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Studies on Solid-Liquid Phase Transfer Equilibrium of Onium Salts(Ⅱ)
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作者 Zhao Yingying and Zheng Luo (Department of Chemistry, Jilin University, Changchun)Shen Yusheng (Department of Chemistry, South-Central College for Nationalities, Wuhan) 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1992年第1期5-9,共5页
The present paper contains the effects of the ammonium ion, counter ion, solvent and anion being transferred on the solid-liquid phase transfer equilibrium constant of quaternary ammonium salts. The most striking diff... The present paper contains the effects of the ammonium ion, counter ion, solvent and anion being transferred on the solid-liquid phase transfer equilibrium constant of quaternary ammonium salts. The most striking difference between solid-liquid and liquid-liquid phase transfer equilibriums is that the length of alkyl chain shows a large effect on the latter but little on the former This means that the chain length affects only the hydrophobicity, rather than the lipophilicity.Keywords Quaternary ammonium salt, Phase transfer catalysis, Equilibrium constant, Hydrophobicity, Lipophilicity 展开更多
关键词 SHOW Studies on Solid-Liquid Phase Transfer equilibrium of Onium salts
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