A new single micro-particle electrode(SMPE)fabrication technique the inlaid SMPE technique was introduced in this paper.The preparation procedure of an alloy SMPE was described in detail.Based on the SMPE technique,th...A new single micro-particle electrode(SMPE)fabrication technique the inlaid SMPE technique was introduced in this paper.The preparation procedure of an alloy SMPE was described in detail.Based on the SMPE technique,the electrochemical behavior of LaNi_ 4.7Al_ 0.3 spherical particles with two different radii was investigated.The results of CV study showed that more detailed electrochemical information of the alloy can be provided on the alloy SMPE as compared with that on the composite alloy electrode.The results of potential step study depict that H diffusion coefficient in LaNi_ 4.7Al_ 0.3 keeps almost constant when the size of the alloy particle changes,and the diffusion coefficient measured on the alloy SMPE[(2.5—2.6)×10-9 cm 2/s] is about one order larger than that detected on the composite alloy electrode.展开更多
The addition of propranolol induced the aggregation of gold nanoparticles, and increased Rayleigh light scattering (RLS) intensity greatly. The interaction between them was studied by RLS spectrum, UV-Vis spectrum and...The addition of propranolol induced the aggregation of gold nanoparticles, and increased Rayleigh light scattering (RLS) intensity greatly. The interaction between them was studied by RLS spectrum, UV-Vis spectrum and transmission electron microscopy (TEM). Based on these results, a novel method was proposed for propranolol assay. With the combination of solid phase microextraction (SPME), the proposed method was successfully applied to determine propranolol in urine.展开更多
文摘A new single micro-particle electrode(SMPE)fabrication technique the inlaid SMPE technique was introduced in this paper.The preparation procedure of an alloy SMPE was described in detail.Based on the SMPE technique,the electrochemical behavior of LaNi_ 4.7Al_ 0.3 spherical particles with two different radii was investigated.The results of CV study showed that more detailed electrochemical information of the alloy can be provided on the alloy SMPE as compared with that on the composite alloy electrode.The results of potential step study depict that H diffusion coefficient in LaNi_ 4.7Al_ 0.3 keeps almost constant when the size of the alloy particle changes,and the diffusion coefficient measured on the alloy SMPE[(2.5—2.6)×10-9 cm 2/s] is about one order larger than that detected on the composite alloy electrode.
基金The authors acknowledge the support from the National Natural Science Foundation of China(No.20275028)973 Program(No.2002CB2118)863 Program(No.2002AA2Z2004).
文摘The addition of propranolol induced the aggregation of gold nanoparticles, and increased Rayleigh light scattering (RLS) intensity greatly. The interaction between them was studied by RLS spectrum, UV-Vis spectrum and transmission electron microscopy (TEM). Based on these results, a novel method was proposed for propranolol assay. With the combination of solid phase microextraction (SPME), the proposed method was successfully applied to determine propranolol in urine.
