High-speed directly modulated distributed feedback laser based on detuned loading and photon-photon resonance effect

A monolithic integrated two-section distributed feedback(TS-DFB)semiconductor laser for high-speed direct modulation is proposed and analyzed theoretically.The grating structure of the TS-DFB laser is designed by the reconstructionequivalent-chirp(REC)technique,which can reduce the manufacturing cost and difficulty,and achieve high wavelength controlling accuracy.The detuned loading effect and the photon-photon resonance(PPR)effect are utilized to enhance the modulation bandwidth of the TS-DFB laser,exceeding 37 GHz,while that of the conventional one-section DFB laser is only 16 GHz.When the bit rate of the non-return-to-zero(NRZ)signal reaches 55 Gb/s,a clear eye diagram with large opening can still be obtained.These results show that the proposed method can enhance the modulation bandwidth of DFB laser significantly.

Fano Resonance Effect in CO-Adsorbed Zigzag Graphene Nanoribbons

Quantum interference plays an important role in tuning the transport property of nano-devices. Using the non- equilibrium Green＇s Function method in combination with density functional theory, we investigate the influence to the transport property of a CO molecule adsorbed on one edge of a zigzag graphene nanoribbon device. Our results show that the CO molecule-adsorbed zigzag graphene nanoribbon devices can exhibit the Fano resonance phenomenon. Moreover, the distance between CO molecules and zigzag graphene nanoribbons is closely related to the energy sites of the Fano resonance. Our theoretical analyses indicate that the Fano resonance would be attributed to the interaction between CO molecules and the edge of the zigzag graphene nanoribbon device, which results in the localization of electrons and significantly changes the transmission spectrum.

Resonance Effect in Interaction Between South Asian Summer Monsoon and ENSO During 1958-2018

The study has shown that the shear component of the vertical integrated kinetic energy(Ks)over the box(40oE-100oE,0-20oN)can be used to measure the intensity of the South Asian summer monsoon(SASM).Based on its value averaged between June and August,the SASM can be divided into strong and weak monsoon episodes.Between1958 and 2018,there existed 16(16)strong(weak)monsoon episodes.Based on the calendar year,the relationship between the SASM and ENSO episodes can be grouped into six patterns:weak monsoon-El Ni?o(WM-EN),normal monsoon-El Ni?o(NM-EN),weak monsoon-non ENSO(WM-NE),strong monsoon-La Ni?a(SM-LN),normal monsoon-La Ni?a(NM-LN)and strong monsoon-non ENSO(SM-NE).Previous studies suggest that the WM-EN and SM-LN patterns reflect the correlated relationship between the SASM and El Ni?o/Southern Oscillation(ENSO)events.Therefore,we name these two strongly coupled categories WM-EN and SM-LN as the resonance effect.Two important circulations,i.e.,Walker circulation(WC)and zonal Asian monsoon circulation(MC),in the vertical plane are found to be not always correlated.The MC is controlled by thermal gradients between the Asian landmass and the tropical Indian Ocean,while the WC associated with ENSO events is primarily the east-west thermal gradient between the tropical South Pacific and the tropical Indian Ocean.Furthermore,the gradient directions caused by different surface thermal conditions are different.The main factor for the resonance effect is the phenomenon that the symbols of SSTA in the tropical Indian Ocean and the equatorial eastern Pacific are the same,but are opposite to that of the SSTA near the maritime continent.

Resonance suppression and electromagnetic shielding effectiveness improvement of an apertured rectangular cavity by using wall losses

The cavity-mode resonance effect could result in significant degradation of the shielding effectiveness （SE） of a shielding enclosure around its resonance frequencies. In this paper, the influence of coated wall loss on the suppression of the resonance effect is investigated. For this purpose, an equivalent circuit model is employed to analyze the SE of an apertured rectangular cavity coated with an inside layer of resistive material. The model is developed by extending Robinson＇s equivalent circuit model through incorporating the effect of the wall loss into both the propagation constant and the characteristic impedance of the waveguide. Calculation results show that the wall loss could lead to great improvement on the SE for frequencies near the resonance but almost no effect on the SE for frequencies far away from the resonance.

How minor structural changes generate major consequences in photophysical properties of RE coordination compounds;resonance effect,LMCT state

Lanthanide coordination compounds of the formula Na[Ln(L)4](1 Ln),where Ln=La^3+,Eu^3+,Gd^3+,Tb^3+,L=[L]-and HL=dimethyl(4-methylphenylsulfo nyl)amidophosphate,were synthesized.Their structural and spectro scopic properties were discussed in detail based on X-ray diffraction measurements,IR spectroscopy,absorption and emission spectroscopy at 293 and 77 K and theoretical calculations of the intramolecular energy transfer(IET)rates.DFT calculations were used to investigate the 1 Ln electronic properties re quired to calculate the transition rates.30 and 22 pathways of intramolecular nonradiative energy transfer were examined in the case of 1 Eu and 1 Tb,respectively.It is shown that the main pathway for sensitization of the lanthanide emission is either the triplet(1 Eu)or singlet(1 Tb)transfer,occurring mainly through the exchange mechanism.The energy rates for energy transfer from S1 and T1 equal WS=1.53×10^5 s^-1(1 Eu),WT=5.14×10^6 s^-1(1 Eu)and WS=4.09×10^7 s^-1(1 Tb),WT=6.88×10^5 s^-1(1 Tb).The crucial role of the 7 F5 level in the energy transfer process of 1 Tb and the participation of the LMCT state in the depopulation of the ligand singlet state of 1 Eu were demonstrated.The influence of the resonance effect on the splitting of the7 F1 level in 1 Eu was analyzed.By comparing the properties of 1 Ln with the properties of 2 Ln coordination compounds,sharing the same ligand and crystallizing in the same crystallographic system(monoclinic),but with a different space group,it is demonstrated how slight structural changes can affect the photophysical properties of Ln compounds.

Combined Effect of Classical Chaos and Quantum Resonance on Entanglement Dynamics

We use linear entropy of an exact quantum state to study the entanglement between internal electronic states and external motional states for a two-level atom held in an amplitude-modulated and tilted optical lattice. Starting from an unentangled initial state associated with the regular ＇island＇ of classical phase space, it is demonstrated that the quantum resonance leads to entanglement generation, the chaotic parameter region results in the increase of the generation speed, and the symmetries of the initial probability distribution determine the final degree of entanglement. The entangled initial states are associated with the classical ＇chaotic sea＇, which do not affect the final entanglement degree for the same initial symmetry. The results may be useful in engineering quantum dynamics for quantum information processing.

Photocatalytic seawater splitting by 2D heterostructure of ZnIn_(2)S_(4)/WO_(3) decorated with plasmonic Au for hydrogen evolution under visible light

Photocatalytic H_(2) evolution from seawater splitting presents a promising approach to tackle the fossil energy crisis and mitigate carbon emission due to the abundant source of seawater and sunlight on the earth.However,the development of efficient photocatalysts for seawater splitting remains a formidable challenge.Herein,a 2D/2D ZnIn_(2)S_(4)/WO_(3)(ZIS/WO_(3))heterojunction nanostructure is fabricated to efficiently separate the photoinduced carriers by steering electron transfer from the conduction band minimum of WO_(3) to the valence band maximum of ZIS via constructing internal electric field.Subsequently,plasmonic Au nanoparticles(NPs)as a novel photosensitizer and a reduction cocatalyst are anchored on ZIS/WO_(3) surface to further enhance the optical absorption of ZIS/WO_(3) heterojunction and accelerate the catalytic conversion.The obtained Au/ZIS/WO_(3) photocatalyst exhibits an outstanding H_(2) evolution rate of 2610.6 or 3566.3μmol g^(-1)h~(-1)from seawater splitting under visible or full-spectrum light irradiation,respectively.These rates represent an impressive increase of approximately 7.3-and 6,6-fold compared to those of ZIS under the illumination of the same light source.The unique 2D/2D structure,internal electric field,and plasmonic metal modification together boost the photocatalytic H_(2) evolution rate of Au/ZIS/WO_(3),making it even comparable to H_(2) evolution from pure water splitting.The present work sheds light on the development of efficient photocatalysts for seawater splitting.

A novel, simple and sensitive resonance scattering spectral method for the determination of chlorite in water by means of rhodamine B

A new resonance scattering method was proposed for the determination of chlorite, basing on the resonance scattering effect of rhodamine dye. In HCl-sodium acetate buffer solution, chlorite oxidizes 1- into 12 and the reaction of 12 and excess 1- results in If. It is respectively combined with rhodaminc dyes, including rhodamine B （RhB）, butyl rhodamine B （b-RhB）, rhodamine G （RhG） and rhodamine S （RhS）, to form association complex particles, which exhibit stronger resonance scattering （RS） effect at 400 nm. The chlorite concentration of ClO2 in the range of 0.00726-0.218 μg/ml, 0.0102-0.292 μg/ml, 0.00726-0.145 μg/ml and 0.0290- 0.174 μg/ml is respectively linear to the RS intensity of association complex particle systems at 400 nm for the RhB, b-RhB, RhG and RhS. The detection limits of the four systems were respectively 0.00436, 0.00652, 0.00580 and 0.01450μg/ml ClO2^-. In the four systems, the RhB system possesses good stability and high sensitivity. It has been applied to the analysis of chlorite in wastewater with satisfactory results.

Numerical Analysis of Magnetic-Shielding Effectiveness for Magnetic Resonant Wireless Power Transfer System

Magnetic radiation phenomena appear inevitably in the magnetic-resonance wireless power transfer （MR-WPT） system, and regarding this problem the magnetic-shielding scheme is applied to improve the electromagnetic performance in engineering. In this study, the shielding effectiveness of a two-coil MR-WPT system for different material shields is analyzed in theory using Moser＇s formula and Schelkunoff＇s formula. On this basis a candidate magnetic-shielding scheme with a double-layer structure is determined, which has better shielding effectiveness and coils coupling coefficient. Finally, some finite element simulation results validate the correctness of the theoretical analysis, and the shielding effectiveness with the double-layer shield in maximum is 30？dB larger than the one with the single-layer case.

Resonant magneto-optical Kerr effect induced by hybrid plasma modes in ferromagnetic nanovoids

With nanovoids buried in Co films, resonant structures were observed in spectra of polar magneto-optical Kerr effect（MOKE）, where both a narrow bandwidth and high intensity were acquired. Through changing the thickness of Co films and the lattice of voids, different optical modes were introduced. For a very shallow array of voids, the resonant MOKE was induced by Ag plasma edge resonance, for deeper ones, hybrid plasma modes, such as void plasmons in the voids, surface lattice plasmons between the voids, and the co-action of them, etc. resulted in resonant MOKE. We found that resonant MOKE resulted from the void plasmons resonance which possesses the narrowest bandwidth for the lowest absorption of voids. The simulated electromagnetic field（EF） distribution consolidated different effects of these three optical modes on resonant MOKE modulation. Such resonant polar MOKE possesses high sensitivity, which might pave the way to on-chip MO devices.

Assessment of Resonance Self-shielding Models during Burn-Up Calculations

Various approaches and models are used in deterministic codes to treat the resonance self-shielding behavior of cross-sections.The accuracy of the models used has a significant effect on the precision of calculations;hence it is essential to select the best self-shielding method that yields accurate results within a reasonable computational time.In the present paper,the performance of the statistical subgroup method and the subgroup projection method associated with the DRAGON5 code is assessed during the burnup of a fuel pin.Two types of fuel are investigated:UO2,and PuO2-UO2.The accuracy of the methods is determined by calculating the variation of the infinite multiplication factor and the reaction rates during burnup,and then the results are compared to the stochastic MCNP6 code.It is indicated that the performance of both methods in treating the resonance self-shielding effect is satisfactory and that the subgroup projection method has a better performance during burnup calculations.

Quantum Coupling Effect between Quantum Dot and Quantum Well in a Resonant Tunneling Photon-Number-Resolving Detector

Excited states of lnAs quantum dots （QDs） can be energetically coupled with the confined level of OaAs quantum wells （QWs） in a thin-barrier resonant tunneling diode （RTD）. Single charge variation in the coupled QD can effectively switch on/off the resonant tunneling current passing through RTD, not only for emcient single-photon detection but also for photon-number-resolving detection. We present the study of the Q,D-QW coupling effect in the quantum dot coupled resonant tunneling diode （QD-cRTD） and figure out important factors for further improving the detector performance.

Surface plasmon assisted high-performance photodetectors based on hybrid TiO_(2)@GaO_(x)N_(y)-Ag heterostructure

In this work,we reported a high-performance-based ultraviolet-visible(UV-VIS)photodetector based on a TiO_(2)@GaO_(x)N_(y)-Ag heterostructure.Ag particles were introduced into TiO_(2)@GaO_(x)N_(y)to enhance the visible light detection perfor-mance of the heterojunction device.At 380 nm,the responsivity and detectivity of TiO_(2)@GaO_(x)N_(y)-Ag were 0.94 A/W and 4.79×109 Jones,respectively,and they increased to 2.86 A/W and 7.96×1010 Jones at 580 nm.The rise and fall times of the response were 0.19/0.23 and 0.50/0.57 s,respectively.Uniquely,at 580 nm,the responsivity of fabricated devices is one to four orders of magnitude higher than that of the photodetectors based on TiO_(2),Ga_(2)O_(3),and other heterojunctions.The excellent optoelectronic characteristics of the TiO_(2)@GaO_(x)N_(y)-Ag heterojunction device could be mainly attributed to the synergistic effect of the type-Ⅱband structure of the metal-semiconductor-metal heterojunction and the plasmon resonance effect of Ag,which not only effectively promotes the separation of photogenerated carriers but also reduces the recombination rate.It is fur-ther illuminated by finite difference time domain method(FDTD)simulation and photoelectric measurements.The TiO_(2)@GaO_(x)N_(y)-Ag arrays with high-efficiency detection are suitable candidates for applications in energy-saving communica-tion,imaging,and sensing networks.

A Bi/BiOI/(BiO)_2CO_3 heterostructure for enhanced photocatalytic NO removal under visible light

Narrow-band BiOI photocatalysts usually suffer from low photocatalysis efficiency under visible light exposure because of rapid charge recombination. In this work, to overcome this deficiency of photosensitive BiOI, oxygen vacancies, Bi particles, and Bi2O2CO3 were co-induced in BiOI via a facile in situ assembly method at room temperature using NaBH4 as the reducing agent. In the synthesized ternary Bi/BiOI/(BiO)2CO3, the oxygen vacancies, dual heterojunctions (i.e., Bi/BiOI and Bi- OI/(BiO)2CO3), and surface plasmon resonance effect of the Bi particles contributed to efficient electron-hole separation and an increase in charge carrier concentration, thus boosting the overall visible light photocatalysis efficiency. The as-prepared catalysts were applied for the removal of NO in concentrations of parts per billion from air in continuous air flow under visible light illumination. Bi/BiOI/(BiO)2CO3 exhibited a highly enhanced NO removal ratio of 50.7%, much higher than that of the pristine BiOI (1.2%). Density functional theory calculations and experimental results revealed that the Bi/BiOI/(BiO)2CO3 composites promoted the production of reactive oxygen species for photocatalytic NO oxidation. Thus, this work provides a new strategy to modify narrow-band semiconductors and explore other bismuth-containing heterostructured visible-light-driven photocatalysts.

Novel indirect Z-scheme g-C3N4/Bi2MoO6/Bi hollow microsphere heterojunctions with SPR-promoted visible absorption and highly enhanced photocatalytic performance

The surface plasmonic resonance(SPR)effect of Bi can effectively improve the light absorption abilities and photogenerated charge carrier separation rate.In this study,a novel ternary heterojunction of g-C3N4/Bi2MoO6/Bi(CN/BMO/Bi)hollow microsphere was successfully fabricated through solvothermal and in situ reduction methods.The results revealed that the optimal ternary 0.4 CN/BMO/9 Bi photocatalyst exhibited the highest photocatalytic efficiency toward rhodamine B(RhB)degradation with nine times that of pure BMO.The DRS and valence band of the X-ray photoelectron spectroscopy spectrum demonstrate that the band structure of 0.4 CN/BMO/9 Bi is a z-scheme structure.Quenching experiments also provided solid evidence that the·O^2-(at-0.33 eV)is the main species during dye degradation,and the conduction band of g-C3N4 is only the reaction site,demonstrating that the transfer of photogenerated charge carriers of g-C3N4/Bi2 MoO 6/Bi is through an indirect z-scheme structure.Thus,the enhanced photocatalytic performance was mainly ascribed to the synergetic effect of heterojunction structures between g-C3N4 and Bi2MoO6 and the SPR effect of Bi doping,resulting in better optical absorption ability and a lower combination rate of photogenerated charge carriers.The findings in this work provide insight into the synergism of heterostructures and the SPR absorption ability in wastewater treatment.

Surface plasmon-enhanced dual-band infrared absorber for VO_x-based microbolometer application

We propose a periodic structure as an extra absorption layer（i.e., absorber） based on surface plasmon resonance effects, enhancing dual-band absorption in both middle wavelength infrared（MWIR） and long wavelength infrared（LWIR）regions. Periodic gold disks are selectively patterned onto the top layer of suspended SiN/VO_2/SiN sandwich-structure.We employ the finite element method to model this structure in COMSOL Multiphysics including a proposed method of modulating the absorption peak. Simulation results show that the absorber has two absorption peaks at wavelengths λ =4.8 μm and λ = 9 μm with the absorption magnitudes more than 0.98 and 0.94 in MWIR and LWIR regions, respectively. In addition, the absorber achieves broad spectrum absorption in LWIR region, in the meanwhile, tunable dual-band absorption peaks can be achieved by variable heights of cavity as well as diameters and periodicity of disk. Thus, this designed absorber can be a good candidate for enhancing the performance of dual band uncooled infrared detector, furthermore, the manufacturing process of cavity can be easily simplified so that the reliability of such devices can be improved.

Modeling transmittance through submicron silver slit arrays

Mid-infrared transmittance of submicron silver slit arrays was numerically studied with the finite difference time domain method. The slit width varies from 50 nm to 300 nm and a square feature may attach at either or both slit sides. Although the side length of features is one or two orders of magnitude shorter than the wavelength, the attached nanoscale features can modify the transmittance significantly. The transmittance was also further investigated in detail by looking into the electromagnetic fields and Poynting vectors of selected slit geometries. The investigation results show that such change can be attributed to the cavity resonance effect inside the slit arrays. The work is of great importance to the wavelength-selective devices design in optical devices and thermal application fields.

Removal of ions from produced water using Powder River Basin coal

In addition to being used as an energy source,coal also has significant potential for other,more sustainable uses including water treatment.In this study,we present a simple approach to treat water that was produced during oil production and contained a total dissolved solids(TDS)content of over 150 g/L using Powder River Basin(PRB)coal.PRB coal used as packing material in a flow-through column effectively removed 60%–80%of the cations and anions simultaneously.Additionally,71%–92%of the total organic carbon in the produced water was removed as was all of the total suspended solids.The removal mechanisms of both cations and anions were investigated.Cations were removed by ion exchange with protons from oxygen-containing functional groups such as carboxylic and phenolic hydroxyl groups.Anions,mainly Cl−1,appeared to be removed through either the formation of resonance structures as a result of delocalization of electrons within coal molecules or through ion–πinteractions.We propose that coal is a“pseudo-amphoteric”exchange material that can remove cations and anions simultaneously by exchanging ions with both ionized and non-ionized acids that are ubiquitous in coal structure or resonance effect.

On the Development of Meso-Scale Heavy Rain Parcels in China

Heavy rains occur in China frequently, which often bring us floods and serious disasters in the summer half-year. The meso-scale heavy rain parcels (MHRP) in the mid-latitude are usually developed in following cases:I.By the approaching, meeting and / or overlapping of different weather systems, when two or more different rainfall systems are getting to conjugate, some MHRPs could be developed, such as: 1) a new cold/warm front or squall line approaches an old front or squall, even when the old one is somewhat decrepit; 2) at the places where two or more synoptic systems with different characteristics are meeting together, such as the meeting of tropical cyclone with the cold airs coming from the mid- and / or high-latitudes, or the low latitude vortex meeting with the westerly trough; 3) at the intersections of some different weather systems, such as the intersection of drylines, squall lines or fronts moving from different directions; and 4) by the overlapping of rainfall parcels produced continuously from a meso-generation centre.II.Resonance Effect and Tibetan Plateau Influence are two reasons why high frequency of heavy and torrential rains arround the meiyu front is discussed also.

Molecular and Crystal Structure of 1-(4-Chlorophenyl)-3-(2-nitrophenyl)-1-triazene

The title compound, 1 (4 chlorophenyl) 3 (2 nitrophenyl) 1 triazene (C 12 \|H 9ClN 4O 2, M r =276.68) crystallized in the orthorhombic system,space group Pbca (#15), with a=7.040(1), b=13.520(2), c=26.253(3), V=2498.8(6) 3, D c =1.471g/cm 3, Z=8, μ (Mo Kα )=0.309mm -1 , F (000)=1136. The final R and wR are 0.0345 and 0\^0608 for 2428 observed reflections ( I>2σ(I) ), respectively. The title molecule has trans geometry about the central triazenyl linkage. The dihedral angle between the two phenyl rings is 5.5(2)° and the twist angle for the nitro group is 6.9(2)°. The whole molecule is almost coplanar, which results mainly from the intramolecular hydrogen bonds and the resonance effect in the middle of the skeleton. In the crystal structure, the inversion centre related molecules are packed anti parallely into mixed stacks through π…π interactions along [100] direction, and the interstack forces are mainly the hydrogen bonds and van der Waals interactions.