Derived oil production by catalytic pyrolysis of scrap tires

Scrap tires were pyrolyzed in a continuously stirred batch reactor in the presence and absence of catalysts. The maximum yield of derived oil was up to 55.65 wt%at the optimum temperature, 500 °C. The catalytic pyrolysis was performed using 1.0 wt%（on a scrap tire weight basis） of catalysts based on ZSM‐5, USY,β, SAPO‐11, and ZSM‐22. The oil products were characterized using simula‐tion distillation, elemental analysis, and gas chromatography‐mass spectrometry. The results show that using a catalyst can increase the conversion of scrap tires to gas and decrease char by‐products;the yield of derived oil remains unchanged or a little lower. The oils derived from catalytic pyrolysis had H/C ratios of 1.55–1.65 and contained approximately 70–75 wt%light oil, 0.3–0.58 wt%S and 0.78–1.0 wt%N. Catalysts with high acid strengths and appropriate pore sizes, such as ZSM‐5, USY,β, and SAPO‐11, increased the amount of single‐ring aromatics in the light‐middle‐fraction oil to 45 wt%. The derived oil can therefore be used as a petrochemical feedstock for producing high‐value‐added chemical products or fuel oil.

Adsorption Characteristics of Activated Carbon Derived from Scrap Tires for Malachite Green:Influence of Small Organics

The influence of small organics on the adsorption characteristics of activated carbon produced from industrial pyrolytic tire char(APTC)for malachite green(MG) was investigated by a batch method. Phenol was chosen as the representative of small organics. The effects of phenol on adsorption equilibrium, kinetics and thermodynamics were studied systematically. The results indicate that APTC is a potential adsorbent for MG. The presence of phenol decreases the adsorption capacity of APTC for MG, but improves the rate of adsorption, while the adsorption characteristics, such as equilibrium, kinetics and thermodynamics are not affected by phenol. The adsorption equilibrium data follow Langmuir isotherm and the kinetic data are well described by the pseudo-second-order kinetic model. The adsorption process follows intra-particle diffusion model and the adsorption rate is determined by more than one process. Thermodynamic study shows that the adsorption is an endothermic and spontaneous physisorption process.

Use of Scrapped Rubber Tires for Sustainable Construction of Manhole Covers

Scrapped tires from vehicles are produced in large quantities. Despite numerous existing uses of scrapped tires, alarge quantity ends up at the landfill sites, which contributes to environmental degradation. The development ofmore applications of scrapped tire usage can reduce the disposal of tires at landfill sites. This research proposes anovel use of scrapped tires by using the strips taken from scrapped tires in replacement of steel bars as reinforcement. Manhole covers were produced using scrapped tires by completely replacing the steel with scrapped tires.Four different samples of manhole covers were prepared and tested. The highest bearing capacity of 25.5 kN wasrecorded with a sample of 100 mm thickness made with cementitious composite, which is 2.25 times higher thanthe bearing capacity of a conventional reinforced-concrete manhole cover. The use of manhole covers made withscrapped tires can effectively address the theft issue of manhole covers. The lifecycle cost analysis shows that themanhole cover made with scrapped tires is 3.4 times more cost-effective in comparison with the conventionalmanhole cover. This research shows a new avenue of the potential use of scrapped tires as reinforcement in structures, which can improve sustainable construction practices.

Effect of the Substitution of Sand by Rubber of Waste Tires on the Mechanical Properties of Hydraulic Concrete and Exposure to Gamma Radiation

For a long time and until now, rubber is the most used material for the manufacture of tires for motor vehicles. Unfortunately, once the tire meets its life cycle, the remaining rubber cannot be recycled, so the tires are discarded in collection centers and often in clandestine dumps. This represents a serious environmental problem because, in one case, these waste tires become breeding grounds for insects and wildlife that is harmful to humans. In the second case, the tires are burned, releasing highly damaging gases into the atmosphere. On the other hand, concrete is worldwide the construction material par excellence. It is basically composed of cement, gravel and sand. Mixing these three components in different proportions, their mechanical strength in compression can be increased. However, due to its fragile nature, concrete, once a crack is formed, it rapidly advances by fragmenting the material and producing its rapid collapse. In the present work, in order contribute to the care of the environment as well as to modify the fracture mode of the concrete, rubber particles obtained from waste tires were used as sand substitute in hydraulic concrete. In addition, rubber modified samples concrete were lately exposed to 70 kGy of gamma radiation in order to study the effects of this radiation on the mechanical deformation of concrete. The results showed a decrease in the mechanical properties of the concrete with rubber particles with respect to the traditional concrete itself. However, such decreases were offset by the fact that samples with rubber addition do not collapses as fast as the free rubber samples. The acquired data pave the way for research with great benefits, such as the use of recycled tires in concrete for its fracture mode modification in a beneficial way, as well as a possible decrease in the cost of concrete.

Laboratory large-scale pullout investigation of a new reinforcement ofcomposite geosynthetic strip

In this paper,more than 70 large-scale pullout tests were performed to evaluate the performance of an innovative composite geosynthetic strip(CGS)reinforcement in sandy backfill.The CGS reinforcement is composed of a geosynthetic strip(GS)and parts of a scrap truck tire as transverse members.The experimental pullout results for the CGS reinforcement were compared with the suggested theoretical equations and ordinary reinforcements,including the GS,the steel strip(SS),and the steel strip with rib(SSR).The pullout test results show that adding three transverse members to the GS reinforcement(CGS3)with S/H?6.6(where S and H are the space and height of the transverse members,respectively)increases pullout resistance by more than 120%,170%,and 50%compared to the GS,the SS,and the SSR,respectively.This result shows that the CGS3(CGS with three transverse members)reinforcement needs at least 55.5%,63%,and 33.3%smaller length compared to the GS,the SS,and the SSR,respectively.In general,implementation of mechanically stabilized earth wall(MSEW)with the proposed strip may help geotechnical engineers prevent costly designs and solve the problem of MSEW implementation in cases where there are limitations of space.

Seismic analysis of semi-gravity RC cantilever retaining wall with TDA backfill

The seismic behavior of Tire Derived Aggregate （TDA） used as backfill material of 6.10 m high retaining walls was investigated based on nonlinear time-history Finite Element Analysis （FEA）. The retaining walls were semi- gravity reinforced concrete cantilever type. In the backfill, a 2.74 m thick conventional soil layer was placed over a 3.06 m thick TDA layer. For comparison purpose, a conventional all soil-backfill model was also developed, and the analysis results from the two models under the Northridge and Takatori earthquakes were compared. The FEA results showed that both models did not experience major damage in the backfill under the Northridge earthquake. However, under the Takatori earthquake, the TDA-backfiU model developed substantially large displacement in the retaining walls and in the backfill compared with the soil-backfill model. Regions of large plastic strain were mainly formed in the TDA layer, and the soil over the TDA layer did not experience such large plastic strain, suggesting less damage than the soil-backfill model. In addition, the acceleration on the backfill surface of the TDA-backfill model decreased substantially compared with the soil-backfill model. If an acceleration sensitive structure is placed on the surface of the backfill, the TDA backfill may induce less damage to it.