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d区单质“惰性s-价电子效应”的电位判据(Ⅱ)
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作者 陈国强 《贵州师范大学学报(自然科学版)》 CAS 2000年第3期68-69,72,共3页
本文对d区元素进行了普查 ,提出用单质s轨道的标准氧化电位来量度“惰性s -价电子效应” ,当E0 S>0 73V时 ,可作为单质具有“惰性s-价电子效应”的判据。由强到弱的顺序为 :Pt(2 6 4)、Au(1 6 9)、Rh(1 1)、Ir(1 0 )、Ru(0 95 )、... 本文对d区元素进行了普查 ,提出用单质s轨道的标准氧化电位来量度“惰性s -价电子效应” ,当E0 S>0 73V时 ,可作为单质具有“惰性s-价电子效应”的判据。由强到弱的顺序为 :Pt(2 6 4)、Au(1 6 9)、Rh(1 1)、Ir(1 0 )、Ru(0 95 )、Pd(0 92 )、OS(0 85 )、Hg(0 85 )、Ag(0 80 )。 展开更多
关键词 氧化电位 s轨道 d区元素 惰性s-价电子效应
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Construction of LSPR-enhanced 0D/2D CdS/MoO3‒x S-scheme heterojunctions for visible-light-driven photocatalytic H2 evolution 被引量:16
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作者 Jinjun Peng Jun Shen +3 位作者 Xiaohui Yu Hua Tang Zulfiqar Qinqin Liu 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2021年第1期87-96,共10页
Plasmonic nonmetal semiconductors with localized surface plasmon resonance(LSPR)effects possess extended light-response ranges and can act as highly efficient H2 generation photocatalysts.Herein,an LSPR-enhanced 0D/2D... Plasmonic nonmetal semiconductors with localized surface plasmon resonance(LSPR)effects possess extended light-response ranges and can act as highly efficient H2 generation photocatalysts.Herein,an LSPR-enhanced 0D/2D CdS/MoO3‒x heterojunction has been synthesized by the growth of 0D CdS nanoparticles on 2D plasmonic MoO3‒x elliptical nanosheets via a simple coprecipitation method.Taking advantage of the LSPR effect of the MoO3‒x elliptical nanosheets,the light absorption of the CdS/MoO3‒x heterojunction was extended from 600 nm to the near-infrared region(1400 nm).Furthermore,the introduction of 2D plasmonic MoO3‒x elliptical nanosheets not only provided a platform for the growth of CdS nanoparticles,but also contributed to the construction of an LSPR-enhanced S-scheme structure due to the interface between the MoO3‒x and CdS,accelerating the separation of light-induced electrons and holes.Therefore,the CdS/MoO3‒x heterojunction exhibited higher photocatalytic H2 generation activity than pristine CdS under visible light irradiation,including under 420,450,550,and 650 nm monochromic light,as well as improved photo-corrosion performance. 展开更多
关键词 CDS MoO3‒x Photocatalytic H2 evolution s-scheme Localized surface plasmon resonance effect
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Properties of Linear Entropy in k-Photon Jaynes-Cummings Model with Stark Shift and Kerr-Like Medium
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作者 廖庆洪 Muhammad Ashfaq Ahmad +1 位作者 王月媛 刘树田 《Communications in Theoretical Physics》 SCIE CAS CSCD 2010年第5期931-936,共6页
The time evolution of the linear entropy of an taking into consideration Stark shift and Kerr-like medium. atom in k-photon daynes-Cummings model is investigated The effect of both the Stark shift and Kerr-like medium... The time evolution of the linear entropy of an taking into consideration Stark shift and Kerr-like medium. atom in k-photon daynes-Cummings model is investigated The effect of both the Stark shift and Kerr-like medium on the linear entropy is analyzed using a numerical technique for the field initially in coherent state and in even coherent state. The results show that the presence of the Kerr-like medium and Stark shift has an important effect on the properties of the entropy and entanglement. It is also shown that the setting of the initial state plays a significant role in the evolution of the linear entropy and entanglement. 展开更多
关键词 k-photon Jaynes Cummings model linear entropy stark shift Kerr-like medium
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dc Josephson Effect in s-Wave Superconductor/Ferromagnet Insulator/p-Wave Superconductor Junctions
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作者 LI Xiao-Wei 《Communications in Theoretical Physics》 SCIE CAS CSCD 2007年第4期737-740,共4页
The Josephson currents in s-wave superconductor/ferromagnet insulator/p-wave superconductor(s/FI/p) junctions are calculated as a function of temperature and the phase taking into account the roughness scattering ef... The Josephson currents in s-wave superconductor/ferromagnet insulator/p-wave superconductor(s/FI/p) junctions are calculated as a function of temperature and the phase taking into account the roughness scattering effect at interface. The phase dependence of the Josephson current I (φ) between s-wave and px-wave superconductor is predicted to be sin(2φ). The ferromagnet scattering effect, the barrier strength, and the roughness strength at interface suppress the dc currents in s/FI/p junction. 展开更多
关键词 ferromagnet insulator p-wave superconductor dc Josephson current
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Effect of stress on microstructures of creep-aged 2524 alloy 被引量:3
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作者 权力伟 赵刚 +1 位作者 田妮 黄明丽 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第8期2209-2214,共6页
Microstructures of creep-aged 2524 (A1-4.3Cu-1.5Mg) aged at 170 ℃ with various stresses (0, 173 and 250 MPa) were studied on a creep machine. Ageing hardness curves under various stresses were plotted and the cor... Microstructures of creep-aged 2524 (A1-4.3Cu-1.5Mg) aged at 170 ℃ with various stresses (0, 173 and 250 MPa) were studied on a creep machine. Ageing hardness curves under various stresses were plotted and the corresponding microstructures were characterized by transmission electron microscopy (TEM). The results show that the value of peak hardness is increased, while the time to reach the peak hardness is reduced under an external stress. Meanwhile, the length of S(Al2CuMg) phase is shorter and the number density of S phases is larger in the creep-aged alloy. The predominant contribution to the peak hardness can be ascribed to the GPB zones with an elastic stress. 展开更多
关键词 creep-age S phase GPB zone hardness DISLOCATION stress orientation effect
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A 1×4 Polymeric Digital Optical Switch Based on the Thermo-Optic Effect 被引量:1
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作者 唐奕 张昊 +2 位作者 杨建义 王明华 江晓清 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2006年第4期692-695,共4页
We present a 1 × 4 Y-branch digital optical switch in which S-bend variable optical attenuators are integrated. The S-bend waveguides, which are always introduced to connect the switch and the standard fiber arra... We present a 1 × 4 Y-branch digital optical switch in which S-bend variable optical attenuators are integrated. The S-bend waveguides, which are always introduced to connect the switch and the standard fiber array, are made use of and designed as variable optical attenuators. A compact device with low crosstalk and larger branching-angle is obtained. The device is fabricated on the thermo-optic polymer materials,and the performance of the device is measured. With an applied driving power of less than 200mW, the device has a low crosstalk of less than - 35dB at a wavelength of 1.55 μm. 展开更多
关键词 bend waveguide variable optical attenuator thermo-optic effect digital optical switch integrated optics
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Gaussian Weighted Trajectory Method Ⅳ: No Rainbow Effect in Practice
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作者 L. Bonnet 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2009年第2期210-214,共5页
The Gaussian weighted trajectory method (GWTM) is a practical implementation of classical S matrix theory (CSMT) in the random phase approximation, CSMT being the first and simplest semi-classical approach of mole... The Gaussian weighted trajectory method (GWTM) is a practical implementation of classical S matrix theory (CSMT) in the random phase approximation, CSMT being the first and simplest semi-classical approach of molecular collisions, developped in the early seventies. Though very close in spirit to the purely classical description, GWTM accounts to some extent for the quantization of the different degrees-of-freedom involved in the processes. While CSMT may give diverging final state distributions, in relation to the rainbow effect of elastic scattering theory, GWTM has never led to such a mathematical catastrophe. The goal of the present note is to explain this finding. 展开更多
关键词 Gaussian weighted trajectory method Classical S matrix theory Rainbow effect
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偶偶γ不稳定核Stretching效应的微观机制
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作者 吴连坳 丁惠明 《高能物理与核物理》 SCIE EI CAS CSCD 北大核心 1995年第11期1047-1051,共5页
本文通过费米子动力学对称模型(FDSM)给出了Stretching效应的微观机制.这一机制下,理论计算结果与实验结果的相对误差不超过百分之二.
关键词 微观机制 FDSM s-效应 偶偶γ不稳定核
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