Evaluation on the Thermal Stability and Hazards Behaviors of ADVN Using Green Thermal Analysis Approach

ADVN （2,2＇-Azobis （2,4-dimethyl） valeronitrile）, a free radical initiator, is widely applied for the polymerization reaction of polymers in the chemical industries. When ADVN releases free radical during the decomposition process, it can accompany abundant heat and huge pressure to increase the possibility of thermal runaway and hazard, causing unacceptable thermal explosion or fire accidents. To develop an inherently safer process for ADVN, the thermal stability parameters of ADVN were obtained to investigate thermal decomposition characteristics using a DSC （differential scanning calorimetry） and TG （thermogravimetry）. We used various kinetic models to completely depict the kinetic behavior and determine the thermal safety parameters for ADVN. The green thermal analysis approach could be used to substitute for complicated procedures and large-scale experiments of traditional thermal analysis methods, avoiding environmental pollution and energy depletion.

Reasonable selection of yield criteria for quantitative analysis of unsaturated soil slope stability

The yield criterion parameters of the soil material change with different values of the cohesion and the angle of friction because of sustained rainfall infiltration. Based on the Mohr-Coulomb(M-C) and Drucker-Prager(D-P) yield criteria, some reasonable yield criteria selections were discussed for quantitative analysis of unsaturated soil slope stability. Moreover, a critical point was found at the effective angle of friction equaling to 16.5° by transformation of parameters related to unsaturated soil under sustained rainfall. When the effective angle of friction more than 16.5° through parameter transformation of different yield criteria under natural condition, the calculation result of the safety factor was such that: f(DP1) > f(M-C) > f(equivalent M-C) > f(DP2) > f(DP3). While the effective angle of friction less than 16.5°, through parameter transformation, the safety factors were in the following order: f(DP1) > f(M-C) > f(DP2) > f(equivalent M-C) > f(DP3). The calculated results from a case study showed that the equivalent M-C yield criterion should be the best at evaluating soil slope stability before rainfall; the DP2 yield criterion should be selected to calculate the soil slope stability at the effective angle of friction less than 16.5° under sustained rainfall. The yield criterion should be selected or adjusted reasonably to calculate the safety factor of unsaturated soil slopes before and during sustained rainfall.