Approaches to the artificial impoundment and theoretical design of sedimentation retention basin are reviewed with particular attention to best management practice(BMP) to control agriculture and surface runoff. Sedim...Approaches to the artificial impoundment and theoretical design of sedimentation retention basin are reviewed with particular attention to best management practice(BMP) to control agriculture and surface runoff. Sediments retention basins are the small version of farm pond used where a criteria of farm pond is not met. Such basin traps the pollutants and suspended solids prior to entry into streams and lakes. The study is focused with special reference to the assessment and control of non point source pollution(NPSP) from the sub basin area of Tai Lake in the Xishan County of Wuxi City of China. The author suggested two different approaches to conduct this study including theoretical design for sedimentation retention basin and computation of flow, sediment transport and deposition during the artificial impoundment of retention basin for BMP's utilization. Theoretical design will provide a useful function as a first line defense against the movement of sediments and transport of pollutants into the Tai Lake while the assessment of sediments deposition will help to make its proper use and periodic cleanup.展开更多
1 Introduction Sediment provenance study,as an important part of basin analysis,is a key for source area definition,paleogeographic reconstruction,sediment transport route identification,and tectonic evolution(Haughto...1 Introduction Sediment provenance study,as an important part of basin analysis,is a key for source area definition,paleogeographic reconstruction,sediment transport route identification,and tectonic evolution(Haughton et al.,1991;Morton et al.,1999;Fontanelli et al.,2009;Cawood et al.,2012).The Qiongdongnan Basin(QDNB),lies in the northwestern passive continental margin of the South展开更多
137 Cs is an artificial radionuclide with a half-life of 30.2 years,which was released into the environment as a byproduct of atmospheric testing of nuclear weapons during the period of 1950s to 1970s with a peak depo...137 Cs is an artificial radionuclide with a half-life of 30.2 years,which was released into the environment as a byproduct of atmospheric testing of nuclear weapons during the period of 1950s to 1970s with a peak deposition in 1963.137 Cs fallout was strongly and rapidly adsorbed by soil particles when it deposited on the ground mostly with precipitation.Its following movements will associate with the adsorbed particles.137 Cs tracing technique has been widely used in soil erosion and sedimentation studies since 1980s.This paper introduces the basis of the technique and shows several case studies of assessment of soil erosion rates,investigation of sediment sources and dating of reservoir deposits by using the technique in the Loess Plateau and the Upper Yangtze River Basin.展开更多
It is well known that seawater that migrates deep into the Earth’s crust will pass into its supercritical domain at temperatures above 407°C and pressures above 298 bars. In the oceanic crust, these pressures ar...It is well known that seawater that migrates deep into the Earth’s crust will pass into its supercritical domain at temperatures above 407°C and pressures above 298 bars. In the oceanic crust, these pressures are attained at depths of 3 km below sea surface, and sufficiently high temperatures are found near intruding magmas, which have temperatures in the range of 800°C to 1200°C. The physico-chemical behaviour of seawater changes dramatically when passing into the supercritical domain. A supercritical water vapour (ScriW) is formed with a density of 0.3 g/cc and a strongly reduced dipolar character. This change in polarity is causing the ScriW to lose its solubility of the common sea salts (chlorides and sulphates) and a spontaneous precipitation of sea salts takes place in the pore system. However, this is only one of many cases where the very special properties of ScriW affect its surroundings. The objective of this paper is to increase awareness of the many geological processes that are initiated and governed by ScriW. This includes interactions between ScriW and its geological surroundings to initiate and drive processes that are of major importance to the dynamics and livelihood of our planet. ScriW is the driver of volcanism associated with subduction zones, as ScriW deriving from the subduction slab is interacting with the mantle rocks and reducing their melting point. ScriW is also initiating serpentinization processes where olivines in the mantle rocks (e.g. peridotite) are transformed to serpentine minerals upon the uptake of OH-groups from hydrolysed water. The simultaneous oxidation of Fe2+ dissolved from iron-bearing pyroxenes and olivines leads to the formation of magnetite and hydrogen, and consequently, to a very reducing environment. ScriW may also be the potential starter and driver of the poorly understood mud and asphalt volcanism;both submarine and terrestrial. Furthermore, the lack of polarity of the water molecules in ScriW gives the ScriW vapour the potential to dissolve organic matter and petroleum. The same applies to supercritical brines confined in subduction slabs. If these supercritical water vapours migrate upwards to reach the critical point, the supercritical vapour is condensed into steam and dissolved petroleum is partitioned from the water phase to become a separate fluid phase. This opens up the possibility of transporting petroleum long distances when mixed with ScriW. Therefore, we may, popularly, say that ScriW drives a gigantic underground refinery system and also a salt factory. It is suggested that the result of these processes is that ScriW is rejuvenating the world’s ocean waters, as all of the ocean water circulates into the porous oceanic crust and out again in cycles of less than a million years. In summary, we suggest that ScriW participates in and is partly responsible for: 1) Ocean water rejuvenation and formation;2) Fundamental geological processes, such as volcanism, earthquakes, and meta-morphism (including serpentinization);3) Solid salt production, accumulation, transportation, and (salt) dome formation;4) The initiation and driving of mud, serpentine, and asphalt volcanoes;5) Dissolution of organic matter and petroleum, including transportation and phase separation (fractionation), when passing into the subcritical domain of (liquid) water.展开更多
Pollen analyses of 85 samples from the San-jiaocheng section well along the margin of a palaeolake at the end of the Shiyang River, NW China, show that Picea and Sabina dominate the pollen assemblage. Together they re...Pollen analyses of 85 samples from the San-jiaocheng section well along the margin of a palaeolake at the end of the Shiyang River, NW China, show that Picea and Sabina dominate the pollen assemblage. Together they reach as high as 40%-60%, with the percentage of Picea varying inversely with that of Sabina. Similar results were obtained from another section in the Shiyang River drainage. Using modern ecological habitat relationship analogues, pol-len transport characteristics, and the overall pollen assem-blage, we propose that both Picea and Sabina pollen were transported by the river from the mountains at the upper reaches of the Shiyang River, and that the assemblage is more indicative of changes in upland vegetation than of local conditions near the section. This interpretation is supported by pollen data derived from surface samples, water samples, and riverbed samples. Using a moisture indicator (the Picea to Sabina ratio) and calculated pollen concentrations, we identify a series of展开更多
As a potential mineral resource, the clay minerals enriched in rare earth elements including yttrium(REY) in the deep sea have been attracting great attention. However, the enrichment mechanism of REY remains unclea...As a potential mineral resource, the clay minerals enriched in rare earth elements including yttrium(REY) in the deep sea have been attracting great attention. However, the enrichment mechanism of REY remains unclear. To understand the geochemical characteristics and factors controlling REY enrichment in zeolite clay in the deep sea, we conducted mineral identification by XRD, major and trace element measurements by XRF and REY analyses by ICP-MS on a 1.4-m-long sediment core(GC02) located in the Central Indian Oceanic Basin(CIOB). The main findings include:(1) the core sediments in GC02 possess elevated REY contents and exhibited a strong negative Ce anomaly, an apparent MREE bulge and positive Y anomaly. These were comparable with typical REY-rich clays in the Pacific Ocean, indicating the similar REY enrichment mechanism and the presence of REY-rich clays in the CIOB;(2) in comparison with the dataset from the Wharton Basin and DSDP site 213, the higher content of REY and stronger PAAS(Post Archean Australian Shale) normalization patterns in the GC02 sediments were likely caused by the weaker impact of terrigenous materials of GC02. The CIOB was suggested to be a promising place hosting REY rich pelagic sediments.展开更多
Concentrations of 16 polybrominated diphenyl ether(PBDE) congeners were measured in river sediments, paddy soils and three species of paddy-field organisms(crab, loach and carp) collected from the Liaohe River Bas...Concentrations of 16 polybrominated diphenyl ether(PBDE) congeners were measured in river sediments, paddy soils and three species of paddy-field organisms(crab, loach and carp) collected from the Liaohe River Basin, northeastern China. The total contents of PBDEs(∑_(16)PBDEs) in sediments and paddy soils were in the ranges of 273.4–3246.3 pg/g dry weight(dw), and 192.1–1783.8 pg/g dw, respectively. BDE 209 was the dominant congener both in sediments and paddy soils. The concentrations of ∑_(16)PBDEs in sediments were significantly higher than those in the adjacent paddy soils, indicating a potential transport of PBDEs from river to paddy ecosystems via river water irrigation. The biota–soil accumulation factor(BSAF) was calculated as the ratio between the lipid-normalized concentration in paddyfield organisms and the total organic carbon-normalized concentration in paddy soil. The average BSAF values of ∑15PBDEs followed the sequence of crab(3.6) 〉 loach(3.3) 〉 carp(2.1). BDE 154 had the highest BSAF value, and a parabolic trend between BSAF values of individual PBDE congeners and their log KOWvalues was observed. In view of the fact that crab had the larger BSAF value and higher lipid content, the ecological risk and health risk for crab cultivation in paddy fields should be of particular concern.展开更多
To investigate geochemical and mineralogical features of sediments from aquifers containing high levels of dissolved arsenic(As) in western Hetao Basin, Inner Mongolia, sediment samples were collected for XRD(X-ray...To investigate geochemical and mineralogical features of sediments from aquifers containing high levels of dissolved arsenic(As) in western Hetao Basin, Inner Mongolia, sediment samples were collected for XRD(X-ray diffraction), amorphous Fe/Mn oxides, and humic/fulvic acid analyses, in addition to As determination. In the study area, the total As contents in the sediments were in the range 5.3–28.8 mg/kg; while that associated with humic substances in the range 4–9 mg/kg, accounting for 26%–47% of the total As. The results of XRD analysis suggest that clay and silt contain certain small amounts of iron oxides minerals, such as ferrihydrite, hematite and goethite, whereas have higher As and Fe_2O_3 contents. Up to one third of As in the sediments could be extracted by ammonium oxalate, and high As contents were generally found in organic-rich clay or silty clay samples with high FA/HA ratio. As is strongly associated with humic substances and Fe oxyhydroxides, which may be the major sink and source of As in the aquifer sediments.展开更多
This is the first to elucidate the distribution and sources of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/PCDFs),and dioxin-like polychlorinated biphenyls in the waters from Kanzaki River,which is one...This is the first to elucidate the distribution and sources of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/PCDFs),and dioxin-like polychlorinated biphenyls in the waters from Kanzaki River,which is one of the most heavily polluted rivers in Japan.The World Health Organization (WHO)-toxic equivalent quantities (TEQs) in waters from the mainstream exceeded the Japanese environmental standard (1.0 pg-TEQ/L).The PCDD/PCDFs were dominated by highly chlorinated DFs,which predominantly contributed to the WHO-TEQs,suggesting that the main causes would be the incineration-related wastes.To find the sources,the dioxin congener concentrations in water and sediment samples from its tributary small waterways were determined.Abnormally high WHO-TEQs were detected in a water (50 pg-TEQ/L) and a sediment sample (41,000 ng-TEQ/kg dry weight) near the industrial solid waste incinerators (ISWIs).The PCDD/PCDF characteristics agreed well with those of the incinerator-related wastes as seen in the mainstream.These facts indicate that the dioxin pollution in the mainstream could be largely related to the industrial wastes from the ISWIs.Here,a TEQ apportionment method was used to understand the contribution of the pyrogenic sources to the WHO-TEQs.The average contribution ratios of the pyrogenic sources to WHO-TEQs were more than 80% for river waters from the mainstream,indicating that the elevated WHO-TEQs in the mainstream had been largely caused by the ISWIs.展开更多
文摘Approaches to the artificial impoundment and theoretical design of sedimentation retention basin are reviewed with particular attention to best management practice(BMP) to control agriculture and surface runoff. Sediments retention basins are the small version of farm pond used where a criteria of farm pond is not met. Such basin traps the pollutants and suspended solids prior to entry into streams and lakes. The study is focused with special reference to the assessment and control of non point source pollution(NPSP) from the sub basin area of Tai Lake in the Xishan County of Wuxi City of China. The author suggested two different approaches to conduct this study including theoretical design for sedimentation retention basin and computation of flow, sediment transport and deposition during the artificial impoundment of retention basin for BMP's utilization. Theoretical design will provide a useful function as a first line defense against the movement of sediments and transport of pollutants into the Tai Lake while the assessment of sediments deposition will help to make its proper use and periodic cleanup.
基金funded by the China Postdoctoral Science Foundation (No. 2016M602551)the CPSF-CAS Joint Foundation for Excellent Postdoctoral Fellows (No. 2016LH00022)the Nation Natural Science Foundation of China (No. 41576040)
文摘1 Introduction Sediment provenance study,as an important part of basin analysis,is a key for source area definition,paleogeographic reconstruction,sediment transport route identification,and tectonic evolution(Haughton et al.,1991;Morton et al.,1999;Fontanelli et al.,2009;Cawood et al.,2012).The Qiongdongnan Basin(QDNB),lies in the northwestern passive continental margin of the South
基金supported by National Natural Science Foundation of China (Grant No. 40971169,41101259)Ministry of Environmental Protectionof China (Grant No. 2009ZX07104-002-06)State Key Laboratory of Environmental Geochemistry (Grant No. SKLEG9008)
文摘137 Cs is an artificial radionuclide with a half-life of 30.2 years,which was released into the environment as a byproduct of atmospheric testing of nuclear weapons during the period of 1950s to 1970s with a peak deposition in 1963.137 Cs fallout was strongly and rapidly adsorbed by soil particles when it deposited on the ground mostly with precipitation.Its following movements will associate with the adsorbed particles.137 Cs tracing technique has been widely used in soil erosion and sedimentation studies since 1980s.This paper introduces the basis of the technique and shows several case studies of assessment of soil erosion rates,investigation of sediment sources and dating of reservoir deposits by using the technique in the Loess Plateau and the Upper Yangtze River Basin.
文摘It is well known that seawater that migrates deep into the Earth’s crust will pass into its supercritical domain at temperatures above 407°C and pressures above 298 bars. In the oceanic crust, these pressures are attained at depths of 3 km below sea surface, and sufficiently high temperatures are found near intruding magmas, which have temperatures in the range of 800°C to 1200°C. The physico-chemical behaviour of seawater changes dramatically when passing into the supercritical domain. A supercritical water vapour (ScriW) is formed with a density of 0.3 g/cc and a strongly reduced dipolar character. This change in polarity is causing the ScriW to lose its solubility of the common sea salts (chlorides and sulphates) and a spontaneous precipitation of sea salts takes place in the pore system. However, this is only one of many cases where the very special properties of ScriW affect its surroundings. The objective of this paper is to increase awareness of the many geological processes that are initiated and governed by ScriW. This includes interactions between ScriW and its geological surroundings to initiate and drive processes that are of major importance to the dynamics and livelihood of our planet. ScriW is the driver of volcanism associated with subduction zones, as ScriW deriving from the subduction slab is interacting with the mantle rocks and reducing their melting point. ScriW is also initiating serpentinization processes where olivines in the mantle rocks (e.g. peridotite) are transformed to serpentine minerals upon the uptake of OH-groups from hydrolysed water. The simultaneous oxidation of Fe2+ dissolved from iron-bearing pyroxenes and olivines leads to the formation of magnetite and hydrogen, and consequently, to a very reducing environment. ScriW may also be the potential starter and driver of the poorly understood mud and asphalt volcanism;both submarine and terrestrial. Furthermore, the lack of polarity of the water molecules in ScriW gives the ScriW vapour the potential to dissolve organic matter and petroleum. The same applies to supercritical brines confined in subduction slabs. If these supercritical water vapours migrate upwards to reach the critical point, the supercritical vapour is condensed into steam and dissolved petroleum is partitioned from the water phase to become a separate fluid phase. This opens up the possibility of transporting petroleum long distances when mixed with ScriW. Therefore, we may, popularly, say that ScriW drives a gigantic underground refinery system and also a salt factory. It is suggested that the result of these processes is that ScriW is rejuvenating the world’s ocean waters, as all of the ocean water circulates into the porous oceanic crust and out again in cycles of less than a million years. In summary, we suggest that ScriW participates in and is partly responsible for: 1) Ocean water rejuvenation and formation;2) Fundamental geological processes, such as volcanism, earthquakes, and meta-morphism (including serpentinization);3) Solid salt production, accumulation, transportation, and (salt) dome formation;4) The initiation and driving of mud, serpentine, and asphalt volcanoes;5) Dissolution of organic matter and petroleum, including transportation and phase separation (fractionation), when passing into the subcritical domain of (liquid) water.
基金. This work was supported by the National Natural Science Foundation of China (Grant Nos. 49731010 and 49871072).
文摘Pollen analyses of 85 samples from the San-jiaocheng section well along the margin of a palaeolake at the end of the Shiyang River, NW China, show that Picea and Sabina dominate the pollen assemblage. Together they reach as high as 40%-60%, with the percentage of Picea varying inversely with that of Sabina. Similar results were obtained from another section in the Shiyang River drainage. Using modern ecological habitat relationship analogues, pol-len transport characteristics, and the overall pollen assem-blage, we propose that both Picea and Sabina pollen were transported by the river from the mountains at the upper reaches of the Shiyang River, and that the assemblage is more indicative of changes in upland vegetation than of local conditions near the section. This interpretation is supported by pollen data derived from surface samples, water samples, and riverbed samples. Using a moisture indicator (the Picea to Sabina ratio) and calculated pollen concentrations, we identify a series of
基金supported by the National Natural Science Foundation of China(41773005)China Ocean Mineral Resources R&D Association(COMRA)Research Program(DY125-11-R-01,DY125-22-02),the Research Center for Air Pollution and Health(RCAPH)of Zhejiang University
文摘As a potential mineral resource, the clay minerals enriched in rare earth elements including yttrium(REY) in the deep sea have been attracting great attention. However, the enrichment mechanism of REY remains unclear. To understand the geochemical characteristics and factors controlling REY enrichment in zeolite clay in the deep sea, we conducted mineral identification by XRD, major and trace element measurements by XRF and REY analyses by ICP-MS on a 1.4-m-long sediment core(GC02) located in the Central Indian Oceanic Basin(CIOB). The main findings include:(1) the core sediments in GC02 possess elevated REY contents and exhibited a strong negative Ce anomaly, an apparent MREE bulge and positive Y anomaly. These were comparable with typical REY-rich clays in the Pacific Ocean, indicating the similar REY enrichment mechanism and the presence of REY-rich clays in the CIOB;(2) in comparison with the dataset from the Wharton Basin and DSDP site 213, the higher content of REY and stronger PAAS(Post Archean Australian Shale) normalization patterns in the GC02 sediments were likely caused by the weaker impact of terrigenous materials of GC02. The CIOB was suggested to be a promising place hosting REY rich pelagic sediments.
基金supported by the Chinese Public Welfare Projects on Environmental Protection (No. 201309030)the National Natural Science Foundation of China (Nos. 21077102 and 41201491)
文摘Concentrations of 16 polybrominated diphenyl ether(PBDE) congeners were measured in river sediments, paddy soils and three species of paddy-field organisms(crab, loach and carp) collected from the Liaohe River Basin, northeastern China. The total contents of PBDEs(∑_(16)PBDEs) in sediments and paddy soils were in the ranges of 273.4–3246.3 pg/g dry weight(dw), and 192.1–1783.8 pg/g dw, respectively. BDE 209 was the dominant congener both in sediments and paddy soils. The concentrations of ∑_(16)PBDEs in sediments were significantly higher than those in the adjacent paddy soils, indicating a potential transport of PBDEs from river to paddy ecosystems via river water irrigation. The biota–soil accumulation factor(BSAF) was calculated as the ratio between the lipid-normalized concentration in paddyfield organisms and the total organic carbon-normalized concentration in paddy soil. The average BSAF values of ∑15PBDEs followed the sequence of crab(3.6) 〉 loach(3.3) 〉 carp(2.1). BDE 154 had the highest BSAF value, and a parabolic trend between BSAF values of individual PBDE congeners and their log KOWvalues was observed. In view of the fact that crab had the larger BSAF value and higher lipid content, the ecological risk and health risk for crab cultivation in paddy fields should be of particular concern.
基金financially supported by the National Natural Science Foundation of China(No.41572226)
文摘To investigate geochemical and mineralogical features of sediments from aquifers containing high levels of dissolved arsenic(As) in western Hetao Basin, Inner Mongolia, sediment samples were collected for XRD(X-ray diffraction), amorphous Fe/Mn oxides, and humic/fulvic acid analyses, in addition to As determination. In the study area, the total As contents in the sediments were in the range 5.3–28.8 mg/kg; while that associated with humic substances in the range 4–9 mg/kg, accounting for 26%–47% of the total As. The results of XRD analysis suggest that clay and silt contain certain small amounts of iron oxides minerals, such as ferrihydrite, hematite and goethite, whereas have higher As and Fe_2O_3 contents. Up to one third of As in the sediments could be extracted by ammonium oxalate, and high As contents were generally found in organic-rich clay or silty clay samples with high FA/HA ratio. As is strongly associated with humic substances and Fe oxyhydroxides, which may be the major sink and source of As in the aquifer sediments.
文摘This is the first to elucidate the distribution and sources of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/PCDFs),and dioxin-like polychlorinated biphenyls in the waters from Kanzaki River,which is one of the most heavily polluted rivers in Japan.The World Health Organization (WHO)-toxic equivalent quantities (TEQs) in waters from the mainstream exceeded the Japanese environmental standard (1.0 pg-TEQ/L).The PCDD/PCDFs were dominated by highly chlorinated DFs,which predominantly contributed to the WHO-TEQs,suggesting that the main causes would be the incineration-related wastes.To find the sources,the dioxin congener concentrations in water and sediment samples from its tributary small waterways were determined.Abnormally high WHO-TEQs were detected in a water (50 pg-TEQ/L) and a sediment sample (41,000 ng-TEQ/kg dry weight) near the industrial solid waste incinerators (ISWIs).The PCDD/PCDF characteristics agreed well with those of the incinerator-related wastes as seen in the mainstream.These facts indicate that the dioxin pollution in the mainstream could be largely related to the industrial wastes from the ISWIs.Here,a TEQ apportionment method was used to understand the contribution of the pyrogenic sources to the WHO-TEQs.The average contribution ratios of the pyrogenic sources to WHO-TEQs were more than 80% for river waters from the mainstream,indicating that the elevated WHO-TEQs in the mainstream had been largely caused by the ISWIs.