Leaching behavior of Pb and Zn in air pollution control residues and their modeling prediction

Increasing attention has been paid to air pollution control （APC） residues in China recently due to the rising proportion of waste incineration and the hazardous characteristics of the residues, among which heavy metal leaching toxicity plays an important role. Leaching behavior and potential risk of Pb and Zn in the APC residues from a Shanghai municipal solid waste （MSW） incinerator was studied, based on the leaching tests under different conditions and theoretical calculation using a geochemical thermodynamic equilibrium model MINTEQA2. Results showed that, extractant species and liquid to solid （L/S） ratio predominantly controlled the leaching toxicity of Pb and Zn, while ionic strength, vibration method and leaching time had less effect on the metals release. Leachate/final pH determined the metal leaching behavior, which changed the speciation of heavy metals in the extraction system. The equilibrium aqueous speciation, precipitation-dissolution of Pb and Zn was investigated according to the model computation, which was well in agreement with the experimental results.

Early Postemergence Herbicide Tank-Mixtures for Control of Waterhemp Resistant to Four Herbicide Modes of Action in Corn

Multiple-herbicide-resistant (MHR) waterhemp has been confirmed and is difficult to control for growers in Ontario, Canada and in the Midwestern United States. The objective of this study was to evaluate early post-emergence (EPOST) herbicides for control of MHR waterhemp in field corn. Five field trials were conducted over a two-year period (2019, 2020) at sites on Walpole Island, ON and near Cottam, ON, Canada. Thirteen herbicide tank-mixtures containing multiple modes-of-action (MOA) were applied EPOST to 5 cm MHR waterhemp in field corn. Control of MHR waterhemp varied by site due to variable plant density, plant biomass, and number of herbicide-resistant individuals across research sites and years. Control of MHR waterhemp ranged from 90% to 100% with glyphosate + S-metolachlor/mesotrione/ bicyclopyrone/atrazine, glyphosate/2,4-D choline + rimsulfuron + mesotrione + atrazine, glyphosate + S-metolachlor/atrazine/mesotrione, glyphosate + mesotrione + atrazine, glyphosate/S-metolachlor/mesotrione + atrazine, glyphosate + S-metolachlor/mesotrione/bicyclopyrone, glyphosate/2,4-D choline + rimsulfuron + mesotrione, and glyphosate + pyroxasulfone + dicamba/atrazine at 4, 8, and 12 WAA. Control of MHR waterhemp ranged from 70% to 100% with glyphosate + topramezone/dimethenamid-P + dicamba/atrazine, glyphosate + isoxaflutole + atrazine, and glyphosate + tolpyralate + atrazine at 4, 8, and 12 WAA. Control of MHR waterhemp was similar for all herbicide programs, except glyphosate + dicamba/atrazine and glyphosate + S-metolachlor/atrazine which resulted in the lowest control at three of five sites that ranged from 63% to 89% and 61% to 76%, respectively. Crop injury was ≤10% for herbicide programs tested, except 28% to 31% corn injury with glyphosate/2,4-D choline + rimsulfuron + mesotrione + atrazine;however, without effect on corn grain yield. Corn yield was comparable with all herbicide programs evaluated in this study. It is concluded that there are herbicide programs that provide control of emerged and full-season residual control of MHR waterhemp in field corn.

Pesticide Residue Control in the Years 1983-1985

Levels of organochlorinated, organophosphate, dithiocarbamic, benzimidazolic, and phthalimidic compounds, as well as some other pesticide residues obtained from Regional Laboratories in the years 1983-1985, were assembled and presented as a part of a study aimed at evaluating food contamination. Approximately 2000 samples of vegetables, fruits, cereals, and food of animal origin were analyzed by local laboratories during the years 1983, 1984, and 1985. Samples were randomly obtained from the market, at production levels, or sometimes at custom sites. Approximately 10,000 determinations of single compounds or classes of compounds were carried out. The analytical results are presented and compared with the Italian maximum residue limits. In the majority of the samples analyzed, either there were no residues or the residues were below the permitted level for the specific pesticide in each commodity. High levels of residues were present in a few cases, mainly with respect to some fungicides in fruits and vegetables and chlorinated compounds in some animal products. (c)1989 Academic Press, Inc.

Pesticide Residue Control in the Years 1986-1987

Results of analytical surveys on pesticide residue levels in foods for the years 1986-1987 are presented. Analytical data obtained from regional laboratories are tabulated in terms of various commodity groups (vegetables, fruit, cereals, processed or derived foodstuffs, other commodities, legumes, environmental samples, others) and are compared with maximum legal tolerances established by the ministerial ordinance (Italian Ministry of Health) 6.6. 1985.On a total number of 4715 determinations of classes of compounds or of single compounds made on 1601 commodities samples, only N 53 (1.1 %) violative results appeared. No residue was found at levels exceeding regulatory limits or found in commodities where a tolerance had not been established for a specific pesticide/commodity combination.

Pesticide Residue Control in the Years 1988-1989 in Italy

The paper reports the monitoring for pesticide residue contamination of foodstuffs carried out in the years 1988-1989 by the Italian peripheral laboratories officially commissioned for the task. The tables show the analytical data for each class of substrate versus the limits in force at the time. 2506 food samples and 555 samples from the environment were analysed and a total of 16259 determinations made.The residues were absent in 90% of the cases; the percentage of irregularities was 1.52%. These results confirm the data obtained in previous years, which is particularly significant considering the much larger number of analytical determinations performed this time.It has been deemed convenient to survey specific types of foodstuffs (for example, cereals and animal products) by examining a larger number of samples.

ToMFIR-based fault detection approach in frequency domain

This paper is to explore further results for total measurable fault information-based residual（ToMFIR） approach to fault detection in dynamic systems.The ToMFIR contains the essential fault information and remains unaffected by control actions in a closed-loop system.It is composed of controller residual and output residual and some of further results are developed in frequency domain.Besides the ability of detecting actuator and sensor faults,it is able to detect faults/failures resulting from the computer used for control purpose that generates control signals.Currently,all of existing fault detection schemes cannot achieve the same task at all.A practical DC motor example,with a PID controller,is used to demonstrate the effectiveness of the ToMFIR-based fault detection.A comparison with the standard observer-based technique is also provided.

Double Misplaces of SOE＇s Ownership and the Loss of Claim Rights

Modem enterprise theory defines onterprise＇s ownership through the concepts of residual rights of control and claim to residue. It also believes that when they are in homologous, the ownership of enterprise can be arranged in the best place. When the enterprise is under normal run, shareholders are its owner, but when it goes into bankruptcy, claimers should take place of shareholders becoming the owner of the enterprise. But in China, the ownership of state-owned enterprise （SEE） goes into double misplaces. Management controls the enterprise under the normal run, which leads salaries to seize the earnings and share equities. The state who acts as the shareholder not only lessens investments but also fixes its earnings as much as possible. It gives up the claim to residue, which leads claimers to bear the enterprise＇s residual risks （when the residual income is negative）. When the enterprise goes into bankruptcy, as the shareholder, the state determines whether it can exist or not in order to maximize its own utility. Rights of claimer are being seriously damaged as they can be manipulated freely in the enterprise. Banks＇ bad debts are also in an extremely high level. In this article, the author will establish a model and use the relative data to do technical analysis.