Copper-organic Framework Constructed from Rod-shaped Secondary Building Units with Selective Sorption Property

One novel metal-organic framework [Cu2（L）（μ3-OH）]n（1, H3L = [1,1＇：3＇,1＇＇-terphenyl]-4,4＇＇,5＇-tricarboxylic acid） has been synthesized and characterized by single-crystal powder X-ray diffraction, IR and thermogravimetric analyses. Complex 1 crystallizes in orthorhombic crystal system, space group Pbca with a = 21.573（19）, b = 5.404（5）, c = 33.78（3） ？, C21H（12）O7Cu2, Mr = 503.39, V = 3938（6） A^3, Z = 8, Dc = 1.698 g·cm^-3, μ = 2.202 mm^-1, F（000） = 2016, 1.531〈θ〈25.009°, λ（Mo Kα） = 0.71073 A, T = 293（2） K, the final R = 0.0448 and wR = 0.1002. The structure of complex 1 is a three-dimensional（3D） framework based on infinite rod-shaped secondary building units and can be simplified as kgd topology. The gas adsorption measurements for N2, CO2, H2O, CH3OH and CH3CH2OH have been done. Fortunately, the selective sorption of CO2 over N2 was found at 195 K.

Characterization of dominant giant rod-shaped magnetotactic bacteria from a low tide zone of the China Sea

Magnetotactic bacteria are a group of Gram-negative bacteria that synthesize magnetic crystals, enabling them to navigate in relation to magnetic field lines. Morphologies of magnetotactic bacteria include spirillum, coccoid, rod, vibrio, and multicellular morphotypes. The coccid shape is generally the most abundant morphotype among magnetotactic bacteria. Here we describe a species of giant rod-shaped magnetotactic bacteria(designated QR-1) collected from sediment in the low tide zone of Huiquan Bay(Yellow Sea, China). This morphotype accounted for 90% of the magnetotactic bacteria collected, and the only taxonomic group which was detected in the sampling site. Microscopy analysis revealed that QR-1 cells averaged(6.71±1.03)×(1.54±0.20) m m in size, and contained in each cell 42–146 magnetosomes that are arranged in a bundle formed one to four chains along the long axis of the cell. The QR-1 cells displayed axial magnetotaxis with an average velocity of 70±28 mm/s. Transmission electron microscopy based analysis showed that QR-1 cells had two tufts of fl agella at each end. Phylogenetic analysis of the 16 S r RNA genes revealed that QR-1 together with three other rod-shaped uncultivated magnetotactic bacteria are clustered into a deep branch of A lphaproteobacteria.

SYNTHESIS AND CHARACTERIZATION OF MAIN CHAIN AROMATIC LIQUID CRYSTAL COPOLYESTERS WITH X-SHAPED AND ROD-SHAPED MESOGENIC UNITS

A series of main chain liquid crystal aromatic copolyesters with X-shaped and rod-shaped mesogenic units were synthesized via solution condensation polymerizations of 4,4'-(alpha,omega-octanedioyloxy)-dibenzoyl dichlorides with 2,5-bis(p-octanoxy benzoyloxy)-hydroquinone and diphenol. All of the copolyesters showed thermotropic liquid crystalline behaviors through observations using DSC, polarized microscopy and X-ray diffraction. The melting point (T-m) and the isotropization temperature (T-i) change regularly with varying the content of diphenol unit in the copolymers.

Research on Penetration Rules of LY-12cz Thin Sheet Subjected to Rod-Shaped Fragment

By establishing the finite element models and corresponding calculation methods for the target board and rod-shaped fragment, the penetration effect of the high-velocity rod-shaped fragments＇ impact on the LY- 12cz thin sheet is analyzed by analog calculation. The variation rules of the residual velocity and residual mass of fragments, chock mass and crevasse shape are obtained when the fragment penetrates target board with different incidence velocities and attack angles. Corresponding fitting computation formulas are concluded from the above calculating data. The conclusions are helpful to analyzing the destructivity of fragment and protective ability of aircraft structure. In addition, they can guide the research for battle damage mode and assessment effectively.

Influences of the Shape of Rods in Two Dimension Photonic Crystals on Their Defect Eigenmodes

The cross section of photonic crystal fiber (PCF) is a two dimensional photonic crystal. The rods formed in PCF are not exact cylinders, the shape of rods will affect the eigenmode formed in two dimensional photonic crystals around a defect. Based on the relations between the defect eigenmodes and the radius of dielectric cylinders, the defect eigenmodes in photonic crystals in which the ellipse rods take the place of cylinders are studied by numerical calculation. The analysis of the relation between the eigenfrequency and the minor axis radius of ellipse rods show that the defect eigenfrequency is controlled by the cross section area of rods and the distribution of electromagnetic field around the defect is also affected by the cross section shape of rods. It provides a better way to modify the distribution of electromagnetic fields in photonic crystal and keeps the eigenfrequency unchanged.

棒电极直径和端部形状对短空气间隙交流击穿电压的影响研究

空气间隙交流击穿特性试验常采用棒棒、棒板电极作为试验电极,目前棒电极直径、棒端部形状对空气间隙交流击穿电压的影响尚不清晰。为此,用直径2 cm、1 cm的圆棒和直径1 cm的尖棒搭建棒棒、棒板电极,开展5~40 cm短空气间隙下的交流击穿试验,研究棒电极直径和端部形状对空气间隙交流击穿电压的影响。结果表明:在试验棒电极直径和端部形状范围内,空气间隙距离5~20 cm时,各棒棒或棒板电极空气间隙击穿电压相对偏差在5.93%~33%之间,随着空气间隙距离增大,棒电极直径和端部形状对棒棒、棒板空气间隙击穿电压的影响逐渐减弱;空气间隙距离大于20 cm时,各棒棒或棒板电极空气间隙击穿电压相对偏差均小于5%。研究认为,空气间隙距离超过20 cm时,棒电极直径和端部形状对棒棒、棒板空气间隙击穿电压无影响。

基于角度偏差自校正的光纤形状传感结构设计

光纤形状传感中FBG的放置角度误差会影响曲率的计算精度,从而增大形状反演的误差。为了实现传感胶棒的角度自校正,设计了一种自校正形状传感结构,在传感胶棒的感知截面上布设9个FBG,以120°等角度间隔作为基准位置,分别提取±10°位置上的应变,从而实现FBG响应与角度偏差的函数映射。提出了一种基于角度偏差自校正算法,通过适应度函数完成对传感参量α与k的阈值优化,实现任意角度偏差的自校正。仿真分析不同α与k条件下的响应关系,发现α具有很好的线性变化特性,k仅随主敏感FBG波动的特性。在单截面实验中,加载0~100 N应力变化后,9个FBG的平均响应度介于[-1.012με/N,0.987με/N]之间。响应度的正负可以表征弯曲方向,相邻FBG的响应也具有很好的线性度。在组合截面实验中,根据反演结果重建传感胶棒三维结构,输出各点位坐标和应力值信息。

棒状结构NaGdF_(4):Yb^(3+),Er^(3+)上转换发光性能的研究

以乙二胺四乙酸二钠(EDTD-2Na)为螯合剂,采用水热法合成了棒状结构的NaGdF_(4):Yb^(3+),Er^(3+)纳米粉末。分别借助X射线衍射(XRD)、荧光光谱仪(PL)和扫描显微镜(SEM)对其晶体结构、发光强度和表面形貌进行分析和表征。探究了稀土前驱体、水热温度和水热时间的实验条件对NaGdF_(4):Yb^(3+),Er^(3+)纳米粉末上转换发光强度的影响;研究了氟源和钠源对NaGdF_(4):Yb^(3+),Er^(3+)晶体形貌和上转换发光强度的改善;同时,采用煅烧处理的方法,进一步探究样品的形貌和发光强度收到的影响。实验结果表明NH4F与NaOH作为氟源和钠源及200℃煅烧1 h得到的棒状结构NaGdF_(4):Yb^(3+),Er^(3+)的发光强度最好,色坐标(CIE)绿色发光强度从84%提升到94.88%。

轧钢硬线盘条卷形质量控制优化改造实践

为了提升硬线盘条卷形质量和尺寸精度,先后实施了预精轧水冷段失水段参数调整、优化加热工艺,降低均热段加热温度,优化轧机动态速降补偿系数,优化17架轧机料形尺寸,设计吐丝管专用存放货架,在双芯棒升降缸处设置防挂线装置等技术改造,项目实施后取得了良好的效果。

花篮拉杆式型钢悬挑脚手架施工技术应用

基于悬挑外架的发展历程和形式,着重介绍一种花篮拉杆式型钢悬挑脚手架,结合实际项目,对该脚手架施工工艺流程及应用情况进行了阐述,并分析其在成本、进度、质量、安全等方面的优势,得出其在同类工程中推广应用的可行性。

TLC-FID法测定延迟焦化原料油族组成

用三种不同极性展开剂在棒状薄层色谱棒上较好地将延迟焦化原料油分离为饱和烃、芳烃、胶质和沥青质四个族组分,建立了用棒状薄层色谱法-氢焰检测器(TLC-FID)快速测定延迟焦化原料油族组成的方法。通过重复性试验考察本方法的精密度,四组分相对标准偏差均小于3.00%,极差值均小于3.50%。

地铁用e型弹条异常断裂原因分析

材质为60Si2Mn的某e型弹条进行疲劳试验时,当循环次数仅为60万次时发生断裂。为查找断裂原因,对e型弹条断裂处的形貌、能谱、金相组织、硬度和化学成分等进行分析。分析结果表明:由于弹条原材料表面存在拉伤沟和夹杂物,在疲劳试验过程中受高应力交变载荷的作用,在弹条拉伤沟处产生应力集中,并逐渐形成微裂纹。同时,由于回火马氏体的存在,导致形变过程中产生位错塞积,形成高应力区,加快裂纹扩展,最终导致弹条在较短时间内断裂。

襄阳东站钢屋盖超多杆连接节点设计与足尺模型试验研究

襄阳东站屋盖南北向长358m,东西向最大跨度86m,采用焊接球钢网架,整体不设变形缝,南端开设瀑布造型大洞口,由于屋盖结构超长、不连续、大悬挑及瀑布造型使得钢屋盖空间受力十分复杂,特在分叉柱柱顶沿南北向设置加强杆以加强屋盖瀑布区洞口两侧边缘约束刚度及改善结构整体受力性能。钢屋盖瀑布区悬挑端分叉柱柱顶节点相连杆件达12根之多,该节点作为屋盖结构的关键节点,其受力状态尤为复杂,创新地采用了半铸造半相贯焊连接形式并采取了构造加强措施,针对该超多杆连接节点进行了足尺模型加载试验验证,详细介绍了试验加载装置、加载方案、试验现象及试验结果,并进行了有限元对比分析。结果表明有限元对比分析结果与加载试验吻合较好;该超多杆半铸造半相贯焊连接节点构造合理、承载力高,薄弱部位出现在与铸造本体相连的接长钢管上,满足强节点弱构件、强连接弱构件的设计要求。

上拉杆式悬挑脚手架在异形幕墙施工中的应用研究

对型钢悬挑脚手架及上拉杆式悬挑脚手架等2种类型悬挑脚手架钢梁受力模式进行了对比,说明了上拉杆式悬挑脚手架的受力优势。重点分析了上拉杆式悬挑脚手架体系的上拉杆上端偏离悬挑梁所在竖平面对该体系受力的影响。以上海某城市核心区综合体项目幕墙装饰施工为例,针对裙房影院部分调控区外墙为非结构混凝土墙,外部为异形幕墙装饰,导致施工存在的难题,为保证现场施工进度及施工安全,成功应用了上拉杆式悬挑脚手架,确保了施工过程安全并降低工程费用,总结的经验可供类似工程参考。

月牙形系杆拱桥设计方案研究

拱桥的结构型式优美,空间造型符合景观性要求,在平原区得到广泛应用。文章依托浙江阜溪桥,提出一种月牙形系杆拱桥设计方案,对月牙形拱圈的空间定位方法进行研究。采用Midas Civil有限元分析软件建立空间计算模型,对月牙形系杆拱桥的拱圈、桥面系及吊杆等构件进行了系统的强度、刚度和稳定性验算。验算结果表明,月牙形系杆拱桥满足结构受力需求,是一种新颖可行的桥型结构。

ANALYTICAL SOLUTIONS FOR RESPONSE OF COLLISION OF PARTICLE WITH CONICAL ROD CAUSED BY LONGITUDINAL VIBRATION

The objective is to present exact analytical solutions of longitudinal impact analysis for slender conical rods struck by a particle and a new method is proposed for conical rod-particle impact analysis, in which the superposition method is used and the response of the rod is presented. These analytical results are exact and can be used to validate the numerical methods or other analytical results. The numerical example shows that one of the advantages of the present method is that the analytical form is very simple. The result is that mass ratio and some variables describing the geometrical shape of rods such as taper, length and radius play an important role in impact dynamic system.

中空杆状C/WS_(2)复合材料的制备及其储钠性能研究

二硫化钨由于具有独特的层状结构、大的层间距等优点,已经成为一种非常有潜力的钠离子电池负极材料,但是其导电性差、充放电过程中易发生体积膨胀的不足限制了它进一步的广泛应用.本文以六氯化钨、硫代乙酰胺以及自制的空心碳壳为原料,采用溶剂热法合成了一种中空杆状结构的C/WS_(2)复合材料,将其用于钠离子电池来改善其上述存在的问题.结果表明,在2 A g^(-1)的电流密度下,循环90圈后,C/WS_(2)电极的比容量仍能达到417.1 mAh g^(-1);在10.0 A g^(-1)的大电流密度下,还具有343.3 mAh g^(^(-1))的比容量.因此,中空杆状C/WS2复合材料具有优异的储钠性能.

杆状内构件对旋风分离器流场和性能的调控

采用雷诺应力模型(Reynold Stress Model,RSM)和DPM模型(Discrete Phase Model,DPM)对增设杆状内构件的Stairmand型旋风分离器内的气固两相流动进行了数值模拟分析,考察了不同杆件位置对旋流流场特征和涡结构及分离效率的影响规律。计算结果表明,增设杆件于旋分器内部非轴心位置,随着杆远离几何中心切向速度先增大后减小,且当杆件置于外旋流区域时切向速度降低幅度更大。因此,杆件置于非轴心位置时能起到减阻的效果,且随着杆远离几何中心,减阻幅度先增加后减小,杆件位于外旋流时减阻幅度最大,最高可达38.3%。随着杆件远离旋风分离器几何中心,Stk 50先增大后减小,其分离性能先降低后升高。杆件置于轴心位置时,分离效率最高,同时压力降也最高。杆件位置的改变能影响旋风器的流场分布,从而影响其性能。可以根据应用场景的需求,选择合适杆件的位置。以高分离效率为标准时,可将杆件置于距离几何中心较近的位置,甚至置于几何中心处。以低能耗为标准时,可将杆件置于距离几何中心较远的位置。

柱状珊瑚砂静水沉降试验研究

沉降速度是珊瑚砂的一个重要物理参数。由于柱状珊瑚砂与其他形状的珊瑚砂有着明显的差异,套用现有珊瑚砂的沉速公式进行计算并不合适。本文选取柱状珊瑚砂进行单颗粒沉降试验,研究静水中柱状珊瑚砂沉降速度及其影响因素,通过讨论分析不同的等效粒径和形状系数对柱状珊瑚砂沉降速度的影响,发现柱状珊瑚砂的沉降速度与等容粒径和Corey形状系数密切相关,基于本文试验数据推求了适用于计算柱状珊瑚砂沉降速度的经验公式,丰富了海岸泥沙理论。

三水碳酸镁焙烧法制备纳米多孔中空棒状氧化镁研究

以MgCl_(2)·6H_(2)O为原料、(NH_(4))_(2)CO_(3)为沉淀剂,采用液相沉淀法制备前驱体MgCO_(3)·3H_(2)O,并焙烧前驱体制备获得具有纤维结构的氧化镁。主要探讨沉淀剂浓度、反应温度、焙烧温度和焙烧时间对产物的平均粒径和物相组成的影响,并探究其形成机理。结果表明:沉淀剂浓度为1.5 mol/L、反应温度40℃、焙烧温度600℃、焙烧时间120 min时,可获得纳米中空棒状氧化镁,其表面由片状物相互连接形成多孔结构,前驱体三水碳酸镁在高温焙烧过程中起到模板作用。