The low-melting phosphate glass was prepared for production of glass binders for protective coating of steel slab. Effects of different O/P ratios on glass structures and properties were analyzed. Differential thermal...The low-melting phosphate glass was prepared for production of glass binders for protective coating of steel slab. Effects of different O/P ratios on glass structures and properties were analyzed. Differential thermal analysis （DTA） and infrared spectroscopy （IR） techniques were applied for low-melting glass binder. It was found that the glass transition temperature（T） was about 300 ℃ and softening temperature（T1） was about 480 ℃. The choice of O/P ratio was very important to the glass transition and softening temperatures. When more P=O bonds existed in the glass networks, P-O-P bond angle was deformed with decreasing of the ratio of O/E The coatings could adhere to the substrates instantaneously at 800 ℃ when the content of binder exceeded 3wt%. The optimal content of glass binder was 5wt%.展开更多
The fact that the amount of the mold flux components differs at differentlocations on the cracking surface indicates that the longitudinal surface cracks are initiallyformed in the mold and are enlarged in the seconda...The fact that the amount of the mold flux components differs at differentlocations on the cracking surface indicates that the longitudinal surface cracks are initiallyformed in the mold and are enlarged in the secondary cooling zone. Based on the hot ductilitymeasurement of two typical container used steels, it is known that the steels are in severeembrittlement state in the temperature range of 825-775 deg C. By means of increasing Cr/Ni platingthickness on the upper part of the mold, reducing mold heat flux, adopting new secondary coolingpattern, etc., the occurrence of the surface longitudinal cracks on the steel CC (continuouscasting) slabs has been significantly reduced.展开更多
A coupled dynamics computation model for metro vehicles, along with a steel-spring floating-slab track, is developed based on the theory of vehicle-track coupled dynamics. Using the developed model, the influences of ...A coupled dynamics computation model for metro vehicles, along with a steel-spring floating-slab track, is developed based on the theory of vehicle-track coupled dynamics. Using the developed model, the influences of the thickness, length and mass of floating-slab, spring rate and its arrangement space, running speed, etc. on the time and frequency domain characteristics of steel-spring fulcrum force are analyzed. The applicability of steel-spring floatingslab track is discussed through two integrated example cases of metro and buildings possessing distinct natural vibra- tion characteristics. It is concluded that, it is quite significant, in the optimization modular design of the parameters of steel-spring floating-slab track, to take the matching relationship of both the amplitude-frequency characteristics of steel-spring fulcrum force and natural vibration characteristics of integrated structures into comprehensive consideration. In this way the expensive steel-spring floating-slab track can be economically and efficiently utilized according to the site condition, and at the same time, the economic losses and bad social impact resulted from the resonance during usage of steel-spring floating-slab track can be avoided.展开更多
The comparison of different submerged entry nozzles(SEN)was made by numerical simulation regarding the influence of liquid steel flow field,heat transfer and mold fluxes,as well as solidification shell stress and surf...The comparison of different submerged entry nozzles(SEN)was made by numerical simulation regarding the influence of liquid steel flow field,heat transfer and mold fluxes,as well as solidification shell stress and surface quality of thin slabs.The optimum internal shape of mold and the SEN were obtained.The foundation for choice of internal shape and casting parameters of mold was built.展开更多
Based on their hot ductilities, Nb, V and Ti microalloying steels can be classified into two groups. The first group includes steels with lower carbon content (≤0.10%). Ductilities of steels of this group recover and...Based on their hot ductilities, Nb, V and Ti microalloying steels can be classified into two groups. The first group includes steels with lower carbon content (≤0.10%). Ductilities of steels of this group recover and rise with decreasing temperature when temperature lowers to below 825℃. Another group includes steels which contain more carbon (>0.12%) or contain more Nb and V. The low ductility temperature Region Ⅲ for steels of mis group extends to temperature as low as 725℃. The occurrence of the transverse corner cracks of the Nb, V and Ti microalloying steel CC slabs has be considerably decreased by stabilizing casting speed, increasing mold steel level automatic control ratio,enhancing caster segment radial alignment and adopting proper secondary cooling patterns to make slab corner temperature at straightening out off the low ductility temperature region.展开更多
Hot ductility of the Nb- and Ti-containing line-pipe steel CC slab specimens were measured under the sirain rate of 1 x 10-3/s. Three types of precipitates were found in the fractured specimens. One was the block-shap...Hot ductility of the Nb- and Ti-containing line-pipe steel CC slab specimens were measured under the sirain rate of 1 x 10-3/s. Three types of precipitates were found in the fractured specimens. One was the block-shaped coarse TiN particles precipitated at high temperature. Another type was the fine dynamic precipitation products precipitated at 950～900℃ which caused remarkable ductility reduction of the steel. The third type was the co-existed precipitates formed by fine Nb precipitates nucleating and growing on TiN paricles. Compared with Nb-containing steel which contains no Ti, there was no ductility drop for Nb- and Ti-containing steel at temperature between 850℃ and Ar3 and, the γ→α transformation inside the grain matrixes proceeded faster, which both improved the ductility of the steel in the low ductility temperature Region Ⅲ.展开更多
At Baoshan Iron ＆ Steel Co., Ltd., comer cracks of boron containing LCAK steel slabs had caused remarkable quality loss and mass flow disorder. With the help of fractography and thermodynamics analysis, the embrittle...At Baoshan Iron ＆ Steel Co., Ltd., comer cracks of boron containing LCAK steel slabs had caused remarkable quality loss and mass flow disorder. With the help of fractography and thermodynamics analysis, the embrittlement mechanism of this steel grade was studied and the results are as follows： 1 The transformation from 3＇ to a starts at the austenite grain boundaries and a layer of thin ferrite film gradually forms around the austenite grains. Strain concentration will preferentially start inside the ferrite phase when the stress accumulates to a certain level. 2 The coarse BN particles acceleratedly precipitated at the γ/α interfaces further deteriorate the ductility of the ferrite film, and brittleness results in strain concentration and microvoid coalescence inside the ferrite film. Therefore the austenite grain boundaries are prone to intergranular failure. 3 The stoichiometry among Al, N and B is a very important factor influencing the hot ductility of this steel grade. By controling the B-to-N atomic ratio to above 1, all N can be fixed by B instead of A1. Thus coarsegrained steel is available and fewer grain boundaries and higher ductility can reduce the risk of comer cracks. （4） By adjusting the B-to-N atomic ratio,Baoshan Iron ＆ Steel Co.,Ltd. successfully reduced the number of cracks to nearly one tenth of that in the past and the hot tensile tests confirmed remarkable improvement in the hot ductility of this steel.展开更多
In order to analyze the effect of electromagnetic stirring on the slab＇ s surface purity, the continuously cast slab surface inclusions and subsurface blisters have been investigated. The results indicate that the mo...In order to analyze the effect of electromagnetic stirring on the slab＇ s surface purity, the continuously cast slab surface inclusions and subsurface blisters have been investigated. The results indicate that the mold electromagnetic stirrer （M -EMS） is useful for the improvement of IF steel slabs＇ surface quality. The continuously cast slab surface inclusions and subsurface blisters have been significantly reduced. The distribution of bubbles in the slab is non-homogeneous in terms of both width and depth. The continuously cast slab surface inclusions tend to miniaturization through M-EMS and most of the inclusions are less than 10 μm in size.展开更多
Thermal behavior of the solidifying shell in continuous casting mold is very important to final steel products.In the present work,one two-dimension transient thermal-mechanical finite element model was developed to s...Thermal behavior of the solidifying shell in continuous casting mold is very important to final steel products.In the present work,one two-dimension transient thermal-mechanical finite element model was developed to simulate the thermal behavior of peritectic steel solidifying in slab continuous casting mold by using the sequential coupling method.In this model,the steel physical properties at high temperature was gotten from the micro-segregation model withδ/γtransformation in mushy zone,and the heat flux was obtained according to the displacement between the surface of solidifying shell and the hot face of mold as solidification contraction,the liquid-solid structure and distribution of mold flux,and the temperature distribution of slab surface and mold hot face,in addition,the rate-dependent elastic-viscoplastic constitutive equation was applied to account for the evolution of shell stress in the mold.With this model,the variation characteristics of surface temperature,heat flux, and growth of the solidifying shell corner,as well as the thickness distribution of the liquid flux,solidified flux,air gap and the corresponding thermal resistance were described.展开更多
The hot ductility of the V-containing micro-alloying steel CC (continuouscasting) slabs and precipitation of vanadium carbide in the tensile specimens were investigated. Theresults indicate that the precipitation rati...The hot ductility of the V-containing micro-alloying steel CC (continuouscasting) slabs and precipitation of vanadium carbide in the tensile specimens were investigated. Theresults indicate that the precipitation ratio and precipitation rate of vanadium in the specimensreach maximum respectively at 900, -825 and 825 deg C. There is still l0 percent-l7 percent ofvanadium precipitated when the deformation temperature decreases to 800-700 deg C. Vanadium largelyaffects the ductility of the steel in the low ductility temperature Region III. Embrittlement ofsteel with higher V content is severer in the region and the embrittlement extends to lowertemperature.展开更多
On April 23,2009,a new single strand slab caster at ThyssenKrupp Acciai Speciali Terni(TKAST) was successfully started up with the first cast of AISI 304 grade in Terni plant,central Italy.TKAST is the Italian company...On April 23,2009,a new single strand slab caster at ThyssenKrupp Acciai Speciali Terni(TKAST) was successfully started up with the first cast of AISI 304 grade in Terni plant,central Italy.TKAST is the Italian company of ThyssenKrupp Stainless group. The new caster is designed for a total capacity of approx.900.000 tpy of stainless steel slabs covering the complete range of stainless grades,including AISI 300 and 400 families(austenitic,ferritic and martensitic grades).This state of the art caster for the production of 215 mm thick slabs replaced an existing thin slab caster. This paper resumes the reasons of the installation of the new plant designed,manufactured erected and commissioned by Danieli and describes the technological solution,main features as well as the excellent results of this state of the art caster.展开更多
In order to solve the problem of the high surface longitudinal crack ratio of heavy peritectic steel slabs produced by the No. 3 continuous caster at Baosteel,the physical properties of the original mold flux and the ...In order to solve the problem of the high surface longitudinal crack ratio of heavy peritectic steel slabs produced by the No. 3 continuous caster at Baosteel,the physical properties of the original mold flux and the optimized mold flux were compared in a comprehensive way by using analytical measures, such as a slag film heat-flow simulator, a thermowire molten flux crystallization tester and an X-ray diffractometer in the laboratory. The results reveal that one of the major reasons for the cracks is the poor heat transfer ability of the original mold flux. However, the optimized mold flux with a high basicity features a high crystallizing rate,low crystallization temperature and low heat-flow density. Therefore, the optimized mold flux is more suitable for casting peritectic steel by the heavy slab continuous caster. The test results show that the slabs produced by using the optimized mold flux had no surface longitudinal crack in four test casts, while the surface longitudinal crack ratio of the slabs produced by using the original mold flux was 5%. The optimized mold flux can effectively prevent slab surface longitudinal cracks from occurring.展开更多
基金Funded by the National Natural Science Foundation of China(No.51202249)the Key Projects in the National Science&Technology Pillar Program in the Twelfth Five-year Plan Period(No.2012BAB08B04)
文摘The low-melting phosphate glass was prepared for production of glass binders for protective coating of steel slab. Effects of different O/P ratios on glass structures and properties were analyzed. Differential thermal analysis （DTA） and infrared spectroscopy （IR） techniques were applied for low-melting glass binder. It was found that the glass transition temperature（T） was about 300 ℃ and softening temperature（T1） was about 480 ℃. The choice of O/P ratio was very important to the glass transition and softening temperatures. When more P=O bonds existed in the glass networks, P-O-P bond angle was deformed with decreasing of the ratio of O/E The coatings could adhere to the substrates instantaneously at 800 ℃ when the content of binder exceeded 3wt%. The optimal content of glass binder was 5wt%.
文摘The fact that the amount of the mold flux components differs at differentlocations on the cracking surface indicates that the longitudinal surface cracks are initiallyformed in the mold and are enlarged in the secondary cooling zone. Based on the hot ductilitymeasurement of two typical container used steels, it is known that the steels are in severeembrittlement state in the temperature range of 825-775 deg C. By means of increasing Cr/Ni platingthickness on the upper part of the mold, reducing mold heat flux, adopting new secondary coolingpattern, etc., the occurrence of the surface longitudinal cracks on the steel CC (continuouscasting) slabs has been significantly reduced.
基金supported by the Key Project of Science and Technology in an Action of Shanghai Scientific and Technological Innovation (No. 09231201600)the National Natural Science Foundation of China(No. 50823004)the Science and Technology Department of Sichuan Province
文摘A coupled dynamics computation model for metro vehicles, along with a steel-spring floating-slab track, is developed based on the theory of vehicle-track coupled dynamics. Using the developed model, the influences of the thickness, length and mass of floating-slab, spring rate and its arrangement space, running speed, etc. on the time and frequency domain characteristics of steel-spring fulcrum force are analyzed. The applicability of steel-spring floatingslab track is discussed through two integrated example cases of metro and buildings possessing distinct natural vibra- tion characteristics. It is concluded that, it is quite significant, in the optimization modular design of the parameters of steel-spring floating-slab track, to take the matching relationship of both the amplitude-frequency characteristics of steel-spring fulcrum force and natural vibration characteristics of integrated structures into comprehensive consideration. In this way the expensive steel-spring floating-slab track can be economically and efficiently utilized according to the site condition, and at the same time, the economic losses and bad social impact resulted from the resonance during usage of steel-spring floating-slab track can be avoided.
基金Item Sponsored by National Natural Science Foundation of China(59174140)
文摘The comparison of different submerged entry nozzles(SEN)was made by numerical simulation regarding the influence of liquid steel flow field,heat transfer and mold fluxes,as well as solidification shell stress and surface quality of thin slabs.The optimum internal shape of mold and the SEN were obtained.The foundation for choice of internal shape and casting parameters of mold was built.
文摘Based on their hot ductilities, Nb, V and Ti microalloying steels can be classified into two groups. The first group includes steels with lower carbon content (≤0.10%). Ductilities of steels of this group recover and rise with decreasing temperature when temperature lowers to below 825℃. Another group includes steels which contain more carbon (>0.12%) or contain more Nb and V. The low ductility temperature Region Ⅲ for steels of mis group extends to temperature as low as 725℃. The occurrence of the transverse corner cracks of the Nb, V and Ti microalloying steel CC slabs has be considerably decreased by stabilizing casting speed, increasing mold steel level automatic control ratio,enhancing caster segment radial alignment and adopting proper secondary cooling patterns to make slab corner temperature at straightening out off the low ductility temperature region.
文摘Hot ductility of the Nb- and Ti-containing line-pipe steel CC slab specimens were measured under the sirain rate of 1 x 10-3/s. Three types of precipitates were found in the fractured specimens. One was the block-shaped coarse TiN particles precipitated at high temperature. Another type was the fine dynamic precipitation products precipitated at 950～900℃ which caused remarkable ductility reduction of the steel. The third type was the co-existed precipitates formed by fine Nb precipitates nucleating and growing on TiN paricles. Compared with Nb-containing steel which contains no Ti, there was no ductility drop for Nb- and Ti-containing steel at temperature between 850℃ and Ar3 and, the γ→α transformation inside the grain matrixes proceeded faster, which both improved the ductility of the steel in the low ductility temperature Region Ⅲ.
文摘At Baoshan Iron ＆ Steel Co., Ltd., comer cracks of boron containing LCAK steel slabs had caused remarkable quality loss and mass flow disorder. With the help of fractography and thermodynamics analysis, the embrittlement mechanism of this steel grade was studied and the results are as follows： 1 The transformation from 3＇ to a starts at the austenite grain boundaries and a layer of thin ferrite film gradually forms around the austenite grains. Strain concentration will preferentially start inside the ferrite phase when the stress accumulates to a certain level. 2 The coarse BN particles acceleratedly precipitated at the γ/α interfaces further deteriorate the ductility of the ferrite film, and brittleness results in strain concentration and microvoid coalescence inside the ferrite film. Therefore the austenite grain boundaries are prone to intergranular failure. 3 The stoichiometry among Al, N and B is a very important factor influencing the hot ductility of this steel grade. By controling the B-to-N atomic ratio to above 1, all N can be fixed by B instead of A1. Thus coarsegrained steel is available and fewer grain boundaries and higher ductility can reduce the risk of comer cracks. （4） By adjusting the B-to-N atomic ratio,Baoshan Iron ＆ Steel Co.,Ltd. successfully reduced the number of cracks to nearly one tenth of that in the past and the hot tensile tests confirmed remarkable improvement in the hot ductility of this steel.
文摘In order to analyze the effect of electromagnetic stirring on the slab＇ s surface purity, the continuously cast slab surface inclusions and subsurface blisters have been investigated. The results indicate that the mold electromagnetic stirrer （M -EMS） is useful for the improvement of IF steel slabs＇ surface quality. The continuously cast slab surface inclusions and subsurface blisters have been significantly reduced. The distribution of bubbles in the slab is non-homogeneous in terms of both width and depth. The continuously cast slab surface inclusions tend to miniaturization through M-EMS and most of the inclusions are less than 10 μm in size.
文摘Thermal behavior of the solidifying shell in continuous casting mold is very important to final steel products.In the present work,one two-dimension transient thermal-mechanical finite element model was developed to simulate the thermal behavior of peritectic steel solidifying in slab continuous casting mold by using the sequential coupling method.In this model,the steel physical properties at high temperature was gotten from the micro-segregation model withδ/γtransformation in mushy zone,and the heat flux was obtained according to the displacement between the surface of solidifying shell and the hot face of mold as solidification contraction,the liquid-solid structure and distribution of mold flux,and the temperature distribution of slab surface and mold hot face,in addition,the rate-dependent elastic-viscoplastic constitutive equation was applied to account for the evolution of shell stress in the mold.With this model,the variation characteristics of surface temperature,heat flux, and growth of the solidifying shell corner,as well as the thickness distribution of the liquid flux,solidified flux,air gap and the corresponding thermal resistance were described.
文摘The hot ductility of the V-containing micro-alloying steel CC (continuouscasting) slabs and precipitation of vanadium carbide in the tensile specimens were investigated. Theresults indicate that the precipitation ratio and precipitation rate of vanadium in the specimensreach maximum respectively at 900, -825 and 825 deg C. There is still l0 percent-l7 percent ofvanadium precipitated when the deformation temperature decreases to 800-700 deg C. Vanadium largelyaffects the ductility of the steel in the low ductility temperature Region III. Embrittlement ofsteel with higher V content is severer in the region and the embrittlement extends to lowertemperature.
文摘On April 23,2009,a new single strand slab caster at ThyssenKrupp Acciai Speciali Terni(TKAST) was successfully started up with the first cast of AISI 304 grade in Terni plant,central Italy.TKAST is the Italian company of ThyssenKrupp Stainless group. The new caster is designed for a total capacity of approx.900.000 tpy of stainless steel slabs covering the complete range of stainless grades,including AISI 300 and 400 families(austenitic,ferritic and martensitic grades).This state of the art caster for the production of 215 mm thick slabs replaced an existing thin slab caster. This paper resumes the reasons of the installation of the new plant designed,manufactured erected and commissioned by Danieli and describes the technological solution,main features as well as the excellent results of this state of the art caster.
文摘In order to solve the problem of the high surface longitudinal crack ratio of heavy peritectic steel slabs produced by the No. 3 continuous caster at Baosteel,the physical properties of the original mold flux and the optimized mold flux were compared in a comprehensive way by using analytical measures, such as a slag film heat-flow simulator, a thermowire molten flux crystallization tester and an X-ray diffractometer in the laboratory. The results reveal that one of the major reasons for the cracks is the poor heat transfer ability of the original mold flux. However, the optimized mold flux with a high basicity features a high crystallizing rate,low crystallization temperature and low heat-flow density. Therefore, the optimized mold flux is more suitable for casting peritectic steel by the heavy slab continuous caster. The test results show that the slabs produced by using the optimized mold flux had no surface longitudinal crack in four test casts, while the surface longitudinal crack ratio of the slabs produced by using the original mold flux was 5%. The optimized mold flux can effectively prevent slab surface longitudinal cracks from occurring.
