Effect of safety valve types on the gas venting behavior and thermal runaway hazard severity of large-format prismatic lithium iron phosphate batteries

The safety valve is an important component to ensure the safe operation of lithium-ion batteries(LIBs).However,the effect of safety valve type on the thermal runaway(TR)and gas venting behavior of LIBs,as well as the TR hazard severity of LIBs,are not known.In this paper,the TR and gas venting behavior of three 100 A h lithium iron phosphate(LFP)batteries with different safety valves are investigated under overheating.Compared to previous studies,the main contribution of this work is in studying and evaluating the effect of gas venting behavior and TR hazard severity of LFP batteries with three safety valve types.Two significant results are obtained:(Ⅰ)the safety valve type dominates over gas venting pressure of battery during safety venting,the maximum gas venting pressure of LFP batteries with a round safety valve is 3320 Pa,which is one order of magnitude higher than other batteries with oval or cavity safety valve;(Ⅱ)the LFP battery with oval safety valve has the lowest TR hazard as shown by the TR hazard assessment model based on gray-fuzzy analytic hierarchy process.This study reveals the effect of safety valve type on TR and gas venting,providing a clear direction for the safety valve design.

STUDY ON VARIATION OF SETTING AND STOPPING PRESSURES OF SAFETY VALVE WITH STRUCTURAL MODIFICATION

The possibility of pressure control with the structural change of a safety valve is investigated Safety valve is commonly used as safety devices for numerous applications which include boilers,ships,industrial plants,and piping Setting and stopping pressures of a safety valve, p set and p sto ,are traditionally adjusted with a fine tuning of seat ring and valve ring heights, h sr and h vr However, it is not easy to achieve the proper setting and stopping pressures of a safety valve in practice The depth of inside and outside grooves in a valve, d i and d o are modified and their effects on setting and stopping pressures of a safety vlave are tested The most appropriate values appear 1 0 mm in d i and 0 5～1 0 mm in d o,respectively The valve ring height, h vr ,shows that the best results can be achieved at 2 3 mm for setting pressures of 0 1～0 4 MPa and 1 0 mm for setting pressures of 0 5～1 0 MPa The stopping pressures increases with the increase of seat ring height, h sr , upto certain h sr value and then becomes independent to the seat ring height This implies that there exists the optimum h sr ,which provides the largest flow rate and the proper stopping pressure Stopping pressures of a safety valve are adjusted with the seat ring and valve ring heights This study,however,demonstrated that the modification of value grooves also changes setting and stopping pressures of a safety valve Therefore,the proper selection in dimensions of the inside and outside grooves should be considered for the safety valve design

Properties analysis of a large flow-rate safety valve test device

In order to solve the problem of property test of large flow-rate safety, the property parameter of safety valve test system was analyzed, and a device for property oflarge flow-rate safety valve test was designed.The device used accumulators as power source and a united function cylinder, which can realized the large flow-rate output for the test system.Analyzed the test data and made a particular research on the test device by testing different flow-rate safety valves;it verifies that the test device can be used tode-sign larger flow-rate safety valve test system and can make the flow-rate test and analysis and dynamic characteristics for the large-flow safety valve.

A Study of the Gas Flow through a LNG Safety Valve

A safety valve functions to control an upper limit of pressure inside the LNG line of transportation. If the pressure inside the safety valve nozzle exceeds a predetermined value on the valve sheet which plugs the nozzle, an excess of LNG discharges through the gap between the nozzle exit and valve sheet. In this situation, the forces acting on the valve sheet are gasdynamic forces generated by the discharge of LNG and mechanical forces supported by the spring behind the valve sheet. The flow through the gap is very complicated, involving vortices, flow separation, and shock waves. These affect adversely on the system accompanying with noise and vibration. The present study aims at understanding the flow physics of safety valve. A computational work using the twodimensional, axisymmetric, compressible Navier-Stokes equations is carried out to simulate the gas flow between the nozzle exit and valve sheet, and compared with the theoretical results. It has been found that there exists a distance between nozzle exit and valve sheet in which the thrust coefficient at the valve sheet increases abruptly.