We propose the Dantzig selector based on the l_(1-q)(1<q≤2)minimization model for the sparse signal recovery.First,we discuss some properties of l_(1-q)minimization model and give some useful inequalities.Then,we ...We propose the Dantzig selector based on the l_(1-q)(1<q≤2)minimization model for the sparse signal recovery.First,we discuss some properties of l_(1-q)minimization model and give some useful inequalities.Then,we give a sufficient condition based on the restricted isometry property for the stable recovery of signals.The l_(1-2)minimization model of Yin-Lou-He is extended to the l_(1-q)minimization model.展开更多
Aristotle related both dependent variables:democratization and autocratization in his broader explanation of regime change.For him two factors were crucial,the number of rulers(one,a few,the masses)and their values an...Aristotle related both dependent variables:democratization and autocratization in his broader explanation of regime change.For him two factors were crucial,the number of rulers(one,a few,the masses)and their values and behavior in terms of normal times and in crises periods.Here we try to be as parsimonious as possible emphasizing the size of the selectorate,as Aristotle knew already.The selectorate comprises the people who have a say in selecting political leaders.In this respect selectorate theory(Bueno de Mesquita et al.)is purely formal and helps to explain both,the origins of democracy and autocracy as well as their dismissal.The size of the selectorate is the crucial intervening variable in linking more specific causes and circumstances for bringing about the respective states on the dependent variables.Other theoretical glimpses will be taken at crises of democracies and autocracies.The size of the electorate can be limited by(brute)force or even through abstaining from the right to vote or using it to abolish democracy for autocracy(Przeworski,Zimmermann,and Saalfeld).Here we emphasize four major blocs of variables:(1)economic success(Lipset,Huntington),(2)the relative size of the consenters,dissenters,and assenters(Easton,Wright,Linz)bolstering even badly performing democratic and autocratic regimes,(3)the exit options and alternatives created for and by political and economic elites,possibly tied to potential mass mobilization and protest action,and(4)democratic peace theory as to external challenges to regime change.A causal model will be developed around those factors hopefully bringing about a consistent understanding of the basic processes of democratization and autocratization.展开更多
Today’s explosion of data urgently requires memory technologies capable of storing large volumes of data in shorter time frames,a feat unattain-able with Flash or DRAM.Intel Optane,commonly referred to as three-dimen...Today’s explosion of data urgently requires memory technologies capable of storing large volumes of data in shorter time frames,a feat unattain-able with Flash or DRAM.Intel Optane,commonly referred to as three-dimensional phase change memory,stands out as one of the most promising candidates.The Optane with cross-point architecture is constructed through layering a storage element and a selector known as the ovonic threshold switch(OTS).The OTS device,which employs chalcogenide film,has thereby gathered increased attention in recent years.In this paper,we begin by providing a brief introduction to the discovery process of the OTS phenomenon.Subsequently,we summarize the key elec-trical parameters of OTS devices and delve into recent explorations of OTS materials,which are categorized as Se-based,Te-based,and S-based material systems.Furthermore,we discuss various models for the OTS switching mechanism,including field-induced nucleation model,as well as several carrier injection models.Additionally,we review the progress and innovations in OTS mechanism research.Finally,we highlight the successful application of OTS devices in three-dimensional high-density memory and offer insights into their promising performance and extensive prospects in emerging applications,such as self-selecting memory and neuromorphic computing.展开更多
To increase efficiency and improve performance, reducing cost and emissions, advanced single crystal Ni-based superalloys are required in aerospace propulsion and power generating gas turbines. With the development of...To increase efficiency and improve performance, reducing cost and emissions, advanced single crystal Ni-based superalloys are required in aerospace propulsion and power generating gas turbines. With the development of alloy, significant improvements in casting techniques have been achieved by introducing the directionally solidified (DS) casting process followed by single crystal (SX) technique. The deviation of preferred orientation of single crystal superalloys is one of the most important defects in casting. In directional solidification equipment with high temperature gradient, single crystal specimens of DZ417G alloy were prepared successfully by the modified Bridgeman method with spiral grain selector. The orientation was investigated by means of X-ray diffraction (XRD) and electron backscattered diffraction (EBSD).The results show that the crystal selector with a smaller angle can effectively reduce the deviation of preferred orientation.展开更多
The massive Russian invasion of Ukraine in 2022 will have unforeseeable effects on the themes addressed here,from international regime change to infra-structural re-orientation to value changes.Here we concentrate on ...The massive Russian invasion of Ukraine in 2022 will have unforeseeable effects on the themes addressed here,from international regime change to infra-structural re-orientation to value changes.Here we concentrate on the positive cycle of effects globalization has brought about before the new war in Europe,mainly economic growth and(some)pressures for democratic development,as well as the negative cycle that originates in(relative)economic decline,elite dissent,even failed states and regime change,often in the direction of counter-democracy.The causal links between 13 independent and intervening variables and public goods as the dependent variable are specified in this explanatory sketch.There is need for broadening the view in explaining causal paths between globalization factors and the production of public goods.In doing that we focus in particular on variables like elite dissent,immigration,and new minorities,all three weakening the capacities of states to respond.Further we state that all four:ecological challenges,economic and social inequality and polarization,regime change,and international terrorism can be viewed as to their joint effects on the production of public goods.Selectorate theory is crucial.It explains political regimes on the base of the size of the selectorate with large(s)electorates producing public goods,as in democracies,and small ones only private ones,as in sultanist regimes and dictatorships.展开更多
In a paper conceived about five years ago(“Globalization and Public Goods:Too Big to Tackle?”)roughly a dozen factors were linked to explain important causal paths from globalization to the potential output of publi...In a paper conceived about five years ago(“Globalization and Public Goods:Too Big to Tackle?”)roughly a dozen factors were linked to explain important causal paths from globalization to the potential output of public goods.The Russian invasion of Ukraine,the corona epidemic,and the increased hegemonic rivalry between China and the U.S.interrupted or even destroyed many of the linkages between globalization and potential public good production.About five important detrimental paths involved in the meantime.In the present article we aim at linking what is left from the previous level of globalization or emerging to form a new and simplified causal model for likely linkages between truncated or(re-)emerging globalization,and the deadly needed output of public goods.These linkages refer to rules of climate control,go to trade linkages and arbitrary tariffs and trade interventions.Regime change,regime formation,and alliance restructuring address aspects of domestic rule and international stability.Selectorate theory,regime type,and exit options for political elites provide key explanatory factors in explaining globalization and public goods productions,or their decay.Where possible we use some data and transformation experiences corroborating our arguments.In other instances need for further empirical macro research will become clear.展开更多
The single crystal of nickel-base super alloy is widely used for making turbine blades.The microstructure of the alloy,especially the deviation of preferred orientation of single crystal,possesses the most important e...The single crystal of nickel-base super alloy is widely used for making turbine blades.The microstructure of the alloy,especially the deviation of preferred orientation of single crystal,possesses the most important effects on the mechanical properties of the blades.In this study,the single crystal ingot and blade of DZ417G alloy are prepared by means of the spiral crystal selector as well as the directional solidification method,and the effect of the parameters(i.e.,the shape of samples,the withdrawal rate)and the structure of the spiral crystal selector on the formation of single crystal and the crystal orientation are investigated.This method can prepare not only the single crystal ingot with simple shape but also the single crystal blades with the complex shape,the simple with rod-shape can form the single crystal easily with a relatively fast withdrawal rate,but the blade with complex shape requires much slower withdrawal rate to form single crystal.The length of the crystal selector almost has no effect on the crystal orientation.However,the angle of selector plays an obvious role on the orientation;the selector with a smaller angle can effectively reduce the deviation of preferred orientation;the appropriate angle of selector to obtain optimal orientation is found to be around30°and the deviation of preferred orientation is about30°for this selector.展开更多
The water-soluble carboxymethyl-cyclodextrin polymer (CM-CD polymer) was synthesized and used as capillary electrophoresis chiral selector. Verrapamil and thiopentorusodium were well separated using CM-CD polymer as c...The water-soluble carboxymethyl-cyclodextrin polymer (CM-CD polymer) was synthesized and used as capillary electrophoresis chiral selector. Verrapamil and thiopentorusodium were well separated using CM-CD polymer as chiral selector.展开更多
The impact of the variations of threshold voltage(V_(th))and hold voltage(V_(hold))of threshold switching(TS)selector in1 S1 R crossbar array is investigated.Based on ON/OFF state I–V curves measurements from a large...The impact of the variations of threshold voltage(V_(th))and hold voltage(V_(hold))of threshold switching(TS)selector in1 S1 R crossbar array is investigated.Based on ON/OFF state I–V curves measurements from a large number of Ag-filament TS selectors,V_(th)and V_(hold)are extracted and their variations distribution expressions are obtained,which are then employed to evaluate the impact on read process and write process in 32×321 S1 R crossbar array under different bias schemes.The results indicate that V_(th)and V_(hold)variations of TS selector can lead to degradation of 1 S1 R array performance parameters,such as minimum read/write voltage,bit error rate(BER),and power consumption.For the read process,a small V_(hold)variation not only results in the minimum read voltage increasing but it also leads to serious degradation of BER.As the standard deviation of V_(hold)and V_(th)increases,the BER and the power consumption of 1 S1 R crossbar array under 1/2 bias,1/3 bias,and floating scheme degrade,and the case under 1/2 bias tends to be more serious compared with other two schemes.For the write process,the minimum write voltage also increases with the variation of V_(hold)from small to large value.A slight increase of V_(th)standard deviation not only decreases write power efficiency markedly but also increases write power consumption.These results have reference significance to understand the voltage variation impacts and design of selector properly.展开更多
With rapid advancement and deep integration of artificial intelligence and the internet-of-things,artificial intelligence of things has emerged as a promising technology changing people’s daily life.Massive growth of...With rapid advancement and deep integration of artificial intelligence and the internet-of-things,artificial intelligence of things has emerged as a promising technology changing people’s daily life.Massive growth of data generated from the devices challenges the AIoT systems from information collection,storage,processing and communication.In the review,we introduce volatile threshold switching memristors,which can be roughly classified into three types:metallic conductive filament-based TS devices,amorphous chalcogenide-based ovonic threshold switching devices,and metal-insulator transition based TS devices.They play important roles in high-density storage,energy efficient computing and hardware security for AIoT systems.Firstly,a brief introduction is exhibited to describe the categories(materials and characteristics)of volatile TS devices.And then,switching mechanisms of the three types of TS devices are discussed and systematically summarized.After that,attention is focused on the applications in 3D cross-point memory technology with high storage-density,efficient neuromorphic computing,hardware security(true random number generators and physical unclonable functions),and others(steep subthreshold slope transistor,logic devices,etc.).Finally,the major challenges and future outlook of volatile threshold switching memristors are presented.展开更多
Erythromycin as a new chiral selector was first used for chrial separation of four derivatives of biphenyldimethylester enantiomers on CE. The influence of pH, the chiral selector concentration and organic modifiers ...Erythromycin as a new chiral selector was first used for chrial separation of four derivatives of biphenyldimethylester enantiomers on CE. The influence of pH, the chiral selector concentration and organic modifiers were preliminarily studied. Experiments show that the erythromycin as chiral selector is useful to CE.展开更多
This paper considers approximately sparse signal and low-rank matrix’s recovery via truncated norm minimization minx∥xT∥q and minX∥XT∥Sq from noisy measurements.We first introduce truncated sparse approximation p...This paper considers approximately sparse signal and low-rank matrix’s recovery via truncated norm minimization minx∥xT∥q and minX∥XT∥Sq from noisy measurements.We first introduce truncated sparse approximation property,a more general robust null space property,and establish the stable recovery of signals and matrices under the truncated sparse approximation property.We also explore the relationship between the restricted isometry property and truncated sparse approximation property.And we also prove that if a measurement matrix A or linear map A satisfies truncated sparse approximation property of order k,then the first inequality in restricted isometry property of order k and of order 2k can hold for certain different constantsδk andδ2k,respectively.Last,we show that ifδs(k+|T^c|)<√(s-1)/s for some s≥4/3,then measurement matrix A and linear map A satisfy truncated sparse approximation property of order k.It should be pointed out that when Tc=Ф,our conclusion implies that sparse approximation property of order k is weaker than restricted isometry property of order sk.展开更多
Six new kinds of amino acid derived β-cyclodextrins were synthesized to improve their water solubility and chiral separation properties. They are heptakis{2,6-di-O-[3-L-(1-isopropyl carboxyl methyl amino)-2-(hydroxy)...Six new kinds of amino acid derived β-cyclodextrins were synthesized to improve their water solubility and chiral separation properties. They are heptakis{2,6-di-O-[3-L-(1-isopropyl carboxyl methyl amino)-2-(hydroxy) propyl]}-β-cyclodextrin (i.e. L-Val-β-CD), heptakis{2,6-di-O-[3-L-(1-benzyl carboxyl methyl amino)-2-hydroxy propyl]}-β-cyclodextrin (i.e. L-Phe-β-CD), heptakis{2,6-di-O-[3-(D, L-1-benzyl carboxyl methyl amino)-2-hydroxy propyl]}-β-cyclodextrin (i.e. D,L-Phe-β-CD), heptakis{2,6-di-O-[3-(L-1-hydroxymethyl carboxyl methyl amino)-2-hydroxy propyl]}-β-cyclodextrin (i.e. L-Ser-β-CD), heptakis{2,6-di-O-[3-(L-1-carboxylmethyl carboxyl methyl amino)- 2-hydroxy propyl]}-β-cyclodextrin (i.e. L-Asp-β-CD), heptakis{2,6-di-O-[3-(L-2-carboxyl tetramethylene amino)-2-hydroxy propyl]}-β-cyclodextrin (i.e. L-Pro-β-CD). Their chemical structures were certified using FTIR and ()~1H NMR. Except for L-Phe-β-CD and D,L-Phe-β-CD, that are in soluble in water, the other amino acid derived β-CDs all have good water solubility. D,L-tyrosine and promethazine were baselinely separated by L-Val-β-CD in capillary electrophoresis.展开更多
A cationic cyclodextrin derivative 6-O-(hydroxypropyltrimethylammonia)-β-cyclodextrin (GTA-β-CD) with low degree of substitution was prepared through a convenient method in solid phase. The product could be used...A cationic cyclodextrin derivative 6-O-(hydroxypropyltrimethylammonia)-β-cyclodextrin (GTA-β-CD) with low degree of substitution was prepared through a convenient method in solid phase. The product could be used as a valuable chiral selector in the capillary electrophoresis (CE) separation of some acidic drug enantiomers such as naproxen, ofloxacin, ibuprofen and warfarin.展开更多
The utilization of liquid–liquid extraction for the separation of 2-phenylbutyric acid(2-PBA) enantiomers was proposed. Factors affecting the extract process were investigated, including organic solvents, β-cyclod...The utilization of liquid–liquid extraction for the separation of 2-phenylbutyric acid(2-PBA) enantiomers was proposed. Factors affecting the extract process were investigated, including organic solvents, β-cyclodextrin derivatives, cyclodextrin concentration, p H and temperature. A model was proposed to describe the separation process based on the homogeneous phase reaction mechanism. Important parameters of this model were determined experimentally. The physical distribution coefficients for molecular and ionic 2-PBA were0.129 and 7.455, respectively. The equilibrium constants of the complexation reactions were 89.36 and36.78 L·mol^-1 for(+)-and(-)-2-PBA, respectively. The model was verified by experiments and proved to be an excellent means to optimize the separation system. Through modeling prediction and experiment, the best conditions(e.g., pH value of 3.00, extractant concentration of 0.1 mol·L^-1, temperature of 5.0 ℃) were acquired. Under this condition, the maximum enantioselectivity(2.096) was obtained.展开更多
Selector devices are indispensable components of large-scale memristor array systems.The thereinto,ovonic threshold switching(OTS)selector is one of the most suitable candidates for selector devices,owing to its high ...Selector devices are indispensable components of large-scale memristor array systems.The thereinto,ovonic threshold switching(OTS)selector is one of the most suitable candidates for selector devices,owing to its high selectivity and scalability.However,OTS selectors suffer from poor endurance and stability which are persistent tricky problems for applica-tion.Here,we report on a multilayer OTS selector based on simple GeSe and doped-GeSe.The experimental results show im-proving selector performed extraordinary endurance up to 1010 and the fluctuation of threshold voltage is 2.5%.The reason for the improvement may lie in more interface states which strengthen the interaction among individual layers.These develop-ments pave the way towards tuning a new class of OTS materials engineering,ensuring improvement of electrical perform-ance.展开更多
基金supported by the National Natural Science Foundation of China“Variable exponential function spaces on variable anisotropic Euclidean spaces and their applications”(12261083),“Harmonic analysis on affine symmetric spaces”(12161083).
文摘We propose the Dantzig selector based on the l_(1-q)(1<q≤2)minimization model for the sparse signal recovery.First,we discuss some properties of l_(1-q)minimization model and give some useful inequalities.Then,we give a sufficient condition based on the restricted isometry property for the stable recovery of signals.The l_(1-2)minimization model of Yin-Lou-He is extended to the l_(1-q)minimization model.
文摘Aristotle related both dependent variables:democratization and autocratization in his broader explanation of regime change.For him two factors were crucial,the number of rulers(one,a few,the masses)and their values and behavior in terms of normal times and in crises periods.Here we try to be as parsimonious as possible emphasizing the size of the selectorate,as Aristotle knew already.The selectorate comprises the people who have a say in selecting political leaders.In this respect selectorate theory(Bueno de Mesquita et al.)is purely formal and helps to explain both,the origins of democracy and autocracy as well as their dismissal.The size of the selectorate is the crucial intervening variable in linking more specific causes and circumstances for bringing about the respective states on the dependent variables.Other theoretical glimpses will be taken at crises of democracies and autocracies.The size of the electorate can be limited by(brute)force or even through abstaining from the right to vote or using it to abolish democracy for autocracy(Przeworski,Zimmermann,and Saalfeld).Here we emphasize four major blocs of variables:(1)economic success(Lipset,Huntington),(2)the relative size of the consenters,dissenters,and assenters(Easton,Wright,Linz)bolstering even badly performing democratic and autocratic regimes,(3)the exit options and alternatives created for and by political and economic elites,possibly tied to potential mass mobilization and protest action,and(4)democratic peace theory as to external challenges to regime change.A causal model will be developed around those factors hopefully bringing about a consistent understanding of the basic processes of democratization and autocratization.
基金M.Zhu acknowledges support by the National Outstanding Youth Program(62322411)the Hundred Talents Program(Chinese Academy of Sciences)+1 种基金the Shanghai Rising-Star Program(21QA1410800)The financial support was provided by the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB44010200).
文摘Today’s explosion of data urgently requires memory technologies capable of storing large volumes of data in shorter time frames,a feat unattain-able with Flash or DRAM.Intel Optane,commonly referred to as three-dimensional phase change memory,stands out as one of the most promising candidates.The Optane with cross-point architecture is constructed through layering a storage element and a selector known as the ovonic threshold switch(OTS).The OTS device,which employs chalcogenide film,has thereby gathered increased attention in recent years.In this paper,we begin by providing a brief introduction to the discovery process of the OTS phenomenon.Subsequently,we summarize the key elec-trical parameters of OTS devices and delve into recent explorations of OTS materials,which are categorized as Se-based,Te-based,and S-based material systems.Furthermore,we discuss various models for the OTS switching mechanism,including field-induced nucleation model,as well as several carrier injection models.Additionally,we review the progress and innovations in OTS mechanism research.Finally,we highlight the successful application of OTS devices in three-dimensional high-density memory and offer insights into their promising performance and extensive prospects in emerging applications,such as self-selecting memory and neuromorphic computing.
基金Project (51074105) supported by the National Natural Science Foundation of ChinaProjects (08DZ1130100, 10520706400) supported by the Science and Technology Commission of Shanghai Municipality, ChinaProject (2007CB613606) supported by the National Basic Research Program of China
文摘To increase efficiency and improve performance, reducing cost and emissions, advanced single crystal Ni-based superalloys are required in aerospace propulsion and power generating gas turbines. With the development of alloy, significant improvements in casting techniques have been achieved by introducing the directionally solidified (DS) casting process followed by single crystal (SX) technique. The deviation of preferred orientation of single crystal superalloys is one of the most important defects in casting. In directional solidification equipment with high temperature gradient, single crystal specimens of DZ417G alloy were prepared successfully by the modified Bridgeman method with spiral grain selector. The orientation was investigated by means of X-ray diffraction (XRD) and electron backscattered diffraction (EBSD).The results show that the crystal selector with a smaller angle can effectively reduce the deviation of preferred orientation.
文摘The massive Russian invasion of Ukraine in 2022 will have unforeseeable effects on the themes addressed here,from international regime change to infra-structural re-orientation to value changes.Here we concentrate on the positive cycle of effects globalization has brought about before the new war in Europe,mainly economic growth and(some)pressures for democratic development,as well as the negative cycle that originates in(relative)economic decline,elite dissent,even failed states and regime change,often in the direction of counter-democracy.The causal links between 13 independent and intervening variables and public goods as the dependent variable are specified in this explanatory sketch.There is need for broadening the view in explaining causal paths between globalization factors and the production of public goods.In doing that we focus in particular on variables like elite dissent,immigration,and new minorities,all three weakening the capacities of states to respond.Further we state that all four:ecological challenges,economic and social inequality and polarization,regime change,and international terrorism can be viewed as to their joint effects on the production of public goods.Selectorate theory is crucial.It explains political regimes on the base of the size of the selectorate with large(s)electorates producing public goods,as in democracies,and small ones only private ones,as in sultanist regimes and dictatorships.
文摘In a paper conceived about five years ago(“Globalization and Public Goods:Too Big to Tackle?”)roughly a dozen factors were linked to explain important causal paths from globalization to the potential output of public goods.The Russian invasion of Ukraine,the corona epidemic,and the increased hegemonic rivalry between China and the U.S.interrupted or even destroyed many of the linkages between globalization and potential public good production.About five important detrimental paths involved in the meantime.In the present article we aim at linking what is left from the previous level of globalization or emerging to form a new and simplified causal model for likely linkages between truncated or(re-)emerging globalization,and the deadly needed output of public goods.These linkages refer to rules of climate control,go to trade linkages and arbitrary tariffs and trade interventions.Regime change,regime formation,and alliance restructuring address aspects of domestic rule and international stability.Selectorate theory,regime type,and exit options for political elites provide key explanatory factors in explaining globalization and public goods productions,or their decay.Where possible we use some data and transformation experiences corroborating our arguments.In other instances need for further empirical macro research will become clear.
基金Project(51074105)supported by the National Natural Science Foundation of ChinaProjects(08DZ1130100,10520706400)supported by the Science and Technology Commission of Shanghai Municipality,ChinaProject(2007CB613606)supported by the National Basic Research Program of China
文摘The single crystal of nickel-base super alloy is widely used for making turbine blades.The microstructure of the alloy,especially the deviation of preferred orientation of single crystal,possesses the most important effects on the mechanical properties of the blades.In this study,the single crystal ingot and blade of DZ417G alloy are prepared by means of the spiral crystal selector as well as the directional solidification method,and the effect of the parameters(i.e.,the shape of samples,the withdrawal rate)and the structure of the spiral crystal selector on the formation of single crystal and the crystal orientation are investigated.This method can prepare not only the single crystal ingot with simple shape but also the single crystal blades with the complex shape,the simple with rod-shape can form the single crystal easily with a relatively fast withdrawal rate,but the blade with complex shape requires much slower withdrawal rate to form single crystal.The length of the crystal selector almost has no effect on the crystal orientation.However,the angle of selector plays an obvious role on the orientation;the selector with a smaller angle can effectively reduce the deviation of preferred orientation;the appropriate angle of selector to obtain optimal orientation is found to be around30°and the deviation of preferred orientation is about30°for this selector.
文摘The water-soluble carboxymethyl-cyclodextrin polymer (CM-CD polymer) was synthesized and used as capillary electrophoresis chiral selector. Verrapamil and thiopentorusodium were well separated using CM-CD polymer as chiral selector.
基金Project supported by the MOST of China(Grant No.2016YFA0201801)the Beijing Advanced Innovation Center for Future Chip(ICFC)+2 种基金Beijing Municipal Science and Technology Project(Grant No.D161100001716002)the National Natural Science Foundation of China(Grant Nos.61674089,61674087,61674092,61076115,and 61774012)the Research Fund from Beijing Innovation Center for Future Chip(Grant No.KYJJ2016008)
文摘The impact of the variations of threshold voltage(V_(th))and hold voltage(V_(hold))of threshold switching(TS)selector in1 S1 R crossbar array is investigated.Based on ON/OFF state I–V curves measurements from a large number of Ag-filament TS selectors,V_(th)and V_(hold)are extracted and their variations distribution expressions are obtained,which are then employed to evaluate the impact on read process and write process in 32×321 S1 R crossbar array under different bias schemes.The results indicate that V_(th)and V_(hold)variations of TS selector can lead to degradation of 1 S1 R array performance parameters,such as minimum read/write voltage,bit error rate(BER),and power consumption.For the read process,a small V_(hold)variation not only results in the minimum read voltage increasing but it also leads to serious degradation of BER.As the standard deviation of V_(hold)and V_(th)increases,the BER and the power consumption of 1 S1 R crossbar array under 1/2 bias,1/3 bias,and floating scheme degrade,and the case under 1/2 bias tends to be more serious compared with other two schemes.For the write process,the minimum write voltage also increases with the variation of V_(hold)from small to large value.A slight increase of V_(th)standard deviation not only decreases write power efficiency markedly but also increases write power consumption.These results have reference significance to understand the voltage variation impacts and design of selector properly.
基金supported by the STI 2030—Major Projects(Grant No.2021ZD0201201)National Natural Science Foundation of China(Grant No.92064012)Hubei Province Postdoctoral Innovation Research Program(Grant No.0106182103)。
文摘With rapid advancement and deep integration of artificial intelligence and the internet-of-things,artificial intelligence of things has emerged as a promising technology changing people’s daily life.Massive growth of data generated from the devices challenges the AIoT systems from information collection,storage,processing and communication.In the review,we introduce volatile threshold switching memristors,which can be roughly classified into three types:metallic conductive filament-based TS devices,amorphous chalcogenide-based ovonic threshold switching devices,and metal-insulator transition based TS devices.They play important roles in high-density storage,energy efficient computing and hardware security for AIoT systems.Firstly,a brief introduction is exhibited to describe the categories(materials and characteristics)of volatile TS devices.And then,switching mechanisms of the three types of TS devices are discussed and systematically summarized.After that,attention is focused on the applications in 3D cross-point memory technology with high storage-density,efficient neuromorphic computing,hardware security(true random number generators and physical unclonable functions),and others(steep subthreshold slope transistor,logic devices,etc.).Finally,the major challenges and future outlook of volatile threshold switching memristors are presented.
文摘Erythromycin as a new chiral selector was first used for chrial separation of four derivatives of biphenyldimethylester enantiomers on CE. The influence of pH, the chiral selector concentration and organic modifiers were preliminarily studied. Experiments show that the erythromycin as chiral selector is useful to CE.
基金supported by the National Natural Science Foundation of China(11871109)NSAF(U1830107)the Science Challenge Project(TZ2018001)
文摘This paper considers approximately sparse signal and low-rank matrix’s recovery via truncated norm minimization minx∥xT∥q and minX∥XT∥Sq from noisy measurements.We first introduce truncated sparse approximation property,a more general robust null space property,and establish the stable recovery of signals and matrices under the truncated sparse approximation property.We also explore the relationship between the restricted isometry property and truncated sparse approximation property.And we also prove that if a measurement matrix A or linear map A satisfies truncated sparse approximation property of order k,then the first inequality in restricted isometry property of order k and of order 2k can hold for certain different constantsδk andδ2k,respectively.Last,we show that ifδs(k+|T^c|)<√(s-1)/s for some s≥4/3,then measurement matrix A and linear map A satisfy truncated sparse approximation property of order k.It should be pointed out that when Tc=Ф,our conclusion implies that sparse approximation property of order k is weaker than restricted isometry property of order sk.
文摘Six new kinds of amino acid derived β-cyclodextrins were synthesized to improve their water solubility and chiral separation properties. They are heptakis{2,6-di-O-[3-L-(1-isopropyl carboxyl methyl amino)-2-(hydroxy) propyl]}-β-cyclodextrin (i.e. L-Val-β-CD), heptakis{2,6-di-O-[3-L-(1-benzyl carboxyl methyl amino)-2-hydroxy propyl]}-β-cyclodextrin (i.e. L-Phe-β-CD), heptakis{2,6-di-O-[3-(D, L-1-benzyl carboxyl methyl amino)-2-hydroxy propyl]}-β-cyclodextrin (i.e. D,L-Phe-β-CD), heptakis{2,6-di-O-[3-(L-1-hydroxymethyl carboxyl methyl amino)-2-hydroxy propyl]}-β-cyclodextrin (i.e. L-Ser-β-CD), heptakis{2,6-di-O-[3-(L-1-carboxylmethyl carboxyl methyl amino)- 2-hydroxy propyl]}-β-cyclodextrin (i.e. L-Asp-β-CD), heptakis{2,6-di-O-[3-(L-2-carboxyl tetramethylene amino)-2-hydroxy propyl]}-β-cyclodextrin (i.e. L-Pro-β-CD). Their chemical structures were certified using FTIR and ()~1H NMR. Except for L-Phe-β-CD and D,L-Phe-β-CD, that are in soluble in water, the other amino acid derived β-CDs all have good water solubility. D,L-tyrosine and promethazine were baselinely separated by L-Val-β-CD in capillary electrophoresis.
文摘A cationic cyclodextrin derivative 6-O-(hydroxypropyltrimethylammonia)-β-cyclodextrin (GTA-β-CD) with low degree of substitution was prepared through a convenient method in solid phase. The product could be used as a valuable chiral selector in the capillary electrophoresis (CE) separation of some acidic drug enantiomers such as naproxen, ofloxacin, ibuprofen and warfarin.
基金Supported by the National Basic Research Program of China(2014CB260407)
文摘The utilization of liquid–liquid extraction for the separation of 2-phenylbutyric acid(2-PBA) enantiomers was proposed. Factors affecting the extract process were investigated, including organic solvents, β-cyclodextrin derivatives, cyclodextrin concentration, p H and temperature. A model was proposed to describe the separation process based on the homogeneous phase reaction mechanism. Important parameters of this model were determined experimentally. The physical distribution coefficients for molecular and ionic 2-PBA were0.129 and 7.455, respectively. The equilibrium constants of the complexation reactions were 89.36 and36.78 L·mol^-1 for(+)-and(-)-2-PBA, respectively. The model was verified by experiments and proved to be an excellent means to optimize the separation system. Through modeling prediction and experiment, the best conditions(e.g., pH value of 3.00, extractant concentration of 0.1 mol·L^-1, temperature of 5.0 ℃) were acquired. Under this condition, the maximum enantioselectivity(2.096) was obtained.
基金supported by National Natural Science Foundation of China(Grant Nos.61974164,62074166,61804181,62004219,and 6200422).
文摘Selector devices are indispensable components of large-scale memristor array systems.The thereinto,ovonic threshold switching(OTS)selector is one of the most suitable candidates for selector devices,owing to its high selectivity and scalability.However,OTS selectors suffer from poor endurance and stability which are persistent tricky problems for applica-tion.Here,we report on a multilayer OTS selector based on simple GeSe and doped-GeSe.The experimental results show im-proving selector performed extraordinary endurance up to 1010 and the fluctuation of threshold voltage is 2.5%.The reason for the improvement may lie in more interface states which strengthen the interaction among individual layers.These develop-ments pave the way towards tuning a new class of OTS materials engineering,ensuring improvement of electrical perform-ance.