The influence of oxide scales on the corrosion behaviors of B510 L hot-rolled steel strips was investigated in this study. Focused ion beams and scanning electron microscopy were used to observe the morphologies of ox...The influence of oxide scales on the corrosion behaviors of B510 L hot-rolled steel strips was investigated in this study. Focused ion beams and scanning electron microscopy were used to observe the morphologies of oxide scales on the surface and cross sections of the hot-rolled steel. Raman spectroscopy and X-ray diffraction were used for the phase analysis of the oxide scales and corrosion products. The corrosion potential and impedance were measured by anodic polarization and electrochemical impedance spectroscopy. According to the results, oxide scales on the hot-rolled strips mainly comprise iron and iron oxides. The correlation between mass gain and test time follows a power exponential rule in the damp-heat test. The corrosion products are found to be mainly composed of γ-Fe OOH, Fe3O4, ？-Fe OOH, and γ-Fe2O3. The contents of the corrosion products are different on the surfaces of the steels with and without oxide scales. The steel with oxide scales is found to show a higher corrosion resistance and lower corrosion rate.展开更多
A method was proposed to improve the anti-rust property of hot rolled rebar, which uses oil–water emulsion cooling instead of water cooling after hot rolling. The experiments were carried out by two cooling methods, ...A method was proposed to improve the anti-rust property of hot rolled rebar, which uses oil–water emulsion cooling instead of water cooling after hot rolling. The experiments were carried out by two cooling methods, one cooled by water, the other cooled by oil–water emulsion. The results of wet/dry cyclic accelerated corrosion test showed that the anti-rust property of rebar cooled by oil–water emulsion was better than that by water obviously. The results of OM, SEM and EPMA analysis indicated that these two scales contained three layers: an outer Fe_3O_4 layer, an intermediate Fe O layer with island-shaped pro-eutectoid Fe_3O_4, an inner eutectoid Fe_3O_4 layer. For the water cooled rebar, all three layers of oxide scale were relatively thin. Moreover, the scale had plenty of defects such as porosity, and crack. However, for the oil–water emulsion cooled rebar, all three layers of oxide scale were relatively thick and compact, which played an important role in protecting the rebar from atmospheric rust.展开更多
The types and growth of various oxide scales formed during the different phases of the production of hotrolled strip steel products are reviewed. Similarities and differences between the ＂tertiary scale＂ on the surf...The types and growth of various oxide scales formed during the different phases of the production of hotrolled strip steel products are reviewed. Similarities and differences between the ＂tertiary scale＂ on the surface of carbon steels at high temperatures and the oxide scale on pure iron are compared. The micro-structural features of the ＂final oxide scale＂ on the surface of strip steels at room temperature as well as the relationship between these features and the position of the steel coil （plate） and the subsequent processes of recoiling, temper rolling and trimming, etc. are summarized. The actual oxide scales retained on the commercial hot-rolled strip steels at room temperature have been proposed to define as ＂ quartus scale＂ for the first time. The micro-structural development and phase transformation of the initial ＂tertiary scale＂ during and after cooling and coiling are described. The reasons for the ＂tertiary scale＂ on carbon steels differing from the oxide scale formed on pure iron, and the major influencing factors in the formation of various types of ＂quartus scales＂ are analyzed from both thermodynamic and dynamic viewpoints. The development mechanism of ＂ quartus scales＂ is discussed and the potential effects of the ＂ quartus scale＂ state （thickness, constitution, structure and defects）, on the rusting and pickling properties of commercial hot-rolled strip steel, as well as on the mechanical properties of oxide scales are analyzed.展开更多
In this study, the matrix structure, state and composition of the mill scales of four typical domestically made 510L hot-rolled strips were observed and analyzed by means of optical microscopy （OM） ,scanning electro...In this study, the matrix structure, state and composition of the mill scales of four typical domestically made 510L hot-rolled strips were observed and analyzed by means of optical microscopy （OM） ,scanning electron microscopy （SEM） and X-ray diffraction （XRD）. The corrosion behavior of the steels with and without mill scales were investigated by means of hot-humid corrosion tests under the condition of relative humidity （ RH ） of 95% at 50℃ and 70℃, respectively. The results show that the matrix structures, state, composition and thickness of mill scales vary in the strips. The rusting starting time of the specimens with scales is generally a bit longer than that of the specimens without scales, but their corrosion mass-gain is higher. For these two kinds of specimens ,their corrosion rate increases significantly with the increase of temperature. The rusting behavior of the 510L strips produced by various plants is different due to the variations of hot-rolling processes and designed chemical compositions. Various relevant aspects should be taken into account in the evaluation of the corrosion behavior of hot-rolled strips.展开更多
A new processing method for producing hot dip galvanized steel is designed and tested, in which pickling is skipped. Hot-rolled low carbon steel sheets are roiled with oxide scale in an experimental mill at room tempe...A new processing method for producing hot dip galvanized steel is designed and tested, in which pickling is skipped. Hot-rolled low carbon steel sheets are roiled with oxide scale in an experimental mill at room temperature, prior to annealing under a 20% hydrogen reducing atmosphere and galvanizing on a hot-dip galvanizing simulator. Micro-cracks formed in the oxide scale during cold rolling roughen the steel surface and enlarge the specific surface. Through-thickness cracks provide transport channels for hydrogen, and hence the reduction of oxide scale is en- hanced. When the sheet is dipped in the zinc bath, cracks are submerged by liquated zinc and the defects are not dis- tinct after hot-dip galvanizing. The overlay coating occludes with rough surface of the sheet, whereby a superior coat- ing adherence is realized.展开更多
In the last few years,substantial experimental simulation and mumerical modelling hare been carried out in IMMPETUS to characterise the interfacial heat transfer and friction conditions during hot forging and rolling ...In the last few years,substantial experimental simulation and mumerical modelling hare been carried out in IMMPETUS to characterise the interfacial heat transfer and friction conditions during hot forging and rolling of steels. Emphasis has been placed on the influence of the oxide scale which forms on the steel workpiece. In the present paper, the experimental methods used for investigating interfacial heat transfer and friction conditions are described. Theses include hot flat rolling of steel slabs and hot axi- symmetric forging of steel cylinders and rings.Temperature measurements and computations demon- strate that for similar conditions, similar conditions, the effective interfacial heat transfer coefficients (IHTC) derived for hot rolling are significantly higher than those for forging, mainly due to the contribution of scale cracking during rolling. On the basis of experimental observations and numerical analysis,physical models for interfacial heat transfer in forging and rolling have been established. In addition, hot' sandwich' rolling and hot tensile tests with finite element modelling have been carried out to evaluate the hot ductility of the oxide scale.The results indicate that the defomation, cracking and decohesion behaviour of the oxide scale depend on deformation temperature, strain and relative strengths of the scale layer and scale - steel interface.Finaly, friction results from hot ring compression tests and from hot rolling with forward/backward slip measurements are reported.展开更多
基金supported by the National Natural Science Foundation of China(No.51222106)the Fundamental Research Funds for the Central Universities(No.FRF-TP-14-011C1)+1 种基金the Major State Basic Research Development Program of China(No.2014CB643300)the Beijing Municipal Commission of Education
文摘The influence of oxide scales on the corrosion behaviors of B510 L hot-rolled steel strips was investigated in this study. Focused ion beams and scanning electron microscopy were used to observe the morphologies of oxide scales on the surface and cross sections of the hot-rolled steel. Raman spectroscopy and X-ray diffraction were used for the phase analysis of the oxide scales and corrosion products. The corrosion potential and impedance were measured by anodic polarization and electrochemical impedance spectroscopy. According to the results, oxide scales on the hot-rolled strips mainly comprise iron and iron oxides. The correlation between mass gain and test time follows a power exponential rule in the damp-heat test. The corrosion products are found to be mainly composed of γ-Fe OOH, Fe3O4, ？-Fe OOH, and γ-Fe2O3. The contents of the corrosion products are different on the surfaces of the steels with and without oxide scales. The steel with oxide scales is found to show a higher corrosion resistance and lower corrosion rate.
基金Project(51374069) supported by the National Natural Science Foundation of China
文摘A method was proposed to improve the anti-rust property of hot rolled rebar, which uses oil–water emulsion cooling instead of water cooling after hot rolling. The experiments were carried out by two cooling methods, one cooled by water, the other cooled by oil–water emulsion. The results of wet/dry cyclic accelerated corrosion test showed that the anti-rust property of rebar cooled by oil–water emulsion was better than that by water obviously. The results of OM, SEM and EPMA analysis indicated that these two scales contained three layers: an outer Fe_3O_4 layer, an intermediate Fe O layer with island-shaped pro-eutectoid Fe_3O_4, an inner eutectoid Fe_3O_4 layer. For the water cooled rebar, all three layers of oxide scale were relatively thin. Moreover, the scale had plenty of defects such as porosity, and crack. However, for the oil–water emulsion cooled rebar, all three layers of oxide scale were relatively thick and compact, which played an important role in protecting the rebar from atmospheric rust.
文摘The types and growth of various oxide scales formed during the different phases of the production of hotrolled strip steel products are reviewed. Similarities and differences between the ＂tertiary scale＂ on the surface of carbon steels at high temperatures and the oxide scale on pure iron are compared. The micro-structural features of the ＂final oxide scale＂ on the surface of strip steels at room temperature as well as the relationship between these features and the position of the steel coil （plate） and the subsequent processes of recoiling, temper rolling and trimming, etc. are summarized. The actual oxide scales retained on the commercial hot-rolled strip steels at room temperature have been proposed to define as ＂ quartus scale＂ for the first time. The micro-structural development and phase transformation of the initial ＂tertiary scale＂ during and after cooling and coiling are described. The reasons for the ＂tertiary scale＂ on carbon steels differing from the oxide scale formed on pure iron, and the major influencing factors in the formation of various types of ＂quartus scales＂ are analyzed from both thermodynamic and dynamic viewpoints. The development mechanism of ＂ quartus scales＂ is discussed and the potential effects of the ＂ quartus scale＂ state （thickness, constitution, structure and defects）, on the rusting and pickling properties of commercial hot-rolled strip steel, as well as on the mechanical properties of oxide scales are analyzed.
文摘In this study, the matrix structure, state and composition of the mill scales of four typical domestically made 510L hot-rolled strips were observed and analyzed by means of optical microscopy （OM） ,scanning electron microscopy （SEM） and X-ray diffraction （XRD）. The corrosion behavior of the steels with and without mill scales were investigated by means of hot-humid corrosion tests under the condition of relative humidity （ RH ） of 95% at 50℃ and 70℃, respectively. The results show that the matrix structures, state, composition and thickness of mill scales vary in the strips. The rusting starting time of the specimens with scales is generally a bit longer than that of the specimens without scales, but their corrosion mass-gain is higher. For these two kinds of specimens ,their corrosion rate increases significantly with the increase of temperature. The rusting behavior of the 510L strips produced by various plants is different due to the variations of hot-rolling processes and designed chemical compositions. Various relevant aspects should be taken into account in the evaluation of the corrosion behavior of hot-rolled strips.
基金Item Sponsored by National Science and Technology Pillar Program of China(2011BAE13B04)
文摘A new processing method for producing hot dip galvanized steel is designed and tested, in which pickling is skipped. Hot-rolled low carbon steel sheets are roiled with oxide scale in an experimental mill at room temperature, prior to annealing under a 20% hydrogen reducing atmosphere and galvanizing on a hot-dip galvanizing simulator. Micro-cracks formed in the oxide scale during cold rolling roughen the steel surface and enlarge the specific surface. Through-thickness cracks provide transport channels for hydrogen, and hence the reduction of oxide scale is en- hanced. When the sheet is dipped in the zinc bath, cracks are submerged by liquated zinc and the defects are not dis- tinct after hot-dip galvanizing. The overlay coating occludes with rough surface of the sheet, whereby a superior coat- ing adherence is realized.
文摘In the last few years,substantial experimental simulation and mumerical modelling hare been carried out in IMMPETUS to characterise the interfacial heat transfer and friction conditions during hot forging and rolling of steels. Emphasis has been placed on the influence of the oxide scale which forms on the steel workpiece. In the present paper, the experimental methods used for investigating interfacial heat transfer and friction conditions are described. Theses include hot flat rolling of steel slabs and hot axi- symmetric forging of steel cylinders and rings.Temperature measurements and computations demon- strate that for similar conditions, similar conditions, the effective interfacial heat transfer coefficients (IHTC) derived for hot rolling are significantly higher than those for forging, mainly due to the contribution of scale cracking during rolling. On the basis of experimental observations and numerical analysis,physical models for interfacial heat transfer in forging and rolling have been established. In addition, hot' sandwich' rolling and hot tensile tests with finite element modelling have been carried out to evaluate the hot ductility of the oxide scale.The results indicate that the defomation, cracking and decohesion behaviour of the oxide scale depend on deformation temperature, strain and relative strengths of the scale layer and scale - steel interface.Finaly, friction results from hot ring compression tests and from hot rolling with forward/backward slip measurements are reported.
