As one of the most promising propulsion systems in the future,shock-induced combustion ramjet engine can remedy the disadvantages in the integrated design of scramjet engine and airframe.It can shorten the length of t...As one of the most promising propulsion systems in the future,shock-induced combustion ramjet engine can remedy the disadvantages in the integrated design of scramjet engine and airframe.It can shorten the length of the combustor,lighten the structure weight of the engine and keep better performance in a broad range of flight Mach number.The elementary principle of shock-induced combustion ramjet engine is introduced.The key technologies of this kind of propulsion system are described,while their research status is presented in detail.Suggestion on the development of shcramjet engine in China is put forward.展开更多
Element W can effectively improve the density of energetic structural materials. However, W is an inert element and does not combust in air. To change the reaction characteristics of W, 60 at.% Al was introduced into ...Element W can effectively improve the density of energetic structural materials. However, W is an inert element and does not combust in air. To change the reaction characteristics of W, 60 at.% Al was introduced into W through mechanical alloying. XRD analysis shows that after 50 h of ball milling, the diffraction peak of Al completely disappears and W(Al60) super-saturated solid solution powder is obtained. Further observation by HAADF and HRTEM reveals that the W(Al60) super-saturated solid solution powder is a mixture of solid solution and amorphous phase. Based on the good thermal stability of W(Al60) alloy powder below 1000℃, W(Al60)-Al composite was synthesized by hot pressing process.Impact initiation experiments suggest that the W(Al60)-Al composite has excellent reaction characteristics, and multiple types of tungsten oxides are detected in the reaction products, showing that the modified W is combustible in air. Due to the combustion of tungsten, the energy release rate of the W(Al60)-Al composite at speed of 1362 m/s reaches 2.71 kJ/g.展开更多
We investigate experimentally and analytically the combustion behavior of a high-metal magnesium-based hydro- reactive fuel under high temperature gaseous atmosphere. The fuel studied in this paper contains 73% magnes...We investigate experimentally and analytically the combustion behavior of a high-metal magnesium-based hydro- reactive fuel under high temperature gaseous atmosphere. The fuel studied in this paper contains 73% magnesium powders. An experimental system is designed and experiments are carried out in both argon and water vapor atmo- spheres. It is found that the burning surface temperature of the fuel is higher in water vapor than that in argon and both of them are higher than the melting point of magnesium, which indicates the molten state of magnesium particles in the burning surface of the fuel. Based on physical considerations and experimental results, a mathematical one-dimensional model is formulated to describe the combustion behavior of the high-metal magnesium-based hydro-reactive fuel. The model enables the evaluation of the burning surface temperature, the burning rate and the flame standoff distance each as a function of chamber pressure and water vapor concentration. The results predicted by the model show that the burning rate and the surface temperature increase when the chamber pressure and the water vapor concentration increase, which are in agreement with the observed experimental trends.展开更多
In this study,boron–magnesium agglomerates with varying mass ratios were prepared by drying a micron-sized boron–magnesium mixed suspension,and the combustion process of these agglomerates under different oxygen-ric...In this study,boron–magnesium agglomerates with varying mass ratios were prepared by drying a micron-sized boron–magnesium mixed suspension,and the combustion process of these agglomerates under different oxygen-rich concentrations were investigated using a laser ignition system.The test results showed that when the mass fraction of magnesium powder in boron-magnesium agglomerates exceeded a certain threshold(between 2%and 5%),flame extinction and reignition occurred after a significant reduction in the agglomerate volume during combustion.This process is referred to as the transient flameout process,which is affected by the magnesium content of the agglomerate and the oxygen concentration in the ambient atmosphere.An increase in the magnesium content or oxygen concentration makes this phenomenon more pronounced.During weakening of the flame intensity,a dark film gradually covered the particle surfaces.X-ray diffraction and elemental analyses of the cross-section and outer surface of the condensed combustion product suggested that the dark film is primarily composed of Mg-B-O ternary oxides.This film prevents direct contact between boron and oxygen,thereby inhibiting surface and gas-phase reactions and leading to the occurrence of the transient flameout phenomenon.展开更多
Experiments were conducted to determine the effects of the mixing section configurations on the Mg-CO_(2)Martian ramjet combustion efficiency.It was carried out at a mainstream mass flow rate of 110 g/s and a temperat...Experiments were conducted to determine the effects of the mixing section configurations on the Mg-CO_(2)Martian ramjet combustion efficiency.It was carried out at a mainstream mass flow rate of 110 g/s and a temperature of 810 K.The chamber pressure was measured under different configurations and Oxidizer to Fuel(O/F)ratios.Results showed that the engine achieved self-sustaining combustion and worked stably during experiments.The pre-combustion chamber is needed to increase the combustion efficiency and promote the full combustion of the powder.After the configuration of the pre-combustion chamber,the best combustion efficiency reached 80%when radial powder injection and lateral carbon dioxide intake were used.In addition,the O/F ratio in the pre-combustion chamber decreased from 0.67 to 0.31,resulting in an 8%increase in the combustion efficiency.It was speculated that different mixing section configurations and the variations in an O/F ratio within the pre-combustion chamber impacted the combustion efficiency and in essence,all affected the flow velocity and residence time of the two-phase flow in the com-bustion chamber.展开更多
In ramjet combustion chambers,carbon dioxide(CO_(2))produced by the combustion of carbonaceous fuel enters the chamber together with boron agglomerates.In order to investigate the effect of CO_(2)concentration present...In ramjet combustion chambers,carbon dioxide(CO_(2))produced by the combustion of carbonaceous fuel enters the chamber together with boron agglomerates.In order to investigate the effect of CO_(2)concentration present in an oxygen-containing atmosphere on the combustion characteristics and oxidation mechanisms of boron agglomerates,we used a laser ignition system,an X-ray diffractometer(XRD),and a thermogravimetric-differential scanning calorimetry(TG-DSC)combined thermal analysis system.Single-particle boron was tested in the laser-ignition experiments as the control group.The ignition experiment results showed that with a fixed O2 concentration of 20%,when the particle temperature reaches the melting point of boron,increasing CO_(2)content causes the combustion process of boron agglomerates to transition from single-particle molten droplet combustion to porous-particle combustion.Furthermore,XRD analysis results indicated that the condensed-phase combustion products(CCPs)of boron particles in a mixed atmosphere of O2 and CO_(2)contained B4C,which is responsible for the porous structure of the particles.At temperatures below 1200℃,the addition of CO_(2)has no obvious promotion effect on boron exothermic reaction.However,in the laser-ignition experiment,when the oxygen concentration was fixed at 20%while the CO_(2)concentration increased from 0%to 80%,the maximum temperature of boron agglomerates rose from 2434 to 2573 K,the self-sustaining combustion time of single-particle boron decreased from 396 to 169 ms,and the self-sustaining combustion time of boron agglomerates decreased from 198 to 40 ms.This study conclusively showed that adding CO_(2)to an oxygen-containing atmosphere facilitates boron reaction and consumption pathways,which is beneficial to promoting exothermic reaction of boron agglomerates at relatively high temperatures.展开更多
基金supported by the National Natural Science Foundation of China (Grant No.90816016)the Excellent Student Innovative Project of National University of Defense Technology (Grant No.B070101)the Hunan Provincial Innovation Foundation for Postgraduate (Grant No.3206)
文摘As one of the most promising propulsion systems in the future,shock-induced combustion ramjet engine can remedy the disadvantages in the integrated design of scramjet engine and airframe.It can shorten the length of the combustor,lighten the structure weight of the engine and keep better performance in a broad range of flight Mach number.The elementary principle of shock-induced combustion ramjet engine is introduced.The key technologies of this kind of propulsion system are described,while their research status is presented in detail.Suggestion on the development of shcramjet engine in China is put forward.
基金supported by the National Natural Science Foundation of China, [Award number: 11972372] and [Award number: U20A20231]。
文摘Element W can effectively improve the density of energetic structural materials. However, W is an inert element and does not combust in air. To change the reaction characteristics of W, 60 at.% Al was introduced into W through mechanical alloying. XRD analysis shows that after 50 h of ball milling, the diffraction peak of Al completely disappears and W(Al60) super-saturated solid solution powder is obtained. Further observation by HAADF and HRTEM reveals that the W(Al60) super-saturated solid solution powder is a mixture of solid solution and amorphous phase. Based on the good thermal stability of W(Al60) alloy powder below 1000℃, W(Al60)-Al composite was synthesized by hot pressing process.Impact initiation experiments suggest that the W(Al60)-Al composite has excellent reaction characteristics, and multiple types of tungsten oxides are detected in the reaction products, showing that the modified W is combustible in air. Due to the combustion of tungsten, the energy release rate of the W(Al60)-Al composite at speed of 1362 m/s reaches 2.71 kJ/g.
基金Project supported by the Young Scientist Fund of the National Natural Science Foundation of China(Grant No.51006118)
文摘We investigate experimentally and analytically the combustion behavior of a high-metal magnesium-based hydro- reactive fuel under high temperature gaseous atmosphere. The fuel studied in this paper contains 73% magnesium powders. An experimental system is designed and experiments are carried out in both argon and water vapor atmo- spheres. It is found that the burning surface temperature of the fuel is higher in water vapor than that in argon and both of them are higher than the melting point of magnesium, which indicates the molten state of magnesium particles in the burning surface of the fuel. Based on physical considerations and experimental results, a mathematical one-dimensional model is formulated to describe the combustion behavior of the high-metal magnesium-based hydro-reactive fuel. The model enables the evaluation of the burning surface temperature, the burning rate and the flame standoff distance each as a function of chamber pressure and water vapor concentration. The results predicted by the model show that the burning rate and the surface temperature increase when the chamber pressure and the water vapor concentration increase, which are in agreement with the observed experimental trends.
基金financial support provided by the National Natural Science Foundation of China(grant No.52006240)supported by Hunan Provincial Natural Science Foundation of China(grant No.2020JJ4665 and No.2021JJ30775).
文摘In this study,boron–magnesium agglomerates with varying mass ratios were prepared by drying a micron-sized boron–magnesium mixed suspension,and the combustion process of these agglomerates under different oxygen-rich concentrations were investigated using a laser ignition system.The test results showed that when the mass fraction of magnesium powder in boron-magnesium agglomerates exceeded a certain threshold(between 2%and 5%),flame extinction and reignition occurred after a significant reduction in the agglomerate volume during combustion.This process is referred to as the transient flameout process,which is affected by the magnesium content of the agglomerate and the oxygen concentration in the ambient atmosphere.An increase in the magnesium content or oxygen concentration makes this phenomenon more pronounced.During weakening of the flame intensity,a dark film gradually covered the particle surfaces.X-ray diffraction and elemental analyses of the cross-section and outer surface of the condensed combustion product suggested that the dark film is primarily composed of Mg-B-O ternary oxides.This film prevents direct contact between boron and oxygen,thereby inhibiting surface and gas-phase reactions and leading to the occurrence of the transient flameout phenomenon.
基金supported by the Fund of Advance Research Projects of Manned Spaceflight,China(No.050303).
文摘Experiments were conducted to determine the effects of the mixing section configurations on the Mg-CO_(2)Martian ramjet combustion efficiency.It was carried out at a mainstream mass flow rate of 110 g/s and a temperature of 810 K.The chamber pressure was measured under different configurations and Oxidizer to Fuel(O/F)ratios.Results showed that the engine achieved self-sustaining combustion and worked stably during experiments.The pre-combustion chamber is needed to increase the combustion efficiency and promote the full combustion of the powder.After the configuration of the pre-combustion chamber,the best combustion efficiency reached 80%when radial powder injection and lateral carbon dioxide intake were used.In addition,the O/F ratio in the pre-combustion chamber decreased from 0.67 to 0.31,resulting in an 8%increase in the combustion efficiency.It was speculated that different mixing section configurations and the variations in an O/F ratio within the pre-combustion chamber impacted the combustion efficiency and in essence,all affected the flow velocity and residence time of the two-phase flow in the com-bustion chamber.
基金the National Natural Science Foundation of China(No.52006240)the Hunan Provincial Natural Science Foundation of China(Nos.2020JJ4665 and 2021JJ30775).
文摘In ramjet combustion chambers,carbon dioxide(CO_(2))produced by the combustion of carbonaceous fuel enters the chamber together with boron agglomerates.In order to investigate the effect of CO_(2)concentration present in an oxygen-containing atmosphere on the combustion characteristics and oxidation mechanisms of boron agglomerates,we used a laser ignition system,an X-ray diffractometer(XRD),and a thermogravimetric-differential scanning calorimetry(TG-DSC)combined thermal analysis system.Single-particle boron was tested in the laser-ignition experiments as the control group.The ignition experiment results showed that with a fixed O2 concentration of 20%,when the particle temperature reaches the melting point of boron,increasing CO_(2)content causes the combustion process of boron agglomerates to transition from single-particle molten droplet combustion to porous-particle combustion.Furthermore,XRD analysis results indicated that the condensed-phase combustion products(CCPs)of boron particles in a mixed atmosphere of O2 and CO_(2)contained B4C,which is responsible for the porous structure of the particles.At temperatures below 1200℃,the addition of CO_(2)has no obvious promotion effect on boron exothermic reaction.However,in the laser-ignition experiment,when the oxygen concentration was fixed at 20%while the CO_(2)concentration increased from 0%to 80%,the maximum temperature of boron agglomerates rose from 2434 to 2573 K,the self-sustaining combustion time of single-particle boron decreased from 396 to 169 ms,and the self-sustaining combustion time of boron agglomerates decreased from 198 to 40 ms.This study conclusively showed that adding CO_(2)to an oxygen-containing atmosphere facilitates boron reaction and consumption pathways,which is beneficial to promoting exothermic reaction of boron agglomerates at relatively high temperatures.