The shape-selective toluene disproportionation catalyst SD-01 developed by SINOPEC Shanghai Petrochemical Research Institute had undergone the commercial tests in December 2005 in the aromatics unit at Tianjin Petroch...The shape-selective toluene disproportionation catalyst SD-01 developed by SINOPEC Shanghai Petrochemical Research Institute had undergone the commercial tests in December 2005 in the aromatics unit at Tianjin Petrochemical Company. The toluene disproportionation unit, which was put on stream with success at the first attempt, ran smoothly and performed a continuous examination calibration for 72 hours in January 2006. At a space velocity of 4.0 h^-1, the average toluene conversion was higher than 30 %, with the para-isomer selectivity exceeding 92 % and the B/X ratio less than 1.4 (mol/mol).展开更多
文摘The shape-selective toluene disproportionation catalyst SD-01 developed by SINOPEC Shanghai Petrochemical Research Institute had undergone the commercial tests in December 2005 in the aromatics unit at Tianjin Petrochemical Company. The toluene disproportionation unit, which was put on stream with success at the first attempt, ran smoothly and performed a continuous examination calibration for 72 hours in January 2006. At a space velocity of 4.0 h^-1, the average toluene conversion was higher than 30 %, with the para-isomer selectivity exceeding 92 % and the B/X ratio less than 1.4 (mol/mol).