely related to reservoir water.The chemical properties of reservoir water are very important for reservoir evaluation and are significant indicators of the sealing of reservoir oil and gas resources.Therefore,the caprock of the Chang 6 reservoir in the Yanchang Formation was evaluated.The authors tested and analyzed the chemical characteristics of water samples selected from 30 wells in the Chang 6 reservoir of Ansai Oilfield in the Ordos Basin.The results show that the Chang 6 reservoir water in Ansai Oilfield is dominated by calcium-chloride water type with a sodium chloride coefficient of generally less than 0.5.The chloride magnesium coefficients are between 33.7 and 925.5,most of which are greater than 200.The desulfurization coefficients range from 0.21 to 13.4,with an average of 2.227.The carbonate balance coefficients are mainly concentrated below 0.01,with an average of 0.008.The calcium and magnesium coefficients are between 0.08 and 0.003,with an average of 0.01.Combined with the characteristics of the four-corner layout of the reservoir water,the above results show that the graphics are basically consistent.The study indicates that the Chang 6 reservoir in Ansai Oilfield in the Ordos Basin is a favorable block for oil and gas storage with good sealing properties,great preservation conditions of oil and gas,and high pore connectivity.

气顶边水油藏油气协同开发下流体界面运移特征

气顶边水油藏的开发,存在明显的油气水互侵现象,导致产量快速递减,开发难度增大。为了防止生产井过早停产,需明确流体界面运移特征,制定油气协同开发生产制度。通过油藏数值模拟方法,建立了月东油田气顶边水油藏实际模型与机理模型,根据气顶与边水作用能量强弱,将油气协同开发区域划分为边水控制区、气顶控制区和气顶边水联合控制区三类进行研究,综合评估气窜、水淹、油侵风险,明确油气、油水界面运移特征并形成运移速度图版。结果表明:随着开发的进行,气顶膨胀导致油气界面从油藏顶部向油井方向运移,边水侵入导致油水界面从油藏底部向油井与气井方向运移,油井存在气窜与水淹的风险,气井存在水淹与油侵的风险,剩余油主要分布在气顶下部和井间高部位,确定月东油田气顶边水油藏合理采气速度为6%~8%。基于实际与理论研究形成的成果认识为气顶边水油藏油气协同高效开发提供理论指导。

Simulation studies on optimizing oil productivity in oil rim reservoirs under gas cap blow down production strategy

Gas cap blow down strategy is normally deployed for Ultra-thin oil rim reservoirs with huge gas caps due to extremely high gas oil ratios from wells in such reservoirs.The current state leads to loss of production from the oil reserves due to high initial reservoir pressure thus,reducing its net present value.Data on important factors essential to the productivity of oil rim reservoirs are used to build a heterogeneous ultra-thin reservoir with a time step of 10,000 days using the Eclipse software and its embedded correlations.The reservoir is subjected to a gas cap blowdown via a gas well,then an oil well is initiated into the model at onset and after time periods of 2000 days,4000 days,6000 days and 8000 days to estimate the oil recovery.It is expected that due to the large nature of the gas cap,pressure decline will be drastic and leading to a low oil recovery,hence the injection of water and gas at different rates at the periods indicated.The results indicate an oil recovery of 4.3%during gas cap blow down and 10.34%at 6000 days.Peak oil recoveries of 12.64%and 10.80%are estimated under 30,000 Mscf/day at 4000 days and 1000 stb/day at 6000 days respectively.This shows an incremental oil recovery of 8.34%and 6.5%over that recorded during gas cap blow down.The results also indicate that the gas production at those periods was not greatly affected with an estimated increment of 257 Bscf recorded during 30,000 Mscf/day at 4000 days.All secondary injection schemes at the respective time steps had positive impact on the overall oil recoveries.It is recommended that extra production and injection wells be drilled,enhanced oil recovery options and injection patterns be considered to further increase oil recovery.

Evaluation of sour gas-low salinity waterflooding in carbonate reservoirs-A numerical simulation approach

Although significant amount of H_(2)S(sour gas)rich natural gas is estimated globally,but not much attention has been given to the application of H_(2)S in the oil recovery process.Recent studies on the use of H_(2)S in oil recovery processes showed that H_(2)S has the potential of improving the oil recovery,and it can be even more effective than using CO_(2) in some processes.H_(2)S can equally dissolve in the water,react with the reservoir rock to change its surface charge,porosity,and permeability.However,previous in-vestigations on H_(2)S oil recovery attributed the improved oil recoveries to the higher miscibility of H_(2)S in the oil,and the reduction in the oil viscosity.Therefore,there is limited understanding on the H_(2)S-oil-brine-rock geochemical interactions,and how they impact the oil recovery process.This study aims to investigate the interactions between H_(2)S,oil,and carbonate formations,and to assess how the combi-nation of H_(2)S and low salinity water can impact the wettability and porosity of the reservoirs.A triple layer surface complexation model was used to understand the influence of key parameters(e.g.,pressure,brine salinity,and composition)on the H_(2)S-brine-oil-rock interactions.Moreover,the effects of mineral content of the carbonate rock on H_(2)S interactions were studied.Thereafter,the results of the H_(2)S-oil-brine-rock interactions were compared with a study where CO_(2) was used as the injected gas.Results of the study showed that the seawater and its diluted forms yielded identicalζ-potential values of about 3.31 mV at a pH of 3.24.This indicates that at very low pH condition,pH controls the ζ-potential of the oil-brine interface regardless of the brine's ionic strength.The study further demonstrated that the presence of other minerals in the carbonate rock greatly reduced the calcite dissolution.For instance,the calcite dissolution was reduced by 4.5%when anhydrite mineral was present in the carbonate rock.Findings from the simulation also indicated that CO_(2) produced negative ζ-potential values for the car-bonate rocks,and these values were reduced by 18.4%-20% when H_(2)S was used as the gas phase.This implies that the H_(2)S shifted the carbonate rockζ-potentials towards positive.The outcomes of this study can be applied when designing CO_(2) flooding and CO_(2) storage where the gas stream contains H_(2)S gas since H_(2)S greatly influences the dissolution of the carbonate mineral.