Phase chemical relation of quaternary systems KBr-REBr3-HBr (13%)-H2O (25℃, RE=La, Sm) were determined, and the rule of phase change was also discovered bere when RE are light rare earth elements. It is found from th...Phase chemical relation of quaternary systems KBr-REBr3-HBr (13%)-H2O (25℃, RE=La, Sm) were determined, and the rule of phase change was also discovered bere when RE are light rare earth elements. It is found from the experiment that the quaternary systems in which KBr and REBr3 react in hydrobromic acid belong to a simple eutectic type,so the reaction mechanism for synthesizing compound K2REBr5 type and real action of the first step reaction can be explained with Meyer’s method. Furthermore, it can be seen from comparison between the systems in this paper and the system CsBr-REBr-HBr (13%)-H2O (25℃) that CsBr and REBr3 acting in hydrobromic acid with each other can form doublecompound easier than KBr and REBr3.展开更多
Solubilities and properties (density, conductivity and pH value) of solutions in the quaternary system Li +,K +//CO 2- 3,B 4O 2- 7-H 2O at 288 K were experimentally studied with the isothermal equilibrium method. The ...Solubilities and properties (density, conductivity and pH value) of solutions in the quaternary system Li +,K +//CO 2- 3,B 4O 2- 7-H 2O at 288 K were experimentally studied with the isothermal equilibrium method. The phase diagram of the system consisted of two invariant points E and F, five univariant curves, and four crystallization fields that belonged to K 2CO 3·3/2H 2O,Li 2 B 4O 7·3H 2O, K 2 B 4O 7 ·4H 2O and Li 2CO 3. The composition of the solution corresponding to E was w(CO 2- 3)=2.27 %, w(B 4O 2- 7) =6.05 %, w(K + ) =4.30%,w(Li + )=0.30 % and the equilibrium solids were Li 2 B 4O 7· 3H 2O+K 2 B 4O 7·4H 2O+Li 2CO 3;The composition of the solution for F was w(CO 2- 3) =22.45%,w(B 4O 2- 7)=1.88%,w(K + )=29.96%,w(Li + )=0.03% and the equilibrium solids were K 2CO 3·3/2H 2O+ K 2 B 4O 7·4H 2O+Li 2CO 3. K 2CO 3 possesses strong salting-out effect on K 2 B 4O 7,Li 2CO 3 and Li 2 B 4O 7.展开更多
文摘Phase chemical relation of quaternary systems KBr-REBr3-HBr (13%)-H2O (25℃, RE=La, Sm) were determined, and the rule of phase change was also discovered bere when RE are light rare earth elements. It is found from the experiment that the quaternary systems in which KBr and REBr3 react in hydrobromic acid belong to a simple eutectic type,so the reaction mechanism for synthesizing compound K2REBr5 type and real action of the first step reaction can be explained with Meyer’s method. Furthermore, it can be seen from comparison between the systems in this paper and the system CsBr-REBr-HBr (13%)-H2O (25℃) that CsBr and REBr3 acting in hydrobromic acid with each other can form doublecompound easier than KBr and REBr3.
文摘Solubilities and properties (density, conductivity and pH value) of solutions in the quaternary system Li +,K +//CO 2- 3,B 4O 2- 7-H 2O at 288 K were experimentally studied with the isothermal equilibrium method. The phase diagram of the system consisted of two invariant points E and F, five univariant curves, and four crystallization fields that belonged to K 2CO 3·3/2H 2O,Li 2 B 4O 7·3H 2O, K 2 B 4O 7 ·4H 2O and Li 2CO 3. The composition of the solution corresponding to E was w(CO 2- 3)=2.27 %, w(B 4O 2- 7) =6.05 %, w(K + ) =4.30%,w(Li + )=0.30 % and the equilibrium solids were Li 2 B 4O 7· 3H 2O+K 2 B 4O 7·4H 2O+Li 2CO 3;The composition of the solution for F was w(CO 2- 3) =22.45%,w(B 4O 2- 7)=1.88%,w(K + )=29.96%,w(Li + )=0.03% and the equilibrium solids were K 2CO 3·3/2H 2O+ K 2 B 4O 7·4H 2O+Li 2CO 3. K 2CO 3 possesses strong salting-out effect on K 2 B 4O 7,Li 2CO 3 and Li 2 B 4O 7.
