In this paper, we study the long-time behavior of solutions of the single-layer quasi-geostrophic model arising from geophysical fluid dynamics. We obtain the lower bound of the decay estimate of the solution. Utilizi...In this paper, we study the long-time behavior of solutions of the single-layer quasi-geostrophic model arising from geophysical fluid dynamics. We obtain the lower bound of the decay estimate of the solution. Utilizing the Fourier splitting method, under suitable assumptions on the initial data, for any multi-index α, we show that the solution Ψ satisfies .展开更多
The single-layer latticed cylindrical shell is one of the most widely adopted space-framed structures. In this paper, free vibration properties and dynamic response to horizontal and vertical seismic waves of single-l...The single-layer latticed cylindrical shell is one of the most widely adopted space-framed structures. In this paper, free vibration properties and dynamic response to horizontal and vertical seismic waves of single-layer latticed cylindrical shells are analyzed by the finite clement method using ANSYS software. In the numerical study, where hundreds of cases were analyzed, the parameters considered included rise-span ratio, length-span ratio, surface load and member section size. Moreover, to better define the actual behavior of single-layer latticed shells, the study is focused on the dynamic stress response to both axial forces and bending moments. Based on the numerical results, the effects of the parameters considered on the stresses are discussed and a modified seismic force coefficient method is suggested. In addition, some advice based on these rescarch results is presented to help in the future design of such structures.展开更多
Single-layer superconductors are ideal materials for fabricating superconducting nano devices.However,up to date,very few single-layer elemental superconductors have been predicted and especially no one has been succe...Single-layer superconductors are ideal materials for fabricating superconducting nano devices.However,up to date,very few single-layer elemental superconductors have been predicted and especially no one has been successfully synthesized yet.Here,using crystal structure search techniques and ab initio calculations,we predict that a single-layer planar carbon sheet with 4-and 8-membered rings called T-graphene is a new intrinsic elemental superconductor with superconducting critical temperature(Tc)up to around 20.8 K.More importantly,we propose a synthesis route to obtain such a single-layer T-graphene,that is,a T-graphene potassium intercalation compound(C4 K with P4/mmm symmetry)is firstly synthesized at high pressure(>11.5 GPa)and then quenched to ambient condition;and finally,the single-layer T-graphene can be either exfoliated using the electrochemical method from the bulk C4 K,or peeled off from bulk T-graphite C4,where C4 can be obtained from C4 K by evaporating the K atoms.Interestingly,we find that the calculated Tc of C4 K is about 30.4 K at 0 GPa,which sets a new record for layered carbon-based superconductors.The present findings add a new class of carbon-based superconductors.In particular,once the single-layer T-graphene is synthesized,it can pave the way for fabricating superconducting devices together with other 2 D materials using the layer-by-layer growth techniques.展开更多
We report near-zero crossover for vanadium cross-permeation through single-layer graphene immobilized at the interface of two Nafion?polymer electrolyte membranes.Vanadium ion diffusion and migration,including proton ...We report near-zero crossover for vanadium cross-permeation through single-layer graphene immobilized at the interface of two Nafion?polymer electrolyte membranes.Vanadium ion diffusion and migration,including proton mobility through membrane composites,were studied with and without graphene under diffusion and migration conditions.Single-layer graphene was found to effectively inhibit vanadium ion diffusion and migration under specific conditions.The single-layer graphene composites also enabled remarkable ion transmission selectivity improvements over pure Nafion membranes,with proton transport being four orders of magnitude faster than vanadium ion transport.Resistivity values of 0.02±0.005Ωcm^(2) for proton and 223±4Ωcm^(2) for vanadium ion through single atomic layer graphene are reported.This high selectivity may have significant impact on flow battery applications or for other electrochemical devices where proton conductivity is required,and transport of other species is detrimental.Our results emphasize that crossover may be essentially completely eliminated in some cases,enabling for greatly improved operational viability.展开更多
Single-layer superconductors[1]have been the subject of considerable interests as they are ideal systems for the fundamental understanding of two-dimensional(2D)physics and for device applications.A few singlelayer su...Single-layer superconductors[1]have been the subject of considerable interests as they are ideal systems for the fundamental understanding of two-dimensional(2D)physics and for device applications.A few singlelayer superconductors are experimentally achieved(e.g.,FeSe,MoS2,and NbSe2[2-4]in the field where either charge doping or tensile strain is often required to promote the superconductivity.展开更多
Two-dimensional(2D) layered organic-inorganic hybrid perovskites have attracted much more attention for some applications than their three-dimensional(3D) perovskite counterparts due to their promising thermal and moi...Two-dimensional(2D) layered organic-inorganic hybrid perovskites have attracted much more attention for some applications than their three-dimensional(3D) perovskite counterparts due to their promising thermal and moisture stabilities.In particular, the 2D perovskite devices have shown better promise for optoelectronic applications.However, tunability of optoelectronic properties is often demanded to improve the device performance.Herein, we adopt a newly method to tune the electronic properties of 2D perovskite by introducing pseudohalide into the structure.In this work, we designed a pseudohalidesubstituted 2D perovskite by substituting the out-of-plane halide with pseudohalide and studied the electronic and excitonic properties of 2D-BA2MX4 and 2D-BA2MX2Ps2(M=Ge^(2+), Sn^(2+), and Pb^(2+);X=I;Ps=NCO, NCS, OCN, SCN, Se CN).We revealed the dependence of electronic properties including band gaps, composition of band edges, bonding characteristics, work functions, effective masses, and exciton binding energies on different pseudohalides substituted in 2D perovskite.Our results indicate that the substitution of pseudohalide in 2D perovskites is energetically favorable and can significantly affect the bonding characteristics as well as the CBM and VBM that often play major role in determining their performance in optoelectronic devices.It is expected that the pseudohalide substitution will be helpful in developing more advanced optoelectronic device based on 2D perovskite by optimizing band alignment and promoting charge extraction.展开更多
Electronic structures and optical properties of single-layer In1-xGaxN are studied by employ-ing Heyd-Scuseria-Ernzerh(HSE)method based on the first-principles.The band structure and density of states(DOS)of single-la...Electronic structures and optical properties of single-layer In1-xGaxN are studied by employ-ing Heyd-Scuseria-Ernzerh(HSE)method based on the first-principles.The band structure and density of states(DOS)of single-layer In1-xGaxN are calculated,and the band gap ranges from 1.8 eV to 3.8 eV as the ratio x changes,illustrating the potential for the tun-ability of band gap values via Ga doped.We also have investigated optical properties of single-layer In1-xGaxN such as dielectric function,refractive index and absorption coeficient,the main peak of dielectric function spectrum and the absorption edge are found to have a remarkable blue-shift as the concentration of Ga increases.Furthermore,the optical properties of single-layer In1-xGaxN are analyzed based on the band structures and DOS analysis.Such unique optical properties have profound application in nanoelectronics and optical devices.展开更多
We theoretically provide a magnetic phase diagram for the single-layer(SL)CrBr_(3),which could be effectively tuned by both strain engineering and charge doping in SL-CrBr_(3).Through systematical first-principles cal...We theoretically provide a magnetic phase diagram for the single-layer(SL)CrBr_(3),which could be effectively tuned by both strain engineering and charge doping in SL-CrBr_(3).Through systematical first-principles calculations and Heisenberg model Hamiltonian simulations,three different magnetic phases in SL-CrBr_(3),which are off-plane ferromagnetic,in-plane ferromagnetic and in-plane Neél-antiferromagnetic phases,are found in the strain and charge doping regimes we studied.Furthermore,our results show that higher order Heisenberg exchange parameters and anisotropy exchange parameters should be taken into account for accurately illustrating the magnetic phase transition in SL-CrBr_(3).As a result,we find from the SpinW simulation that the Curie temperature is about T_(c)=38.4 K,which is well consistent with the experimental result 34 K[Nano Lett.193138(2019)].The findings here may be confirmed in future experiments,and may be useful for the potential applications of SL-CrBr_(3)in spintronics field.展开更多
Contrary to conventional design methods that assume uniform and slow temperature changes tied to atmospheric conditions,single-layer spherical reticulated shells undergo significant non-uniform and time-variant temper...Contrary to conventional design methods that assume uniform and slow temperature changes tied to atmospheric conditions,single-layer spherical reticulated shells undergo significant non-uniform and time-variant temperature variations due to dynamic environmental coupling.These differences can affect structural performance and pose safety risks.Here,a systematic numerical method was developed and applied to simulate long-term temperature variations in such a structure under real environmental conditions,revealing its non-uniform distribution characteristics and time-variant regularity.A simplified design method for non-uniform thermal loads,accounting for time-variant environmental factors,was theoretically derived and validated through experiments and simulations.The maximum deviation and mean error rate between calculated and tested results were 6.1℃ and 3.7%,respectively.Calculated temperature fields aligned with simulated ones,with deviations under 6.0℃.Using the design method,non-uniform thermal effects of the structure are analyzed.Maximum member stress and nodal displacement under non-uniform thermal loads reached 119.3 MPa and 19.7 mm,representing increases of 167.5%and 169.9%,respectively,compared to uniform thermal loads.The impacts of healing construction time on non-uniform thermal effects were evaluated,resulting in construction recommendations.The methodologies and conclusions presented here can serve as valuable references for the thermal design,construction,and control of single-layer spherical reticulated shells or similar structures.展开更多
Harnessing solar energy for photocatalytic hydrogen peroxide(H_(2)O_(2))synthesis represents a pinnacle of environmentally-sensitive and sustainable methodologies.While single-layer crystalline triazine-based organic ...Harnessing solar energy for photocatalytic hydrogen peroxide(H_(2)O_(2))synthesis represents a pinnacle of environmentally-sensitive and sustainable methodologies.While single-layer crystalline triazine-based organic frameworks(CTFs)are known for their prodigious photocatalytic potential in H_(2)O_(2)generation,ramifications of the connecting group within the triazine ring(TR)on underlying photocatalytic mechanism warrant deeper exploration.In this study,we simulate three distinct CTFs characterized by different TR linkers:CTF-1(benzene group(BG)),CTF-2(horizontally-oriented naphthyl group(NGH)),and CTF-DCN(vertically-oriented naphthyl group(NGV)).These diverse TR linkers profoundly modulate the absorption band edge of CTFs,subsequently dictating the orientation and constitution of the frontier orbitals.Such modulation plays a decisive role in determining the requisite energy for photoexcitation in CTFs,orchestrating the generation and distribution of photo-induced electrons and holes.Remarkably,the NGV linkage imparts CTF-DCN with unparalleled light ab-sorption,superior charge separation efficiency,and the lowest energy barrier for associated reactions.Through this investigation,we illuminate the pivotal influence of TR linkers in sculpting the photocatalytic dynamics of CTFs,providing fresh perspectives for architecting CTFs with amplified photocatalytic prowess in H_(2)O_(2)synthesis.展开更多
NO_2 sensors with ultrahigh sensitivity are demanded for future electronic sensing systems. However,traditional sensors are considerably limited by the relative low sensitivity, high cost and complicated process. Here...NO_2 sensors with ultrahigh sensitivity are demanded for future electronic sensing systems. However,traditional sensors are considerably limited by the relative low sensitivity, high cost and complicated process. Here, we report a simply and reliable flexible NO_2 sensor based on single-layer MoS_2. The flexible sensor exhibits high sensitivity to NO_2 gas due to ultra-large specific surface area and the nature of two-dimensional(2 D) semiconductor. When the NO_2 is 400 ppb(parts per billion), compared with the dark and strain-free conditions, the sensitivity of the single-layer sensor is enhanced to 671% with a625 nm red light-emitting diode(LED) illumination of 4 mW/cm^2 power under 0.67% tensile strain.More important, the response time is dramatically reduced to $16 s and it only needs $65 s to complete90% recovery. A theoretical model is proposed to discuss the microscopic mechanisms. We find that the remarkable sensing characteristics are the result of coupling among piezoelectricity, photoelectricity and adsorption-desorption induced charges transfer in the single-layer MoS_2 Schottky junction based device.Our work opens up the way to further enhancements in the sensitivity of gas sensor based on single-layer MoS_2 by introducing photogating and piezo-phototronic effects in mesoscopic systems.展开更多
MXenes,a family of two-dimensional(2D)materials,exhibit peculiar microwave-absorbing behaviors due to their unique chemical composition and structure.Although laminated Ti_(3)C_(2)T_(x) MXenes with a multilayer struct...MXenes,a family of two-dimensional(2D)materials,exhibit peculiar microwave-absorbing behaviors due to their unique chemical composition and structure.Although laminated Ti_(3)C_(2)T_(x) MXenes with a multilayer structure have been used for microwave absorption,real 2D MXenes with a single-layer structure have not yet been investigated.Here,the electromagnetic wave response behavior of single-layer Ti_(3)C_(2)T_(x) MXenes was explored in detail.The permittivity of Ti_(3)C_(2)T_(x) MXene rises dramatically with an increase in filler loading,and Ti_(3)C_(2)T_(x) MXene features a distinct dielectric response wherein dipolar polarization and interfacial polarization makes a greater contribution at low filler loading;conductive loss becomes more prominent at high filler loading.Versus laminated Ti_(3)C_(2)T_(x) MXene,single-layer Ti_(3)C_(2)T_(x) MXene delivers superior absorbing capability:The RLminvalue of SL-Ti_(3)C_(2)T_(x)-22%reaches-43.5 d B at 6.5 GHz,and a broad EAB of 6.88 GHz can be attained at a thickness of 1.8 mm due to enhanced dipolar polarization,interfacial polarization,and conductive loss.This work is of great significance in guiding the future development of MXene-based absorbers.展开更多
By considering the interaction between Fowler-Nordheim tunneling injection theory and charge carriers transporting through the bulk, an electroluminescence model for organic single-layer diodes is presented. The expre...By considering the interaction between Fowler-Nordheim tunneling injection theory and charge carriers transporting through the bulk, an electroluminescence model for organic single-layer diodes is presented. The expressions of the recombination current density, recombination efficiency and conductivity of the diodes are provided, which elucidate the controlling role of the electric field on mobility and recombination zone. The equilibrium of two opposite charge carriers injection and the central position of recombination zone are two important preconditions for reducing the leakage current. Space-charge-limited current occurs only over a certain high bias, meanwhile, the quantity of injection carriers increases over the transport capacity of the bulk.展开更多
Dried longan fruit has become an important export product of Thailand.Knowledge about drying kinetics is essential to optimize the drying process.In this study,drying kinetics of unpeeled longan fruits was investigate...Dried longan fruit has become an important export product of Thailand.Knowledge about drying kinetics is essential to optimize the drying process.In this study,drying kinetics of unpeeled longan fruits was investigated by varying the parameters as follows:air temperature 50~90℃,relative humidity 4%~20%,air velocity 0.2~0.5 m/s,and size of the fruits.The drying curves of longan fruit,dried in a single layer,were strongly affected by the temperature of the drying air and fruit size but less dependent on relative humidity and velocity of the drying air.Eight single-layer drying models were selected from literature to identify suitable ones for fitting moisture ratio curves to data obtained from the drying experiments.Both,the proportional and exponential coefficient of drying time in the‘Page’model could be given in a generalized function for each of the investigated drying parameters.Moreover,the two coefficients could be correlated to all drying parameters simultaneously.This allowed establishing a generalized‘Page’model for estimating drying curves for any value of temperature,fruit size,relative humidity and air velocity within the range of performed experiments.The analysis also revealed an inner correlation between the two‘Page’coefficients,which opens new doors for further research on the application of the‘Page’model for describing drying processes.展开更多
Free vibration of elastically constrained rectangular single-layered M0S_(2)is investigated by using a nonlocal Kirchhoff plate model with an initial stress.The variationally consistent elastically constrained boundar...Free vibration of elastically constrained rectangular single-layered M0S_(2)is investigated by using a nonlocal Kirchhoff plate model with an initial stress.The variationally consistent elastically constrained boundary conditions are obtained by using the weighted residual method,while the governing equations of the nonlocal Kirchhoff plate model are known.A modified Fourier series method is applied to study the vibrational behaviors of elastically constrained nonlocal Kirchhoff plate models.The convergence and reliability of the modified Fourier series method is verified via comparison with the finite element method.A comprehensive parametric study is performed to show the influences of the boundary elastic constant,nonlocal parameter and initial stress on the vibrational behaviors of single-layered M0S2.The results should be good for the design of nanoresonators.展开更多
Valley,as a new degree of freedom for electrons,has drawn considerable attention due to its significant potential for encoding and storing information.Lifting the energy degeneracy to achieve valley polarization is ne...Valley,as a new degree of freedom for electrons,has drawn considerable attention due to its significant potential for encoding and storing information.Lifting the energy degeneracy to achieve valley polarization is necessary for realizing valleytronic devices.Here,on the basis of first-principles calculations,we show that single-layer FeCl_(2)exhibits a large spontaneous valley polarization(∼101 meV)arising from the broken time-reversal symmetry and spin-orbital coupling,which can be continuously tuned by varying the direction of magnetic crystalline.By employing the perturbation theory,the underlying physical mechanism is unveiled.Moreover,the coupling between valley degree of freedom and ferromagnetic order could generate a spin-and valley-polarized anomalous Hall current in the presence of the in-plane electric field,facilitating its experimental exploration and practical applications.展开更多
Background: The myometrium at the location of the CS (caesarean section) scars, also known as residual myometrium thickness (RMT), is larger after a double-layer uterine closure procedure than following a single-layer...Background: The myometrium at the location of the CS (caesarean section) scars, also known as residual myometrium thickness (RMT), is larger after a double-layer uterine closure procedure than following a single-layer one. It may lessen the formation of a niche that is the myometrium’s disruption at the location of the scar of the uterus. Gynecological manifestations, obstetric problems in a future pregnancy and birth, and maybe subfertility are linked to thin RMT and a niche. Objective: To ascertain if double-layer unlocked closure of the uterus is better than single-layer one in terms of post-menstrual spotting and niche development following a first CS. Patients and Methods: In this randomized clinical study, 287 patients were evaluated for qualifying. Of all eligible individuals, 57 patients were excluded from the study based on the inclusion criteria. Results: The variation in ages, gestational age, body mass index (BMI), and cesarean section indications between the two assigned groups is statistically insignificant. However, postmenstrual spotting was statistically significantly more common in single-layer group compared to in double-group. The current study revealed ultrasound findings suggestive of niche formation was statistically significantly more common in single-layer group compared to in double-layer group. Conclusion: As evident from the current study, it demonstrates the advantages of double-layer unlocked closure of the uterus over single-layer one in terms of post-menstrual spotting and niche development following first-time cs. Thus, we deduced that fewer niches are formed, and fewer menstrual spotting occurs in the presence of double unlocked layers closure. To ascertain the impact of uterus closure method on post-operative niche development and the risk of obstetrics and gynaecological problems, further prospective trials with extended follow-up periods are required.展开更多
Single-layer reticulated shells(SLRSs)find widespread application in the roofs of crucial public structures,such as gymnasiums and exhibition center.In this paper,a new neural-network-based method for structural damag...Single-layer reticulated shells(SLRSs)find widespread application in the roofs of crucial public structures,such as gymnasiums and exhibition center.In this paper,a new neural-network-based method for structural damage identification in SLRSs is proposed.First,a damage vector index,NDL,that is related only to the damage localization,is proposed for SLRSs,and a damage data set is constructed from NDL data.On the basis of visualization of the NDL damage data set,the structural damaged region locations are identified using convolutional neural networks(CNNs).By cross-dividing the damaged region locations and using parallel CNNs for each regional location,the damaged region locations can be quickly and efficiently identified and the undamaged region locations can be eliminated.Second,a damage vector index,DS,that is related to the damage location and damage degree,is proposed for SLRSs.Based on the damaged region identified previously,a fully connected neural network(FCNN)is constructed to identify the location and damage degree of members.The effectiveness and reliability of the proposed method are verified by considering a numerical case of a spherical SLRS.The calculation results showed that the proposed method can quickly eliminate candidate locations of potential damaged region locations and precisely determine the location and damage degree of members.展开更多
To develop the microwave absorbing(MA)properties of cementitious material mixed with mine solid waste,the iron tailings cementitious microwave absorbing materials were prepared.The iron tailings was treated into diffe...To develop the microwave absorbing(MA)properties of cementitious material mixed with mine solid waste,the iron tailings cementitious microwave absorbing materials were prepared.The iron tailings was treated into different particle sizes by planetary ball mill,and the physicochemical properties of iron tailings were tested by laser particle size analyzer and scanning electron microscope(SEM).The electromagnetic parameters of iron tailings cementitious materials were characterized by a vector network analyzer and simulated MA properties,and the MA properties of iron tailings-cement composite system with steel fiber as absorber was studied.Based on the design of the single-layer structure,optimum mix ratio and thickness configuration method of double-layer structure were further studied,meanwhile,the mechanical properties and engineering application were analyzed and discussed.The results show that the particle size of iron tailings can afiect its electromagnetic behavior in cementitious materials,and the smaller particles lead the increase of demagnetisation efiect induced by domain wall motion and achieve better microwave absorbing properties in cementitious materials.When the thickness of matching layer and absorbing layer is 5 mm,the optimized microwave absorbing properties of C1/C3 double-layer cementitious material can obtain optimal RL value of-27.61 dB and efiective absorbing bandwidth of 0.97 GHz,which attributes to the synergistic efiect of impedance matching and attenuation characteristics.The double-layer microwave absorbing materials obtain excellent absorbing properties and show great design flexibility and diversity,which can be used as a suitable candidate for the preparation of favorable microwave absorbing cementitious materials.展开更多
文摘In this paper, we study the long-time behavior of solutions of the single-layer quasi-geostrophic model arising from geophysical fluid dynamics. We obtain the lower bound of the decay estimate of the solution. Utilizing the Fourier splitting method, under suitable assumptions on the initial data, for any multi-index α, we show that the solution Ψ satisfies .
基金National Natural Science Foundation of China,Grant No.59895410
文摘The single-layer latticed cylindrical shell is one of the most widely adopted space-framed structures. In this paper, free vibration properties and dynamic response to horizontal and vertical seismic waves of single-layer latticed cylindrical shells are analyzed by the finite clement method using ANSYS software. In the numerical study, where hundreds of cases were analyzed, the parameters considered included rise-span ratio, length-span ratio, surface load and member section size. Moreover, to better define the actual behavior of single-layer latticed shells, the study is focused on the dynamic stress response to both axial forces and bending moments. Based on the numerical results, the effects of the parameters considered on the stresses are discussed and a modified seismic force coefficient method is suggested. In addition, some advice based on these rescarch results is presented to help in the future design of such structures.
基金Supported by the National Key Research and Development Program of China under Grant No 2016YFA0300404the National Basic Research Program of China under Grant No 2015CB921202+2 种基金the National Nature Science Foundation of China under Grant Nos 11574133 and 11834006the Nature Science Foundation of Jiangsu Province under Grant No BK20150012the Fundamental Research Funds for the Central Universities,the Science Challenge Project(No TZ2016001)
文摘Single-layer superconductors are ideal materials for fabricating superconducting nano devices.However,up to date,very few single-layer elemental superconductors have been predicted and especially no one has been successfully synthesized yet.Here,using crystal structure search techniques and ab initio calculations,we predict that a single-layer planar carbon sheet with 4-and 8-membered rings called T-graphene is a new intrinsic elemental superconductor with superconducting critical temperature(Tc)up to around 20.8 K.More importantly,we propose a synthesis route to obtain such a single-layer T-graphene,that is,a T-graphene potassium intercalation compound(C4 K with P4/mmm symmetry)is firstly synthesized at high pressure(>11.5 GPa)and then quenched to ambient condition;and finally,the single-layer T-graphene can be either exfoliated using the electrochemical method from the bulk C4 K,or peeled off from bulk T-graphite C4,where C4 can be obtained from C4 K by evaporating the K atoms.Interestingly,we find that the calculated Tc of C4 K is about 30.4 K at 0 GPa,which sets a new record for layered carbon-based superconductors.The present findings add a new class of carbon-based superconductors.In particular,once the single-layer T-graphene is synthesized,it can pave the way for fabricating superconducting devices together with other 2 D materials using the layer-by-layer growth techniques.
文摘We report near-zero crossover for vanadium cross-permeation through single-layer graphene immobilized at the interface of two Nafion?polymer electrolyte membranes.Vanadium ion diffusion and migration,including proton mobility through membrane composites,were studied with and without graphene under diffusion and migration conditions.Single-layer graphene was found to effectively inhibit vanadium ion diffusion and migration under specific conditions.The single-layer graphene composites also enabled remarkable ion transmission selectivity improvements over pure Nafion membranes,with proton transport being four orders of magnitude faster than vanadium ion transport.Resistivity values of 0.02±0.005Ωcm^(2) for proton and 223±4Ωcm^(2) for vanadium ion through single atomic layer graphene are reported.This high selectivity may have significant impact on flow battery applications or for other electrochemical devices where proton conductivity is required,and transport of other species is detrimental.Our results emphasize that crossover may be essentially completely eliminated in some cases,enabling for greatly improved operational viability.
文摘Single-layer superconductors[1]have been the subject of considerable interests as they are ideal systems for the fundamental understanding of two-dimensional(2D)physics and for device applications.A few singlelayer superconductors are experimentally achieved(e.g.,FeSe,MoS2,and NbSe2[2-4]in the field where either charge doping or tensile strain is often required to promote the superconductivity.
基金funded by the National Key Research and Development Program of China (2017YFA0204800/2016YFA0202403)the Fundamental Research Funds for the Central Universities (2018CBLZ006)+5 种基金the National Natural Science Foundation of China (61604091 and 61674098)the 111 Project (B14041)the Changjiang Scholar and Innovative Research Team (IRT_14R33)the Chinese National 1000 Talents Plan program (1110010341)the China Postdoctoral Science foundation (2018M633455)the Fundamental Research Funds for the Central Universities (GK201903055)
文摘Two-dimensional(2D) layered organic-inorganic hybrid perovskites have attracted much more attention for some applications than their three-dimensional(3D) perovskite counterparts due to their promising thermal and moisture stabilities.In particular, the 2D perovskite devices have shown better promise for optoelectronic applications.However, tunability of optoelectronic properties is often demanded to improve the device performance.Herein, we adopt a newly method to tune the electronic properties of 2D perovskite by introducing pseudohalide into the structure.In this work, we designed a pseudohalidesubstituted 2D perovskite by substituting the out-of-plane halide with pseudohalide and studied the electronic and excitonic properties of 2D-BA2MX4 and 2D-BA2MX2Ps2(M=Ge^(2+), Sn^(2+), and Pb^(2+);X=I;Ps=NCO, NCS, OCN, SCN, Se CN).We revealed the dependence of electronic properties including band gaps, composition of band edges, bonding characteristics, work functions, effective masses, and exciton binding energies on different pseudohalides substituted in 2D perovskite.Our results indicate that the substitution of pseudohalide in 2D perovskites is energetically favorable and can significantly affect the bonding characteristics as well as the CBM and VBM that often play major role in determining their performance in optoelectronic devices.It is expected that the pseudohalide substitution will be helpful in developing more advanced optoelectronic device based on 2D perovskite by optimizing band alignment and promoting charge extraction.
基金supported by the National Natural Science Foundation of China (No.11404230)Foundation of Science and Technology Bureau of Sichuan Province (No.2013JY0085)
文摘Electronic structures and optical properties of single-layer In1-xGaxN are studied by employ-ing Heyd-Scuseria-Ernzerh(HSE)method based on the first-principles.The band structure and density of states(DOS)of single-layer In1-xGaxN are calculated,and the band gap ranges from 1.8 eV to 3.8 eV as the ratio x changes,illustrating the potential for the tun-ability of band gap values via Ga doped.We also have investigated optical properties of single-layer In1-xGaxN such as dielectric function,refractive index and absorption coeficient,the main peak of dielectric function spectrum and the absorption edge are found to have a remarkable blue-shift as the concentration of Ga increases.Furthermore,the optical properties of single-layer In1-xGaxN are analyzed based on the band structures and DOS analysis.Such unique optical properties have profound application in nanoelectronics and optical devices.
基金Project supported by the National Natural Science Foundation of China(Grant No.11625415)the Innovation Development Foundation of China Academy of Engineering Physics(Grant No.ZYCX1921-02)。
文摘We theoretically provide a magnetic phase diagram for the single-layer(SL)CrBr_(3),which could be effectively tuned by both strain engineering and charge doping in SL-CrBr_(3).Through systematical first-principles calculations and Heisenberg model Hamiltonian simulations,three different magnetic phases in SL-CrBr_(3),which are off-plane ferromagnetic,in-plane ferromagnetic and in-plane Neél-antiferromagnetic phases,are found in the strain and charge doping regimes we studied.Furthermore,our results show that higher order Heisenberg exchange parameters and anisotropy exchange parameters should be taken into account for accurately illustrating the magnetic phase transition in SL-CrBr_(3).As a result,we find from the SpinW simulation that the Curie temperature is about T_(c)=38.4 K,which is well consistent with the experimental result 34 K[Nano Lett.193138(2019)].The findings here may be confirmed in future experiments,and may be useful for the potential applications of SL-CrBr_(3)in spintronics field.
基金This work is supported by the National Natural Science Foundation of China(Nos.51578491 and 52238001).
文摘Contrary to conventional design methods that assume uniform and slow temperature changes tied to atmospheric conditions,single-layer spherical reticulated shells undergo significant non-uniform and time-variant temperature variations due to dynamic environmental coupling.These differences can affect structural performance and pose safety risks.Here,a systematic numerical method was developed and applied to simulate long-term temperature variations in such a structure under real environmental conditions,revealing its non-uniform distribution characteristics and time-variant regularity.A simplified design method for non-uniform thermal loads,accounting for time-variant environmental factors,was theoretically derived and validated through experiments and simulations.The maximum deviation and mean error rate between calculated and tested results were 6.1℃ and 3.7%,respectively.Calculated temperature fields aligned with simulated ones,with deviations under 6.0℃.Using the design method,non-uniform thermal effects of the structure are analyzed.Maximum member stress and nodal displacement under non-uniform thermal loads reached 119.3 MPa and 19.7 mm,representing increases of 167.5%and 169.9%,respectively,compared to uniform thermal loads.The impacts of healing construction time on non-uniform thermal effects were evaluated,resulting in construction recommendations.The methodologies and conclusions presented here can serve as valuable references for the thermal design,construction,and control of single-layer spherical reticulated shells or similar structures.
基金supported by the National Natural Science Foundation of China(22278169 and 51973078)the Excellent Scientific Research and Innovation Team of Education Department of Anhui Province(2022AH010028)+2 种基金the Major Projects of Education Department of Anhui Province(2022AH040068)the Key Foundation of Educational Commission of Anhui Province(2022AH050396 and 2022AH050376)Anhui Provincial Quality Engineering Project(2022sx134).
文摘Harnessing solar energy for photocatalytic hydrogen peroxide(H_(2)O_(2))synthesis represents a pinnacle of environmentally-sensitive and sustainable methodologies.While single-layer crystalline triazine-based organic frameworks(CTFs)are known for their prodigious photocatalytic potential in H_(2)O_(2)generation,ramifications of the connecting group within the triazine ring(TR)on underlying photocatalytic mechanism warrant deeper exploration.In this study,we simulate three distinct CTFs characterized by different TR linkers:CTF-1(benzene group(BG)),CTF-2(horizontally-oriented naphthyl group(NGH)),and CTF-DCN(vertically-oriented naphthyl group(NGV)).These diverse TR linkers profoundly modulate the absorption band edge of CTFs,subsequently dictating the orientation and constitution of the frontier orbitals.Such modulation plays a decisive role in determining the requisite energy for photoexcitation in CTFs,orchestrating the generation and distribution of photo-induced electrons and holes.Remarkably,the NGV linkage imparts CTF-DCN with unparalleled light ab-sorption,superior charge separation efficiency,and the lowest energy barrier for associated reactions.Through this investigation,we illuminate the pivotal influence of TR linkers in sculpting the photocatalytic dynamics of CTFs,providing fresh perspectives for architecting CTFs with amplified photocatalytic prowess in H_(2)O_(2)synthesis.
基金supported by the National Key Research and Development Program of China(2016YFA0202703,2016YFA0202704)the National Natural Science Foundation of China(51472056)+1 种基金the Thousands Talents Plan For Pioneer Researcher And His Innovation Team,Chinathe Recruitment Program of Global Youth Experts,China
文摘NO_2 sensors with ultrahigh sensitivity are demanded for future electronic sensing systems. However,traditional sensors are considerably limited by the relative low sensitivity, high cost and complicated process. Here, we report a simply and reliable flexible NO_2 sensor based on single-layer MoS_2. The flexible sensor exhibits high sensitivity to NO_2 gas due to ultra-large specific surface area and the nature of two-dimensional(2 D) semiconductor. When the NO_2 is 400 ppb(parts per billion), compared with the dark and strain-free conditions, the sensitivity of the single-layer sensor is enhanced to 671% with a625 nm red light-emitting diode(LED) illumination of 4 mW/cm^2 power under 0.67% tensile strain.More important, the response time is dramatically reduced to $16 s and it only needs $65 s to complete90% recovery. A theoretical model is proposed to discuss the microscopic mechanisms. We find that the remarkable sensing characteristics are the result of coupling among piezoelectricity, photoelectricity and adsorption-desorption induced charges transfer in the single-layer MoS_2 Schottky junction based device.Our work opens up the way to further enhancements in the sensitivity of gas sensor based on single-layer MoS_2 by introducing photogating and piezo-phototronic effects in mesoscopic systems.
基金the Natural Science Basic Research Plan in Shaanxi Province of China(Nos.2021JQ-190,2020JM-82)the Fundamental Research Funds for the Central Universities(No.QTZX2146)。
文摘MXenes,a family of two-dimensional(2D)materials,exhibit peculiar microwave-absorbing behaviors due to their unique chemical composition and structure.Although laminated Ti_(3)C_(2)T_(x) MXenes with a multilayer structure have been used for microwave absorption,real 2D MXenes with a single-layer structure have not yet been investigated.Here,the electromagnetic wave response behavior of single-layer Ti_(3)C_(2)T_(x) MXenes was explored in detail.The permittivity of Ti_(3)C_(2)T_(x) MXene rises dramatically with an increase in filler loading,and Ti_(3)C_(2)T_(x) MXene features a distinct dielectric response wherein dipolar polarization and interfacial polarization makes a greater contribution at low filler loading;conductive loss becomes more prominent at high filler loading.Versus laminated Ti_(3)C_(2)T_(x) MXene,single-layer Ti_(3)C_(2)T_(x) MXene delivers superior absorbing capability:The RLminvalue of SL-Ti_(3)C_(2)T_(x)-22%reaches-43.5 d B at 6.5 GHz,and a broad EAB of 6.88 GHz can be attained at a thickness of 1.8 mm due to enhanced dipolar polarization,interfacial polarization,and conductive loss.This work is of great significance in guiding the future development of MXene-based absorbers.
基金This work was financed by the National Natural Science Foundation of China (Grant Nos. 29992530 and 19974002) the Paper Foundation of Northern Jiaotong University.
文摘By considering the interaction between Fowler-Nordheim tunneling injection theory and charge carriers transporting through the bulk, an electroluminescence model for organic single-layer diodes is presented. The expressions of the recombination current density, recombination efficiency and conductivity of the diodes are provided, which elucidate the controlling role of the electric field on mobility and recombination zone. The equilibrium of two opposite charge carriers injection and the central position of recombination zone are two important preconditions for reducing the leakage current. Space-charge-limited current occurs only over a certain high bias, meanwhile, the quantity of injection carriers increases over the transport capacity of the bulk.
基金Deutsche Forschungsgemeinschaft(DFG)within the collaborative research program"Sustainable rural development in mountainous regions of Southeast Asia"(SFB 564)。
文摘Dried longan fruit has become an important export product of Thailand.Knowledge about drying kinetics is essential to optimize the drying process.In this study,drying kinetics of unpeeled longan fruits was investigated by varying the parameters as follows:air temperature 50~90℃,relative humidity 4%~20%,air velocity 0.2~0.5 m/s,and size of the fruits.The drying curves of longan fruit,dried in a single layer,were strongly affected by the temperature of the drying air and fruit size but less dependent on relative humidity and velocity of the drying air.Eight single-layer drying models were selected from literature to identify suitable ones for fitting moisture ratio curves to data obtained from the drying experiments.Both,the proportional and exponential coefficient of drying time in the‘Page’model could be given in a generalized function for each of the investigated drying parameters.Moreover,the two coefficients could be correlated to all drying parameters simultaneously.This allowed establishing a generalized‘Page’model for estimating drying curves for any value of temperature,fruit size,relative humidity and air velocity within the range of performed experiments.The analysis also revealed an inner correlation between the two‘Page’coefficients,which opens new doors for further research on the application of the‘Page’model for describing drying processes.
基金We gratefully acknowledge the support from the Natural Science Foundation of Chongqing(cstc2020jcyj-msxmX0037)State Key Laboratory of Mechanics and Control of Mechanical Structures(Nanjing University of Aeronautics and astronautics)under Grants MCMS-E-0120G01National Natural Science Foundation of China under Grants Nos.11925205 and 51921003,and the Fundamental Research Funds for the Central Universities of China.
文摘Free vibration of elastically constrained rectangular single-layered M0S_(2)is investigated by using a nonlocal Kirchhoff plate model with an initial stress.The variationally consistent elastically constrained boundary conditions are obtained by using the weighted residual method,while the governing equations of the nonlocal Kirchhoff plate model are known.A modified Fourier series method is applied to study the vibrational behaviors of elastically constrained nonlocal Kirchhoff plate models.The convergence and reliability of the modified Fourier series method is verified via comparison with the finite element method.A comprehensive parametric study is performed to show the influences of the boundary elastic constant,nonlocal parameter and initial stress on the vibrational behaviors of single-layered M0S2.The results should be good for the design of nanoresonators.
基金This work is supported by the National Natural Science Foundation of China(No.11804190)Shandong Provincial Natural Science Founda-tion of China(Nos.ZR2019QA011 and ZR2019MEM013)Qilu Young Scholar Program of Shandong University,and Taishan Scholar Program of Shandong Province,and Youth Science and Technology Talents En-rollment Project of Shandong Province.
文摘Valley,as a new degree of freedom for electrons,has drawn considerable attention due to its significant potential for encoding and storing information.Lifting the energy degeneracy to achieve valley polarization is necessary for realizing valleytronic devices.Here,on the basis of first-principles calculations,we show that single-layer FeCl_(2)exhibits a large spontaneous valley polarization(∼101 meV)arising from the broken time-reversal symmetry and spin-orbital coupling,which can be continuously tuned by varying the direction of magnetic crystalline.By employing the perturbation theory,the underlying physical mechanism is unveiled.Moreover,the coupling between valley degree of freedom and ferromagnetic order could generate a spin-and valley-polarized anomalous Hall current in the presence of the in-plane electric field,facilitating its experimental exploration and practical applications.
文摘Background: The myometrium at the location of the CS (caesarean section) scars, also known as residual myometrium thickness (RMT), is larger after a double-layer uterine closure procedure than following a single-layer one. It may lessen the formation of a niche that is the myometrium’s disruption at the location of the scar of the uterus. Gynecological manifestations, obstetric problems in a future pregnancy and birth, and maybe subfertility are linked to thin RMT and a niche. Objective: To ascertain if double-layer unlocked closure of the uterus is better than single-layer one in terms of post-menstrual spotting and niche development following a first CS. Patients and Methods: In this randomized clinical study, 287 patients were evaluated for qualifying. Of all eligible individuals, 57 patients were excluded from the study based on the inclusion criteria. Results: The variation in ages, gestational age, body mass index (BMI), and cesarean section indications between the two assigned groups is statistically insignificant. However, postmenstrual spotting was statistically significantly more common in single-layer group compared to in double-group. The current study revealed ultrasound findings suggestive of niche formation was statistically significantly more common in single-layer group compared to in double-layer group. Conclusion: As evident from the current study, it demonstrates the advantages of double-layer unlocked closure of the uterus over single-layer one in terms of post-menstrual spotting and niche development following first-time cs. Thus, we deduced that fewer niches are formed, and fewer menstrual spotting occurs in the presence of double unlocked layers closure. To ascertain the impact of uterus closure method on post-operative niche development and the risk of obstetrics and gynaecological problems, further prospective trials with extended follow-up periods are required.
基金the financial support provided by the National Natural Science Foundation of China(Grant No.51478335).
文摘Single-layer reticulated shells(SLRSs)find widespread application in the roofs of crucial public structures,such as gymnasiums and exhibition center.In this paper,a new neural-network-based method for structural damage identification in SLRSs is proposed.First,a damage vector index,NDL,that is related only to the damage localization,is proposed for SLRSs,and a damage data set is constructed from NDL data.On the basis of visualization of the NDL damage data set,the structural damaged region locations are identified using convolutional neural networks(CNNs).By cross-dividing the damaged region locations and using parallel CNNs for each regional location,the damaged region locations can be quickly and efficiently identified and the undamaged region locations can be eliminated.Second,a damage vector index,DS,that is related to the damage location and damage degree,is proposed for SLRSs.Based on the damaged region identified previously,a fully connected neural network(FCNN)is constructed to identify the location and damage degree of members.The effectiveness and reliability of the proposed method are verified by considering a numerical case of a spherical SLRS.The calculation results showed that the proposed method can quickly eliminate candidate locations of potential damaged region locations and precisely determine the location and damage degree of members.
基金Funded by the Natural Science Foundation of Nanping of China(No.N2021J002)Guangdong Basic and Applied Basic Research Foundation(No.2020A1515110304)+3 种基金Guangzhou Science and Technology Plan(No.202102020224)Natural Science Foundation of Fujian Province(No.2020Y0092)Natural Science Foundation of Fujian Province(No.2023J011044)Resource Chemical Industry and Technology Foundation of Nanping(No.N2020Z003)。
文摘To develop the microwave absorbing(MA)properties of cementitious material mixed with mine solid waste,the iron tailings cementitious microwave absorbing materials were prepared.The iron tailings was treated into different particle sizes by planetary ball mill,and the physicochemical properties of iron tailings were tested by laser particle size analyzer and scanning electron microscope(SEM).The electromagnetic parameters of iron tailings cementitious materials were characterized by a vector network analyzer and simulated MA properties,and the MA properties of iron tailings-cement composite system with steel fiber as absorber was studied.Based on the design of the single-layer structure,optimum mix ratio and thickness configuration method of double-layer structure were further studied,meanwhile,the mechanical properties and engineering application were analyzed and discussed.The results show that the particle size of iron tailings can afiect its electromagnetic behavior in cementitious materials,and the smaller particles lead the increase of demagnetisation efiect induced by domain wall motion and achieve better microwave absorbing properties in cementitious materials.When the thickness of matching layer and absorbing layer is 5 mm,the optimized microwave absorbing properties of C1/C3 double-layer cementitious material can obtain optimal RL value of-27.61 dB and efiective absorbing bandwidth of 0.97 GHz,which attributes to the synergistic efiect of impedance matching and attenuation characteristics.The double-layer microwave absorbing materials obtain excellent absorbing properties and show great design flexibility and diversity,which can be used as a suitable candidate for the preparation of favorable microwave absorbing cementitious materials.