M-N-C(M=Fe,Co,Ni,etc.) catalyst owns high catalytic activity in the oxygen catalytic reaction which is the most likely to replace the Pt-based catalysts.But it is still a challenge to further increase the active site ...M-N-C(M=Fe,Co,Ni,etc.) catalyst owns high catalytic activity in the oxygen catalytic reaction which is the most likely to replace the Pt-based catalysts.But it is still a challenge to further increase the active site density.This article constructs the high-efficiency FeMn-N/S-C-1000 catalyst to realize ORR/OER bifunctional catalysis by hetero-atom,bimetal(Fe,Mn) doped simultaneously strategy.When evaluated it as bi-functional electro-catalysts,FeMn-N/S-C-1000 exhibits excellent catalytic activity(E_(1/2)=0.924 V,E_(j=10)=1.617 V) in alkaline media,outperforms conventional Pt/C,RuO_(2) and most non-precious-metal catalysts reported recently,Such outstanding performance is owing to N,S co-coordinated with metal to form multi-types of single atom,dual atom active sites to carry out bi-catalysis.Importantly,nitrite poison test provides the proof that the active sites of FeMn-N/S-C are more than that of single-atom catalysts to promote catalytic reactions directly.To better understand the local structure of Fe and Mn active sites,XAS and DFT were employed to reveal that FeMn-N_5/S-C site plays the key role during catalysis.Notably,the FeMn-N/S-C-1000 based low-temperature rechargeable flexible Zn-air also exhibits superior discharge performance and extraordinary durability at-40℃.This work will provide a new idea to design diatomic catalysts applied in low-temperature rechargeable batteries.展开更多
针对电子财务会计信息电算化系统在复杂环境下存在的工作时效性差和运营成本高等问题,文中提出一种新的ERP环境下电子财务会计信息电算化系统。首先,该系统选择C/S方式、B/S模式和Web服务器,并且采用Interface Package作为数据接口构建...针对电子财务会计信息电算化系统在复杂环境下存在的工作时效性差和运营成本高等问题,文中提出一种新的ERP环境下电子财务会计信息电算化系统。首先,该系统选择C/S方式、B/S模式和Web服务器,并且采用Interface Package作为数据接口构建混合模式结构,完成电算化系统编码;其次,结合三层结构构建数据访问层与业务逻辑层,分离数据实体与业务逻辑;最后,考虑到数据访问的便捷性和安全性,通过SQL Server 2018数据库完成科目编码设计与实体关系描述,采用可视化工具优化数据库,设计数据库视图功能,完成ERP环境下电子财务会计信息电算化系统的设计。实验结果表明,所设计系统的运营成本中,支出仅为500万元,收入为923万元,相比于企业未应用该系统前,支出降低329万元,收入增加521万元,且时效均在2天以内。该系统能够大幅度降低运营成本,显著地提升会计信息的时效性。展开更多
基金supported by the National Natural Science Foundation of China(21603171)the Basic Research Foundation of Xi’an Jiaotong University(xjh012020027)。
文摘M-N-C(M=Fe,Co,Ni,etc.) catalyst owns high catalytic activity in the oxygen catalytic reaction which is the most likely to replace the Pt-based catalysts.But it is still a challenge to further increase the active site density.This article constructs the high-efficiency FeMn-N/S-C-1000 catalyst to realize ORR/OER bifunctional catalysis by hetero-atom,bimetal(Fe,Mn) doped simultaneously strategy.When evaluated it as bi-functional electro-catalysts,FeMn-N/S-C-1000 exhibits excellent catalytic activity(E_(1/2)=0.924 V,E_(j=10)=1.617 V) in alkaline media,outperforms conventional Pt/C,RuO_(2) and most non-precious-metal catalysts reported recently,Such outstanding performance is owing to N,S co-coordinated with metal to form multi-types of single atom,dual atom active sites to carry out bi-catalysis.Importantly,nitrite poison test provides the proof that the active sites of FeMn-N/S-C are more than that of single-atom catalysts to promote catalytic reactions directly.To better understand the local structure of Fe and Mn active sites,XAS and DFT were employed to reveal that FeMn-N_5/S-C site plays the key role during catalysis.Notably,the FeMn-N/S-C-1000 based low-temperature rechargeable flexible Zn-air also exhibits superior discharge performance and extraordinary durability at-40℃.This work will provide a new idea to design diatomic catalysts applied in low-temperature rechargeable batteries.
文摘针对电子财务会计信息电算化系统在复杂环境下存在的工作时效性差和运营成本高等问题,文中提出一种新的ERP环境下电子财务会计信息电算化系统。首先,该系统选择C/S方式、B/S模式和Web服务器,并且采用Interface Package作为数据接口构建混合模式结构,完成电算化系统编码;其次,结合三层结构构建数据访问层与业务逻辑层,分离数据实体与业务逻辑;最后,考虑到数据访问的便捷性和安全性,通过SQL Server 2018数据库完成科目编码设计与实体关系描述,采用可视化工具优化数据库,设计数据库视图功能,完成ERP环境下电子财务会计信息电算化系统的设计。实验结果表明,所设计系统的运营成本中,支出仅为500万元,收入为923万元,相比于企业未应用该系统前,支出降低329万元,收入增加521万元,且时效均在2天以内。该系统能够大幅度降低运营成本,显著地提升会计信息的时效性。
