Evolution and Application of Sealing Ability of Gypsum Caprocks under Temperature-Pressure Coupling:An Example of the ZS5 Well in the Tazhong Area of the Tarim Basin

Gypsum caprocks'sealing ability is affected by temperature-pressure coupling.Due to the limitations of experimental conditions,there is still a lack of triaxial stress-strain experiments that simultaneously consider changes in temperature and pressure conditions,which limits the accuracy of the comprehensive evaluation of the brittle plastic evolution and sealing ability of gypsum rocks using temperature pressure coupling.Triaxial stress-strain tests were utilized to investigate the differences in the evolution of the confinement capacity of gypsum rocks under coupled temperaturepressure action and isothermal-variable pressure action on the basis of sample feasibility analysis.According to research,the gypsum rock's peak and residual strengths decrease under simultaneous increases in temperature and pressure over isothermal pressurization experimental conditions,and it becomes more ductile.This reduces the amount of time it takes for the rock to transition from brittle to plastic.When temperature is taken into account,both the brittle–plastic transformation's depth limit and the lithological transformation of gypsum rocks become shallower,and the evolution of gypsum rocks under variable temperature and pressure conditions is more complicated than that under isothermal pressurization.The sealing ability under the temperature-pressure coupling is more in line with the actual geological context when the application results of the Well#ZS5 are compared.This provides a theoretical basis for precisely determining the process of hydrocarbon accumulation and explains why the early hydrocarbon were not well preserved.

Fracture sealing performance of granular lost circulation materials at elevated temperature:A theoretical and coupled CFD-DEM simulation study

Lost circulation is a common downhole problem of drilling in geothermal and high-temperature,high-pressure(HTHP)formations.Lost circulation material(LCM)is a regular preventive and remedial measure for lost circulation.However,conventional LCMs seem ineffective in high-temperature formations.This may be due to the changes in the mechanical properties of LCMs and their sealing performance under high-temperature conditions.To understand how high temperature affects the fracture sealing performance of LCMs,we developed a coupled computational fluid dynamics-discrete element method(CFD-DEM)model to simulate the behavior of granular LCMs in fractures.We summarized the literature on the effects of high temperature on the mechanical properties of LCMs and the rheological properties of drilling fluid.We conducted sensitivity analyses to investigate how changing LCM slurry properties affected the fracture sealing efficiency at increasing temperatures.The results show that high temperature reduces the size,strength,and friction coefficient of LCMs as well as the drilling fluid viscosity.Smaller,softer,and less frictional LCM particles have lower bridging probability and slower bridging initiation.Smaller particles tend to form dual-particle bridges rather than single-particle bridges.These result in a deeper,tighter,but unstable sealing zone.Reduced drilling fluid viscosity leads to faster and shallower sealing zones.

Preparation and property of seal coating for gas turbine compressor

Double-layer structure of seal coating which consisted of a Ni5Al bond coating and a Ni25 graphite top coating were prepared on steel substrate of gas turbine compressor cylinder block.Bond coating was prepared by atmospheric plasma spraying and top coating was prepared by flame spraying.The microstructure,mechanical properties and abradability of the coating were characterized by scanning elec-tron microscope(SEM),hardness tester,universal testing machine,thermal shock testing machine and abradability testing machine.The res-ults show that the overall spraying structure of the seal coating is uniform,the nickel metal phase is the skeleton supporting the entire coat-ing,and the coating is well bonded without separation.The seal coating has a bonding strength of not less than 7.7 MPa,excellent thermal stability,and thermal shock resistance cycle numbers at 500℃more than 50;the scratch length,deepest invasion depth and wear amount of the coating increase with rise of test temperature,with almost no coating adhesion,indicating that the seal coating has excellent abradability.

Application of Choquet Integral-Importance-Performance Analysis and TOPSIS Methods in Approaching the Preference Factors of Calligraphy and Seal Engraving Imagery

Classical Chinese characters,presented through calligraphy,seal engraving,or painting,can exhibit different aesthetics and essences of Chinese characters,making them the most important asset of the Chinese people.Calligraphy and seal engraving,as two closely related systems in traditional Chinese art,have developed through the ages.Due to changes in lifestyle and advancements in modern technology,their original functions of daily writing and verification have gradually diminished.Instead,they have increasingly played a significant role in commercial art.This study utilizes the Evaluation Grid Method(EGM)and the Analytic Hierarchy Process(AHP)to research the key preference factors in the application of calligraphy and seal engraving imagery.Different from the traditional 5-point equal interval semantic questionnaire,this study employs a non-equal interval semantic questionnaire with a golden ratio scale,distinguishing the importance ratio of adjacent semantic meanings and highlighting the weighted emphasis on visual aesthetics.Additionally,the study uses Importance-Performance Analysis(IPA)and Technique for Order Preference by Similarity to Ideal Solution(TOPSIS)to obtain the key preference sequence of calligraphy and seal engraving culture.Plus,the Choquet integral comprehensive evaluation is used as a reference for IPA comparison.It is hoped that this study can provide cultural imagery references and research methods,injecting further creativity into industrial design.

Study on Sealing Characteristics of Sliding Seal Assembly of Aircraft Hydraulic Actuator

The hydraulic actuator,known as the"muscle"of military aircraft,is responsible for flight attitude adjustment,trajectory control,braking turn,landing gear retracting and other actions,which directly affect its flight efficiency and safety.However,the sealing assembly often has the situation of over-aberrant aperture fit clearance or critical over-aberrant clearance,which increases the failure probability and degree of movable seal failure,and directly affects the flight efficiency and safety of military aircraft.In this paper,the simulation model of hydraulic actuator seal combination is established by ANSYS software,and the sealing principle is described.The change curve of contact width and contact pressure of combination seal under the action of high-pressure fluid is drawn.The effects of different oil pressure,fit clearance and other parameters on the sealing performance are analyzed.Finally,the accelerated life test of sliding seal components is carried out on the hydraulic actuator accelerated life test rig,and the surface morphology is compared and analyzed.The research shows that the O-ring is the main sealing element and the role of the check ring is to protect and support the O-ring to prevent damage caused by squeezing into the fit clearance,so the check ring bears a large load and is prone to shear failure.Excessive fit clearance is the main factor affecting the damage of the check ring,and the damage parts are mainly concentrated at the edge of the sealing surface.This paper provides a theoretical basis for the design of hydraulic actuator and the improvement of sealing performance.

Air tightness of compressed air storage energy caverns with polymer sealing layer subjected to various air pressures

During the operation of compressed air storage energy system,the rapid change of air pressure in a cavern will cause drastic changes in air density and permeability coefficient of sealing layer.To calculate and properly evaluate air tightness of polymer sealing caverns,the air-pressure-related air density and permeability must be considered.In this context,the high-pressure air penetration in the polymer sealing layer is studied in consideration of thermodynamic change of the cavern structure during the system operation.The air tightness model of compressed air storage energy caverns is then established.In the model,the permeability coefficient and air density of sealing layer vary with air pressure,and the effectiveness of the model is verified by field data in two test caverns.Finally,a compressed air storage energy cavern is taken as an example to understand the air tightness.The air leakage rate in the caverns is larger than that using air-pressure-independent permeability coefficient and air density,which is constant and small in the previous leakage rate calculation.Under the operating pressure of 4.5-10 MPa,the daily air leakage in the compressed air storage energy cavern of Yungang Mine with high polymer butyl rubber as the sealing material is 0.62%,which can meet the sealing requirements of compressed air storage energy caverns.The air tightness of the polymer sealing cavern is mainly affected by the cavern operating pressure,injected air temperature,cavern radius,and sealing layer thickness.The cavern air leakage rate will be decreased to reduce the cavern operating pressure the injection air temperature,or the cavern radius and sealing layer thickness will be increased.

Study on the effect of thermal deformation on the liquid seal of high-temperature molten salt pump in molten salt reactor

The high-temperature molten salt pump is the core equipment in a molten salt reactor that drives the flow of the molten salt coolant.Rotor stability is key to the continuous and reliable operation of the molten salt pump,and the liquid seal at the wear ring can affect the dynamic characteristics of the rotor system.When the molten salt pump is operated in the hightemperature molten salt medium,thermal deformation of the submerged parts inevitably occurs,changing clearance between the stator and rotor,affecting the leakage and dynamic characteristics of the seal.In this study,the seal leakage,seal dynamic characteristics,and rotor system dynamic characteristics are simulated and analyzed using finite element simulation software based on two cases of considering the effect of seal thermal deformation effect or not.The results show a significant difference in the leakage characteristics and dynamic characteristics of the seal obtained by considering the effect of seal thermal deformation and neglecting the effect of thermal deformation.The leakage flow rate decreases,and the first-order critical speed of the seal-bearing-rotor system decrease after considering the seal’s thermal deformation.

MRI insight on multiphase flow in hydrate-bearing sediment and development mechanism of hydrate seal

Gas and water migration through the hydrate-bearing sediment are characteristic features in marine gas hydrate reservoirs worldwide.However,there are few experimental investigations on the effect of water-gas flow on the gas hydrate reservoir.In this study,gas-water migration in gas hydrate stability zone(GHSZ)was investigated visually employing a high-resolution magnetic resonance imaging(MRI)apparatus,and the formation of hydrate seal was experimentally investigated.Results revealed that normal flow of gas-water at the low flow rate of 1–0.25 mL/min will induce the hydrate reformation.Conversely,higher gas-water flow rates(at 2–0.5 and 4–1 mL/min)need higher reservoir pressure to induce the hydrate reformation.In addition,the hydrate reformation during the gas-water flow process produced the hydrate seal,which can withstand an over 9.0 MPa overpressure.This high overpressure provides the development condition for the underlying gas and/or water reservoir.A composite MRI image of the whole hydrate seal was obtained through the MRI.The pore difference between hydrate zone and coexistence zone produces a capillary sealing effect for hydrate seal.The hydrate saturation of hydrate seal was more than 51.6%,and the water saturation was more than 19.3%.However,the hydrate seal can be broken through when the overpressure exceeded the capillary pressure of the hydrate seal,which induced the sudden drop of reservoir pressure.This study provides a scientific explanation for the existence of high-pressure underlying gas below the hydrate layer and is significant for the safe exploitation of these common typical marine hydrate reservoirs.

On the installation of an in situ large-scale vertical SEALing (VSEAL) experiment on bentonite pellet-powder mixture

Recently,the Institute for Radiological protection and Nuclear Safety(IRSN)has launched VSEAL(Vertical SEALing)project to investigate the impact of gas migration on the long-term performance of bentonite based vertical sealing systems(VSS).The first VSEAL in situ test was emplaced in IRSN’s Underground Research Laboratory(URL)in Tournemire(France)in 2019 and was equipped with 76 wired and wireless sensors.The test is still in progress,but the collected set of data provides already valuable information of the hydro-mechanical behavior of VSS during hydration.The swelling core consists of a mixture of highdensity pellets and powder of MX80 bentonite in a ratio of 80/20(in dry mass).An innovative method was adopted to drill a 1-m diameter and w10-m deep shaft in order to minimize the rock perturbation at the sidewalls.Because a specific protocol was adopted to install the bentonite mixture together with a careful characterization of the core during construction,VSEAL 1 constitutes the unique in situ sealing test with a well-known initial structural distribution of the pellets and the powder.Some heterogeneities occurred within the experiment during the installation process:a damaged zone developed around the shaft walls due to the interruption of the installation operations caused by COVID19 lockdown in France;a technological gap with a variable thickness between the last pellets layer and the top confining lid and a heterogeneous distribution of the bentonite powder at some layers inducing large inter pellets voids close to the bentonite-rock interface.Artificially injected water volume,relative humidity,water content and swelling pressure in both radial and axial directions were monitored.Comparison of the results showed that the presence of installation-induced heterogeneities led to the generation of preferential flow paths that influenced the swelling pressure evolution at radial and axial directions.

Propagation and sealing efficiency of chemical grouting in a two-dimensional fracture network with flowing water

In this study, an orthogonal array experiment is conducted by using a transparent fracture network replica. Image processing and theoretical analysis are performed to investigate the model sealing efficiency(SE), factors influencing SE, and the effect of flowing water on propagation. The results show that grout propagation can be classified into three patterns in the fracture network: sealing off, partial sealing,and major erosion. The factors controlling the SE in a descending order of the amount of influence are the initial water flow speed, fracture aperture, grout take, and gel time. An optimal value for the combination of the gel time and grout take(artificial factors) can result in a good SE. The grouting and seepage pressures are measured, and the results reveal that their variations can indicate the SE to some extent. The SE is good when the seepage pressure at each point increases overall;the frequent fluctuations in the seepage pressure indicate a moderately poor SE, and an overall decline in the seepage pressure indicates a major erosion type. The deflection effect of grouting shows an approximately elliptical propagation with the long axis expanding along the wider fracture opening, demonstrating further application in grouting design.

Preparation and property of self-sealed plasma electrolytic oxide coating on magnesium alloy

Plasma electrochemical oxidation (PEO) is a surface modification technology to form ceramic coatings on magnesium alloys However,its application is limited due to its defects.This work reports a novel preparation of in-situ sealing of PEO coatings by four-layer voltage and sol addition.The morphology and structure were characterized by scanning electron microscopy (SEM),energy dispersive X-ray spectroscopy (EDS),and X-ray diffractometer (XRD).Image-Pro Plus 6.0 was used to determine the porosity of the coating,which was decreased from 8.53%to 0.51%.Simultaneously,the coating thickness was increased by a factor of four.The anti-corrosion performance of each sample was evaluated using electrochemical tests,and the findings revealed that the corrosion current density of coatings (i_(corr)) of the samples were lowered from 9.152×10^(-2) to 6.152×10^(-4) mA·cm^(-2),and the total resistance (R_(T)) of the samples were enhanced from 2.19×10^(4) to 2.33×10^(5)Ω·cm^(2).The salt spray test used to simulate the actual environment showed that corrosion points appeared on the surface of the coating only at the 336 h.In addition,the mechanism of PEO self-sealing behavior was described in this article.

Geopolymer-based modification of blasting sealing materials and optimization of blasting block size in coal seams of open pit mines

This research proposes the utilization of a geopolymer-based blasting sealing material to improve the profitability of coal sales and reduce the rate of coal fragmentation during blasting in open pit mines.The study first focused on optimizing the strength of the sealant material and reducing curing time.This was achieved by regulating the slag doping and sodium silicate solution modulus.The findings demonstrated that increasing slag content and improving the material resulted in an early rise in strength while increasing the modulus of the sodium silicate solution extended the curing time.The slag doping level was fixed at 80 g,and the sodium silicate solution modulus was set at 1.5.To achieve a strength of 3.12 MPa,the water/gel ratio was set at 0.5.The initial setting time was determined to be 33 min,meeting the required field test duration.Secondly,the strength requirements for field implementation were assessed by simulating the action time and force destruction process of the sealing material during blasting using ANSYS/LS-DYNA software.The results indicated that the modified material meets these requirements.Finally,the Shengli Open Pit Coal Mine served as the site for the field test.It was observed that the hole-sealing material’s hydration reaction created a laminated and flocculated gel inside it.This enhanced the density of the modified material.Additionally,the pregelatinized starch,functioning as an organic binder,filled the gaps between the gels,enhancing the cohesion and bonding coefficient of the material.Upon analyzing the post-blasting shooting effect diagram using the Split-Desktop software,it was determined that the utilization of the modified blast hole plugging material resulted in a decrease in the rate of coal fragmentation from 33.2%to 21.1%.This reduction exhibited a minimal error of 1.63%when compared to the field measurement,thereby providing further confirmation of the exceptional plugging capabilities of the modified material.This study significantly contributes to establishing a solid theoretical basis for enhancing the blasting efficiency of open pit mines and,in turn,enhancing their economic advantages.

甘蔗制造! 德国SEALABLE公司研发环保型隧道管片密封垫

目前,大部分的管片密封垫采用三元乙丙橡胶制成。这种材料耐臭氧、耐热、耐老化,性能优异,是常见的建筑防水材料。三元乙丙橡胶主要使用乙烯和丙烯生产,这些原材料传统上都是从原油中提取的。最近,德国的隧道管片密封垫制造商SEALABLE开始尝试从甘蔗中提取生物基乙烯,以此作为原材料来生产隧道管片密封垫。据称,这种使用甘蔗生产的管片密封垫的材料特性和传统管片密封垫没有不同,不会对性能产生负面影响。

Experimental Investigation on the Effect of Seal Presence on the Behavior of Double-Deck Floating Roofs in Cylindrical Steel Storage Tanks

Liquid storage,particularly oil and petrochemical products which are considered hazardous liquid,are an important part of the oil industry.Thin-walled vertical cylindrical steel storage tanks are widely used in recent years.Due to high sensitivity of these structures in an earthquake and other external excitations may lead to catastrophic consequences.For instance,huge economic losses,environmental damages,and casualities,many studies have been done about these structures.past studies showed that liquid storage tanks,equipped with a floating roof,are potentially vulnerable while subjected to seismic loads and earthquake has been considered as one of the most destructive natural hazards.The reason is that such tanks are made of two separated parts(shell and roof)which each may have its own responses;sometimes causing resonance phenomenon and so that,roof movements,rooffluid interaction,roof-shell interaction,and also the way they are attached should still be investigated.Experimental tests of floating roof’s vertical fluctuation was performed in a full-scale reservoir tank and assessing of the results demonstrated that presence of a seal between floating roof and shell plate can significantly increase damping ratio in liquid sloshing and also suppress the roof`s vertical displacements.In other words,seal can control a floating roof and make it stop moving vertically over few cycles.

A multiphysical-geochemical coupling model for caprock sealing efficiency in CO_(2) geosequestration

Precipitation or dissolution due to geochemical reactions has been observed in the caprocks for CO_(2) geosequestration.Geochemical reactions modify the caprock sealing efficiency with self-limiting or self-enhancement.However,the effect of this modification on the caprock sealing efficiency has not been fully investigated through multiphysical-geochemical coupling analysis.In this study,a multiphysical-geochemical coupling model was proposed to analyze caprock sealing efficiency.This coupling model considered the full couplings of caprock deformation,two-phase flow,CO_(2) concentration diffusion,geochemical reaction,and CO_(2) sorption.The two-phase flow only occurs in the fracture network and the CO_(2) may partially dissolve into water and diffuse through the concentration difference.The dissolved CO_(2) has geochemical reactions with some critical minerals,thus altering flow channels.The CO_(2) in the fracture network diffuses into matrix,causing the matrix swelling.This fully coupling model was validated with a penetration experiment on a cement cube and compared with two other models for CO_(2) storage plumes.Finally,the effects of geochemical reactions on penetration depth and pore pressure were studied through parametric study.The numerical simulations reveal that the coupling of geochemical reactions and matrix diffusion significantly affect the caprock sealing efficiency.Geochemical reactions occur at a short time after the arrival of CO_(2) concentration and modify the fracture porosity.The CO_(2) diffusion into the matrix requires a much longer time and mainly induces matrix swelling.These effects may produce selfenhancement or self-limiting depending on the flow rate in the fracture network,thus significantly modifying caprock sealing efficiency.

Seal&Protect^(TM)对牙本质作用的扫描电镜研究

目的 通过扫描电镜观察Seal&ProtectTM封闭人离体牙牙本质小管的效果 ,探讨作用机理。方法 选择新鲜的离体牙进行脱敏治疗 ,立即制备标本 ,进行扫描电镜观察其牙本质横纵断面的结构变化。结果 对照组牙本质表面凹凸不平 ,呈弹坑状 ,牙本质小管口完全暴露 ;实验组牙本质表面呈均匀一致状 ,大部分牙本质小管被封闭 ,极少数小管外露。结论 Seal&ProtectTM能有效地封闭牙本质小管 ,达到治疗牙本质过敏症的目的。

Seal演算与Boxed Ambient演算的关系分析

研究不同演算系统之间的逻辑结构和描述能力具有重要的理论意义。本文在系统分析Seal演算与BoxedAmbient演算的语法结构和语义规约系统的基础上给出了一些等价关系:通信等价、通信原语等价和代码移动等价。最后给出了Seal演算通信进程到BoxedAmbient演算通信进程的一种结构化转换方法。

A STUDY ON THE SEALING PERFORMANCE BETWEEN CYLINDER HEAD AND CYLINDER SLEEVE IN DIESEL ENGINES

针对12V型整体式气缸盖柴油机的气缸盖/气缸套密封系统，采用有限元法，研究了固紧螺栓预紧力大小及分配、固紧螺栓位置、气缸盖材料等因素对密封系统性能的影响规律。对确定的气缸爆发压力，计算出了理论上能保证密封的最小预紧力。得出的结论有益于对整体式气缸盖柴油机的改进设计。文中计算采用了SDRC公司的I-DEASTM软件。

Seal演算的偶图语义

偶图反应系统是一种新的理论工具,其基础是一种强调位置和连接的移动计算图形化模型——偶图,偶图范化了π演算和移动Ambient演算的特征,能够表示具有位置和移动性质的复杂系统.偶图反应系统为普适计算不同层次的设计和实现提供了统一的建模框架.Seal演算是一种用于描述移动计算的进程语言,具有良好的安全性质.文中给出了一种不带复制进程表达式的Seal演算的偶图表示,分析了该Seal演算与其偶图表示间的结构对应和操作对应.本研究扩展了偶图理论的应用范围,展示了偶图理论在描述安全演算方面的能力,为在偶图反应系统框架下研究Seal演算的性质和应用奠定了基础.

Seal演算的等式特性

为完善Seal演算的自身性质及形式化证明移动代码的安全性,从上下文等价性角度研究了Seal演算的等式特性及其应用。首先定义了Seal演算的可观察性和上下文等价性,然后通过两个判断上下文等价性的定理给出了Seal演算上下文等价性的判定方法,最后依据上下文等价性证明了Seal演算的防火墙等式。结果表明,Seal演算上下文等价性可以正确地描述Seal演算的等式特性,并可判定Seal演算的安全特性。