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Insight into microstructure evolution on anti-corrosion property of Al_(x)CoCrFeNiC_(0.01) high-entropy alloys using scanning vibration electrode technique
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作者 Bo-Kai Liao Zhan-Xiang Liang +6 位作者 Zhi-Gang Luo Yue Liu Hao-Wei Deng Tao Zhang Xing-Peng Guo Qi-Sen Ren Hong-En Ge 《Rare Metals》 SCIE EI CAS CSCD 2023年第10期3455-3467,共13页
The effect of micro structure on the corrosion resistance of Al_(x)CoCrFeNiC_(0.01)(x=0.2,0.7,and 1.2)high-entropy alloys(HEAs) was systematically studied in this work.The microstructure evolution by regulating the Al... The effect of micro structure on the corrosion resistance of Al_(x)CoCrFeNiC_(0.01)(x=0.2,0.7,and 1.2)high-entropy alloys(HEAs) was systematically studied in this work.The microstructure evolution by regulating the Al content was analyzed in detail.Corrosion behavior was in situ monitored using the scanning vibration electrode technique,as well as some traditional electrochemical measurements.It is interesting to find that the compositions of body-centered cubic(bcc) and face-centered cubic(fcc)phases changed with the rising Al content,while the corresponding electrochemical responses for both phases were discriminated using the scanning Kelvin probe force microscopy method.Cr element was mainly distributed in the bcc phase for Al0.2(x=0.2) alloy,while its distribution changed to the fcc phase for the A10.7 and Al1.2alloys.The micro-galvanic corrosion cells formed between Cr-depleted and Cr-rich phases,resulting in the localized corrosion behaviors for the Al_(x)CoCrFeNiC_(0.01) HEAs,and the order for anti-corrosion property was Al0.2>Al1.2> Al0.7 HEAs. 展开更多
关键词 High-entropy alloy Corrosion Mechanical property scanning vibration electrode technique
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Effect of scratch on corrosion resistance of calcium phosphate conversion coated AZ80 magnesium alloy 被引量:5
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作者 Xue-jiao JIA Jiang-feng SONG +4 位作者 Xiao-rong QU Fu-yong CAO Bin JIANG Andrej ATRENS Fu-sheng PAN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第1期147-161,共15页
In order to analyze the effect of scratch on the corrosion behaviour of a calcium phosphate conversion coating(CPCC)on AZ80,the electrochemical testing,scanning vibrating electrode technique(SVET),immersion test and h... In order to analyze the effect of scratch on the corrosion behaviour of a calcium phosphate conversion coating(CPCC)on AZ80,the electrochemical testing,scanning vibrating electrode technique(SVET),immersion test and hydrogen evolution experiment were performed to study the corrosion resistance of AZ80,AZ80 with CPCC and coated AZ80 with scratch.The results show that the coating improves the corrosion resistance of the AZ80 from a current density of(85±4)to(4±1)μA/cm^(2).When the coating was damaged,its protection on substrate would be reduced.The scratch with a length of around 12 mm on the coating reduced the corrosion resistance to a current density of(39±1)μA/cm^(2).In addition,the corrosion occurred initially in the scratch area and the corrosion site first occurred at the junction of the scratch and the coating.Besides,the micro corrosion mechanism of the specimen containing scratch was clarified. 展开更多
关键词 magnesium alloy AZ80 alloy SCRATCH conversion coating corrosion resistance scanning vibrating electrode technique(SVET)
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A review on the synergism between corrosion and fatigue of magnesium alloys:Mechanisms and processes on the micro-scale
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作者 Mara Cristina Lopes de Oliveira Rejane Maria Pereira da Silva +1 位作者 Ricardo M.Souto Renato Altobelli Antunes 《Journal of Magnesium and Alloys》 SCIE EI CAS 2024年第8期3062-3093,共32页
Understanding the interaction between cyclic stresses and corrosion of magnesium(Mg)and its alloys is increasingly in demand due to the continuous expansion of structural applications of these materials.This review is... Understanding the interaction between cyclic stresses and corrosion of magnesium(Mg)and its alloys is increasingly in demand due to the continuous expansion of structural applications of these materials.This review is dedicated to exploring the corrosion-fatigue mechanisms of these materials,with an emphasis on microscale processes,and the possibility of expanding current knowledge on this topic using scanning electrochemical techniques.The interaction between fatigue and corrosion of Mg alloys is analyzed by considering the microstructural aspects(grain size,precipitates,deformation twins),as well as the formation of pits.Furthermore,in the case of coated alloys,the role of coating defects in these phenomena is also described.In this context,the feasibility of using scanning electrochemical microscopy(SECM),scanning vibrating electrode technique(SVET),scanning ion-selective electrode technique(SIET),localized electrochemical impedance spectroscopy(LEIS)and scanning Kelvin probe(SKP)methods to study the corrosion-fatigue interaction of Mg alloys is examined.A comprehensive review of the current literature in this field is presented,and the opportunities and limitations of consolidating the use of these techniques to study the microscale processes involved in Mg corrosion-fatigue are discussed. 展开更多
关键词 Magnesium alloys Localized corrosion and protection Fatigue scanning electrochemical microscopy scanning vibrating electrode technique scanning ion-selective electrode technique scanning Kelvin probe Chemical imaging
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Relationship between La and Ce additions on microstructure and corrosion resistance of hot-dip galvanized steel 被引量:4
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作者 Hong-qiang Fan Wen-can Xu +3 位作者 Liang Wei Zhi-hong Zhang Yu-bao Liu Qian Li 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2020年第9期1108-1116,共9页
Scanning electron microscopy,X-ray diffraction,a neutral salt spray test,and electrochemical methods were applied to observe the microstructure and test the corrosion resistance of hot-dip galvanized steel before and ... Scanning electron microscopy,X-ray diffraction,a neutral salt spray test,and electrochemical methods were applied to observe the microstructure and test the corrosion resistance of hot-dip galvanized steel before and after the addition of La and Ce.La/Ce mixture existed in the form of(La,Ce)Zn13 on the coated surface,decreased the coating thickness and accelerated the zinc dendritic growth.The corrosion current density of Zn-0.1La-0.1Ce coating was 63%less than that of pure Zn coating.This phenomenon can be explained that La/Ce mixture inhibited the transformation of Zn5(OH)8Cl2·H2O into Zn5(CO3)2(OH)6 or ZnO,reduced the time for appearance of red rust,and thus enhanced the stability of corrosion products and delayed the oxidation and corrosion processes of galvanized coating.La/Ce mixture improved the corrosion resistance compared to a single La or a single Ce addition.A competitive relationship between La and Ce was observed in the corrosion resistance improvement of hot-dip galvanized steel. 展开更多
关键词 Hot-dip galvanized steel Rare earth· COATING Corrosion resistance scanning vibrating electrode technique
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Galvanic Corrosion Behavior of Copper-Drawn Steel for Grounding Grids in the Acidic Red Soil Simulated Solution 被引量:3
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作者 Xiao-Lei Fan Yun-Xiang Chen +3 位作者 Jun-Xi Zhang De-Yuan Lin Xuan-Xuan Liu Xiao-Jian Xia 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2020年第11期1571-1582,共12页
The influence of pH and metallographic structure on the corrosion behavior of copper-drawn steel is studied with the simulated system.The effect of pH on the corrosion behavior of copper-drawn steel has been investiga... The influence of pH and metallographic structure on the corrosion behavior of copper-drawn steel is studied with the simulated system.The effect of pH on the corrosion behavior of copper-drawn steel has been investigated using open-circuit potential,potentiodynamic polarization,galvanic current measurement,scanning electron microscopy and scanning vibrating electrode technique techniques.The steel is corroded as anode,while the corrosion of copper plate is protected as cathode.All the results revealed that pH and metallographic structure had a significant influence on the corrosion behavior of copper-drawn steel.With the decrease in pH value from 6 to 2.4,the corrosion rate of copper-drawn steel galvanic couple(Cu-Fe GC)obviously increased in the simulated solution of acidic red soil.The electric field formed by the Cu-Fe GC changes the direction of ion migration between the copper and drawn steel electrodes,which impacts the composition and microstructure of corrosion products formed on the electrode surface. 展开更多
关键词 Cu-Fe galvanic couple Electrochemical test scanning vibrating electrode technique(SVET)measurement Soil corrosion
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Initiation and propagation of localized corrosion induced by(Zr,Ti,Al)-O_(x) inclusions in low-alloy steels in marine environment 被引量:1
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作者 Wen-zhui Wei Kai-ming Wu +2 位作者 Jing Liu Lin Cheng Xian Zhang 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2021年第4期453-463,共11页
The effects of inclusions on localized corrosion of Zr–Ti deoxidized low-alloy steels in marine environment were investigated by various analytical techniques including scanning electron microscopy with X-ray microan... The effects of inclusions on localized corrosion of Zr–Ti deoxidized low-alloy steels in marine environment were investigated by various analytical techniques including scanning electron microscopy with X-ray microanalysis(SEM/EDS),confocal Raman microscopy(CRM),and in situ scanning vibrating electrode technique(SVET).It was found that complex(Zr,Ti,Al)-O_(x)inclusions were responsible for the initiation of localized corrosion.Localized corrosion pref-erentially occurred at Fe matrix adjacent to these inclusions and formed micro-gaps.In the early stage of corrosion,catalytic-occluded cells and the diffusion of chloride ions played a major role in the propagation of corrosion,further accelerating the dissolution of Fe matrix and(Zr,Ti,Al)-O_(x)inclusions.Combining SVET and CRM results,it revealed that the maximum anodic current density in local area gradually decreased with prolonged exposure time,indicating that corrosion products covered the steel surface and lowered the propagation rate of corrosion.In the later stage of corrosion,the barrier effect of corrosion products played an important role in inhibiting localized corrosion. 展开更多
关键词 (Zr Ti Al)-O_(x)inclusion Localized corrosion Low-alloy steel Marine environment scanning vibrating electrode technique
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Inhibition of galvanic corrosion in Al/Cu coupling model by synergistic combination of 3-Amino-1,2,4-triazole-5-thiol and cerium chloride
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作者 Inime Ime Udoh Hongwei Shi +2 位作者 Mohammad Soleymanibrojeni Fuchun Liu En-Hou Han 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2020年第9期102-115,共14页
Asynergistic inhibition study was carried out on an aluminium/copper galvanic coupling model in neutral aerated NaCl solution using scanning vibrating electrode technique(SVET).The approach allows the simulation of th... Asynergistic inhibition study was carried out on an aluminium/copper galvanic coupling model in neutral aerated NaCl solution using scanning vibrating electrode technique(SVET).The approach allows the simulation of the local micro-galvanic cells of AA2024-T3 obtained from the potential difference between the intermetallic particles(IMPs)and the aluminium matrix.The inhibition effect of CeCl3 and 3-Amino-1,2,4-triazole-5-thiol(ATAT)was demonstrated by the reduction in the galvanic current density over Al and Cu surfaces.An improved inhibition from positive synergistic effect was revealed by the combination of the two inhibitors after 24 h of immersion,with the best inhibition recorded for Ce1.5ATAT3.5.Scanning electron microscopy(SEM),X-ray photoelectron spectroscopy(XPS)and time of flight secondary ion mass spectrometry(ToF-SIMS)were used to characterize the Ce-and ATAT-based complex film formed and to illustrate the mechanism of inhibition. 展开更多
关键词 Aluminium alloy Galvanic corrosion Neutral inhibition scanning vibrating electrode technique (SVET) X-ray photoelectron spectroscopy(XPS) Time of flight secondary ion mass spectrometry(ToF-SIMS)
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Effects of chloride on electrochemical and stress corrosion cracking behavior of 9Cr ferritic-martensitic steel
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作者 Zhen Zhang Zheng-fei Hu +4 位作者 Liang He Xiao-bo Zhang Xin-xian Fang Bao-sen Zhang Zhi-xin Ba 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2020年第6期719-731,共13页
The electrochemical and stress corrosion cracking behavior of 9Cr ferritic-martensitic steel is investigated in the chloride environment by using the traditional electrochemical method, the scanning vibrating electrod... The electrochemical and stress corrosion cracking behavior of 9Cr ferritic-martensitic steel is investigated in the chloride environment by using the traditional electrochemical method, the scanning vibrating electrode technique and the slow strain rate test (SSRT). Results of the static corrosion tests and corrosion morphology show that the prior austenite grain boundaries and martensite lath boundaries are the preferred sites for pit nucleation and growth in chloride environment. Results of SSRT coupled with insitu electrochemical test show that the transition from pitting corrosion to uniform corrosion, as well as the nucleation of stress corrosion crack, is the synergistic effects of the chloride and applied load. Stress corrosion cracking of the steel in the chloride environment can be divided into three different regions as follows: fast and uniform corrosion activ-ity, microcrack nucleation and propagation, and active crack growth regions. 展开更多
关键词 9Cr ferritic-martensitic steel CHLORIDE In situ electrochemical test scanning vibrating electrode technique Stress corrosion cracking
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