The separation characteristics of the PVA-CS (polyvinyl alcohol-chitosan) blended composite membrane for dehydration of ethanol-water mixture are examined. The relationships of flux and separation factor with the feed...The separation characteristics of the PVA-CS (polyvinyl alcohol-chitosan) blended composite membrane for dehydration of ethanol-water mixture are examined. The relationships of flux and separation factor with the feed concentration and operation temperature are established. Using this correlated equation, the continuous-flow pervaporation process about 500 kilolitres/year dehydrated ethanol is designed. The numbers of stage and reheater are calculated by stage-by-stage method for two kinds of cascades: one with equal membrane area and the other with 10℃ of temperature decrement per section. The results show that when the numbers of stage and reheater are the same, the cascade with 10℃ of temperature decrement has more advantages than that with equal membrane area. The influences of feed concentration and flow rate on the numbers of stage and reheater in the cascades are discussed.展开更多
Dividing wall column(DWC)is shown to be energy efficient compared to conventional column sequence for multi components separation,which is used for olefin separation in fluidization methanol to propylene process in th...Dividing wall column(DWC)is shown to be energy efficient compared to conventional column sequence for multi components separation,which is used for olefin separation in fluidization methanol to propylene process in the present work.Detailed design for pilot DWC was performed and five control structures,i.e.composition control(CC),temperature control(TC),composition-temperature control(CC-TC),temperature difference control(TDC),double temperature difference control(DTDC)were proposed to circumvent feed disturbance.Sensitivity analysis and singular value decomposition(SVD)were used as criterion to select the controlled temperature locations in TC,CC-TC,TDC and DTDC control loops.The steady simulation result demonstrates that 25.7% and 30.2% duty can be saved for condenser and reboiler by substituting conventional column sequence with DWC,respectively.As for control structure selection,TC and TDC perform better than other three control schemes with smaller maximum deviation and shorter settling time.展开更多
We propose a cascade system of filters for realizing a non-uniform waveband separation for optical networks. The use of such separation is required at the DEMUX stage in a optical OXC switching wavebands. The design o...We propose a cascade system of filters for realizing a non-uniform waveband separation for optical networks. The use of such separation is required at the DEMUX stage in a optical OXC switching wavebands. The design of the system is based on optimized balanced tree, which minimizes the overall optical loss.展开更多
A new concept of a supercritical water (SCW) circulating fiuidized bed reactor is proposed to produce hydrogen from coal/biomass gasification. The cyclone is a key component of the reactor system, in this paper, cyc...A new concept of a supercritical water (SCW) circulating fiuidized bed reactor is proposed to produce hydrogen from coal/biomass gasification. The cyclone is a key component of the reactor system, in this paper, cyclones with a single circular inlet (SCI) or a double circular inlet (DCI) were designed to adapt to the supercritical conditions. We evaluated the separation performance of the two cyclones using numerical simulations. A three-dimensional Reynolds stress model was used to simulate the turbulent flow of the fluid, and a stochastic Lagrangian model was used to simulate the particle motion. The flow fields of both cyclones were three-dimensionally unsteady and similar to those of traditional gas-solid cyclones. Secondary circulation phenomena were discovered and their influence on particle separation was estimated. Analyzing the distribution of the turbulence kinetic energy revealed that the most intensive turbulence existed in the zone near the vortex finder while the flow in the central part was relatively stable. The particle concentration distribution was non-uniform because of centrifugal forces. The distribution area can be divided into three parts according to the motion of the particles. In addition, the separation efficiency of both cyclones increased with the inlet SCaN velocity. Because of its perturbance flow, the DCI separator had higher separation efficiency than the SCI separator under comparable simulations. However, this was at the expense of a higher pressure drop across the cyclone.展开更多
基金Supported by the National Natural Science Foundation of China(No.29836160) and Commission of Science & Technology of Zhejiang Province(No.924010,No.85-12-02-05).
文摘The separation characteristics of the PVA-CS (polyvinyl alcohol-chitosan) blended composite membrane for dehydration of ethanol-water mixture are examined. The relationships of flux and separation factor with the feed concentration and operation temperature are established. Using this correlated equation, the continuous-flow pervaporation process about 500 kilolitres/year dehydrated ethanol is designed. The numbers of stage and reheater are calculated by stage-by-stage method for two kinds of cascades: one with equal membrane area and the other with 10℃ of temperature decrement per section. The results show that when the numbers of stage and reheater are the same, the cascade with 10℃ of temperature decrement has more advantages than that with equal membrane area. The influences of feed concentration and flow rate on the numbers of stage and reheater in the cascades are discussed.
基金Supported by Open Research Project of State Key Laboratory of Chemical Engineering(Grant No.SKL-Ch E-16B06)
文摘Dividing wall column(DWC)is shown to be energy efficient compared to conventional column sequence for multi components separation,which is used for olefin separation in fluidization methanol to propylene process in the present work.Detailed design for pilot DWC was performed and five control structures,i.e.composition control(CC),temperature control(TC),composition-temperature control(CC-TC),temperature difference control(TDC),double temperature difference control(DTDC)were proposed to circumvent feed disturbance.Sensitivity analysis and singular value decomposition(SVD)were used as criterion to select the controlled temperature locations in TC,CC-TC,TDC and DTDC control loops.The steady simulation result demonstrates that 25.7% and 30.2% duty can be saved for condenser and reboiler by substituting conventional column sequence with DWC,respectively.As for control structure selection,TC and TDC perform better than other three control schemes with smaller maximum deviation and shorter settling time.
文摘We propose a cascade system of filters for realizing a non-uniform waveband separation for optical networks. The use of such separation is required at the DEMUX stage in a optical OXC switching wavebands. The design of the system is based on optimized balanced tree, which minimizes the overall optical loss.
文摘A new concept of a supercritical water (SCW) circulating fiuidized bed reactor is proposed to produce hydrogen from coal/biomass gasification. The cyclone is a key component of the reactor system, in this paper, cyclones with a single circular inlet (SCI) or a double circular inlet (DCI) were designed to adapt to the supercritical conditions. We evaluated the separation performance of the two cyclones using numerical simulations. A three-dimensional Reynolds stress model was used to simulate the turbulent flow of the fluid, and a stochastic Lagrangian model was used to simulate the particle motion. The flow fields of both cyclones were three-dimensionally unsteady and similar to those of traditional gas-solid cyclones. Secondary circulation phenomena were discovered and their influence on particle separation was estimated. Analyzing the distribution of the turbulence kinetic energy revealed that the most intensive turbulence existed in the zone near the vortex finder while the flow in the central part was relatively stable. The particle concentration distribution was non-uniform because of centrifugal forces. The distribution area can be divided into three parts according to the motion of the particles. In addition, the separation efficiency of both cyclones increased with the inlet SCaN velocity. Because of its perturbance flow, the DCI separator had higher separation efficiency than the SCI separator under comparable simulations. However, this was at the expense of a higher pressure drop across the cyclone.