Silane coupling agent KH560 was used to modify the surface of nano-α-Al<sub>2</sub>O<sub>3</sub> in ethanol-aqueous solution with different proportions. The particle size of nano-α-Al<sub&...Silane coupling agent KH560 was used to modify the surface of nano-α-Al<sub>2</sub>O<sub>3</sub> in ethanol-aqueous solution with different proportions. The particle size of nano-α-Al<sub>2</sub>O<sub>3</sub> was determined by nano-particle size analyzer, and the effects of nano-α-Al<sub>2</sub>O<sub>3</sub> content, ethanol-aqueous solution ratio and KH560 dosage on the dispersion and particle size of nano-α-Al<sub>2</sub>O<sub>3</sub> were investigated. The material structure before and after modification was determined by Fourier transform infrared spectroscopy (FTIR). Aqueous polyurethane resin and inorganic components are combined with modified nano-α-Al<sub>2</sub>O<sub>3</sub> dispersion to form chromium-free passivation solution. The solution is coated on the galvanized sheet, the adhesion and surface hardness are tested, the bonding strength of the coating and the surface hardness of the substrate are discussed. The corrosion resistance and surface morphology of the matrix were investigated by electrochemical test, neutral salt spray test and scanning electron microscope test. The chromium-free passivation film formed after the modification of nano-α-Al<sub>2</sub>O<sub>3</sub> increases the surface hardness of galvanized sheet by about 85%. The corrosion resistance of the film is better than that of a single polyurethane film. The results show that the surface hardness and corrosion resistance of polyurethane resin composite passivation film are significantly improved by the introduction of nano-α-Al<sub>2</sub>O<sub>3</sub>.展开更多
The molten mixtures of alkali metal fluorides and aluminum fluoride are applied as aluminum electrolytes or brazing fluxes.However,the presence of Al2F-7^-in such molten systems is disputed.In the present study,MF-AlF...The molten mixtures of alkali metal fluorides and aluminum fluoride are applied as aluminum electrolytes or brazing fluxes.However,the presence of Al2F-7^-in such molten systems is disputed.In the present study,MF-AlF3(M=K,Cs)systems with molar ratios<1 were studied by in-situ Raman spectroscopy and molecular simulation.The results show that,in addition to AlF6^(3-),AlF5^(2-),and AlF4^-,the systems also contained Al2F-7^-.The characteristic bands in the Raman spectra belonging to Al2F-7^-were located at about 225 cm^-1,315 cm^-1,479 cm^-1,and 720 cm^-1.There are two possible structures of Al2F-7^-,which belong to the D3d and D3hpoint groups.Both of these structures are linear,and their single-point energies were found to differ by only 0.31 kcal/mol.展开更多
A novel In203/Bi24O31Br10 composite photocatalyst, where In2O3 nanoparticleswith the diameter of about 5-10 nm were tightly attached on the surface of Bi24O31Br10 plates, wasprepared by using hydrolysis, impregnation ...A novel In203/Bi24O31Br10 composite photocatalyst, where In2O3 nanoparticleswith the diameter of about 5-10 nm were tightly attached on the surface of Bi24O31Br10 plates, wasprepared by using hydrolysis, impregnation method and post-thermal process. Photocatalyticactivity was evaluated by the degradation of Rhodamine B under the visible light irradiation.Effects of the contents of In203 nanoparticles on the optical property and photocatalytic activity of In203/Bi24O31Br10 composite were also investigated. Compared with neat In203 and Bi24O31Brlomaterials, 15In203/Bi24O31Br10 composite exhibits the best photocatalytic activity owing to theefficient separation of photogenerated electron and hole pairs, which is evidenced byphotoluminence spectra. More than 95% of Rhodamine B solution can be degraded by15In203/Bi24O31Brlo sample in 30 min.展开更多
Test alloys ZG40Cr24 with alloying of 3 wt% aluminium were cast by intermediate frequency induction furnace. The oxidation resistance of test alloys at 1 000 ℃ for 500 hours was examined according to oxidation weight...Test alloys ZG40Cr24 with alloying of 3 wt% aluminium were cast by intermediate frequency induction furnace. The oxidation resistance of test alloys at 1 000 ℃ for 500 hours was examined according to oxidation weight gain method. The scale morphology and composition were studied using scanning electron microscope （SEM） and X-ray diffraction （XRD） respectively. By energy dispersive spectroscopy （EDS） studies, a kind of composite oxide scale compounded highly by Cr2O3, Al2O3 and spinel MCr2O4 in molecule scale came into being at high temperature. With flat and compact structure, fine and even grains, such composite scale granted complete oxidation resistance to alloy ZG40Cr24. The oxidation resistance mechanism was studied deeply in electrochemistry corrosion. The P＋N semiconductor composite scale composed plenty of inner PN junctions, of which the unilateral conductive and the out-of-order arrangement endowed itself insulating in all directions. The positive and negative charges in scale could not move, and the mobile number and transferring rate of them both dropped enormously, as a result, the oxidation rate of the matrix metal was cut down greatly. So the composite scale presented excellent oxidation resistance.展开更多
Quantum chemical calculations on some possible equilibrium geometries of C24O2 isomers derived from C24 （D6） and C24O have been performed using density functional theory （DFT） method. The geometric and electronic ...Quantum chemical calculations on some possible equilibrium geometries of C24O2 isomers derived from C24 （D6） and C24O have been performed using density functional theory （DFT） method. The geometric and electronic structures as well as the relative energies and thermal stabilities of various C24O2 isomers at the ground state have been calculated at the B3LYP/6-31G（d） level of theory. And the 1,4,2,5-C24O2 isomer was found to be the most stable geometry where two oxygen atoms were added to the longest carbon-carbon bonds in the same pentagon from a thermodynamic point of view. Based on the optimized neutral geometries, the vertical ionization potential and vertical electron affinity have been obtained. Meanwhile, the vibrational frequencies, IR spectrum, and 13C chemical shifts of various C24O2 isomers have been calculated and analyzed.展开更多
以纳米ZrO 、微米Al O 为原料,采用无压烧结方式制备了ZTA 复相陶瓷。结果表明:nano-ZrO 的 2 2 3 2加入有利于制备细晶ZTA 复相陶瓷。此外,nano-ZrO 的加入对 Al O 陶瓷的显微结构也产生影响,ZrO ...以纳米ZrO 、微米Al O 为原料,采用无压烧结方式制备了ZTA 复相陶瓷。结果表明:nano-ZrO 的 2 2 3 2加入有利于制备细晶ZTA 复相陶瓷。此外,nano-ZrO 的加入对 Al O 陶瓷的显微结构也产生影响,ZrO 颗粒以 2 2 3 2“晶内型”和晶界型两种形式存在。合理的配方组成及制备工艺有利于 Z r O 以四方亚稳相存在。Z r O 含量为 2 23 0 w t % 时,其四方相含量可达 6 9 %,有利于应力诱导相变增韧,该 Z T A 复相陶瓷的抗弯强度、断裂韧性分别达到 604MPa、6.87MPa·m1/2。展开更多
文摘Silane coupling agent KH560 was used to modify the surface of nano-α-Al<sub>2</sub>O<sub>3</sub> in ethanol-aqueous solution with different proportions. The particle size of nano-α-Al<sub>2</sub>O<sub>3</sub> was determined by nano-particle size analyzer, and the effects of nano-α-Al<sub>2</sub>O<sub>3</sub> content, ethanol-aqueous solution ratio and KH560 dosage on the dispersion and particle size of nano-α-Al<sub>2</sub>O<sub>3</sub> were investigated. The material structure before and after modification was determined by Fourier transform infrared spectroscopy (FTIR). Aqueous polyurethane resin and inorganic components are combined with modified nano-α-Al<sub>2</sub>O<sub>3</sub> dispersion to form chromium-free passivation solution. The solution is coated on the galvanized sheet, the adhesion and surface hardness are tested, the bonding strength of the coating and the surface hardness of the substrate are discussed. The corrosion resistance and surface morphology of the matrix were investigated by electrochemical test, neutral salt spray test and scanning electron microscope test. The chromium-free passivation film formed after the modification of nano-α-Al<sub>2</sub>O<sub>3</sub> increases the surface hardness of galvanized sheet by about 85%. The corrosion resistance of the film is better than that of a single polyurethane film. The results show that the surface hardness and corrosion resistance of polyurethane resin composite passivation film are significantly improved by the introduction of nano-α-Al<sub>2</sub>O<sub>3</sub>.
基金the National Natural Science Foundation of China(grant no.51474060)the National Key R&D Program of China(grant no.2017 YFC0805100)+1 种基金the National Natural Science Foundation of Liaoning Province(China)(grant no.2019-MS-129)the Fundamental Research Funds for the Central Universities of China(grant no.N162502002).
文摘The molten mixtures of alkali metal fluorides and aluminum fluoride are applied as aluminum electrolytes or brazing fluxes.However,the presence of Al2F-7^-in such molten systems is disputed.In the present study,MF-AlF3(M=K,Cs)systems with molar ratios<1 were studied by in-situ Raman spectroscopy and molecular simulation.The results show that,in addition to AlF6^(3-),AlF5^(2-),and AlF4^-,the systems also contained Al2F-7^-.The characteristic bands in the Raman spectra belonging to Al2F-7^-were located at about 225 cm^-1,315 cm^-1,479 cm^-1,and 720 cm^-1.There are two possible structures of Al2F-7^-,which belong to the D3d and D3hpoint groups.Both of these structures are linear,and their single-point energies were found to differ by only 0.31 kcal/mol.
基金supported by the Natural Science Foundation of Fujian Province(2016J01740)National Natural Science Foundation of China(21473096)the Outstanding Youth Scientific Research Cultivation Plan in Fujian Province University,and the guiding project of Fujian Province(2016Y0073)
文摘A novel In203/Bi24O31Br10 composite photocatalyst, where In2O3 nanoparticleswith the diameter of about 5-10 nm were tightly attached on the surface of Bi24O31Br10 plates, wasprepared by using hydrolysis, impregnation method and post-thermal process. Photocatalyticactivity was evaluated by the degradation of Rhodamine B under the visible light irradiation.Effects of the contents of In203 nanoparticles on the optical property and photocatalytic activity of In203/Bi24O31Br10 composite were also investigated. Compared with neat In203 and Bi24O31Brlomaterials, 15In203/Bi24O31Br10 composite exhibits the best photocatalytic activity owing to theefficient separation of photogenerated electron and hole pairs, which is evidenced byphotoluminence spectra. More than 95% of Rhodamine B solution can be degraded by15In203/Bi24O31Brlo sample in 30 min.
文摘Test alloys ZG40Cr24 with alloying of 3 wt% aluminium were cast by intermediate frequency induction furnace. The oxidation resistance of test alloys at 1 000 ℃ for 500 hours was examined according to oxidation weight gain method. The scale morphology and composition were studied using scanning electron microscope （SEM） and X-ray diffraction （XRD） respectively. By energy dispersive spectroscopy （EDS） studies, a kind of composite oxide scale compounded highly by Cr2O3, Al2O3 and spinel MCr2O4 in molecule scale came into being at high temperature. With flat and compact structure, fine and even grains, such composite scale granted complete oxidation resistance to alloy ZG40Cr24. The oxidation resistance mechanism was studied deeply in electrochemistry corrosion. The P＋N semiconductor composite scale composed plenty of inner PN junctions, of which the unilateral conductive and the out-of-order arrangement endowed itself insulating in all directions. The positive and negative charges in scale could not move, and the mobile number and transferring rate of them both dropped enormously, as a result, the oxidation rate of the matrix metal was cut down greatly. So the composite scale presented excellent oxidation resistance.
文摘Quantum chemical calculations on some possible equilibrium geometries of C24O2 isomers derived from C24 （D6） and C24O have been performed using density functional theory （DFT） method. The geometric and electronic structures as well as the relative energies and thermal stabilities of various C24O2 isomers at the ground state have been calculated at the B3LYP/6-31G（d） level of theory. And the 1,4,2,5-C24O2 isomer was found to be the most stable geometry where two oxygen atoms were added to the longest carbon-carbon bonds in the same pentagon from a thermodynamic point of view. Based on the optimized neutral geometries, the vertical ionization potential and vertical electron affinity have been obtained. Meanwhile, the vibrational frequencies, IR spectrum, and 13C chemical shifts of various C24O2 isomers have been calculated and analyzed.
文摘以纳米ZrO 、微米Al O 为原料,采用无压烧结方式制备了ZTA 复相陶瓷。结果表明:nano-ZrO 的 2 2 3 2加入有利于制备细晶ZTA 复相陶瓷。此外,nano-ZrO 的加入对 Al O 陶瓷的显微结构也产生影响,ZrO 颗粒以 2 2 3 2“晶内型”和晶界型两种形式存在。合理的配方组成及制备工艺有利于 Z r O 以四方亚稳相存在。Z r O 含量为 2 23 0 w t % 时,其四方相含量可达 6 9 %,有利于应力诱导相变增韧,该 Z T A 复相陶瓷的抗弯强度、断裂韧性分别达到 604MPa、6.87MPa·m1/2。
