In this work, a simple method was carried out to successfully fabricate superoleophilic and superhydrophobic N-dodecyltrimethoxysilane@tungsten trioxide coated copper mesh. The as-fabricated copper mesh displayed prom...In this work, a simple method was carried out to successfully fabricate superoleophilic and superhydrophobic N-dodecyltrimethoxysilane@tungsten trioxide coated copper mesh. The as-fabricated copper mesh displayed prominent superoleophilicity and superhydrophobicity with a huge water contact angle about 154.39° and oil contact angle near 0° Moreover, the coated copper mesh showed high separation efficiency approximately 99.3%, and huge water flux about 9962.3 L·h^-1·m-2, which could be used to separate various organic solvents/ water mixtures. Furthermore, the coated copper mesh showed favorable stability that the separation efficiency remained above 90% after 10 separation cycles. Benefiting from the excellent photocatalytic degradation ability of tungsten trioxide, the coated copper mesh possessed the self-cleaning capacity. Therefore, the mesh contaminated with lubricating oil could regain superhydrophobic property, and this property of self-cleaning permitted that the fabricated copper mesh could be repeatedly used for oil and water separation.展开更多
After conducting a lot of screening experiments the appropriate flocculating formulations for treating high-concentration wastewater discharged from a certain refinery were selected. The oil removal rate and COD remov...After conducting a lot of screening experiments the appropriate flocculating formulations for treating high-concentration wastewater discharged from a certain refinery were selected. The oil removal rate and COD removal achieved by these flocculating formulations were better than that achieved by the conventional compound formulation consisting of polyaluminium chloride(PAC) and polyacrylamide(PAA) . Addition of an oil/water separating agent to the formulation could improve its oil removal performance to facilitate the oil/water separation of the oil-in-water emulsion in the high-concentration wastewater along with improved adaptability of the formulation to the wastewater containing high concentration of pollutants. This flocculating agent has promising prospects for commercial application.展开更多
The main purpose of the research is to discuss the influence on ground water by NH4-N in polluted river and river bed.In the lab-scale experiment three kinds of natural sand were chosen as infiltration medium,and poll...The main purpose of the research is to discuss the influence on ground water by NH4-N in polluted river and river bed.In the lab-scale experiment three kinds of natural sand were chosen as infiltration medium,and polluted rivers were simulated by domestic sewage,after 10-month sand column test it was found that NH_4-N came to adsorption sa- turation on the 17th day in coarse sand and on the 130～140th day in medium sand,then had a higher effluent concentration because of desorption.It is concluded that NH_4-N eas- ily moved to ground water.When the concentration of NH_4-N in Liangshui River were 46.86,26.95 mg/L,that in groundwater are less than 1.10 mg/L.It is found that Liangshui River have a little influence on groundwater because of bottom mud,thickness and char- acter of the infiltration medium under the river bed and seepage quantity of river water. Clean water leaching test states that after the silt is cleared away and clean water is poured,NH_4-N in the penetration media under the polluted river is obviously carried into ground water,and ground water is polluted secondly.展开更多
The escalating challenges in water treatment,exacerbated by climate change,have catalyzed the emergence of innovative solutions.Novel adsorption separation and membrane filtration methodologies,achieved through molecu...The escalating challenges in water treatment,exacerbated by climate change,have catalyzed the emergence of innovative solutions.Novel adsorption separation and membrane filtration methodologies,achieved through molecular structure manipulation,are gaining traction in the environmental and energy sectors.Separation technologies,integral to both the chemical industry and everyday life,encompass concentration and purification processes.Macrocycles,recognized as porous materials,have been prevalent in water treatment due to their inherent benefits:stability,adaptability,and facile modification.These structures typically exhibit high selectivity and reversibility for specific ions or molecules,enhancing their efficacy in water purification processes.The progression of purification methods utilizing macrocyclic frameworks holds promise for improved adsorption separations,membrane filtrations,resource utilization,and broader water treatment applications.This review encapsulates the latest breakthroughs in macrocyclic host-guest chemistry,with a focus on adsorptive and membrane separations.The aim is to spotlight strategies for optimizing macrocycle designs and their subsequent implementation in environmental and energy endeavors,including desalination,elemental extraction,seawater energy harnessing,and sustainable extraction.Hopefully,this review can guide the design and functionality of macrocycles,offering a significantly promising pathway for pollutant removal and resource utilization.展开更多
基金the National Natural Science Foundation of China(No.21776319 and No.21476269).
文摘In this work, a simple method was carried out to successfully fabricate superoleophilic and superhydrophobic N-dodecyltrimethoxysilane@tungsten trioxide coated copper mesh. The as-fabricated copper mesh displayed prominent superoleophilicity and superhydrophobicity with a huge water contact angle about 154.39° and oil contact angle near 0° Moreover, the coated copper mesh showed high separation efficiency approximately 99.3%, and huge water flux about 9962.3 L·h^-1·m-2, which could be used to separate various organic solvents/ water mixtures. Furthermore, the coated copper mesh showed favorable stability that the separation efficiency remained above 90% after 10 separation cycles. Benefiting from the excellent photocatalytic degradation ability of tungsten trioxide, the coated copper mesh possessed the self-cleaning capacity. Therefore, the mesh contaminated with lubricating oil could regain superhydrophobic property, and this property of self-cleaning permitted that the fabricated copper mesh could be repeatedly used for oil and water separation.
文摘After conducting a lot of screening experiments the appropriate flocculating formulations for treating high-concentration wastewater discharged from a certain refinery were selected. The oil removal rate and COD removal achieved by these flocculating formulations were better than that achieved by the conventional compound formulation consisting of polyaluminium chloride(PAC) and polyacrylamide(PAA) . Addition of an oil/water separating agent to the formulation could improve its oil removal performance to facilitate the oil/water separation of the oil-in-water emulsion in the high-concentration wastewater along with improved adaptability of the formulation to the wastewater containing high concentration of pollutants. This flocculating agent has promising prospects for commercial application.
基金the National Natural Science Foundation of China(40772165)
文摘The main purpose of the research is to discuss the influence on ground water by NH4-N in polluted river and river bed.In the lab-scale experiment three kinds of natural sand were chosen as infiltration medium,and polluted rivers were simulated by domestic sewage,after 10-month sand column test it was found that NH_4-N came to adsorption sa- turation on the 17th day in coarse sand and on the 130～140th day in medium sand,then had a higher effluent concentration because of desorption.It is concluded that NH_4-N eas- ily moved to ground water.When the concentration of NH_4-N in Liangshui River were 46.86,26.95 mg/L,that in groundwater are less than 1.10 mg/L.It is found that Liangshui River have a little influence on groundwater because of bottom mud,thickness and char- acter of the infiltration medium under the river bed and seepage quantity of river water. Clean water leaching test states that after the silt is cleared away and clean water is poured,NH_4-N in the penetration media under the polluted river is obviously carried into ground water,and ground water is polluted secondly.
基金supported by the National Key Research&Development Program(2022YFE0199800)National Natural Science Foundation of China(82104065,32061143045)+1 种基金Distinguished Young Research Project of Anhui Higher Education Institution(2022AH020035)Science and Technology Plans of Tianjin(22ZYJDSS00070).
文摘The escalating challenges in water treatment,exacerbated by climate change,have catalyzed the emergence of innovative solutions.Novel adsorption separation and membrane filtration methodologies,achieved through molecular structure manipulation,are gaining traction in the environmental and energy sectors.Separation technologies,integral to both the chemical industry and everyday life,encompass concentration and purification processes.Macrocycles,recognized as porous materials,have been prevalent in water treatment due to their inherent benefits:stability,adaptability,and facile modification.These structures typically exhibit high selectivity and reversibility for specific ions or molecules,enhancing their efficacy in water purification processes.The progression of purification methods utilizing macrocyclic frameworks holds promise for improved adsorption separations,membrane filtrations,resource utilization,and broader water treatment applications.This review encapsulates the latest breakthroughs in macrocyclic host-guest chemistry,with a focus on adsorptive and membrane separations.The aim is to spotlight strategies for optimizing macrocycle designs and their subsequent implementation in environmental and energy endeavors,including desalination,elemental extraction,seawater energy harnessing,and sustainable extraction.Hopefully,this review can guide the design and functionality of macrocycles,offering a significantly promising pathway for pollutant removal and resource utilization.
