During 2006 and 2011, following the implementation of dioxin contamination monitoring in poultry meat, levels higher than legally allowed in meat from poultry slaughtered for human consumption, were found. The wood sh...During 2006 and 2011, following the implementation of dioxin contamination monitoring in poultry meat, levels higher than legally allowed in meat from poultry slaughtered for human consumption, were found. The wood shavings used as bedding material in the poultry farm showed considerable high contaminations, indicating that these materials were the likely source of contamination of the animals. Wood shavings samples (n = 23), used as poultry litters in intensive farms of broilers, were analysed. In both episodes, contamination profiles of higher and lower concentrations, seem to be very similar, being OCDD, OCDF, 1,2,3,4,6,7,8-HpCDD and 1,2,3,4,6,7,8-HpCDF responsible for 97.4 % of the total contamination. The present work describes the analytical adapted, used methodology and the specific clean-up procedures, which revealed that recoveries of <sup>13</sup>C<sub>12</sub>-Labelled compounds added to the wood shavings samples ranged from 71.3% to 86.3%.展开更多
Bamboo shavings, the outer or intermediate layer of bamboo stems, are the bulk of by-products produced in bamboo processing. In this study we investigated the isolation, chemical characterization, and immunostimulator...Bamboo shavings, the outer or intermediate layer of bamboo stems, are the bulk of by-products produced in bamboo processing. In this study we investigated the isolation, chemical characterization, and immunostimulatory activity in vitro of the hemicelluloses from bamboo shavings. Shavings were first pretreated by steam explosion. The optimal pretreatment was found to be steam explosion at 2.2 MPa for 1 min. Following this pretreatment, the yield of hemicelluloses reached(2.05±0.22)%(based on the dry dewaxed raw materials), which was 5.7-fold higher than that of untreated samples. Bamboo-shavings hemicellulose(BSH) was then prepared by hot water extraction and ethanol precipitation from the steam-exploded shavings. Purification of BSH by anion-exchange chromatography of diethylaminoethanol(DEAE)-sepharose Fast Flow resulted in a neutral fraction(BSH-1, purity of 95.3%, yield of 1.06%) and an acidic fraction(BSH-2, purity of 92.5%, yield of 0.79%). The weight-average molecular weights(Mw) of BSH-1 and BSH-2 were 12 800 and 11 300 g/mol, respectively. Chemical and structural analyses by Fourier transform infrared spectroscopy(FT-IR), 1D(^1H and ^13C) and 2D(heteronuclear single quantum correlation(HSQC)) nuclear magnetic resonance(NMR) spectra revealed that BSH-1 was O-acetylated-arabinoxylan and BSH-2 was O-acetylated-(4-Omethylglucurono)-arabinoxylan. BSH-1 had a higher content of acetyl groups than BSH-2. For the immunomodulatory activity in vitro, BSH and BSH-2 significantly stimulated mouse splenocyte proliferation while BSH-1 had no effect; BSH, BSH-1, and BSH-2 markedly enhanced the phagocytosis activity and nitric oxide production of the murine macrophage RAW264.7 in a dose-dependent manner. Our results suggest that the water-extractable hemicelluloses from steam-exploded bamboo shavings are naturally acetylated and have immunostimulatory activity.展开更多
Chrome shavings(CS),a kind of solid wastes discharged from tanneries,always pose serious environmental problems due to the presence of chromium.In this work,kinetic study of the pyrolysis of CS was investigated using ...Chrome shavings(CS),a kind of solid wastes discharged from tanneries,always pose serious environmental problems due to the presence of chromium.In this work,kinetic study of the pyrolysis of CS was investigated using a thermogravimetric analyzer in nitrogen atmosphere.The results obtained from the thermogravimetric analysis indicated that there are three stages in the temperature range 25 to 600℃.The second stage is the main weight loss stage and it could be mainly attributed to the pyrolysis of collagenous materials.Iso-conversional and generalized master-plots method were first employed to estimate the activation energy value and possible reaction mechanism of CS pyrolysis.The results showed that the pyrolysis process could not be described accurately by single-step reaction due to the heterogeneous nature of CS.Afterwards,the thermogravimetric kinetic of CS pyrolysis was studied using combined kinetic analysis.It was found that three-parallel-reaction model allowed better fitting relevance for CS pyrolysis.This information was important for simulating and predicting the pyrolysis behaviors of CS.展开更多
The reduction of gained heat,heat peak shifting,and the mitigation of air temperature fluctuations are some desirable properties that are sought after in any thermal insulation system.It cannot be overstated that thes...The reduction of gained heat,heat peak shifting,and the mitigation of air temperature fluctuations are some desirable properties that are sought after in any thermal insulation system.It cannot be overstated that these fac-tors,in addition to others,govern the performance of such systems thus their effect on indoor ambient conditions.The effect of such systems extends also to Heating,Ventilation and Air-conditioning(HVAC)systems that are set up to operate optimally in certain conditions.Where literature shows that PCMs and natural materials such as wood-shavings can provide efficient passive insulation for buildings,it is evident that such approaches utilise methods that are of a degree of intricacy which require specialist knowledge and complex techniques,such as micro-encapsulation for instance.With technical and economic aspects in mind,an amalgam of PCM and wood-shavings has been created to be utilised as a feasible thermal insulation.The amalgamation was performed in the simplest of methods,through submerging the wood shavings in PCM.An experimental procedure was devised to test the thermal performance of the amalgam and compare this to the performance of the same un-amalgamated materials.Comparative analysis revealed that no significant thermal gains would be expected from such amal-gamation.However,a significant reduction in the total weight of the insulation system would be achieved that,in this case,shown to be up to 20.94%.Thus,further reducing possible strains on structural elements due to the application of insulation on buildings.This can be especially beneficial in vernacular architectural approaches where considerably large amounts and thicknesses of insulations are used.In addition,cost reduction could be attained as wood shavings are significantly cheaper compared to the cost of PCMs.展开更多
Chromium shavings are wet by-products of the leather industry,of which thousands of tons accrue worldwide during leather manufacture.Due to their chromium content,chromium shavings are responsible for the most importa...Chromium shavings are wet by-products of the leather industry,of which thousands of tons accrue worldwide during leather manufacture.Due to their chromium content,chromium shavings are responsible for the most important ecological challenges caused by the leather industry.They are stable towards temperatures of up to 110°C and enzymatic degradation.This high stability is caused by the three-dimensional native structure,typical for collagen,and additional chemical cross-links between the collagen fibres achieved by Cr3+salts in the tanning process.Therefore,hitherto chromium shavings are not utilized industrially to produce biogas.In order to generate biogas,this stable structure has to be denatured.Chromium shavings were pre-treated by extrusion and hydrothermal methods.To prove the enzymatic degradability,the different pre-treatments were evaluated by differential scanning calorimetry(DSC),enzymatic assays,and by measuring the solubility in water.The biogas production potential was investigated using batch trials to examine feasibility.Results demonstrated that both pretreatments allowed enzymatic attack and increased degradability of the chromium shavings reducing the lag-phase of biogas production and the remaining waste.展开更多
In renewable energy systems,energy storage systems can reduce the power fluctuation of renewable energy sources and compensate for the prediction deviation.However,if the renewable energy prediction deviation is small...In renewable energy systems,energy storage systems can reduce the power fluctuation of renewable energy sources and compensate for the prediction deviation.However,if the renewable energy prediction deviation is small,the energy storage system may work in an underutilized state.To efficiently utilize a renewable-energy-sided energy storage system(RES),this study proposed an optimization dispatching strategy for an energy storage system considering its unused capacity sharing.First,this study proposed an unused capacity-sharing strategy for the RES to fully utilize the storage’s unused capacity and elevate the storage’s service efficiency.Second,RES was divided into“deviation-compensating energy storage(DES)”and“sharing energy storage(SES)”to clarify the function of RES in the operation process.Third,this study established an optimized dispatching model to achieve the lowest system operating cost wherein the unused capacity-sharing strategy could be integrated.Finally,a case study was investigated,and the results indicated that the proposed model and algorithm effectively improved the utilization of renewable-energy-side energy storage systems,thereby reducing the total operation cost and pressure on peak shaving.展开更多
According to the multi-time-scale characteristics of power generation and demand-side response(DR)resources,as well as the improvement of prediction accuracy along with the approaching operating point,a rolling peak s...According to the multi-time-scale characteristics of power generation and demand-side response(DR)resources,as well as the improvement of prediction accuracy along with the approaching operating point,a rolling peak shaving optimization model consisting of three different time scales has been proposed.The proposed peak shaving optimization model considers not only the generation resources of two different response speeds but also the two different DR resources and determines each unit combination,generation power,and demand response strategy on different time scales so as to participate in the peaking of the power system by taking full advantage of the fast response characteristics of the concentrating solar power(CSP).At the same time,in order to improve the accuracy of the scheduling results,the combination of the day-ahead peak shaving phase with scenario-based stochastic programming can further reduce the influence of wind power prediction errors on scheduling results.The testing results have shown that by optimizing the allocation of scheduling resources in each phase,it can effectively reduce the number of starts and stops of thermal power units and improve the economic efficiency of system operation.The spinning reserve capacity is reduced,and the effectiveness of the peak shaving strategy is verified.展开更多
In this paper,the combustion conditions in the boiler furnace of a 660 MWtangential fired pulverized coal boiler are numerically simulated at 15%and 20%rated loads,to study the flexibility of coal-fired power units on...In this paper,the combustion conditions in the boiler furnace of a 660 MWtangential fired pulverized coal boiler are numerically simulated at 15%and 20%rated loads,to study the flexibility of coal-fired power units on ultra-low load operation.The numerical results show that the boiler can operate safely at 15%and 20%ultra-low loads,and the combustion condition in the furnace is better at 20%load,and the tangent circles formed by each characteristic section in the furnace are better,and when the boiler load is decreased to 15%,the tangent circles in the furnace begin to deteriorate.The average flue gas temperature of different areas of the furnace shows that when the boiler furnace operates under ultra-low load conditions,the average smoke temperature of the cold ash hopper at 20%load is basically the same as the average smoke temperature at 15%load;in the burner area,the average smoke temperature of the cold ash hopper at 20%load is about 50 K higher than that at 15%load;in the burned out area,the average smoke temperature of the cold ash hopper at 20%load is slightly higher than that at 15%load.The average temperature of flue gas in the furnace showed a tendency to increase rapidly with the height of the furnace,then slow down and fluctuate the temperature in the burner area,and finally increase slightly in the burnout area due to the further combustion of combustible components to release heat,and then began to decrease.展开更多
To adress the problems of insufficient consideration of charging pile resource limitations,discrete-time scheduling methods that do not meet the actual demand and insufficient descriptions of peak-shaving response cap...To adress the problems of insufficient consideration of charging pile resource limitations,discrete-time scheduling methods that do not meet the actual demand and insufficient descriptions of peak-shaving response capability in current electric vehicle(EV)opti-mization scheduling,edge intelligence-oriented electric vehicle optimization scheduling and charging station peak-shaving response capability assessment methods are proposed on the basis of the consideration of electric vehicle and charging pile matching.First,an edge-intelligence-oriented electric vehicle regulation frame for charging stations is proposed.Second,continuous time variables are used to represent the available charging periods,establish the charging station controllable EV load model and the future available charging pile mathematical model,and establish the EV and charging pile matching matrix and constraints.Then,with the goal of maximizing the user charging demand and reducing the charging cost,the charging station EV optimal scheduling model is established,and the EV peak response capacity assessment model is further established by considering the EV load shifting constraints under different peak response capacities.Finally,a typical scenario of a real charging station is taken as an example for the analysis of optimal EV scheduling and peak shaving response capacity,and the proposed method is compared with the traditional method to verify the effectiveness and practicality of the proposed method.展开更多
Resource utilization of chrome shavings(CS)has attracted a lot of attention from scientists and technologists in leather industry.Especially,the collagen hydrolysates extracted from CS are expected to find potential a...Resource utilization of chrome shavings(CS)has attracted a lot of attention from scientists and technologists in leather industry.Especially,the collagen hydrolysates extracted from CS are expected to find potential application values in agricultural field.However,there is no biotoxicity analysis of collagen hydrolysates from CS.Herein,the collagen hydrolysates with different molecular weights were produced from CS by three hydrolysis dechroming methods including alkaline hydrolysis,enzymatic hydrolysis and alkaline-enzymatic synergistic hydrolysis,and the optimal hydrolysis process of CS was designed and conducted.To evaluate their toxicity,the three collagen hydrolysates were formulated into a nutrient solution for zebrafish development.The obtained results indicated that the hydrolysates with low concentrations(less than 0.6 mg/mL)were safe and could promote the development for zebrafish embryos.Furthermore,the three collagen hydrolysates were utilized as organic nitrogen sources and formulated into amino acid water-soluble fertilizers(AAWSF)including alkaline type fertilizer(OH),enzymatic type fertilizer(M)and alkaline-enzymatic type fertilizer(OH-M)for the early soilless seeding cultivation of wheat,soybean and rapeseed.It is worth mentioning that the chromium contents in the prepared AAWSF were less than 10 mg/kg,which is far less than the limit value in the standard(China,50 mg/kg).The growth and development of seedlings(germination rate,plant height,fresh weight of leaves,soluble sugar content and chlorophyll content)were investigated.The corresponding results showed that the growth of seedlings watered with AAWSF was better compared with the other treatments,and the OH-M fertilizer had the best promoting effect on the seedlings growth and development,followed by the M and OH fertilizers.The safe toxicity assessment of the collagen hydrolysates will expand their application scope,and the use of collagen hydrolysates extracted from CS for seedlings growth also provides an effective and reason-able way to deal with the chromium-containing leather solid waste,which is an effective way to realize its resource utilization.展开更多
PART ONEⅠ.用适当的语法形式或词汇填空。从[A]、[B]、[C]、[D]四个选项中,选出一个正确答案。(本大题共30小题,每小题1分,共30分)1. Doctors _parents to give their childrenhealthier snacks such as fruit, vegetables, and juice....PART ONEⅠ.用适当的语法形式或词汇填空。从[A]、[B]、[C]、[D]四个选项中,选出一个正确答案。(本大题共30小题,每小题1分,共30分)1. Doctors _parents to give their childrenhealthier snacks such as fruit, vegetables, and juice.A. inform B. teachC. advise D. help2. He knew that a promotion was_.展开更多
Grid-level large-scale electrical energy storage(GLEES) is an essential approach for balancing the supply–demand of electricity generation, distribution, and usage. Compared with conventional energy storage methods, ...Grid-level large-scale electrical energy storage(GLEES) is an essential approach for balancing the supply–demand of electricity generation, distribution, and usage. Compared with conventional energy storage methods, battery technologies are desirable energy storage devices for GLEES due to their easy modularization, rapid response, flexible installation, and short construction cycles. In general, battery energy storage technologies are expected to meet the requirements of GLEES such as peak shaving and load leveling, voltage and frequency regulation, and emergency response, which are highlighted in this perspective. Furthermore, several types of battery technologies, including lead–acid, nickel–cadmium, nickel–metal hydride, sodium–sulfur, lithium-ion, and flow batteries, are discussed in detail for the application of GLEES. Moreover, some possible developing directions to facilitate efforts in this area are presented to establish a perspective on battery technology, provide a road map for guiding future studies, and promote the commercial application of batteries for GLEES.展开更多
In the electrical energy transformation process,the grid-level energy storage system plays an essential role in balancing power generation and utilization.Batteries have considerable potential for application to grid-...In the electrical energy transformation process,the grid-level energy storage system plays an essential role in balancing power generation and utilization.Batteries have considerable potential for application to grid-level energy storage systems because of their rapid response,modularization,and flexible installation.Among several battery technologies,lithium-ion batteries(LIBs)exhibit high energy efficiency,long cycle life,and relatively high energy density.In this perspective,the properties of LIBs,including their operation mechanism,battery design and construction,and advantages and disadvantages,have been analyzed in detail.Moreover,the performance of LIBs applied to grid-level energy storage systems is analyzed in terms of the following grid services:(1)frequency regulation;(2)peak shifting;(3)integration with renewable energy sources;and(4)power management.In addition,the challenges encountered in the application of LIBs are discussed and possible research directions aimed at overcoming these challenges are proposed to provide insight into the development of grid-level energy storage systems.展开更多
To optimize peaking operation when high proportion new energy accesses to power grid,evaluation indexes are proposed which simultaneously consider wind-solar complementation and source-load coupling.A typical wind-sol...To optimize peaking operation when high proportion new energy accesses to power grid,evaluation indexes are proposed which simultaneously consider wind-solar complementation and source-load coupling.A typical wind-solar power output scene model based on peaking demand is established which has anti-peaking characteristic.This model uses balancing scenes and key scenes with probability distribution based on improved Latin hypercube sampling(LHS)algorithm and scene reduction technology to illustrate the influence of wind-solar on peaking demand.Based on this,a peak shaving operation optimization model of high proportion new energy power generation is established.The various operating indexes after optimization in multi-scene peaking are calculated,and the ability of power grid peaking operation is compared whth that considering wind-solar complementation and source-load coupling.Finally,a case of high proportion new energy verifies the feasibility and validity of the proposed operation strategy.展开更多
China has set carbon emission goals for 2030 and 2060.Renewable energy sources,primarily wind and photovoltaic power,are being considered as the future of power generation.The major limitation to the development of ne...China has set carbon emission goals for 2030 and 2060.Renewable energy sources,primarily wind and photovoltaic power,are being considered as the future of power generation.The major limitation to the development of new energies is the limited flexibility of regulations on power system resources,resulting in insufficient consumption capacity.Thus,the flexible resource costs for peak shaving as well as the reasonable coordinated development and operation optimization of regional renewable energy need to be considered.In this study,a renewable energy development layout configuration analysis method was established by considering the composite cost of a power system,comprehensively analyzing the potential of various flexibility regulation resources for the power system and its composite peak shaving cost,and combining renewable energy output characteristics,load forecasting,grid development,and other factors.For the optimization of various flexible resource utilization methods,a peak shaving cost estimation method from the perspective of the entire power system was established by combining the on-grid electricity prices and operating costs of different power sources.A collaborative optimization model of power system operation that aims at the lowest peak shaving cost and satisfies the constraints of operation,safety,and environmental protection was proposed.Finally,a certain area of Gansu Province was used as an example to perform detailed analysis and calculation,which demonstrated that the model has an optimal effect.This model can provide an analysis method for regional renewable energy development layout configurations and system optimization operations.展开更多
Geopolymers are inorganic aluminosilicate materials,which have been a great research interest as a material for sustainable development.However,they possess relatively low toughness properties similar to brittle solid...Geopolymers are inorganic aluminosilicate materials,which have been a great research interest as a material for sustainable development.However,they possess relatively low toughness properties similar to brittle solids.The limitation may be altered by fiber reinforcement to improve their strength and toughness.This research describes the synthesis of bamboo shaving(BS)reinforced geopolymer composites and the characterization of their mechanical properties.The effect of BS content(0–2 wt.%)on the physical and mechanical properties and microstructure of metakaolin based geopolymer paste were investigated.The workability,setting time,bulk density,apparent porosity,thermal conductivity,compressive strength,flexural strength,scanning electron microscopy(SEM),and X-ray diffraction(XRD)of geopolymer paste were determined.The results showed that the workability,setting time,density,and thermal conductivity decreased with the increasing of BS content.The BS content was proportional to the apparent porosity and a good linear relation was found between apparent porosity and BS content.The highest mechanical properties were achieved at an optimum BS content of 1.0 wt.%.The results of microstructural analysis revealed that BS act as inforcing phase in matrix,reducing cracks and making a dense geopolymer,which leads to favorable adhesion of the composites and produces a geopolymer composite with better mechanical properties than that of pure geopolymer.However,when the BS content exceeded 1.0 wt.%,interfacial bonding between BS and geopolymer matrix became less.XRD analysis showed that BS has little effect on the mineral composition of metakaolin-based geopolymer and no new phase is formed.展开更多
Increasing railway traffic and energy utilization issues prompt electrified railway systems to be more economical,efficient and sustainable.As regenerative braking energy in railway systems has huge potential for opti...Increasing railway traffic and energy utilization issues prompt electrified railway systems to be more economical,efficient and sustainable.As regenerative braking energy in railway systems has huge potential for optimized utilization,a lot of research has been focusing on how to use the energy efficiently and gain sustainable benefits.The energy storage system is an alternative because it not only deals with regenerative braking energy but also smooths drastic fluctuation of load power profile and optimizes energy management.In this work,we propose a co-phase traction power supply system with super capacitor(CSS_SC)for the purpose of realizing the function of energy management and power quality management in electrified railways.Besides,the coordinated control strategy is presented to match four working modes,including traction,regenerative braking,peak shaving and valley filling.A corresponding simulation model is built in MATLAB/Simulink to verify the feasibility of the proposed system under dynamic working conditions.The results demonstrate that CSS_SC is flexible to deal with four different working conditions and can realize energy saving within the allowable voltage unbalance of 0.008%in simulation in contrast to 1.3%of the standard limit.With such a control strategy,the performance of super capacitor is controlled to comply with efficiency and safety constraints.Finally,a case study demonstrates the improvement in power fluctuation with the valley-to-peak ratio reduced by 20.3%and the daily load factor increased by 17.9%.展开更多
This study proposes a combined hybrid energy storage system(HESS) and transmission grid(TG) model, and a corresponding time series operation simulation(TSOS) model is established to relieve the peak-shaving pressure o...This study proposes a combined hybrid energy storage system(HESS) and transmission grid(TG) model, and a corresponding time series operation simulation(TSOS) model is established to relieve the peak-shaving pressure of power systems under the integration of renewable energy. First, a linear model for the optimal operation of the HESS is established, which considers the different power-efficiency characteristics of the pumped storage system, electrochemical storage system, and a new type of liquid compressed air energy storage. Second, a TSOS simulation model for peak shaving is built to maximize the power entering the grid from the wind farms and HESS. Based on the proposed model, this study considers the transmission capacity of a TG. By adding the power-flow constraints of the TG, a TSOS-based HESS and TG combination model for peak shaving is established. Finally, the improved IEEE-39 and IEEE-118 bus systems were considered as examples to verify the effectiveness and feasibility of the proposed model.展开更多
文摘During 2006 and 2011, following the implementation of dioxin contamination monitoring in poultry meat, levels higher than legally allowed in meat from poultry slaughtered for human consumption, were found. The wood shavings used as bedding material in the poultry farm showed considerable high contaminations, indicating that these materials were the likely source of contamination of the animals. Wood shavings samples (n = 23), used as poultry litters in intensive farms of broilers, were analysed. In both episodes, contamination profiles of higher and lower concentrations, seem to be very similar, being OCDD, OCDF, 1,2,3,4,6,7,8-HpCDD and 1,2,3,4,6,7,8-HpCDF responsible for 97.4 % of the total contamination. The present work describes the analytical adapted, used methodology and the specific clean-up procedures, which revealed that recoveries of <sup>13</sup>C<sub>12</sub>-Labelled compounds added to the wood shavings samples ranged from 71.3% to 86.3%.
基金Project supported by the National Key Technology R&D Program of China(No.2012BAK01B03)
文摘Bamboo shavings, the outer or intermediate layer of bamboo stems, are the bulk of by-products produced in bamboo processing. In this study we investigated the isolation, chemical characterization, and immunostimulatory activity in vitro of the hemicelluloses from bamboo shavings. Shavings were first pretreated by steam explosion. The optimal pretreatment was found to be steam explosion at 2.2 MPa for 1 min. Following this pretreatment, the yield of hemicelluloses reached(2.05±0.22)%(based on the dry dewaxed raw materials), which was 5.7-fold higher than that of untreated samples. Bamboo-shavings hemicellulose(BSH) was then prepared by hot water extraction and ethanol precipitation from the steam-exploded shavings. Purification of BSH by anion-exchange chromatography of diethylaminoethanol(DEAE)-sepharose Fast Flow resulted in a neutral fraction(BSH-1, purity of 95.3%, yield of 1.06%) and an acidic fraction(BSH-2, purity of 92.5%, yield of 0.79%). The weight-average molecular weights(Mw) of BSH-1 and BSH-2 were 12 800 and 11 300 g/mol, respectively. Chemical and structural analyses by Fourier transform infrared spectroscopy(FT-IR), 1D(^1H and ^13C) and 2D(heteronuclear single quantum correlation(HSQC)) nuclear magnetic resonance(NMR) spectra revealed that BSH-1 was O-acetylated-arabinoxylan and BSH-2 was O-acetylated-(4-Omethylglucurono)-arabinoxylan. BSH-1 had a higher content of acetyl groups than BSH-2. For the immunomodulatory activity in vitro, BSH and BSH-2 significantly stimulated mouse splenocyte proliferation while BSH-1 had no effect; BSH, BSH-1, and BSH-2 markedly enhanced the phagocytosis activity and nitric oxide production of the murine macrophage RAW264.7 in a dose-dependent manner. Our results suggest that the water-extractable hemicelluloses from steam-exploded bamboo shavings are naturally acetylated and have immunostimulatory activity.
基金the Key Scientific Research Projects of Henan Province,China[grant number 21A430034]National Key R&D Program of China[grant number 2017YFB0308500].
文摘Chrome shavings(CS),a kind of solid wastes discharged from tanneries,always pose serious environmental problems due to the presence of chromium.In this work,kinetic study of the pyrolysis of CS was investigated using a thermogravimetric analyzer in nitrogen atmosphere.The results obtained from the thermogravimetric analysis indicated that there are three stages in the temperature range 25 to 600℃.The second stage is the main weight loss stage and it could be mainly attributed to the pyrolysis of collagenous materials.Iso-conversional and generalized master-plots method were first employed to estimate the activation energy value and possible reaction mechanism of CS pyrolysis.The results showed that the pyrolysis process could not be described accurately by single-step reaction due to the heterogeneous nature of CS.Afterwards,the thermogravimetric kinetic of CS pyrolysis was studied using combined kinetic analysis.It was found that three-parallel-reaction model allowed better fitting relevance for CS pyrolysis.This information was important for simulating and predicting the pyrolysis behaviors of CS.
文摘The reduction of gained heat,heat peak shifting,and the mitigation of air temperature fluctuations are some desirable properties that are sought after in any thermal insulation system.It cannot be overstated that these fac-tors,in addition to others,govern the performance of such systems thus their effect on indoor ambient conditions.The effect of such systems extends also to Heating,Ventilation and Air-conditioning(HVAC)systems that are set up to operate optimally in certain conditions.Where literature shows that PCMs and natural materials such as wood-shavings can provide efficient passive insulation for buildings,it is evident that such approaches utilise methods that are of a degree of intricacy which require specialist knowledge and complex techniques,such as micro-encapsulation for instance.With technical and economic aspects in mind,an amalgam of PCM and wood-shavings has been created to be utilised as a feasible thermal insulation.The amalgamation was performed in the simplest of methods,through submerging the wood shavings in PCM.An experimental procedure was devised to test the thermal performance of the amalgam and compare this to the performance of the same un-amalgamated materials.Comparative analysis revealed that no significant thermal gains would be expected from such amal-gamation.However,a significant reduction in the total weight of the insulation system would be achieved that,in this case,shown to be up to 20.94%.Thus,further reducing possible strains on structural elements due to the application of insulation on buildings.This can be especially beneficial in vernacular architectural approaches where considerably large amounts and thicknesses of insulations are used.In addition,cost reduction could be attained as wood shavings are significantly cheaper compared to the cost of PCMs.
文摘Chromium shavings are wet by-products of the leather industry,of which thousands of tons accrue worldwide during leather manufacture.Due to their chromium content,chromium shavings are responsible for the most important ecological challenges caused by the leather industry.They are stable towards temperatures of up to 110°C and enzymatic degradation.This high stability is caused by the three-dimensional native structure,typical for collagen,and additional chemical cross-links between the collagen fibres achieved by Cr3+salts in the tanning process.Therefore,hitherto chromium shavings are not utilized industrially to produce biogas.In order to generate biogas,this stable structure has to be denatured.Chromium shavings were pre-treated by extrusion and hydrothermal methods.To prove the enzymatic degradability,the different pre-treatments were evaluated by differential scanning calorimetry(DSC),enzymatic assays,and by measuring the solubility in water.The biogas production potential was investigated using batch trials to examine feasibility.Results demonstrated that both pretreatments allowed enzymatic attack and increased degradability of the chromium shavings reducing the lag-phase of biogas production and the remaining waste.
文摘In renewable energy systems,energy storage systems can reduce the power fluctuation of renewable energy sources and compensate for the prediction deviation.However,if the renewable energy prediction deviation is small,the energy storage system may work in an underutilized state.To efficiently utilize a renewable-energy-sided energy storage system(RES),this study proposed an optimization dispatching strategy for an energy storage system considering its unused capacity sharing.First,this study proposed an unused capacity-sharing strategy for the RES to fully utilize the storage’s unused capacity and elevate the storage’s service efficiency.Second,RES was divided into“deviation-compensating energy storage(DES)”and“sharing energy storage(SES)”to clarify the function of RES in the operation process.Third,this study established an optimized dispatching model to achieve the lowest system operating cost wherein the unused capacity-sharing strategy could be integrated.Finally,a case study was investigated,and the results indicated that the proposed model and algorithm effectively improved the utilization of renewable-energy-side energy storage systems,thereby reducing the total operation cost and pressure on peak shaving.
基金support of the projects Youth Science Foundation of Gansu Province(Source-Grid-Load Multi-Time Interval Optimization Scheduling Method Considering Wind-PV-CSP Combined DC Transmission,No.22JR11RA148)Youth Science Foundation of Lanzhou Jiaotong University(Research on Coordinated Dispatching Control Strategy of High Proportion New Energy Transmission Power System with CSP Power Generation,No.2020011).
文摘According to the multi-time-scale characteristics of power generation and demand-side response(DR)resources,as well as the improvement of prediction accuracy along with the approaching operating point,a rolling peak shaving optimization model consisting of three different time scales has been proposed.The proposed peak shaving optimization model considers not only the generation resources of two different response speeds but also the two different DR resources and determines each unit combination,generation power,and demand response strategy on different time scales so as to participate in the peaking of the power system by taking full advantage of the fast response characteristics of the concentrating solar power(CSP).At the same time,in order to improve the accuracy of the scheduling results,the combination of the day-ahead peak shaving phase with scenario-based stochastic programming can further reduce the influence of wind power prediction errors on scheduling results.The testing results have shown that by optimizing the allocation of scheduling resources in each phase,it can effectively reduce the number of starts and stops of thermal power units and improve the economic efficiency of system operation.The spinning reserve capacity is reduced,and the effectiveness of the peak shaving strategy is verified.
文摘In this paper,the combustion conditions in the boiler furnace of a 660 MWtangential fired pulverized coal boiler are numerically simulated at 15%and 20%rated loads,to study the flexibility of coal-fired power units on ultra-low load operation.The numerical results show that the boiler can operate safely at 15%and 20%ultra-low loads,and the combustion condition in the furnace is better at 20%load,and the tangent circles formed by each characteristic section in the furnace are better,and when the boiler load is decreased to 15%,the tangent circles in the furnace begin to deteriorate.The average flue gas temperature of different areas of the furnace shows that when the boiler furnace operates under ultra-low load conditions,the average smoke temperature of the cold ash hopper at 20%load is basically the same as the average smoke temperature at 15%load;in the burner area,the average smoke temperature of the cold ash hopper at 20%load is about 50 K higher than that at 15%load;in the burned out area,the average smoke temperature of the cold ash hopper at 20%load is slightly higher than that at 15%load.The average temperature of flue gas in the furnace showed a tendency to increase rapidly with the height of the furnace,then slow down and fluctuate the temperature in the burner area,and finally increase slightly in the burnout area due to the further combustion of combustible components to release heat,and then began to decrease.
基金supported by the Science and Technology Project of State Grid Jiangsu Electric Power Company(J2023114).
文摘To adress the problems of insufficient consideration of charging pile resource limitations,discrete-time scheduling methods that do not meet the actual demand and insufficient descriptions of peak-shaving response capability in current electric vehicle(EV)opti-mization scheduling,edge intelligence-oriented electric vehicle optimization scheduling and charging station peak-shaving response capability assessment methods are proposed on the basis of the consideration of electric vehicle and charging pile matching.First,an edge-intelligence-oriented electric vehicle regulation frame for charging stations is proposed.Second,continuous time variables are used to represent the available charging periods,establish the charging station controllable EV load model and the future available charging pile mathematical model,and establish the EV and charging pile matching matrix and constraints.Then,with the goal of maximizing the user charging demand and reducing the charging cost,the charging station EV optimal scheduling model is established,and the EV peak response capacity assessment model is further established by considering the EV load shifting constraints under different peak response capacities.Finally,a typical scenario of a real charging station is taken as an example for the analysis of optimal EV scheduling and peak shaving response capacity,and the proposed method is compared with the traditional method to verify the effectiveness and practicality of the proposed method.
基金the Science&Technology Department of Sichuan Province(No.2018HH0038)is gratefully acknowledged.
文摘Resource utilization of chrome shavings(CS)has attracted a lot of attention from scientists and technologists in leather industry.Especially,the collagen hydrolysates extracted from CS are expected to find potential application values in agricultural field.However,there is no biotoxicity analysis of collagen hydrolysates from CS.Herein,the collagen hydrolysates with different molecular weights were produced from CS by three hydrolysis dechroming methods including alkaline hydrolysis,enzymatic hydrolysis and alkaline-enzymatic synergistic hydrolysis,and the optimal hydrolysis process of CS was designed and conducted.To evaluate their toxicity,the three collagen hydrolysates were formulated into a nutrient solution for zebrafish development.The obtained results indicated that the hydrolysates with low concentrations(less than 0.6 mg/mL)were safe and could promote the development for zebrafish embryos.Furthermore,the three collagen hydrolysates were utilized as organic nitrogen sources and formulated into amino acid water-soluble fertilizers(AAWSF)including alkaline type fertilizer(OH),enzymatic type fertilizer(M)and alkaline-enzymatic type fertilizer(OH-M)for the early soilless seeding cultivation of wheat,soybean and rapeseed.It is worth mentioning that the chromium contents in the prepared AAWSF were less than 10 mg/kg,which is far less than the limit value in the standard(China,50 mg/kg).The growth and development of seedlings(germination rate,plant height,fresh weight of leaves,soluble sugar content and chlorophyll content)were investigated.The corresponding results showed that the growth of seedlings watered with AAWSF was better compared with the other treatments,and the OH-M fertilizer had the best promoting effect on the seedlings growth and development,followed by the M and OH fertilizers.The safe toxicity assessment of the collagen hydrolysates will expand their application scope,and the use of collagen hydrolysates extracted from CS for seedlings growth also provides an effective and reason-able way to deal with the chromium-containing leather solid waste,which is an effective way to realize its resource utilization.
文摘PART ONEⅠ.用适当的语法形式或词汇填空。从[A]、[B]、[C]、[D]四个选项中,选出一个正确答案。(本大题共30小题,每小题1分,共30分)1. Doctors _parents to give their childrenhealthier snacks such as fruit, vegetables, and juice.A. inform B. teachC. advise D. help2. He knew that a promotion was_.
文摘Grid-level large-scale electrical energy storage(GLEES) is an essential approach for balancing the supply–demand of electricity generation, distribution, and usage. Compared with conventional energy storage methods, battery technologies are desirable energy storage devices for GLEES due to their easy modularization, rapid response, flexible installation, and short construction cycles. In general, battery energy storage technologies are expected to meet the requirements of GLEES such as peak shaving and load leveling, voltage and frequency regulation, and emergency response, which are highlighted in this perspective. Furthermore, several types of battery technologies, including lead–acid, nickel–cadmium, nickel–metal hydride, sodium–sulfur, lithium-ion, and flow batteries, are discussed in detail for the application of GLEES. Moreover, some possible developing directions to facilitate efforts in this area are presented to establish a perspective on battery technology, provide a road map for guiding future studies, and promote the commercial application of batteries for GLEES.
文摘In the electrical energy transformation process,the grid-level energy storage system plays an essential role in balancing power generation and utilization.Batteries have considerable potential for application to grid-level energy storage systems because of their rapid response,modularization,and flexible installation.Among several battery technologies,lithium-ion batteries(LIBs)exhibit high energy efficiency,long cycle life,and relatively high energy density.In this perspective,the properties of LIBs,including their operation mechanism,battery design and construction,and advantages and disadvantages,have been analyzed in detail.Moreover,the performance of LIBs applied to grid-level energy storage systems is analyzed in terms of the following grid services:(1)frequency regulation;(2)peak shifting;(3)integration with renewable energy sources;and(4)power management.In addition,the challenges encountered in the application of LIBs are discussed and possible research directions aimed at overcoming these challenges are proposed to provide insight into the development of grid-level energy storage systems.
基金Youth Science and Technology Fund Project of Gansu Province(No.18JR3RA011)Major Projects in Gansu Province(No.17ZD2GA010)+1 种基金Science and Technology Projects Funding of State Grid Corporation(No.522727160001)Science and Technology Projects of State Grid Gansu Electric Power Company(No.52272716000K)
文摘To optimize peaking operation when high proportion new energy accesses to power grid,evaluation indexes are proposed which simultaneously consider wind-solar complementation and source-load coupling.A typical wind-solar power output scene model based on peaking demand is established which has anti-peaking characteristic.This model uses balancing scenes and key scenes with probability distribution based on improved Latin hypercube sampling(LHS)algorithm and scene reduction technology to illustrate the influence of wind-solar on peaking demand.Based on this,a peak shaving operation optimization model of high proportion new energy power generation is established.The various operating indexes after optimization in multi-scene peaking are calculated,and the ability of power grid peaking operation is compared whth that considering wind-solar complementation and source-load coupling.Finally,a case of high proportion new energy verifies the feasibility and validity of the proposed operation strategy.
基金the National Natural Science Foundation of China(No.71273088).
文摘China has set carbon emission goals for 2030 and 2060.Renewable energy sources,primarily wind and photovoltaic power,are being considered as the future of power generation.The major limitation to the development of new energies is the limited flexibility of regulations on power system resources,resulting in insufficient consumption capacity.Thus,the flexible resource costs for peak shaving as well as the reasonable coordinated development and operation optimization of regional renewable energy need to be considered.In this study,a renewable energy development layout configuration analysis method was established by considering the composite cost of a power system,comprehensively analyzing the potential of various flexibility regulation resources for the power system and its composite peak shaving cost,and combining renewable energy output characteristics,load forecasting,grid development,and other factors.For the optimization of various flexible resource utilization methods,a peak shaving cost estimation method from the perspective of the entire power system was established by combining the on-grid electricity prices and operating costs of different power sources.A collaborative optimization model of power system operation that aims at the lowest peak shaving cost and satisfies the constraints of operation,safety,and environmental protection was proposed.Finally,a certain area of Gansu Province was used as an example to perform detailed analysis and calculation,which demonstrated that the model has an optimal effect.This model can provide an analysis method for regional renewable energy development layout configurations and system optimization operations.
基金the Excellent Youth Foundation of Education Department of Hunan Province,China(20B612)Changsha Natural Science Foundation of China(kq2014158).
文摘Geopolymers are inorganic aluminosilicate materials,which have been a great research interest as a material for sustainable development.However,they possess relatively low toughness properties similar to brittle solids.The limitation may be altered by fiber reinforcement to improve their strength and toughness.This research describes the synthesis of bamboo shaving(BS)reinforced geopolymer composites and the characterization of their mechanical properties.The effect of BS content(0–2 wt.%)on the physical and mechanical properties and microstructure of metakaolin based geopolymer paste were investigated.The workability,setting time,bulk density,apparent porosity,thermal conductivity,compressive strength,flexural strength,scanning electron microscopy(SEM),and X-ray diffraction(XRD)of geopolymer paste were determined.The results showed that the workability,setting time,density,and thermal conductivity decreased with the increasing of BS content.The BS content was proportional to the apparent porosity and a good linear relation was found between apparent porosity and BS content.The highest mechanical properties were achieved at an optimum BS content of 1.0 wt.%.The results of microstructural analysis revealed that BS act as inforcing phase in matrix,reducing cracks and making a dense geopolymer,which leads to favorable adhesion of the composites and produces a geopolymer composite with better mechanical properties than that of pure geopolymer.However,when the BS content exceeded 1.0 wt.%,interfacial bonding between BS and geopolymer matrix became less.XRD analysis showed that BS has little effect on the mineral composition of metakaolin-based geopolymer and no new phase is formed.
文摘Increasing railway traffic and energy utilization issues prompt electrified railway systems to be more economical,efficient and sustainable.As regenerative braking energy in railway systems has huge potential for optimized utilization,a lot of research has been focusing on how to use the energy efficiently and gain sustainable benefits.The energy storage system is an alternative because it not only deals with regenerative braking energy but also smooths drastic fluctuation of load power profile and optimizes energy management.In this work,we propose a co-phase traction power supply system with super capacitor(CSS_SC)for the purpose of realizing the function of energy management and power quality management in electrified railways.Besides,the coordinated control strategy is presented to match four working modes,including traction,regenerative braking,peak shaving and valley filling.A corresponding simulation model is built in MATLAB/Simulink to verify the feasibility of the proposed system under dynamic working conditions.The results demonstrate that CSS_SC is flexible to deal with four different working conditions and can realize energy saving within the allowable voltage unbalance of 0.008%in simulation in contrast to 1.3%of the standard limit.With such a control strategy,the performance of super capacitor is controlled to comply with efficiency and safety constraints.Finally,a case study demonstrates the improvement in power fluctuation with the valley-to-peak ratio reduced by 20.3%and the daily load factor increased by 17.9%.
基金supported by the State Grid Science and Technology Project (No.52999821N004)。
文摘This study proposes a combined hybrid energy storage system(HESS) and transmission grid(TG) model, and a corresponding time series operation simulation(TSOS) model is established to relieve the peak-shaving pressure of power systems under the integration of renewable energy. First, a linear model for the optimal operation of the HESS is established, which considers the different power-efficiency characteristics of the pumped storage system, electrochemical storage system, and a new type of liquid compressed air energy storage. Second, a TSOS simulation model for peak shaving is built to maximize the power entering the grid from the wind farms and HESS. Based on the proposed model, this study considers the transmission capacity of a TG. By adding the power-flow constraints of the TG, a TSOS-based HESS and TG combination model for peak shaving is established. Finally, the improved IEEE-39 and IEEE-118 bus systems were considered as examples to verify the effectiveness and feasibility of the proposed model.