The AVO Effect of Formation Pressure on Time-Lapse Seismic Monitoring in Marine Carbon Dioxide Storage

The phase change of CO_(2) has a significant bearing on the siting, injection, and monitoring of storage. The phase state of CO_(2) is closely related to pressure. In the process of seismic exploration, the information of formation pressure can be response in the seismic data. Therefore, it is possible to monitor the formation pressure using time-lapse seismic method. Apart from formation pressure, the information of porosity and CO_(2) saturation can be reflected in the seismic data. Here, based on the actual situation of the work area, a rockphysical model is proposed to address the feasibility of time-lapse seismic monitoring during CO_(2) storage in the anisotropic formation. The model takes into account the formation pressure, variety minerals composition, fracture, fluid inhomogeneous distribution, and anisotropy caused by horizontal layering of rock layers(or oriented alignment of minerals). From the proposed rockphysical model and the well-logging, cores and geological data at the target layer, the variation of P-wave and S-wave velocity with formation pressure after CO_(2) injection is calculated. And so are the effects of porosity and CO_(2) saturation. Finally, from anisotropic exact reflection coefficient equation, the reflection coefficients under different formation pressures are calculated. It is proved that the reflection coefficient varies with pressure. Compared with CO_(2) saturation, the pressure has a greater effect on the reflection coefficient. Through the convolution model, the seismic record is calculated. The seismic record shows the difference with different formation pressure. At present, in the marine CO_(2) sequestration monitoring domain, there is no study involving the effect of formation pressure changes on seismic records in seafloor anisotropic formation. This study can provide a basis for the inversion of reservoir parameters in anisotropic seafloor CO_(2) reservoirs.

Formation damage mechanism and control strategy of the compound function of drilling fluid and fracturing fluid in shale reservoirs

For the analysis of the formation damage caused by the compound function of drilling fluid and fracturing fluid,the prediction method for dynamic invasion depth of drilling fluid is developed considering the fracture extension due to shale minerals erosion by oil-based drilling fluid.With the evaluation for the damage of natural and hydraulic fractures caused by mechanical properties weakening of shale fracture surface,fracture closure and rock powder blocking,the formation damage pattern is proposed with consideration of the compound effect of drilling fluid and fracturing fluid.The formation damage mechanism during drilling and completion process in shale reservoir is revealed,and the protection measures are raised.The drilling fluid can deeply invade into the shale formation through natural and induced fractures,erode shale minerals and weaken the mechanical properties of shale during the drilling process.In the process of hydraulic fracturing,the compound effect of drilling fluid and fracturing fluid further weakens the mechanical properties of shale,results in fracture closure and rock powder shedding,and thus induces stress-sensitive damage and solid blocking damage of natural/hydraulic fractures.The damage can yield significant conductivity decrease of fractures,and restrict the high and stable production of shale oil and gas wells.The measures of anti-collapse and anti-blocking to accelerate the drilling of reservoir section,forming chemical membrane to prevent the weakening of the mechanical properties of shale fracture surface,strengthening the plugging of shale fracture and reducing the invasion range of drilling fluid,optimizing fracturing fluid system to protect fracture conductivity are put forward for reservoir protection.

Application of 9-component S-wave 3D seismic data to study sedimentary facies and reservoirs in a biogasbearing area:A case study on the Pleistocene Qigequan Formation in Taidong area,Sanhu Depression,Qaidam Basin,NW China

To solve the problems in restoring sedimentary facies and predicting reservoirs in loose gas-bearing sediment,based on seismic sedimentologic analysis of the first 9-component S-wave 3D seismic dataset of China,a fourth-order isochronous stratigraphic framework was set up and then sedimentary facies and reservoirs in the Pleistocene Qigequan Formation in Taidong area of Qaidam Basin were studied by seismic geomorphology and seismic lithology.The study method and thought are as following.Firstly,techniques of phase rotation,frequency decomposition and fusion,and stratal slicing were applied to the 9-component S-wave seismic data to restore sedimentary facies of major marker beds based on sedimentary models reflected by satellite images.Then,techniques of seismic attribute extraction,principal component analysis,and random fitting were applied to calculate the reservoir thickness and physical parameters of a key sandbody,and the results are satisfactory and confirmed by blind testing wells.Study results reveal that the dominant sedimentary facies in the Qigequan Formation within the study area are delta front and shallow lake.The RGB fused slices indicate that there are two cycles with three sets of underwater distributary channel systems in one period.Among them,sandstones in the distributary channels of middle-low Qigequan Formation are thick and broad with superior physical properties,which are favorable reservoirs.The reservoir permeability is also affected by diagenesis.Distributary channel sandstone reservoirs extend further to the west of Sebei-1 gas field,which provides a basis to expand exploration to the western peripheral area.

Mapping the landscape of gastric signet ring cell carcinoma:Overcoming hurdles and charting new paths for advancement

BACKGROUND In recent years,the global prevalence of gastric cancer(GC)has witnessed a progressive decrease,accompanied by a step-growth in the incidence of gastric signet ring cell carcinoma(GSRCC).As precision medicine concepts progress,GSRCC,a distinct sub-type of GC,has drawn considerable attention from researchers.However,there still persist some controversies regarding the associated research findings.AIM To summarize the current obstacles and potential future directions for research on GSRCC.METHODS To begin with,all literature related to GSRCC published from January 1,2004 to December 31,2023 was subjected to bibliometric analysis in this article.Additionally,this paper analyzed the research data using CiteSpace,GraphPad Prism v8.0.2,and VOSviewer,which was obtained from the Web of Science Core Collection database.The analysis results were visually represented.RESULTS This study provided a comprehensive overview of the statistical characteristics of the 995 English articles related to GSRCC,including cited references,authors,journals,countries,institutions,and keywords.The popular keywords and clusters contain"prognosis","survival","expression","histology",and"chemotherapy".CONCLUSION The prognosis,precise definition and classification,as well as chemoresistance of GSRCC,continue to be crucial areas of ongoing research,whose directions are closely tied to advancements in molecular biology research on GSRCC.

Formation and evolution of secondary minerals during bioleaching of chalcopyrite by thermoacidophilic Archaea Acidianus manzaensis

The formation and evolution of secondary minerals during bioleaching of chalcopyrite by thermoacidophilic Archaea Acidianus manzaensis were analyzed by combining synchrotron radiation X-ray diffraction（SR-XRD） and S, Fe and Cu Kα X-ray absorption near edge structure（XANES） spectroscopy. Leaching experiment showed that 82.4% of Cu2＋ was dissolved by A. manzaensis after 10 d. The surface of chalcopyrite was corroded apparently and covered with leaching products. During bioleaching, the formation and evolution of secondary minerals were as follows： 1） little elemental sulfur, jarosite, bornite and chalcocite were found at days 2 and 4; and 2） bornite and chalcocite disappeared, covellite formed, and jarosite gradually became the main component at days 6 and 10. These results indicated that metal-deficiency sulfides chalcocite and bornite were first formed with a low redox potential value（360-461 m V）, and then gradually transformed to covellite with a high redox potential value（461-531 m V）.

Deformation mechanism of cold ring rolling in view of texture evolution predicted by a newly proposed polycrystal plasticity model

An explicit polycrystal plasticity model was proposed to investigate the deformation mechanism of cold ring rolling in view of texture evolution. The model was created by deducing a set of linear incremental controlling equations within the framework of crystal plasticity theory. It was directly solved by a linear algorithm within a two-level procedure so that its efficiency and stability were guaranteed. A subroutine VUMAT for ABAQUS/Explicit was developed to combine this model with the 3D FE model of cold ring rolling. Results indicate that the model is reliable in predictions of stress-strain response and texture evolution in the dynamic complicated forming process; the shear strain in RD of the ring is the critical deformation mode according to the sharp Goss component （{110}？100？） of deformed ring; texture and crystallographic structure of the ring blank do not affect texture type of the deformed ring;texture evolves rapidly at the later stage of rolling, which results in a dramatically increasing deformation of the ring.

Study on the Mycorrhizal Formation in the Offspring Tissue Culture Seedling Bottle of Pinus elliottii with Lecanosticta acicola Resistance

[Objective] The research aimed to study the mycorrhizal formation in the offspring tissue culture seedling bottle of Pinus elliottii with Lecanosticta acicola resistance.[Method] The mycorrhizal formation of Pinus elliottii regenerated plant in vitro was studied,and the growth condition of regenerated plant was observed.[Result] The culture substrate and the inoculation amount of mycorrhizal fungi had the big influence on the mycorrhizal formation in vitro.After the root primordia were induced by Pinus elliottii caespitose shoots,it was best to transplant in the perlite substrate and inoculate Pisolithus tinctorius,which was favorable for the mycorrhizal formation.When the two blocks of Pisolithus tinctorius were inoculated in the perlite medium,the mycorrhizal formation rate reached 84.4%.The dichotomous branching short root was the most,and 12.49 roots were formed in every main root.The mycorrhizal formation improved the survival rate of regenerated plant domestication transplantation.The mycorrhizal regenerated plant grew well in the phytotron,and the root system was developed.[Conclusion] The research provided the basis for improving the survival rate of Pinus elliottii tissue culture regenerated plant with Lecanosticta acicola resistance.

Ab initio Study on Formation Mechanism of Spiro-Si-Heterocyclic Ring Compound Involving Ge from H2Ge=Si： and Formaldehyde

H2Ge=Si： and its derivatives （X2Ge=Si：, X=H, Me, F, C1, Br, Ph, Ar, ...） are new species. Its cycloaddition reactions are new area for the study of silylene chemistry. The cycloaddition reaction mechanism of singlet H2Ge=Si： and formaldehyde has been investigated with the MP2/aug-cc-pVDZ method. From the potential energy profile, it could be predicted that the reaction has one dominant reaction pathway. The reaction rule is that two reactants firstly form a four-membered Ge-heterocyclic ring silylene through the [2＋2] cycloaddition reaction. Because of the 3p unoccupied orbital of Si： atom in the four-membered Ge-heterocyclic ring silylene and the π orbital of formaldehyde forming a π--p donor-acceptor bond, the four-membered Ge-heterocyclic ring silylene further combines with formaldehyde to form an intermediate. Because the Si： atom in the intermediate undergoes sp3 hybridization after transition state, then the intermediate isomerizes to a spiro-Si-heterocyclic ring compound involving Ge via a transition state. The result indicates the laws of cycloaddition reaction between H2Ge=Si： or its derivatives （X2Ge=Si：, X=H, Me, F, Cl, Br, Ph, Ar, ...） and asymmetric π-bonded compounds are significant for the synthesis of small-ring involving Si and Ge and spiro-Si-heterocyclic ring compounds involving Ge.

Spark-generated bubble collapse near or inside a circular aperture and the ensuing vortex ring and droplet formation

This paper aims to study the oscillation of a sparkgenerated submerged bubble located near or inside a circular aperture made in a flat plate using high-speed visualization technique. In the case of a bubble oscillating near an aperture the initial free surface of the water was set at the bottom surface of the plate. The effects of aperture size and bubblefree surface distance on the bubble behavior as well as on the ensuing droplet dynamics are investigated. It was found that the direction of the bubble reentrant jet was towards the aperture or away from it respectively when the normalized aperture size was smaller or greater than a certain critical value. In addition, a toroidal vortex ring was observed to form, which rotated inwards as it moved away from the aperture. It was also found that if the bubble was incepted at a distance sufficiently away from a supercritical size aperture a single droplet could be produced. In the case of a bub- ble initiated in the middle of a circular aperture submerged just beneath the water free surface, the bubble was found to take the shape of an ellipsoid during its expansion. Then a reentrant jet was initiated and pierced the bubble from its top side.

Geological Features and Reservoiring Mode of Shale Gas Reservoirs in Longmaxi Formation of the Jiaoshiba Area

This study is based on the sedimentation conditions, organic geochemistry, storage spaces, physical properties, lithology and gas content of the shale gas reservoirs in Longmaxi Formation of the Jiaoshiba area and the gas accumulation mode is summarized and then compared with that in northern America. The shale gas reservoirs in the Longmaxi Formation in Jiaoshiba have good geological conditions, great thickness of quality shales, high organic content, high gas content, good physical properties, suitable depth, good preservation conditions and good reservoir types. The quality shales at the bottom of the deep shelf are the main target interval for shale gas exploration and development. Shale gas in the Longmaxi Formation has undergone three main reservoiring stages：the early stage of hydrocarbon generation and compaction when shale gas reservoirs were first formed; the middle stage of deep burial and large-scale hydrocarbon generation, which caused the enrichment of reservoirs with shale gas; the late stage of uplift, erosion and fracture development when shale gas reservoirs were finally formed.

深水采油树Spring-Seal密封圈接触模型构建与实验测试

为提高深水采油树在高压、高温、低温等工况下长时间工作的稳定性,对采油树密封圈进行重新设计,提出Spring-Seal密封圈(以下简称S密封圈);基于赫兹接触理论、填料密封接触理论,重新构建S密封圈接触力学模型;建立有限元仿真分析模型,分析不同条件下S密封圈的密封性能,同时验证新建接触模型的合理性;利用实验测试S密封圈的实际密封效果。研究结果表明:S密封圈在高压、高温、低温等工况下能够长时间稳定工作且密封性能良好。研究结果可为S密封圈的接触研究及工程运用提供理论参考。

Effect of SDS/THF on thermodynamic and kinetic properties of formation of hydrate from a mixture of gases(CH_4+C_2H_6+C_3H_8) for storing gas as hydrate

In this work, the effect of sodium dodecyl sulfate(SDS) and combined effect of sodium dodecyl sulfate(SDS) and tetrahydrofuran(THF) on thermodynamic and kinetic properties of CH4+C2H6+C3H8hydrate formation have been studied. Four different concentrations of sodium dodecyl sulfate(100 ppm, 500 ppm,1000 ppm and 1500 ppm) have been used to see its effect on phase equilibrium condition and formation kinetics. Though sodium dodecyl sulfate(SDS) does not vary the pressure–temperature condition of hydrate formation, it has a prominent favorable effect on induction time, gas consumption, storage capacity and formation rate. The addition of 3%(mol) tetrahydrofuran(THF) to water + SDS system results in large shifts in phase equilibrium boundary to lower pressure and higher temperature. It has been noticed that the addition of tetrahydrofuran further enhances the formation rate. So the mixture of sodium dodecyl sulfate(SDS) and tetrahydrofuran(THF) can be effectively used as promoter for storing natural gas as hydrate.

Hot deformation in nanocrystalline Nd-Fe-B backward extruded rings

Radially oriented Nd-Fe-B rings are prepared by backward extrusion of fine grained melt-spun powder. Melt- spun powder with the nominal composition of Nd30.5Febal.Co6.0Ga0.6A10.2B0.9 （wt%） is used as starting material. The effects of process variables, such as deformation temperature （Td）, strain rate （ε） and height reduction （△h%）, on the magnetic properties of the rings are investigated. A scanning electron microscope （SEM） equipped with an energy spectrum device is used to study the metallograph and microfracture of the extruded rings. The Br and （BH）max reach the optimum values at Td =800℃,ε= 0.01 mm/s, and △h% = 70%. It is found by SEM observations that the particle boundaries, which seemingly correspond to the interfaces of the starting melt-spun powders, emerge after the corrosion of metallography specimens. This is helpful for studying the effects of powder-powder interface on the local deformation and deformation homogeneity in the rings. For different spatial positions of the extruded rings, there are characteristic metallographies and microfractures. The upper end of the rings has the least deformation and worst texture, and therefore the worst magnetic properties. The magnetic properties in the radial direction increase slightly along the axis from the bottom to the middle, then steeply decrease at the upper end of the ring. The deformation and the formation-of-texturing processes are discussed. The deformation and the texturing formation of melt-spun Nd-Fe-B alloys probably involve grain boundary sliding and grain rotation, the solution-precipitation process and preferential growth of Nd2Fel4B nanograins along the easy growth a-axis.

Salt-Gathering and Potassium Formation of Potassium-Rich Brine during the Triassic in the Sichuan Basin, China

Potassium-rich brine in the Sichuan Basin has been much studied in recent years, but few studies have focused on the distribution and migration of salt basin and the differences of potassium formation mechanisms. This work examined the salt-gathering and potassium formation of potassiumrich brine during the Triassic in the Sichuan Basin using lithofacies palaeogeographic depiction and geochemical analyses.(1) The favorable sedimentary facies controlling the formation of potassium-rich brine during the Triassic in the Sichuan Basin are evaporation platform and restricted platform, whereas the salt basin is one of the main factors controlling the poly-salt center.(2) The distribution and migration of this salt basin were affected by certain factors. The salt basin of the Jialingjiang Formation was mainly distributed in the east and central Sichuan Basin, whereas that of the Leikoupo Formation was mainly distributed in the central and west Sichuan Basin. The sedimentary centers have gradually moved westward and become smaller.(3) Three main formation mechanisms were identified for the potassium-rich brine during the Triassic in the Sichuan Basin, i.e., evaporation and concentration of seawater, surface fresh water leaching, and deep water-rock reaction. Fresh water leaching was characterized by low anomaly δ18 O and δ13 C values. Water-rock reaction was mainly related to temperature, and high temperature environment(caused by burial depth, overthrust and deep hydrothermal fluids) was beneficial to water-rock reaction. The characteristics of water-rock reaction do not correspond to the increase ratio of K·103/Cl and Br·103/Cl in brine, and the Rb+ content of the brine was high.(4) The formation mechanisms of potassium-rich brine differed between different areas of the Sichuan Basin. In east Sichuan, the evaporation and concentration of seawater, together with meteoric fresh water leaching, was the main formation factor, whereas the evaporation and concentration of seawater and water–rock reaction predominated in west Sichuan. This study of the sedimentary environment and formation mechanisms is of significance to the exploration and exploitation of potassium-rich brine in the Sichuan Basin.

The Identification and Modeling of the Volcanic Weathering Crust in the Yingcheng Formation of the Xujiaweizi Fault Depression, Songliao Basin

Through the analysis of core descriptions, well-logs, seismic data, geochemical data and structural settings of the volcanic rock of the Yingcheng Formation in the Xujiaweizi fault depression, Songliao Basin, and the geological section of the Yingcheng Formation in the southeast uplift area, this work determined the existence of volcanic weathering crust exists in the study area. The identification marks on the volcanic weathering crust can be recognized on the scale of core, logging, seismic, geochemistry, etc. In the study area, the structure of this crust is divided into clay layer, leached zone, fracture zone and host rocks, which are 5-118 m thick （averaging 27.5 m）. The lithology of the weathering crust includes basalt, andesite, rhyolite and volcanic breccia, and the lithofacies are igneous effusive and extrusive facies. The volcanic weathering crusts are clustered together in the Dashen zone and the middle of the Xuzhong zone, whereas in the Shengshen zone and other parts of the Xuzhong zone, they have a relatively scattered distribution. It is a major volcanic reservoir bed, which covers an area of 2104.16 km2. According to the geotectonic setting of the Songliao Basin, the formation process of the weathering crust is complete. Combining the macroscopic and microscopic features of the weathering crust of the Yingcheng Formation in Xujiaweizi with the logging and three-dimensional seismic sections, we established a developmental model of the paleo uplift and a developmental model of the slope belt that coexists with the sag on the Xujiaweizi volcanic weathering crust. In addition, the relationship between the volcanic weathering crust and the formation and distribution of the oil/gas reservoir is discussed.

Accumulation Conditions of Organic Matter during the Deposition of Black Shales of the Buxin Formation (Early Paleogene) in the Sanshui Basin, South China

Analyses of organic carbon, nitrogen, sulfur and iron have been performed in order to understand sources and preservation of organic matter in black shale of the Buxin Formation (Early Paleogene) from the Sanshui Basin. The C/N ratios show that the organic matter is characterized by a mixture of terrestrial and phytoplanktonic contributions. The relative importance of different sources depend on climate conditions and most of organic matter is of terrestrial origin. The relationships between C, S and Fe indicate that the brackish environment with alternation of anoxia and low-O2 developed in the bottom waters during the deposition of these organic-rich sediments as a result of a mixed setting of thermal stratification and salinity stratification, the latter being the consequence of intermittent sea water incursion. Bacterial sulfate reduction is the most effective early diagenesis affecting the preservation of organic matter. The intensity of sulfate reduction is related to the relative proportion of metabolizable organic matter supplied to sediments.

EVOLUTIONARY ALGORITHMS WITH PREFERENCE FOR MANUFACTURING CELLS FORMATION

Due to the combinatorial nature of cell formation problem and the characteristics of multi-objective and multi-constrain, a novel method of evolutionary algorithm with preference is proposed. The analytic hierarchy process （AHP） is adopted to determine scientifically the weights of the sub-objective functions. The satisfaction of constraints is considered as a new objective, the ratio of the population which doesn＇t satisfy all constraints is assigned as the weight of new objective. In addition, the self-adaptation of weights is applied in order to converge more easily towards the feasible domain. Therefore, both features multi-criteria and constrains are dealt with simultaneously. Finally, an example is selected from the literature to evaluate the performance of the proposed approach. The results validate the effectiveness of the proposed method in designing the manufacturing cells.

Transcriptional,post-transcriptional and post-translational regulations of gene expression during leaf polarity formation

Leaf morphogenesis requires the establishment of adaxlal-abaxlal polarity after primordium initiation from the snoot apical meristem （SAM）. Several families of transcription factors are known to play critical roles in promoting adaxial or abaxial leaf fate. Recently, post-transcriptional gene silencing pathways have been shown to regulate the establishment of leaf polarity, providing novel and exciting insights into leaf development. For example, microRNAs （miR 165/166） and a trans-acting siRNA （TAS3-derived tasiR-ARF） have been shown to repress the expression of several key transcription factor genes. In addition, yet another level of regulation, post-translational regulation, has been revealed recently by studies on the role of the 26S proteasome in leaf polarity. Although our understanding regarding the molecular mecha- nisms underlying establishment of adaxial-abaxial polarity has greatly improved, there is still much that remains elusive. This review aims to discuss recent progress, as well as the remaining questions, regarding the molecular mechanisms underlying leaf polarity formation.

Water transfer characteristics in the vertical direction during methane hydrate formation and dissociation processes inside non-saturated media

In order to study water transfer characteristics inside non-saturated media during methane hydrate formation and dissociation processes,water changes on the top,middle and bottom locations of experimental media during the reaction processes were continuously followed with a novel apparatus with three pF-meter sensors.Coarse sand,fine sand and loess were chosen as experimental media.It was experimentally observed that methane hydrate was easier formed inside coarse sand and fine sand than inside loess.Methane hydrate formation configuration and water transfer characteristics during methane hydrate formation processes were very different among the different non-saturated media,which were important for understanding methane hydrate formation and dissociation mechanism inside sediments in nature.

Formation mechanism of methane during coal evolution:A density functional theory study

The formation mechanism of methane （CH4） during coal evolution has been investigated by density functional theory （DFT） of quantum chemistry. Thermogenic gas, which is generated during the thermal evolution of medium rank coal, is the main source of coalbed methane （CBM）. Ethylbenzene （A） and 6,7-dimethyl-5,6,7,8-tetrahydro-1-hydroxynaphthalene （B） have been used as model compounds to study the pyrolysis mechanism of highly volatile bituminous coal （R）, according to the similarity of bond orders and bond lengths. All possible paths are designed for each model. It can be concluded that the activation energies for H-assisted paths are lower than others in the process of methane formation; an H radical attacking on β-C to yield CH4 is the dominant path for the formation of CH4 from highly volatile bituminous coal. In addition, the calculated results also reveal that the positions on which H radical attacks and to which intramolecular H migrates have effects on methyl cleavage.