The Essam-Fisher and Rushbrooke relationships (1963) that connect the equilibrium critical exponents of susceptibility, specific heat and order parameter (and some other relations that follow from the scaling hypothes...The Essam-Fisher and Rushbrooke relationships (1963) that connect the equilibrium critical exponents of susceptibility, specific heat and order parameter (and some other relations that follow from the scaling hypothesis) are shown to be valid only if the critical temperature TС > 0 and T → TC. For phase transitions (PT’s) with TC = 0 K these relations are proved to be of different form. This fact has been actually observed experimentally, but the reasons were not quite clear. A general formula containing the classical results as a special case is proposed. This formula is applicable to all equilibrium PT’s of any space dimension for both TC = 0 and TC > 0. The predictions of the theory are consistent with the available experimental data and do not cast any doubts upon the scaling hypothesis.展开更多
Two-phase fluid properties such as entropy, internal energy, and heat capacity are given by thermodynamically defined fit functions. Each fit function is expressed as a temperature function in terms of a power series ...Two-phase fluid properties such as entropy, internal energy, and heat capacity are given by thermodynamically defined fit functions. Each fit function is expressed as a temperature function in terms of a power series expansion about the critical point. The leading term with the critical exponent dominates the temperature variation between the critical and triple points. With β being introduced as the critical exponent for the difference between liquid and vapor densities, it is shown that the critical exponent of each fit function depends (if at all) on β. In particular, the critical exponent of the reciprocal heat capacity c﹣1 is α=1-2β and those of the entropy s and internal energy u are?2β, while that of the reciprocal isothermal compressibility?κ﹣1T is γ=1. It is thus found that in the case of the two-phase fluid the Rushbrooke equation conjectured α +?2β + γ=2 combines the scaling laws resulting from the two relations c=du/dT and?κT=dlnρ/dp. In the context with c, the second temperature derivatives of the chemical potential μ and vapor pressure p are investigated. As the critical point is approached, ﹣d2μ/dT2 diverges as c, while?d2p/dT2 converges to a finite limit. This is explicitly pointed out for the two-phase fluid, water (with β=0.3155). The positive and almost vanishing internal energy of the one-phase fluid at temperatures above and close to the critical point causes conditions for large long-wavelength density fluctuations, which are observed as critical opalescence. For negative values of the internal energy, i.e. the two-phase fluid below the critical point, there are only microscopic density fluctuations. Similar critical phenomena occur when cooling a dilute gas to its Bose-Einstein condensate.展开更多
Temperature dependence of diquark mass has been investigated in the frame work of the quasi particle diquark model. The effective mass of the diquark has been suggested to have a temperature dependence which shows a p...Temperature dependence of diquark mass has been investigated in the frame work of the quasi particle diquark model. The effective mass of the diquark has been suggested to have a temperature dependence which shows a power law behavior. The variation of the diquark mass with temperature has been studied. A decrease in effective mass at temperature T Tc, where Tc is the critical temperature has been observed. Some features of the phase transition have been discussed. The phase transition is found to be of second order. Temperature variation of baryon masses has also been studied. The results are compared and discussed with available works.展开更多
文摘The Essam-Fisher and Rushbrooke relationships (1963) that connect the equilibrium critical exponents of susceptibility, specific heat and order parameter (and some other relations that follow from the scaling hypothesis) are shown to be valid only if the critical temperature TС > 0 and T → TC. For phase transitions (PT’s) with TC = 0 K these relations are proved to be of different form. This fact has been actually observed experimentally, but the reasons were not quite clear. A general formula containing the classical results as a special case is proposed. This formula is applicable to all equilibrium PT’s of any space dimension for both TC = 0 and TC > 0. The predictions of the theory are consistent with the available experimental data and do not cast any doubts upon the scaling hypothesis.
文摘Two-phase fluid properties such as entropy, internal energy, and heat capacity are given by thermodynamically defined fit functions. Each fit function is expressed as a temperature function in terms of a power series expansion about the critical point. The leading term with the critical exponent dominates the temperature variation between the critical and triple points. With β being introduced as the critical exponent for the difference between liquid and vapor densities, it is shown that the critical exponent of each fit function depends (if at all) on β. In particular, the critical exponent of the reciprocal heat capacity c﹣1 is α=1-2β and those of the entropy s and internal energy u are?2β, while that of the reciprocal isothermal compressibility?κ﹣1T is γ=1. It is thus found that in the case of the two-phase fluid the Rushbrooke equation conjectured α +?2β + γ=2 combines the scaling laws resulting from the two relations c=du/dT and?κT=dlnρ/dp. In the context with c, the second temperature derivatives of the chemical potential μ and vapor pressure p are investigated. As the critical point is approached, ﹣d2μ/dT2 diverges as c, while?d2p/dT2 converges to a finite limit. This is explicitly pointed out for the two-phase fluid, water (with β=0.3155). The positive and almost vanishing internal energy of the one-phase fluid at temperatures above and close to the critical point causes conditions for large long-wavelength density fluctuations, which are observed as critical opalescence. For negative values of the internal energy, i.e. the two-phase fluid below the critical point, there are only microscopic density fluctuations. Similar critical phenomena occur when cooling a dilute gas to its Bose-Einstein condensate.
文摘Temperature dependence of diquark mass has been investigated in the frame work of the quasi particle diquark model. The effective mass of the diquark has been suggested to have a temperature dependence which shows a power law behavior. The variation of the diquark mass with temperature has been studied. A decrease in effective mass at temperature T Tc, where Tc is the critical temperature has been observed. Some features of the phase transition have been discussed. The phase transition is found to be of second order. Temperature variation of baryon masses has also been studied. The results are compared and discussed with available works.
