The bottleneck of strontium compounds preparing from celestite is the promotion of Sr/S isolation efficiency.Low energy consumption and zero release method for isolating Sr/S in preparing Sr(OH)2 process from celestit...The bottleneck of strontium compounds preparing from celestite is the promotion of Sr/S isolation efficiency.Low energy consumption and zero release method for isolating Sr/S in preparing Sr(OH)2 process from celestite in mild condition was described.Sr element remained in precipitation with formation of Sr(OH)2,while S element entered into leachate with formation of Na2SO4.The effects of initial concentration of NaOH,conversion temperature,liquid-to-solid(L/S)ratio and conversion time on Sr/S ratio of samples for celestite conversion were systematically investigated by experiments.The results demonstrated that the efficiency of Sr/S isolation increased with the initial concentration of NaOH,L/S ratio and conversion time,and decreased with conversion temperature.The maximum conversion ratio of Sr(OH)2 was 93.88%under the optimum condition,whose Sr/S ratio of sample could reach to 41.16.It illustrated that better isolation efficiency of celestite could be achieved in alkaline treatment.The results of SEM-EDS analyses demonstrated that the conversion reaction was a dissolution-precipitation process.展开更多
The post-AGB star J004441 is the first and the only one CEMP-r/s star found in SMC. Herein, we investigate the observed abun- dance pattern of the heavy elements using our parametric model. A consistent fitting result...The post-AGB star J004441 is the first and the only one CEMP-r/s star found in SMC. Herein, we investigate the observed abun- dance pattern of the heavy elements using our parametric model. A consistent fitting results was obtained for the sample star. Based on the low r = 0.08, the s-process nucleosynthesis occurred in the interior is supposed to belong to the single neutron-exposure v9 ,1/2 mbarn-1 supports a higher efficiency of the s-process nucleosynthesis relative to event. The median value of τ0 =0.44（T9/0.348）mbarn-1 supports a higher efficiency of the s-process nucleosynthesis relative to J004441 than that of the solar system, however, the value is not sufficiently high to favor the formation of a lead star. Thus, J004441 does not belong to lead star group. The large Cs value of J004441 supports the intrinsic characteristic of the s-enrichment. The Cr value is similar with that found in halo CEMP-r/s stars, which indicates that the r-process contributions is critical during heavy element enrichment. This star has a metallicity of [Fe/H] = -1.34, which is larger than that of Galaxy halo CEMP-r/s stars. The reason may be because of the different history of metallicity enrichment between the SMC and the Galaxy halo.展开更多
基金Project(2015-GX-108A)supported by Qinghai Provincial Science and Technology Support Program,China
文摘The bottleneck of strontium compounds preparing from celestite is the promotion of Sr/S isolation efficiency.Low energy consumption and zero release method for isolating Sr/S in preparing Sr(OH)2 process from celestite in mild condition was described.Sr element remained in precipitation with formation of Sr(OH)2,while S element entered into leachate with formation of Na2SO4.The effects of initial concentration of NaOH,conversion temperature,liquid-to-solid(L/S)ratio and conversion time on Sr/S ratio of samples for celestite conversion were systematically investigated by experiments.The results demonstrated that the efficiency of Sr/S isolation increased with the initial concentration of NaOH,L/S ratio and conversion time,and decreased with conversion temperature.The maximum conversion ratio of Sr(OH)2 was 93.88%under the optimum condition,whose Sr/S ratio of sample could reach to 41.16.It illustrated that better isolation efficiency of celestite could be achieved in alkaline treatment.The results of SEM-EDS analyses demonstrated that the conversion reaction was a dissolution-precipitation process.
基金supported by the National Natural Science Foundation of China(Grant Nos.U1231119,11273011,11390371,11003002,11021504 and 10973016)the China Postdoctoral Science Foundation(Grant No.2013M531587)the Natural Science Foundation of Hebei Province(Grant No.A2011205102)
文摘The post-AGB star J004441 is the first and the only one CEMP-r/s star found in SMC. Herein, we investigate the observed abun- dance pattern of the heavy elements using our parametric model. A consistent fitting results was obtained for the sample star. Based on the low r = 0.08, the s-process nucleosynthesis occurred in the interior is supposed to belong to the single neutron-exposure v9 ,1/2 mbarn-1 supports a higher efficiency of the s-process nucleosynthesis relative to event. The median value of τ0 =0.44（T9/0.348）mbarn-1 supports a higher efficiency of the s-process nucleosynthesis relative to J004441 than that of the solar system, however, the value is not sufficiently high to favor the formation of a lead star. Thus, J004441 does not belong to lead star group. The large Cs value of J004441 supports the intrinsic characteristic of the s-enrichment. The Cr value is similar with that found in halo CEMP-r/s stars, which indicates that the r-process contributions is critical during heavy element enrichment. This star has a metallicity of [Fe/H] = -1.34, which is larger than that of Galaxy halo CEMP-r/s stars. The reason may be because of the different history of metallicity enrichment between the SMC and the Galaxy halo.
