Rare earth elemental and Sr isotopic evidence for seawater intrusion event of the Songliao Basin 91 million years ago

Petrogenesis of lacustrine dolostone is closely related with paleo-lake water conditions.Here we report the high spatial-resolution petrographic and geochemical results of a lacustrine dolomite nodule from the Qingshankou Formation,the Songliao Basin.Sedimentary and elemental signatures confirm the protogenetic origin of this nodule and its effectiveness in recording geochemical characteristics of paleo-lake water during dolomitization.The low Y/Ho ratios,middle rare earth element(MREE)enrichment and subtle positive Eu anomalies within the nodule indicate a fresh water source.However,the Sr isotope values in the core of the nodule(0.7076-0.7080)are close to contemporaneous seawater(0.7074),yet different from the modern river(0.7120)and the host black shale(0.7100).On the premise of excluding the influence of hydrothermal fluids,the significantly low strontium isotope values of the lacustrine dolomite might be caused by seawater interference during dolomitization.Our findings demonstrate that lacustrine dolomite within black shales is not only a faithful tracer of diagenetic water environment,but also a novel and easily identified mineralogical evidence for episodic seawater intrusion event(91 Ma)in the Songliao Basin,which supplements other paleontological and geochemical evidence.

Research and Application of High-Density Resistivity Method in Seawater Intrusion Investigation in Laizhou Bay

The disaster of seawater intrusion seriously affects people's lives and restricts economic development,so the detection and treatment of seawater intrusion is a long-term task.On the basis of field investigation and water quality analysis,according to the change characteristics of apparent resistivity of groundwater after Cl-reaches 250 mg/L,the theoretical basis for the application of high-density resistivity method was determined,and the characteristic values of apparent resistivity for seawater intrusion interfaces in different geological characteristic regions in Laizhou Bay area were determined by typical profile tests.Combined with water quality investigation and other means,profiles for the high-density resistivity method were arranged,and the interfaces between saline and fresh water were accurately divided.

Uncertainty analysis of seawater intrusion forecasting

In order to describe the importance of uncertainty analysis in seawater intrusion forecasting and identify the main factors that might cause great differences in prediction results, we analyzed the influence of sea level rise, tidal effect, the seasonal variance of influx, and the annual variance of the pumping rate, as well as combinations of different parameters. The results show that the most important factors that might cause great differences in seawater intrusion distance are the variance of pumping rate and combinations of different parameters. The influence of sea level rise can be neglected in a short-time simulation （ten years, for instance）. Retardation of seawater intrusion caused by tidal effects is obviously important in aquifers near the coastline, but the influence decreases with distance away from the coastline and depth away from the seabed. The intrusion distance can reach a dynamic equilibrium with the application of the sine function for seasonal effects of influx. As a conclusion, we suggest that uncertainty analysis should be considered in seawater intrusion forecasting, if possible.

Simulation of Seawater Intrusion in Coastal Confined Aquifer Using a Point Collocation Method Based Meshfree Model

Seawater intrusion caused by groundwater over-exploitation from coastal aquifers poses a severe problem in many regions. Formulation of proper pumping strategy using a simulation model can assure sustainable supply of fresh water from the coastal aquifers. The focus of the present study is on the development of a numerical model based on Meshfree (MFree) method to study the seawater intrusion problem. For the simulation of seawater intrusion problem, widely used models are based on Finite Difference (FDM) and Finite Element (FEM) Methods, which demand well defined grids/meshes and considerable pre-processing efforts. Here, MFree Point Collocation Method (PCM) based on the Radial Basis Function (RBF) is proposed for the simulation. Diffusive interface approach with density-dependent dispersion and solution of flow and solute transport is adopted. These equations are solved using PCM with appropriate boundary conditions. The developed model has been verified with Henry’s problem, and found to be satisfactory. Further the model has been applied to another established problem and an attempt is made to examine the influence of important system parameters including pumping and recharge on the seawater intrusion. The PCM based MFree model is found computationally efficient as preprocessing is avoided when compared to other numerical methods.

State of seawater intrusion and its adaptive management countermeasures in Longkou City of China

Longkou City is a coastal area,and lacks water resources.The overexploitation of groundwater causes seawater intrusion.At present,seawater intrudes an area of 68 km2.With the decrease of groundwater extraction,the seawater intrusion area has generally declined.The paper expounds the development process of seawater intrusion as well as the corresponding prevention and control measures of using groundwater replenishment and groundwater throttling in Longkou City.In view of the seawater intrusion problem in Longkou City,some adaptive management countermeasures are put forward,which include:Adjusting industrial and agricultural structure,promoting economic and social development to match water resources;improving water usage structure,optimizing the utilization of water resources;advancing the construction of a water-saving society,using water resources efficiently;implementing inter-basin water transfer,using water resources rationally;developing and utilizing unconventional water sources,making full use of water resources;strengthening water infrastructure construction,increasing the development and utilization potential of water resources;carrying out ecological restoration,protecting water resources and ecological environment;improving the management informationalization level,strengthening the capabilities of groundwater monitoring and management;increasing publicity,improving public awareness of participation.

Seawater Intrusion in the Longkou-Laizhou Area, Shandong

The extensive intrusion （covering an area of 83.7-238.3 km;and accounting for 18.6-31.5% of the total area of the plain）, the presence of a transitional zone 1.5-6.0 km in width, and the interconnection in distribution between the seawater intrusion district and the region lower than the sea level caused by the strong drop of the groundwater level are major characteristics of the seawater intrusion in the study area. Cation exchange played an important role during the formation of chemical composition of the groundwater in the seawater intrusion district.

Study on the Status Quo and Prevention-control Measures of Seawater Intrusion in Qingdao City

Firstly, the general situation, influencing factors and damage of seawater intrusion in Qingdao City, Shandong Province were analyzed, and then some appropriate remedial measures were put forward, such as improving groundwater monitoring system in costal areas, exploiting groundwater reasonably, building underground cut-off walls and strengthening river management, which would provide a new approach for the prevention and control of seawater intrusion in Qingdao City.

Study on Seawater Intrusion in Kiaochow Bay Region

General situation of the seawater intrusion in Kiaochow Bay region was analyzed. Current status of the seawater intrusion and its formation mechanism, influence factor and hazard in Kiaochow Bay region were summarized. Finally, against seawater intrusion situation in the region, a series of practical prevention and control countermeasures were proposed.

Assessing the Seawater Intrusion Due to Beach Wells in the Desalination Plant

Short-Term Low Volume (STLV) Sea Water Desalination Plant of 6000 m3/d is under construction in the middle area of Gaza Strip. The plant will provide desalinated water for 75,000 inhabitants in regions in Khanyounis and Rafah. The intake of desalination plant will be indirectly from four beach wells. This article aims at providing the environmental impacts of these wells on the aquifer and the mitigation measures in case of negative impacts. In order to study the impacts of beach wells on the aquifer, a prediction groundwater three-dimensional model for the beach wells area, starting from the year 2000 until year 2030, was used. MODFLOW software was used for modeling the groundwater flow and SEAWAT software was used to model the seawater intrusion effect. The aquifer parameters were set as if they were in the transient model. The long term seasonal recharge rate for the summer and winter is considered to represent the seasonal differences in recharge through each year. The study showed that the steady four-meter drawdown in the beach wells will force the flow from the eastern direction to the sea. This will have positive impacts on the aquifer since it will decrease the seawater intrusion to the aquifer. The beach wells will pump water with Cl concentration equal to 18,000 mg/l. This means that the beach wells will accelerate the flow from the aquifer to the sea direction but still the pumped water is considered as seawater. This indicates the positive impacts on the groundwater aquifer since it will decrease the seawater intrusion in the beach wells area (Gaza Strip Middle area). In conclusion, these beach wells in this desalination plant (small capacity) are safe for the groundwater aquifer and it will decrease the effect of seawater intrusion on the aquifer.

PREDICTING THE CONSEQUENCES OF SEAWATER INTRUSION AND PROTECTION PROJECTS

The simulation of this process and the effects of protection projects lays the foundation of its effective control and defence. The mathematical model of the problem and upwind splitting alternating direction method were presented. Using this method, the numerical simulation of seawater intrusion in Laizhou Bay Area of Shandong Provivce was finished. The numerical results turned out to be identical with the real measurements, so the prediction of the consequences of protection projectects is reasonable.

CHARACTERISTICS-FINITE ELEMENT METHODS FOR SEAWATER INTRUSION NUMERICAL SIMULATION AND THEORETICAL ANALYSIS

Both numerical simulation and theoretical analysis of seawater intrusion in coastal regions are of great theoretical importance in environmental sciences. The mathematical model can be described as a problem of the initial boundary values for a system of 3-dimensional nonlinear parabolic partial differential equations, one being the pressure flow equation and the other is the concentration convection-dispersion equation of the salt contained. For a generic case of a 3-dimensional bounded region, a backward-difference time-stepping scheme is defined. It approximates the pressure by the standard Galerkin procedure and the concentration by a Galerkin method of charederistics, where calculus of variations, theory of prior estimates and techniques are made use of Optimal order estimates in H1 norm are derived for the errors in the approximate solution.

The Alternating-Direction Schemes and Numerical Analysis for the Three-dimensional Seawater Intrusion Simulation

Both numerical simulation and theoretical analysis of seawater intrusion in coastal regions are of great theoretical importance in environmental sciences. The mathematical model can be described as a coupled system of three dimensional nonlinear partial differential equations with initial-boundary value problems. In this paper, according to the actual conditions of molecular and three-dimensional characteristic of the problem, we construct the characteristic finite element alternating-direction schemes which can be divided into three continuous one-dimensional problems. By making use of tensor product algorithm, and priori estimation theory and techniques, the optimal order estimates in H1 norm are derived for the error in the approximate solution.

Solute transport and geochemical modeling of the coastal quaternary aquifer, Delta Dahab Basin, South Sinai, Egypt

The wadi dahab delta is in a dry, arid coastal zone within Egypt’s south Sinai Peninsula’s eastern portion. The primary water source is the Quaternary coastal alluvial aquifer. The groundwater salinity varies from 890to 8213 mg/L, with a mean value of 3417 mg/L. The dissolved major ions have been used to calculate the seawater mixing index(SWMI) using a linear equation that discriminates the groundwater mostly affected by water–rock interaction(SWMI 1>) and other samples mixed with Seawater(SWMI < 1). The isotopic composition of groundwater for specifically chosen groundwater samples ranges from-0.645‰ to +5.212‰ for δ^(18)O and from-9.582‰ to + 22.778‰ for δ^(2)H, where the seawater represented by a Red Sea water sample(δ^(18)O + 1.64‰-δ^(2)H + 9.80‰) and reject brine water are considerably enriched the isotopic groundwater values. The geochemical NETPATH model constrained by the dissolved significant ions, isotopes, and the rock aquifer forming minerals as phases indicate the mixing percent with the seawater ranges from 9% to 97% of seawater from 91% to 3% of original recharge water. According to the SEAWAT 3-D flow models, seawater has penetrated the Northeastern Dahab delta aquifer, with the intrusion zone extending1500 m inland. The salt dissolution, upwelling of saline water, recharge from the upstream mountain block, and seawater encroachment are the primary aspects contributing to the deterioration of groundwater quality. These findings may have significance for effective groundwater withdrawal management in arid locations worldwide with similar hydrogeological systems.

Characteristics and genesis of groundwater salinization in coastal areas of the Lower Reaches of Oujiang Basin

The coastal areas of the lower reaches of Oujiang River Basin are rich in groundwater resources.However,the unsustainable exploitation and utilization of groundwater have led to significant changes in the groundwater environment.Understanding the characteristics and genesis of groundwater salinization is crucial for preventing its deterioration and ensuring sustainable utilization.In this study,a comprehensive approach combining the ion ratio method,mineral saturation index method and multivariate statistical analysis was employed to investigate the hydrochemical characteristics and main controlling factors in the study area.The findings reveal that:(1)Groundwater samples in study area exhibit a neutral to slightly alkaline pH.The predominant chemical types of unconfined water are HCO_(3)-Ca·Na,HCO_(3)·Cl-Na·Ca and HCO_(3)·SO_(4)-Ca·Na,while confined water mainly exhibits Cl·HCO_(3)-Na and Cl-Na types.(2)Salinity coefficients indicate an increase in salinity from unconfined to confined water.TDS,Na^(+)and Cl^(–)concentrations show an increasing trend from mountainous to coastal areas in unconfined water,while confined water displays variability in TDS,Na^(+)and Cl^(–)concentrations.(3)Groundwater salinity is mainly influenced by water-rock interactions,including the dissolution of halite and gypsum,cation exchange,and seawater intrusion etc.Additionally,human activities and carbonate dissolution contribute to salinity in unconfined water.Seawater intrusion is identified as the primary factor leading to higher salinity in confined water compared to unconfined water,with increasing cation exchange and seawater interaction observed from unconfined to confined water.

Uncertainty and Sensitivity Analyses of the Simulated Seawater—Freshwater Mixing Zones in Steady-State Coastal Aquifers

The uncertainty and sensitivity of predicted positions and thicknesses of seawater-freshwater mixing zones with respect to uncertainties of saturated hydraulic conductivity, porosity, molecular diffusivity, longitudinal and transverse dispersivities were investigated in both head-control and flux-control inland boundary systems. It shows that uncertainties and sensitivities of predicted results vary in different boundary systems. With the same designed matrix of uncertain factors in simulation experiments, the variance of predicted positions and thickness in the flux-control system is much larger than that predicted in the head-control system. In a head-control system, the most sensitive factors for the predicted position of the mixing zone are inland freshwater head and transverse dispersivity. However, the predicted position of the mixing zone is more sensitive to saturated hydraulic conductivity in a flux-control system. In a head-control system, the most sensitive factors for the predicted thickness of the mixing zone include transverse dispersivity, molecular diffusivity, porosity, and longitudinal dispersivity, but the predicted thickness is more sensitive to the saturated hydraulic conductivity in a flux-control system. These findings improve our understandings for the development of seawater-freshwater mixing zone during seawater intrusion processes, and give technical support for groundwater resource management in coastal aquifers.

Ground water hydrochemical characteristics: seawater intruded area in eastern and southern coast of Laizhou Bay

Eastern and southern coastal zones of Laizhou Bay are the most representative seawater intruded areas in the world, with two intrusion sources of contemporary seawater and paleobrine. In order to reveal the complicated hydrochemical changing process and the mechanism of fresh groundwater being polluted by saltwater, we conducted long-term observation and hydrochemical analysis at four observing sections of typical salt-fresh water transitional zone. The study indicates that seawater and brine intrusion processes have different hydrochemical features, and that ion exchange and adsorption actions between water and aquifer produce great influence on the intrusion.

Evaluation of Sea-Water Intrusion in Coastal Aquifers Using both Numerical Methods and Causal Research: A Case Study of Mombasa, Kenya

This research carried out in Mombasa Island links research done in 2020 on the effects of sea-water intrusion and the current state. The aquifer in Mombasa Island is semi-confined and consists of limestone and coral rock. Water samples were collected and tested from 32 boreholes to determine chemical qualities. Results showed that chloride levels ranged from 74 mg/l to 412 mg/l, with 34% of boreholes having high chloride concentration. After modelling using MT3D program results indicated that the boreholes near the ocean were interfered by sea-water intrusion because chloride concentration was high. Control measures to prevent further sea-water intrusion should be put in place. Therefore, from a practical point of view, individuals who have sunk boreholes since 2020 try to mitigate the problem by installing Reverse Osmosis systems within their facilities, to reduce chloride levels from borehole water. The current research analyses the impact of intrusion on the installed RO systems on Mombasa Island, including cost implications, with the view of proposing viable mitigation measures. The reverse osmosis system though expensive would save a lot of chloride entering the bore holes. It is a little bit expensive though but the end results are positive and the chloride levels will reduce the cost of using too much soap.

PARAMETERS IDENTIFICATION IN A SALTWATER INTRUSION PROBLEM

This article is devoted to the identification, from observations or field measurements, of the hydraulic conductivity K for the saltwater intrusion problem in confined aquifers. The involved PDE model is a coupled system of nonlinear parabolic-elliptic equations completed by boundary and initial conditions. The main unknowns are the saltwater/freshwater interface depth and the freshwater hydraulic head. The inverse problem is formulated as an optimization problem where the cost function is a least square functional measuring the discrepancy between experimental data and those provided by the model.Considering the exact problem as a constraint for the optimization problem and introducing the Lagrangian associated with the cost function, we prove that the optimality system has at least one solution. Moreover, the first order necessary optimality conditions are established for this optimization problem.

Modeling of the Saltwater Intrusion Using the Level Set Method. Application to Henry’s Problem

The salt intrusion phenomenon is caused by overexploitation of aquifers in coastal areas. This physical phenomenon has been the subject of numerous studies and numerous methods have been proposed, with the aim of protecting the quality of the water in these aquifers. This work proposes a two-dimensional saline intrusion model using the sharp interface approach and the level set method. It consists of a parabolic equation modeling the underground flow and a hyperbolic Equation (the level set equation) which makes it possible to track the evolution of the interface. High-order numerical schemes such as the space scheme WENO5 and the third-order time scheme TVD-RK were used for the numerical resolution of the hyperbolic equation. To limit the tightening of the contour curves of the level set function, the redistanciation or reinitialization algorithm proposed by Sussma et al. (1994) was used. To ensure the effectiveness and reliability of the proposed method, two tests relating to the standard Henry problem and the modified Henry problem were performed. Recall that Henry’s problem uses the variable density modeling approach in a confined and homogeneous aquifer. By comparing the results obtained by the level set method with reinitialization (LSMR) and those obtained by Henry (1964), and by Simpson and Clement (2004), we see in the two test cases that the level set method reproduces well the toe, the tip and the behaviour of the interface. These results correspond to the results obtained by Abarca for Henry’s problem with constant dispersion coefficients. The results obtained with LSMR, reproduced the interface with a slight spacing compared to those obtained by Henry. According to Abarca (2006), this spacing is due to the absence of the longitudinal and transversal dispersion coefficients in the model.

Seasonal metal fluxes derived by the interaction of surface water and groundwater in an aquaculture estuary

Submarine groundwater discharge(SGD)plays a major role as a conveyor of metals to coastal waters.However,the seasonal change of metal fluxes derived through SGD is unclear.Here,we evaluated the behaviours and fluxes of trace metals(Mn,Fe,Ba,Pb,U,Cr,Zn,Cu)in an estuary under different seasonal conditions.The behaviours of trace metals revealed that SGD was the source of Mn(3.51 mmol/(m^(2)·d)),Fe(0.174 mmol/(m^(2)·d))and Ba(0.024 mmol/(m^(2)·d)),but the Cu sink(−0.55μmol/(m^(2)·d))and other metals exhibited a seasonal source‒sink conversion.The seasonal variation of dissolved organic matter and the fresh groundwater proportion in subterranean estuaries may have an important effect on metals fluxes especially for the Fe,Mn and Ba.Our result shows that the single seasonal metal fluxes estimation applied to the annual scale will cause a large deviation,up to 3.6 times for Fe,5.5 times for Mn,and 15 times for Ba.Therefore,the influence of seasonal fluctuations on SGDderived metal fluxes cannot be ignored,and our findings will be important for comprehending the metal budget and cycle in nearshore environment.