Gypsum/salt beds are widely developed in petroliferous basins across the world.Most basins with gypsum/salt beds have been proven to host abundant hydrocarbon resources.Previous studies on the effects of gypsum/salt b...Gypsum/salt beds are widely developed in petroliferous basins across the world.Most basins with gypsum/salt beds have been proven to host abundant hydrocarbon resources.Previous studies on the effects of gypsum/salt beds on hydrocarbon reservoirs primarily focused on their excellent sealing property as cap rocks.However,an increasing number of exploration discoveries have shown that gypsum/salt beds have the potential to promote the formation of high-quality source rocks and hydrocarbon reservoirs.Gypsum/salt beds influence the generation,preservation and accumulation of hydrocarbons.Based on the systematic analysis of the generation of hydrocarbons in global gypsum/saltbearing sequences,the study discussed the control of gypsum/salt beds on play elements,and explore the relationship between the development of gypsum/salt beds and global large-and medium-scale hydrocarbon reservoirs.Furthermore,we analyzed the correlation between typical gypsum/saltbearing sequences and their hydrocarbon generation potentials in China.In-depth analysis shows three patterns in terms of the spatial superimposition of gypsum/salt beds and source rocks,that is,postsalt pattern,inter-salt pattern and pre-salt pattern.Among others,the source rocks of the inter-salt pattern are widely developed in salt basins and of great potential for hydrocarbon exploration.展开更多
A novel utilization way of the sludge from wet calcium-based flue gas desulfurization （FGD） processes has been developed in this paper. This study focused on the conversion of the FGD gypsum into α-hemihydrate calc...A novel utilization way of the sludge from wet calcium-based flue gas desulfurization （FGD） processes has been developed in this paper. This study focused on the conversion of the FGD gypsum into α-hemihydrate calcium sulfate by a hydrothermal salt solution method at atmospheric pressure. Experimental study has been carried out in a batch reactor. Qualitative and quantitative analyses were made by DSC/TG thermal analysis, SEM, XRD, metalloscope and chemical analysis. The experimental results showed that the modification of FGD gypsum was controlled by the dissolution and recrystallization mechanisms. With the introduction of FGD gypsum the salt solution was supersaturated, then crystal nucleus of α-hemihydrate calcium sulfate were produced in the solution. With the submicroscopic structure of FGD gypsum crystal changed, the crystal nucleus grew up into α-hemihydrate calcium sulfate crystals. Thus ,the modification of FGD gypsum was fulfilled.展开更多
Large-scale gypsum rocks associated with world-class Pb-Zn ore formations are widely distributed in the Lanping Basin,Sowthwest China.Geochemical studies alongside field investigations were conducted in this study to ...Large-scale gypsum rocks associated with world-class Pb-Zn ore formations are widely distributed in the Lanping Basin,Sowthwest China.Geochemical studies alongside field investigations were conducted in this study to determine the source and evolutionary processes of the gypsum rocks in this area.The gypsum sequences in the Lanping Basin developed in two formations:the Triassic Sanhedong Formation and the Paleogene Yunlong Formation.The gypsum hosted in the former displays a primary thick-banded structure withδ34SV-CDT values in the range of 14.5‰−14.8‰.Combined with the 87Sr/86Sr values(0.707737−0.707783)of limestone,it can be suggested that the Sanhedong Formation is of marine origin.In contrast,the gypsum from the Paleogene Yunlong Formation is characterized by the dome,bead and diapiric salt structures,wider range of both 87Sr/86Sr(0.707695−0.708629)andδ34SV-CDT values(9.6‰−17‰),thus indicating a marine source but with the input of continental materials.The initial layered salt formations were formed by chemical deposition in a basin and were later intensely deformed by collisional orogeny during the Himalaya period.As a result,variable salt structures were formed.We hereby propose an evolutionary model to elucidate the genesis of the gypsum formations in the Lanping Basin.展开更多
为更好地服务水利水电工程、岩土工程等行业土料勘察工作,建立了盐酸溶液浸提-离子色谱法测定中溶盐石膏(CaSO_(4)·2H_(2)O)含量的新方法。实验采用4.5m M Na_(2)CO_(3)/1.4m M Na HCO_(3)淋洗液,在1.0m L·min^(-1)流速下对...为更好地服务水利水电工程、岩土工程等行业土料勘察工作,建立了盐酸溶液浸提-离子色谱法测定中溶盐石膏(CaSO_(4)·2H_(2)O)含量的新方法。实验采用4.5m M Na_(2)CO_(3)/1.4m M Na HCO_(3)淋洗液,在1.0m L·min^(-1)流速下对硫酸盐进行测定,测定方法的相对标准偏差(RSD)为2.3%,加标回收率为91.0%~102%,检出限为0.003g·kg^(-1)。该方法操作简单、高效、准确度高,适用于工程勘察中大批量样品的测定。展开更多
基金This study was funded by a key project of the National Natural Science Fund of China(41930426)a key project of the Petrochemical Joint Fund(U1663201).
文摘Gypsum/salt beds are widely developed in petroliferous basins across the world.Most basins with gypsum/salt beds have been proven to host abundant hydrocarbon resources.Previous studies on the effects of gypsum/salt beds on hydrocarbon reservoirs primarily focused on their excellent sealing property as cap rocks.However,an increasing number of exploration discoveries have shown that gypsum/salt beds have the potential to promote the formation of high-quality source rocks and hydrocarbon reservoirs.Gypsum/salt beds influence the generation,preservation and accumulation of hydrocarbons.Based on the systematic analysis of the generation of hydrocarbons in global gypsum/saltbearing sequences,the study discussed the control of gypsum/salt beds on play elements,and explore the relationship between the development of gypsum/salt beds and global large-and medium-scale hydrocarbon reservoirs.Furthermore,we analyzed the correlation between typical gypsum/saltbearing sequences and their hydrocarbon generation potentials in China.In-depth analysis shows three patterns in terms of the spatial superimposition of gypsum/salt beds and source rocks,that is,postsalt pattern,inter-salt pattern and pre-salt pattern.Among others,the source rocks of the inter-salt pattern are widely developed in salt basins and of great potential for hydrocarbon exploration.
文摘A novel utilization way of the sludge from wet calcium-based flue gas desulfurization （FGD） processes has been developed in this paper. This study focused on the conversion of the FGD gypsum into α-hemihydrate calcium sulfate by a hydrothermal salt solution method at atmospheric pressure. Experimental study has been carried out in a batch reactor. Qualitative and quantitative analyses were made by DSC/TG thermal analysis, SEM, XRD, metalloscope and chemical analysis. The experimental results showed that the modification of FGD gypsum was controlled by the dissolution and recrystallization mechanisms. With the introduction of FGD gypsum the salt solution was supersaturated, then crystal nucleus of α-hemihydrate calcium sulfate were produced in the solution. With the submicroscopic structure of FGD gypsum crystal changed, the crystal nucleus grew up into α-hemihydrate calcium sulfate crystals. Thus ,the modification of FGD gypsum was fulfilled.
基金Project(41362008)supported by the National Natural Science Foundation of China。
文摘Large-scale gypsum rocks associated with world-class Pb-Zn ore formations are widely distributed in the Lanping Basin,Sowthwest China.Geochemical studies alongside field investigations were conducted in this study to determine the source and evolutionary processes of the gypsum rocks in this area.The gypsum sequences in the Lanping Basin developed in two formations:the Triassic Sanhedong Formation and the Paleogene Yunlong Formation.The gypsum hosted in the former displays a primary thick-banded structure withδ34SV-CDT values in the range of 14.5‰−14.8‰.Combined with the 87Sr/86Sr values(0.707737−0.707783)of limestone,it can be suggested that the Sanhedong Formation is of marine origin.In contrast,the gypsum from the Paleogene Yunlong Formation is characterized by the dome,bead and diapiric salt structures,wider range of both 87Sr/86Sr(0.707695−0.708629)andδ34SV-CDT values(9.6‰−17‰),thus indicating a marine source but with the input of continental materials.The initial layered salt formations were formed by chemical deposition in a basin and were later intensely deformed by collisional orogeny during the Himalaya period.As a result,variable salt structures were formed.We hereby propose an evolutionary model to elucidate the genesis of the gypsum formations in the Lanping Basin.
文摘为更好地服务水利水电工程、岩土工程等行业土料勘察工作,建立了盐酸溶液浸提-离子色谱法测定中溶盐石膏(CaSO_(4)·2H_(2)O)含量的新方法。实验采用4.5m M Na_(2)CO_(3)/1.4m M Na HCO_(3)淋洗液,在1.0m L·min^(-1)流速下对硫酸盐进行测定,测定方法的相对标准偏差(RSD)为2.3%,加标回收率为91.0%~102%,检出限为0.003g·kg^(-1)。该方法操作简单、高效、准确度高,适用于工程勘察中大批量样品的测定。
