Preparation and property of self-sealed plasma electrolytic oxide coating on magnesium alloy

Plasma electrochemical oxidation (PEO) is a surface modification technology to form ceramic coatings on magnesium alloys However,its application is limited due to its defects.This work reports a novel preparation of in-situ sealing of PEO coatings by four-layer voltage and sol addition.The morphology and structure were characterized by scanning electron microscopy (SEM),energy dispersive X-ray spectroscopy (EDS),and X-ray diffractometer (XRD).Image-Pro Plus 6.0 was used to determine the porosity of the coating,which was decreased from 8.53%to 0.51%.Simultaneously,the coating thickness was increased by a factor of four.The anti-corrosion performance of each sample was evaluated using electrochemical tests,and the findings revealed that the corrosion current density of coatings (i_(corr)) of the samples were lowered from 9.152×10^(-2) to 6.152×10^(-4) mA·cm^(-2),and the total resistance (R_(T)) of the samples were enhanced from 2.19×10^(4) to 2.33×10^(5)Ω·cm^(2).The salt spray test used to simulate the actual environment showed that corrosion points appeared on the surface of the coating only at the 336 h.In addition,the mechanism of PEO self-sealing behavior was described in this article.

Experimental Verification and Research for the Distortion in the Integrated Frequency Responses of the High-Pressure Sealed Cabin and Magnetic Field Sensor

Although magnetotelluric sounding method applied to the land is advanced, there are many difficulties when it is applied to marine environment, one of which is how to lay magnetic field sensors down to the seafloor to complete measurements. To protect the magnetic field sensors from intense erosion and high pressure, suitable high-pressure sealed cabins must be designed to load them. For the consideration of magnetic measurement and marine operation, the sealed pressure cabin should be nonmagnetic and transportable. Among all optional materials, LC4 super.hard aluminum alloy has the highest performance of price/quality ratio to make the sealed pressure cabin. However, it does not mean that the high-pressure sealed cabin made using LC4 will be perfect in performance. In fact, because of its weak magnetism, the pressure cabin made using LC4 has distorting effect on frequency responses of the magnetic field sensors sealed in it. This distorting effect does not affect the use of the magnetic field sensor, but if we want to eliminate its effect, we should study it by experimental measurements. In our experiment tests, frequency sweep magnetic field as excitation signal was used, and then responses of the magnetic field sensor before and after being loaded into the high-pressure sealed cabin were measured. Finally, normalized abnormal curves for the frequency responses were obtained, through which we could show how the high-pressure sealed cabin produces effects on the responses of the magnetic field sensor. Experimental results suggest that the response distortion induced by the sealed pressure cabin appears on mid- and high-frequency areas. Using experimental results as standardization data, the frequency responses collected from seafloor magnetotelluric measurements can be corrected to restore real information about the seafloor field source.

EIS Characterization of Sealed Anodic Oxide Films on Titanium Alloy Ti-10V-2Fe-3Al

Anodic oxide films grown on titanium alloy Ti-10V-2Fe-3Al in the solution of sodium tartrate, then sealed in boiling deionised water and calcium acetate solution were observed by using field emission scanning electron microscopy （FE-SEM）, and were chemically analysed by using energy dispersive spectroscopy （EDS）. Corrosion behaviour was investigated in a 3.5% sodium chloride solution, using electrochemical impedance spectroscopy （EIS）. The morphology of the anodic oxide films was dependent on the sealing processes. The surface sealed in calcium acetate solution presented a more homogeneous and smooth structure compared with that sealed in boiling deionised water. The corrosion resistance of the oxide films sealed in calcium acetate solution was better than that sealed in boiling deionised water.

A pressure-calibration method of wavelength modulation spectroscopy in sealed microbial growth environment

A new pressure-calibration method for calibrating the reduction of second harmonic(2f)amplitude caused by pressure broadening effect in sealed microbial growth environment is present.The new method combines with linewidth compensation and modulation depth compensation and makes the 2f amplitude accurately retrieve metabolic CO_(2) in microbial growth.In order to verify the method,a simulation experiment is developed,in which the increasing CO_(2) concentration leads to the increasing pressure.Comparing with the relation between the traditional 2f amplitude and gas concentration,there is a monotonous relation between the calibrated 2f amplitude and CO_(2) concentration,particularly,a linear relation is present when the CO_(2) concentration is replaced with the CO_(2) particle number.In terms of microbial measurement,the growth of Escherichia coli is measured,and the culture bottle is sealed during the microbial growth process.The experimental results show that,comparing to the microbial growth retrieved by traditional 2f amplitude,the calibrated 2f amplitude can accurately retrieve microbial growth in sealed environment.

Influence of the Gas Mixture Ratio on the Correlations Between the Excimer XeCl Emission and the Sealed Gas Temperature in Dielectric Barrier Discharge Lamps

For dielectric barrier discharge lamps filled with various gas mixture ratios, the correlations between the excimer XeCl* emission and the sealed gas temperature have been founded, and a qualitative explication is presented. For gas mixture with chlorine larger than 3%, the emission intensity increases with the sealed gas temperature, while with chlorine about 2%, the emission intensity decreases with the increase in the gas temperature, and could be improved by cooling water. However, if chlorine is less than 1.5%, the discharge appears to be a mixture mode with filaments distributed in a diffused glow-like discharge, and the UV emission is independent on the gas temperature.

Metal Sealing Performance of Subsea X-tree Wellhead Connector Sealer

The metal sealing performance of subsea X-tree wellhead connectors is crucial for the safety and reliability of subsea X-trees. In order to establish the theoretical relation between metal sealing ring＇s contact stress and its structural parameters and working pressure, a mechanical analysis method for double-cone sealing of high pressure vessels is applied in analyzing the metal sealing ring under the condition of preload and operation. As a result, the formula of the unit sealing load for the metal sealing ring under operation with residual preload is shown in this paper, which ensures that the metal sealing ring has an excellent sealing effect and can prevent the metal sealing ring from yielding. Besides, while analyzing the sealing process of the metal sealing ring, the change rule of contact stress and working pressure is concluded here, putting forward that the structural parameters of the metal sealing ring are the major factors affecting the change rule. Finally, the analytical solution through theoretical analysis is compared with the simulation result through finite element analysis in a force feedback experiment, and both are consistent with each other, which fully verifies for the design and calculation theory on metal sealing ring＇s contact stress and its structural parameters and working pressure deduced in this paper. The proposed research will be treated as an applicable theory guiding the design of metal seal for subsea X-tree wellhead connectors.

Protection Performance of Plasma Sprayed Al_(2)O_(3)-13 wt%TiO_(2) Coating Sealed with an Organic-inorganic Hybrid Agent

An organic-inorganic hybrid sealing agent was fabricated and used in the plasma sprayed Al_(2)O_(3)-13 wt%TiO_(2)coating,and conventional silicone agent was also used for comparison.Protection performance of the coatings was comprehensively evaluated based on both anti-corrosion and anti-biofouling properties.The results reveal that the sealing treatment is remarkably useful to decrease the porosity of the coating,and the porosity of the coating sealed with the hybrid agent is only 0.035%.Immersion corrosion test and Tafel polarization test reveal that the sealed coating with the hybrid agent exhibits a better corrosion resistance by compared with the coating sealed with silicone agent.The corrosion current density i_(corr) of the hybrid agent sealed coating is only 0.7×10^(-6)A·cm^(-2).Moreover,anti-biofouling tests both in the outdoor analogue hydraulic environment and in the natural marine environment prove that the mentioned novel coating presents a better combination of corrosion resistance and anti-biofouling property by compared with the other coatings,and it could be used as a protection of metal components in the marine environment.

Direct measurement of oxygen consumption rates from attached and unattached cells in a reversibly sealed, diffusionally isolated sample chamber

Oxygen consumption is a fundamental component of metabolic networks, mitochondrial function, and global carbon cycling. To date there is no method available that allows for replicate measurements on attached and unattached biological samples without compensation for extraneous oxygen leaking into the system. Here we present the Respiratory Detection System, which is compatible with virtually any biological sample. The RDS can be used to measure oxygen uptake in microliter-scale volumes with a reversibly sealed sample chamber, which contains a porphyrin-based oxygen sensor. With the RDS, one can maintain a diffusional seal for up to three hours, allowing for the direct measurement of respiratory function of samples with fast or slow metabolic rates. The ability to easily measure oxygen uptake in small volumes with small populations or dilute samples has implications in cell biology, environmental biology, and clinical diagnostics.

Contact Pressure between the Outside Surface of the Sealer and Cylinder Wall

Character of contract pressure distribution between the outside surface of the sealing material and rigid cylinder wall depending on geometrical sizes and mechanical properties of a sealer under its unilateral compression, is defined. The magnitude of the axial load for achieving tightness is determined. The dependence between the magnitude of the axial load necessary for achieving tightness and geometrical sizes is determined. It is shown that with a decrease in the height of the sealing element, the axial load necessary for achieving tightness greatly increases. Threshold height of the sealer, above which contact pressure depends little on the magnitude of the axial load, is defined. The stress-strain state of the sealing element is defined with regard to viscous-elastic properties of its material. It is shown that this greatly influences its sealing ability.

Molecular Orientation Effect of Heat-Sealed PP Film on Peel Strength and Structure

Heat sealing properties are optimized by controlling temperature, pressure and dwell time, while film strength depends on the drawn ratio and the molecular orientation of the film. However, heat seal strength of polymer films with high drawn ratio shows lower peel strength, because the adhesion of films needs a higher heat sealing energy for molecular orientation relaxation at heat sealing. In the present study, polypropylene films with a drawn ratio of 1.0×, 1.5×, and 2.5× are heat sealed by using the heat sealing technique. The heat sealing condition is set to heat sealing time 1.0 s, sealing pressure 0.2 MPa, and heat sealing temperature 145°C. The effect of drawn ratio and stabilization temperature of PP films for peel strength are investigated using T-Peel test, DSC, FT-IR, and Raman spectroscopy. As a result, it is found that the peel strength is decreased with increasing the drawn ratio and stabilization temperature of PP films. The difference of ?H and melting point from the result of DSC measurement are exhibited for 1.5× drawn ratio film as compared with 2.5× one. In addition, FT-IR imaging and Raman line mapping reveal the influence and variation of high order structure for heat sealed parts of the drawn PP films.

瑞典能源局为建设SEALER原型堆提供资助

【世界核新闻网站2022年2月15日报道】瑞典能源局近日决定向瑞典模块化反应堆公司(Swedish Modular Reactors)提供9900万瑞典克朗(约1060万美元)资金,支持在奥斯卡港核电厂(拥有3座沸水堆,其中2座已永久关闭)建设铅冷模块化小堆SEALER的电热非核原型堆。该原型堆拟于2024年投运,将运行5年时间,用于在高温熔融铅的环境中测试并验证相关材料和技术。

STUDY ON PERFORMANCE OF COMPOSITE JOURNAL BEARING SEALED AND LUBRICATED WITH FERROFLUID

The theoretical computation model of the composite journal bearing sealed and lubricated with ferrofluid is established The oil film pressure distribution,temperature field and heat conduction equation of the bearing liner are jointly calculated The static and dynamic properties of the bearing under condition of different eccentricities and ratios of width to diameter are obtained and discussed The results show the feasibility of this type of bearing for smaller eccentricities and width to diameter ratios,and that the oil film temperature,which is more subject to be influenced by the rotating speed,is higher than that of the bearing with leakage flow The key problem of the further development and application of the bearing is to design more reasonable and effective types of seal structures

Effect of Fluid-Structure Interaction on Sealed Flow Field and Leakage Rate Based on Computational Fluid Dynamics

This paper addresses the issue of reciprocating compressors staggered labyrinth seal structure. The internal flow field of sealed structure, the displacement of cylinder and piston for different tooth profile angles are analyzed synchronously using FLUENT software, and the effects of fluid-structure interaction on the performance of the labyrinth seal are revealed. The results indicate that with the growth of tooth profile angle, the leakage rate of labyrinth seal tends to decrease first, and then increase. The results of fluid-structure interaction analysis are close to those of actual engineering. The effect of fluid-structure interaction makes tiny deformation in calculation mesh of piston and cylinder structure, and the coupling interaction affects the performance of the labyrinth seal.

Magnetic fluid based squeeze film between porous circular disks with sealed boundary

Efforts have been made to study the effect of the magnetic fluid lubricant and the seal-ing of the boundary for the squeeze film between two circular disks when the upper disk having aporous facing with its boundary sealed, approaches the non-porous lower disk normally. The modi-fied Reynolds equations for the fluid region and the governing Laplacian equation for the pressurein porous region are solved with appropriate boundary conditions. Expressions are obtained forpressure, load carrying capacity and the response time. The results are presented graphically. Thecombined effect of the magnetic fluid lubricant and sealing of the boundary increases the load car-rying capacity significantly and hence the performance of the bearing can be enhanced considera-bly by sealing the boundary and taking a magnetic fluid as lubricant.

Evolution and Application of Sealing Ability of Gypsum Caprocks under Temperature-Pressure Coupling:An Example of the ZS5 Well in the Tazhong Area of the Tarim Basin

Gypsum caprocks'sealing ability is affected by temperature-pressure coupling.Due to the limitations of experimental conditions,there is still a lack of triaxial stress-strain experiments that simultaneously consider changes in temperature and pressure conditions,which limits the accuracy of the comprehensive evaluation of the brittle plastic evolution and sealing ability of gypsum rocks using temperature pressure coupling.Triaxial stress-strain tests were utilized to investigate the differences in the evolution of the confinement capacity of gypsum rocks under coupled temperaturepressure action and isothermal-variable pressure action on the basis of sample feasibility analysis.According to research,the gypsum rock's peak and residual strengths decrease under simultaneous increases in temperature and pressure over isothermal pressurization experimental conditions,and it becomes more ductile.This reduces the amount of time it takes for the rock to transition from brittle to plastic.When temperature is taken into account,both the brittle–plastic transformation's depth limit and the lithological transformation of gypsum rocks become shallower,and the evolution of gypsum rocks under variable temperature and pressure conditions is more complicated than that under isothermal pressurization.The sealing ability under the temperature-pressure coupling is more in line with the actual geological context when the application results of the Well#ZS5 are compared.This provides a theoretical basis for precisely determining the process of hydrocarbon accumulation and explains why the early hydrocarbon were not well preserved.

Innovative approach to boosting the chemical stability of AZ31 magnesium alloy using polymer-modified hybrid metal oxides

Meeting the demands of complex and advanced applications requires the development of high-performance hybrid materials with unique properties.However,the integration of polymeric frameworks with MgO/WO_(3) composite layers faces challenges due to the lack of understanding of the formation mechanism and the challenge of determining the impact of self-assembled architecture on anticorrosive properties.In this study,we aimed to enhance the corrosion resistance of the MgO layer produced by plasma electrolysis(PE)of AZ31 Mg alloy by incorporating WO_(3) with partially phosphorated poly(vinyl alcohol)(PPVA).Two types of porous MgO layers were produced using the PE process with an alkaline-phosphate electrolyte,one with and one without WO_(3) nanoparticles,which were subsequently immersed in an aqueous solution of PPVA.Incorporating PPVA into the WO_(3)-MgO layer resulted in hybrids being deposited in a fragmented manner,creating a“laminar reef-like structure”that sealed most of the structural defects in the layer.The PPVA-sealed WO_(3)-based coating exhibited superior corrosion resistance compared to the other samples.Computational analyses were employed to explore the mechanism underlying the formation of PPVA/WO_(3) hybrids on the MgO layer.These findings suggest that PPVA-WO_(3)-MgO hybrid coatings can potentially improve corrosion resistance in various fields.

Rice Variety Classification Based on Optimized Near-Infrared Spectral Classification Model

Accurate classification of rice variety is essential to ensure the brand value of high-quality rice products.Considering the impact of sample state on modeling optimization algorithms,rice samples after grinding and sealing were selected.To enhance the accuracy of rice variety classification,we introduced a spectral characteristic wavelength selection method based on adaptive sliding window permutation entropy(ASW-PE).

Fracture sealing performance of granular lost circulation materials at elevated temperature:A theoretical and coupled CFD-DEM simulation study

Lost circulation is a common downhole problem of drilling in geothermal and high-temperature,high-pressure(HTHP)formations.Lost circulation material(LCM)is a regular preventive and remedial measure for lost circulation.However,conventional LCMs seem ineffective in high-temperature formations.This may be due to the changes in the mechanical properties of LCMs and their sealing performance under high-temperature conditions.To understand how high temperature affects the fracture sealing performance of LCMs,we developed a coupled computational fluid dynamics-discrete element method(CFD-DEM)model to simulate the behavior of granular LCMs in fractures.We summarized the literature on the effects of high temperature on the mechanical properties of LCMs and the rheological properties of drilling fluid.We conducted sensitivity analyses to investigate how changing LCM slurry properties affected the fracture sealing efficiency at increasing temperatures.The results show that high temperature reduces the size,strength,and friction coefficient of LCMs as well as the drilling fluid viscosity.Smaller,softer,and less frictional LCM particles have lower bridging probability and slower bridging initiation.Smaller particles tend to form dual-particle bridges rather than single-particle bridges.These result in a deeper,tighter,but unstable sealing zone.Reduced drilling fluid viscosity leads to faster and shallower sealing zones.

The Application of Bilayer Artificial Dermis Combined with VSD Technology in Chronic Wounds

Background: Bilayer artificial dermis promotes wound healing and offers a treatment option for chronic wounds. Aim: Examine the clinical efficacy of bilayer artificial dermis combined with Vacuum Sealing Drainage (VSD) technology in the treatment of chronic wounds. Method: From June 2021 to December 2023, our hospital treated 24 patients with chronic skin tissue wounds on their limbs using a novel tissue engineering product, the bilayer artificial dermis, in combination with VSD technology to repair the wounds. The bilayer artificial dermis protects subcutaneous tissue, blood vessels, nerves, muscles, and tendons, and also promotes the growth of granulation tissue and blood vessels to aid in wound healing when used in conjunction with VSD technology for wound dressing changes in chronic wounds. Results: In this study, 24 cases of chronic wounds with exposed bone or tendon larger than 1.0 cm2 were treated with a bilayer artificial skin combined with VSD dressing after wound debridement. The wounds were not suitable for immediate skin grafting. At 2 - 3 weeks post-treatment, good granulation tissue growth was observed. Subsequent procedures included thick skin grafting or wound dressing changes until complete wound healing. Patients were followed up on average for 3 months (range: 1 - 12 months) post-surgery. Comparative analysis of the appearance, function, skin color, elasticity, and sensation of the healed chronic wounds revealed superior outcomes compared to traditional skin fl repairs, resulting in significantly higher satisfaction levels among patients and their families. Conclusion: The application of bilayer artificial dermis combined with VSD technology for the repair of chronic wounds proves to be a viable method, yielding satisfactory therapeutic effects compared to traditional skin flap procedures.

Wafer-level hermetically sealed silicon photonic MEMS

The emerging fields of silicon(Si) photonic micro–electromechanical systems(MEMS) and optomechanics enable a wide range of novel high-performance photonic devices with ultra-low power consumption, such as integrated optical MEMS phase shifters, tunable couplers, switches, and optomechanical resonators. In contrast to conventional SiO;-clad Si photonics, photonic MEMS and optomechanics have suspended and movable parts that need to be protected from environmental influence and contamination during operation. Wafer-level hermetic sealing can be a cost-efficient solution, but Si photonic MEMS that are hermetically sealed inside cavities with optical and electrical feedthroughs have not been demonstrated to date, to our knowledge. Here, we demonstrate wafer-level vacuum sealing of Si photonic MEMS inside cavities with ultra-thin caps featuring optical and electrical feedthroughs that connect the photonic MEMS on the inside to optical grating couplers and electrical bond pads on the outside. We used Si photonic MEMS devices built on foundry wafers from the iSiPP50G Si photonics platform of IMEC, Belgium. Vacuum confinement inside the sealed cavities was confirmed by an observed increase of the cutoff frequency of the electro-mechanical response of the encapsulated photonic MEMS phase shifters, due to reduction of air damping. The sealing caps are extremely thin, have a small footprint, and are compatible with subsequent flip-chip bonding onto interposers or printed circuit boards. Thus, our approach for sealing of integrated Si photonic MEMS clears a significant hurdle for their application in high-performance Si photonic circuits.