Serpentinized Peridotite as Source of Aeromagnetic Anomalies

The source of long-wavelength aeromagnetic anomalies appears to originate from the earth's deep crust. Constrained by previous studies on geochemical, petrologic analysis, the eclogite and serpentinized peridotite samples from drill hole ZK703 at Donghai in the western Sulu ultrahigh-pressure (UHP) terrane, East China, were unambiguously exhumed from the lower crust and the upper mantle, providing significant information about the magnetic properties of rocks at a deeper part of the crust. Results show that the serpentinization process favors the neoformation of nearly stoichiometric magnetite, resulting in the enhancement of its magnetization up to 8.6 A/m, which is sufficient enough to contribute to some magnetic anomalies. In contrast, eclogite samples have only weaker magnetization (generally less than 0.05 A/m) compared to serpentinized peridotite. Nevertheless, experiments under the lower crustal conditions are necessary to further support these conclusions.

Petrology and geochemistry of serpentinized peridotites from Hahajima Seamount in Izu-Bonin forearc region

Serpentinites,which contain up to 13 wt%of water,are important reservoirs for chemical recycling in subduction zones.In the past two decades,forearc mantle serpentinites were identified in different locations around the world.Here,we present petrology and whole rock chemistry of ultramafic and mafic rocks dredged from the Hahajima Seamount,which is located 24–40 km west to the junction of the Izu-Bonin Trench and the Mariana Trench.Nearly all the collected samples are extensively hydrated,and olivine grains in ultramafic rocks are replaced by serpentine minerals,with only one sample preserving remaining trace of orthopyroxene.Our new results show that the Hahajima serpentinized peridotite samples are all MgO-rich(~42 wt%),but have low contents in Al2O3,CaO,rare earth and high field strength elements,which is consistent with the overall depleted character of their mantle protoliths.Model calculations indicate that these Hahajima peridotite samples were derived from 10%–25%partial melting of the presumed fertile mantle source,which is generally lower than those of peridotites from Torishima Forearc Seamount,Conical Seamount and South Chamorro Seamount(mostly>25%).All the serpentinites from these four forearc seamounts show strong enrichment in fluid-mobile and lithophile elements(Li,Sr,Pb and U).In details,Hahajima Seamount serpentinites do not have obvious enrichment in Cs and Rb,and display remarkably high abundances of U.These observations indicate that the serpentinization of Hahajima peridotites occurred by addition of seawater or low temperature seawater-derived hydrothermal fluid,without or with little contribution from slab-derived fluids.The geochemical signature of serpentinites from Hahajima Seamount could be interpreted as the result of the combination of extensive partial melting and subsequent percolation of seawater through the mantle wedge.

Chemical Variation of Chromian Spinel Compositions in a Serpentinized Peridotites: Implications for Evolution of the Neoproterozoic Ophiolites

Tectonic setting of the Neoproterozoic ophiolites is poorly understood.Because of extensive serpentinization/metamorphism in the mantle section,accessory chromian spinel has been used as an important geotectonic indicator.

Compressional elastic wave velocities of serpentinized pyroxenite at high pressures and high temperatures and its geological significance

Center for Analysis and Prediction, China Seismological Bureau, Beijing 100036, China 2) Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China

Precipitation of Calcite Veins in Serpentinized Harzburgite at Tianxiu Hydrothermal Field on Carlsberg Ridge(3.67°N),Northwest Indian Ocean:Implications for Fluid Circulation

Serpentinization and calcite precipitation of mantle peridotites exhumed along detachment faults at the slow-to ultraslow-spreading centers can provide important clues to the hydrothermal alteration processes.The Tianxiu hydrothermal field is a new-found active and ultramafichosted hydrothermal vent site along the Carlsberg Ridge,Northwest Indian Ocean.Two types of calcite veins are recognized in serpentinized harzburgite samples collected from the seafloor at the water depth of 3 500 m(3.67°N/63.83°E) and 400 m north of Tianxiu hydrothermal field.Calcite veins Ⅰ occur in the fractures that cut through mesh texture in the highly serpentinized harzburgite,while calcite veins Ⅱ precipitate within the mesh texture in the relatively weaker serpentinized harzburgite.Both veins show similar δ13CPDB(+0.54‰ and +0.58‰) but different δ18OPDB(-16.67‰ and +4.46‰) values,suggesting that they were derived from the same carbon source but precipitated at different temperatures.Taking the deep seawater temperature of 2℃as the precipitation temperature of the calcite veins I,the equilibrium δ18OV-SMOW of calcite-precipitating fluid was calculated to be 1.78‰,which is close to the average δ18OV-SMOW value(1.74‰) of vent fluid samples from the ultramafic-hosted hydrothermal systems worldwide.The formation temperature of calcite veins Ⅱ is inferred to be approximately 134℃,based on the calculated δ18OV-SMOW above.The temperature differences of calcite precipitation probably resulted from the fluid cooling conductively and mixing with seawater along the presumed fractures during slow upflow.The low-temperature calcite postdates the mesh texture,while the high-temperature calcite may precipitate under relatively low water/rock ratios,alkaline and reduced conditions among the mesh texture,which is revealed by the geochemical models.Therefore,it is suggested that they both have been influenced by hydrothermal fluids and the sampling site is near the discharge zone of hydrothermal circulation.

蛇形机器人的运动控制研究

蛇形机器人具有很高的运动稳定性和环境适应性,非常适应于不确定性及复杂的环境中工作,如地震救援、火灾以及其他自然灾害等等.该文研究了一种正交模块组成的蛇形机器人,采用PXA270芯片作为主控制器和AVR128单片机作为从控制器,实现了主从分布式控制.在简化的Serpentine曲线基础上,研究了由离散关节组成的蛇形机器人控制,最后得到机器蛇运动时各个关节电机相应的旋转角度和旋转速度,并通过安装超声波传感器测距实现了自主避障.实验结果表明方案是可行和可靠的.

Crustal S-wave velocity structure across the northeastern South China Sea continental margin: implications for lithology and mantle exhumation

The northeastern margin of the South China Sea (SCS), developed from continental rifting and breakup, is usually thought of as a non-volcanic margin. However, post-spreading volcanism is massive and lower crustal high-velocity anomalies are widespread, which complicate the nature of the margin here. To better understand crustal seismic velocities, lithology, and geophysical properties, we present an S-wave velocity (VS) model and a VP/VS model for the northeastern margin by using an existing P-wave velocity (VP) model as the starting model for 2-D kinematic S-wave forward ray tracing. The Mesozoic sedimentary sequence has lower VP/VS ratios than the Cenozoic sequence;in between is a main interface of P-S conversion. Two isolated high-velocity zones (HVZ) are found in the lower crust of the continental slope, showing S-wave velocities of 4.0–4.2 km/s and VP/VS ratios of 1.73–1.78. These values indicate a mafic composition, most likely of amphibolite facies. Also, a VP/VS versus VP plot indicates a magnesium-rich gabbro facies from post-spreading mantle melting at temperatures higher than normal. A third high-velocity zone (VP : 7.0–7.8 km/s;VP/VS: 1.85–1.96), 70-km wide and 4-km thick in the continent-ocean transition zone, is most likely to be a consequence of serpentinization of upwelled upper mantle. Seismic velocity structures and also gravity anomalies indicate that mantle upwelling/ serpentinization could be the most severe in the northeasternmost continent-ocean boundary of the SCS. Empirical relationships between seismic velocity and degree of serpentinization suggest that serpentinite content decreases with depth, from 43% in the lower crust to 37% into the mantle.

The production of iron oxide during peridotite serpentinization:Influence of pyroxene

Serpentinization produces molecular hydrogen(H2)that can support communities of microorganisms in hydrothermal fields;H2 results from the oxidation of ferrous iron in olivine and pyroxene into ferric iron,and consequently iron oxide(magnetite or hematite)forms.However,the mechanisms that control H2 and iron oxide formation are poorly constrained.In this study,we performed serpentinization experiments at 311℃ and 3.0 kbar on olivine(with <5% pyroxene),orthopyroxene,and peridotite.The results show that serpentine and iron oxide formed when olivine and orthopyroxene individually reacted with a saline starting solution.Olivine-derived serpentine had a significantly lower FeO content(6.57±1.30 wt.%)than primary olivine(9.86 wt.%),whereas orthopyroxene-derived serpentine had a comparable FeO content(6.26±0.58 wt.%)to that of primary orthopyroxene(6.24 wt.%).In experiments on peridotite,olivine was replaced by serpentine and iron oxide.However,pyroxene transformed solely to serpentine.After 20 days,olivine-derived serpentine had a FeO content of 8.18±1.56 wt.%,which was significantly higher than that of serpentine produced in olivine-only experiments.By contrast,serpentine after orthopyroxene had a slightly higher FeO content(6.53±1.01 wt.%)than primary orthopyroxene.Clinopyroxene-derived serpentine contained a significantly higher FeO content than its parent mineral.After 120 days,the FeO content of olivine-derived serpentine decreased significantly(5.71±0.35 wt.%),whereas the FeO content of orthopyroxene-derived serpentine increased(6.85±0.63 wt.%)over the same period.This suggests that iron oxide preferentially formed after olivine serpentinization.Pyroxene in peridotite gained some Fe from olivine during the serpentinization process,which may have led to a decrease in iron oxide production.The correlation between FeO content and SiO_2 or AI_2 O_3 content in olivine-and orthopyroxene-derived serpentine indicates that aluminum and silica greatly control the production of iron oxide.Based on our results and data from natural serpentinites reported by other workers,we propose that aluminum may be more influential at the early stages of peridotite serpentinization when the production of iron oxide is very low,whereas silica may have a greater control on iron oxide production during the late stages instead.

Semisolid A356 alloy feedstock poured through a serpentine channel

Fine spheroidal and equiaxed nondendritic microstructures required for semisolid casting can be formed through a serpentine pouting channel. Effects of the pouring temperature and the vertical section length of the serpentine pouring channel were studied. The results indicate that both favorable semisolid microstructures of A356 aluminum alloy can be generated by a serpentine pouring channel, and the solid shell inside the channel can be avoided when the pouting temperature is in the range from 660 to 680℃. It is also shown that the vertical section length of the serpentine pouting channel has a significant influence on the microstructure of the feedstock, namely both the microstructure of the feedstock and the microstructure uniformity in the radial direction get worse when the vertical section length is shortened; moreover, the pouring temperature for obtaining the feedstock with suitable microstructure decreases. The relevant mechanisms were discussed.

Mechanism of Mg2+ dissolution from olivine and serpentine: Implication for bioleaching of high-magnesium nickel sulfide ore at elevated pH

To inhibit the dissolution of Mg^2+ during the bioleaching process of high-magnesium nickel sulfide ore, the effect of major bioleaching factors on the dissolution of Mg^2+ from olivine and serpentine was investigated and kinetics studies were carried out. The results indicated that the dissolution rate-controlling steps are chemical reaction for olivine and internal diffusion for serpentine. The most influential factor on the dissolution of Mg^2+ from olivine and serpentine was temperature, followed by p H and particle size. A novel method of bioleaching at elevated pH was used in the bioleaching of Jinchuan ore. The results showed that elevated pH could significantly reduce the dissolution of Mg^2+ and acid consumption along with slightly influencing the leaching efficiencies of nickel and cobalt. A model was used to explain the leaching behaviors of high-magnesium nickel sulfide ore in different bioleaching systems. The model suggested that olivine will be depleted eventually, whereas serpentine will remain because of the difference in the rate-controlling steps. Bioleaching at elevated pH is a suitable method for treating high-magnesium nickel sulfide ores.

Tensile properties and microstructure of rheo-diecast 7075 alloy prepared by serpentine channel process

A semisolid slurry of 7075 aluminum alloy was prepared by means of a serpentine channel process (SCP) and rheo-diecasting. The influences of pouring temperature during slurry preparation, the injection pressure and die preheat temperature on the mechanical properties and microstructure of a rheo-diecast 7075 aluminum alloy were investigated. The results show that the as-cast strength and elongation of the tensile samples were 210-260 MPa and 0.2%-1.7%, respectively, with an injection pressure of 130 MPa, a pouring temperature of 700-720℃, a preheat temperature of 280-350℃, and a plunger speed of 0.5 m·S^-1. The results also show that the aged strength and elongation of the tensile samples were 420-453 MPa and 1.0%-1.4%, respectively, when the alloy solution was treated at 470℃ for 12 h and aged at 120℃ for 24 h. The substantial shrinkage porosity in the 7075 aluminum alloy tensile samples was the main cause of low elongation.

Refinement of primary Si grains in Al–20%Si alloy slurry through serpentine channel pouring process

In this study, a serpentine channel pouring process was used to prepare the semi-solid A1-20%Si alloy slurry and refine primary Si grains in the alloy. The effects of the pouring temperature, number of curves in the serpentine channel, and material of the serpentine channel on the size of primary Si grains in the semi-solid A1-20%Si alloy slurry were investigated. The results showed that the pouting temperature, number of the curves, and material of the channel strongly affected the size and distribution of the primary Si grains. The pouring tempera- ture exerted the strongest effect, followed by the number of the curves and then the material of the channel. Under experimental conditions of a four-curve copper channel and a pouring temperature of 701℃, primary Si grains in the semi-solid A1-20%Si alloy slurry were refined to the greatest extent, and the lath-like grains were changed into granular grains. Moreover, the equivalent grain diameter and the average shape coefficient of primary Si grains in the satisfactory semi-solid A1-20%Si alloy slurry were 24.4 μm and 0.89, respectively. Finally, the re- finement mechanism and distribution rule of primary Si grains in the slurry prepared through the serpentine channel pouring process were analyzed and discussed.

Refinement of primary Si grains of A390 alloy slurry through serpentine channel pouring process

In this paper, the serpentine channel pouring process for preparing a semi-solid A390 alloy slurry and refining the primary Si grains of the A390 alloy, was used. The effects of the pouring temperature, the cooling water flow and the number of the curves on the size of the primary Si grains in the semi-solid A390 alloy slurry were investigated. The results show that the pouring temperature, the cooling water flow and the number of the curves have a major effect on the size and the distribution of primary Si grains. Under the experimental condition of the four-curve copper channel whose cooling water flow was 500 L·h-1 and the pouring temperature was 690 oC, the primary Si grains of the semi-solid A390 alloy slurry were refined to the greatest extent and the lath-like grains were changed into granular ones. Additionally, the equivalent grain diameter and the average shape factor of the primary Si grains of the satisfactory semi-solid A390 alloy slurry are 18.6 μm and 0.8, respectively. Further, the refinement mechanism of the primary Si grains through the serpentine channel pouring process was analyzed and discussed. In summary, the primary Si nuclei could be easily precipitated due to the chilling effect of the channel inner wall, thus the primary Si grains were greatly refined. Meanwhile, the subsequent alloy melt fluid also promoted the separation of primary Si grains from the inner wall, further refining the primary Si grains.

Mosquito larvicidal activity of Rauvolfia serpentina L.seeds against Culex quinquefasciatus Say

Objective:To establish the larvicidal activities,if any of solvent extracts of Rauvolfia serpentina (R.serpentina) L.seeds against Culex quinquefasciatus(Cx.quinquefasciatus) Say.1823 as target species.Methods:Seeds of R.serpentina were extracted with five solvents graded according to the polarity[viz.petroleum ether.benzene,ethyl acetate,acetone and absolute alcohol] continuing one after another with the same seeds.Results:Mortality rate with petroleum ether extract was significantly higher than other extracts.The mortality rates of late 3rd instar larvae wore 50.33±5.51.10.00±1.00.0.00±0.00.21.33±1.53 and 0.00±0.00 in 100 ppm concentration of petroleum ether,benzene,ethyl acetate,acetone and absolute alcohol respectively,after 24 h of exposure period.Conclusions:Results of this study show that petroleum ether extract of R. serpentina seed may be considered as a potent source of mosquito larvicidal agent.

Carbonation of Chrysotile under Subduction Conditions

In order to understand the role of serpentine minerals in the global carbon cycle, high-pressure X-ray diffraction (XRD) experiments were performed on chrysotile (Mg3Si2O5(OH)4) using carbon dioxide (CO2) as a pressure medium. Synchrotron XRD patterns revealed the formation of magnesite and high-pressure chrysotile after heating at 170 -C for 1 h at 2.5(1) GPa. The Rietveld refinement suggests that the unit cell composition of the original chrysotile changes to Mg2.4(1)Si2O5(OH)2.4(1) upon the formation of magnesite, which appears to be driven by the dehydrogenation of the innermost hydroxyl group, OH3, and the rearrangement of magnesium (Mg) at the M1 site, leading to the formation of metastable monodehydroxylated chrysotile. Metastable chrysotile is observed up to 5.0(1) GPa and 500 -C, which corresponds to the slab Moho geotherms for the South Sumatra and Ryukyu subduction zone. After recovery to ambient conditions, the characteristic fibrous morphology of the original chrysotile was found to have changed to an earthy form. These results can help us to understand deep carbon cycling along the subduction zones, and may prompt the design of a novel method of asbestos detoxification using pressure and temperature.

A cost-effective approach to recycle serpentine tailings:Destruction of stable layered structure and solvent displacement crystallization

In this work,the stable layer structure of serpentine,which seriously restricts the extraction of magnesium,was broken down,and a nearly 94%leaching efficiency of Mg was obtained by adding 5%fluorite powder.Compared with the system without fluorite,the Mg leaching efficiency increased by 36.42%.This result was achieved because the complexation of fluorinion(F)with Si in serpentine promoted a distorted tetrahedral orientation,which led to a loose crystal structure of serpentine and contributed to exposing more Mg for a remarkable increase in Mg recovery.It is suggested that fluorite powder could replace expensive assisted reagents in the leaching process,which would markedly decreased the cost.Moreover,an energy-efficient‘‘solvent displacement crystallization”(SDC)method was employed to efficiently recover magnesium(99.04%)from pregnant solutions.At the same time,the reuse of fluorinecontaining solutions was explored.

Study on the cementitiousness of asbestos tailings

The cementitiousness of dehydration asbestos tailings(serpentine, 3MgO.2SiO 2.2H 2O) in different conditions was studied. The result shown that dehydration asbestos tailings have better cementitiousness in certain condition and it can be used in building materials industry. It was also found that MgO powder, fly ash or quick lime can improve regularly the cementitiousness of asbestos tailings.

Reactions between olivine and CO2-rich seawater at 300℃:Implications for H2 generation and CO2 sequestration on the early Earth

To understand the influence of fluid CO2 on ultramafic rock-hosted seafloor hydrothermal systems on the early Earth,we monitored the reaction between San Carlos olivine and a CO2-rich NaCl fluid at 300 C and 500 bars.During the experiments,the total carbonic acid concentration（∑XO2） in the fluid decreased from approximately 65 to 9 mmol/kg.Carbonate minerals,magnesite,and subordinate amount of dolomite were formed via the water-rock interaction.The H2 concentration in the fluid reached approximately 39 mmol/kg within 2736 h,which is relatively lower than the concentration generated by the reaction between olivine and a CO2-free NaCl solution at the same temperature.As seen in previous hydrothermal experiments using komatiite,ferrous iron incorporation into Mg-bearing carbonate minerals likely limited iron oxidation in the fluids and the resulting H2 generation during the olivine alteration.Considering carbonate mineralogy over the temperature range of natural hydrothermal fields,H2 generation is likely suppressed at temperatures below approximately 300℃ due to the formation of the Mg-bearing carbonates.Nevertheless,H_2 concentration in fluid at 300℃ could be still high due to the temperature dependency of magnetite stability in ultramafic systems.Moreover,the Mg-bearing carbonates may play a key role in the ocean-atmosphere system on the early Earth.Recent studies suggest that the subduction of carbonated ultramafic rocks may transport surface CO2 species into the deep mantle.This process may have reduced the huge initial amount of CO2 on the surface of the early Earth.Our approximate calculations demonstrate that the subduction of the Mg-bearing carbonates formed in komatiite likely played a crucial role as one of the CO2 carriers from the surface to the deep mantle,even in hot subduction zones.

Enhancing heat transfer at the micro-scale using elastic turbulence

Small concentrations of a high-molecular-weight polymer have been used to create so-called ＂elastic tur- bulence＂ in a micro-scale serpentine channel geometry. It is known that the interaction of large elastic stresses created by the shearing motion within the fluid flow with streamline curvature of the serpentine geometry leads initially to a purely-elastic instability and then the generation of elastic turbulence. We show that this elastic turbulence enhances the heat transfer at the micro-scale in this geometry by up to 300% under creeping flow conditions in comparison to that achieved by the equivalent Newtonian fluid flow.

Devise of a W serpentine shape tube heat exchanger in a hard chromium electroplating process

In a hard chromium electroplating process, a heat exchanger is employed to remove the heat produced from the high current intensity in an electroplating bath.Normally, a conventional U shape heat exchanger is installed in the bath, but it provides low heat removal.Thus, this study designs a novel W serpentine shape heat exchanger with identical heat transfer area to the conventional one for increasing heat removal performance.The performance of the heat exchange is tested with various flow velocities in a cross-section in range of 1.6 to 2.4 m·s^(-1).Mathematical models of this process have been formulated in order to simulate and evaluate the heat exchanger performance.The results show that the developed models give a good prediction of the plating solution and cooling water temperature, and the novel heat exchanger provides better results at any flow velocity.In addition, the W serpentine shape heat exchanger has been implemented in a real hard chromium electroplating plant.Actual data collected have shown that the new design gives higher heat removal performance compared with the U shape heat exchanger with identical heat transfer area; it removes more heat out of the process than the conventional one of about 23%.