SH材料加固夯筑遗址土耐久性试验及机理研究

以添加SH材料加固的明长城古浪段夯筑遗址土为研究对象,对其重塑样进行紫外老化试验、冻融循环试验及耐盐、耐碱试验,研究其力学强度特征及耐久性能,并采用扫描电镜(SEM)、EDS能谱分析以及粒度分析研究SH材料加固夯筑遗址土的机理。试验结果表明,经紫外老化的SH固化后试样的无侧限抗压强度随老化时间增长呈先增后降,SH含量高的试样强度呈一直增长的趋势;随着冻融循环次数的增加,试样的无侧限抗压强度逐渐降低,质量损失率逐渐增加,其中SH固含量为0.8%的试样表现出极好的耐冻性能;相比素土,加固后的试样耐盐、耐碱性能明显有所提高。由机理分析得出,SH材料主要通过团聚、氢键、架桥和包裹等作用使土颗粒排列紧密、增强连接性,提高了遗址土的各种性能;SH材料加固夯筑遗址土具有良好的耐久性能。

嵌段中孔材料SBA-15(SH)的制备及应用

采用共表面活性剂法和嫁接法合成了孔道结构高度有序、粒径均匀且孔径较大的嵌段中孔材料SBA-15(SH),通过N2吸附脱附实验测得材料的孔径为7.8 nm,比表面积为629 m2/g,孔容为1.32 cm3/g,核磁共振与红外光谱结果显示巯基的覆盖率达65%。探讨了嵌段中孔材料SBA-15(SH)动态吸附重金属离子的原理和最佳条件。在pH=7.5,常温下,Hg2+,Cd2+,Pb2+,Ag+,Cr3+,Cr6+,Cu2+,Mn2+和Zn2+可被该材料定量吸附,动态吸附容量分别为17.1,18.7,22.6,12.7,9.7,10.8,10.8,19.2和15.5 mg/g,吸附的重金属离子可用6 mol/L HCl-2 g/L硫脲洗脱,采用原子荧光和原子吸收法测定过柱前后溶液及洗脱液中重金属离子的含量,加标回收实验显示回收率在89.2%～109.6%之间。本方法用于环境水样的处理和测定,结果满意。

SH复配无机材料加固黄土工程特性试验研究

为了研究不同掺量的水泥、石灰和SH单独固化黄土与SH和水泥复配、SH和石灰复配固化黄土的强度特性,通过室内试验对试样进行了抗剪和强度试验,研究新型高分子材料SH复配不同掺量的水泥和石灰改良黄土的工程特性,并探讨了养护龄期对抗压强度的影响。研究结果表明:试件抗压强度和水泥掺量呈线性正相关,养护龄期对SH改良黄土的抗压强度工程特性的影响大于抗剪强度,SH掺量对黄土试件的抗压强度和抗剪强度工程特性改良相当。SH和水泥复配、SH和石灰复配固化黄土的抗压强度得到了很大程度提高,因此,在实际工程中根据工程需求的固化强度,计算所需SH的掺量与水泥和石灰复配,可为工程节约成本。

Effect of NiAl content on phases and microstructures of TiC-TiB_2-NiAl composites fabricated by reaction synthesis

TiC-TiB2-NiAl composites were fabricated by self-propagating high temperature reaction synthesis（SHS） with Ti, B4C, Ni and Al powders as raw materials. The effects of NiAl content on phase constituents and microstructures were investigated. The results show that the reaction products are composed of TiB2, TiC and NiAl. The content of NiAl increases with the adding of Ni＋Al in green compacts. TiB2, TiC and NiAl grains present in different shapes in the matrix, TiB2 being in hexagonal or rectangular shapes, TiC in spherical shapes, and NiAl squeezed into the gaps of TiC and TiB2 grains. With the increase of NiAl content, the grains of TiC-TiB2-NiAl composites are refined, their density and compressive strength are improved, and the shapes of TiC grains become spherical instead of irregular ones. Finally, the fracture mechanism of the composites transforms from intergranular fracture mode to the compounded fracture mode of intergranular fracture and transgranular fracture.

滨海盐渍土改良与利用新途径试验研究

用石灰、粉煤灰和SH固土剂对滨海盐渍土进行改性,击实试验、无侧限抗压强度试验、水稳性试验和三轴UU剪切试验结果表明:滨海盐渍土掺入二灰后,混合料性状得到明显改善,但水稳性较差;掺加SH后,浸水后的无侧限抗压强度和饱和抗剪强度指标明显增大,水稳性得到显著提高．

固化滨海盐渍土耐久性试验研究

对二灰固化滨海盐渍土和SH二灰固化滨海盐渍土进行了水稳定性、抗冻性和次生盐渍化模拟试验,其中抗冻性试验与素土进行了对比。结果表明,SH二灰固化滨海盐渍土具有较好的水稳性和抗冻性。

The effective propagation constants of SH wave in composites reinforced by dispersive parallel nanofibers

In the present paper, the effective propagation constants of elastic SH waves in composites with randomly distributed parallel cylindrical nanofibers are studied. The surface stress effects are considered based on the surface elasticity theory and non-classical interfacial conditions between the nanofiber and the host are derived. The scattering waves from individual nanofibers embedded in an infinite elastic host are obtained by the plane wave expansion method. The scattering waves from all fibers are summed up to obtain the multiple scattering waves. The interactions among random dispersive nanofibers are taken into account by the effective field approximation. The effective propagation constants are obtained by the configurational average of the multiple scattering waves. The effective speed and attenuation of the averaged wave and the associated dynamical effective shear modulus of composites are numerically calculated. Based on the numerical results, the size effects of the nanofibers on the effective propagation constants and the effective modulus are discussed.