The research studies the effect of the distance between the sample and the plasma sputtering source on the properties of the junction (silicon wafer-carbon nanotubes). The silicon wafer is fixed at (near, medium and f...The research studies the effect of the distance between the sample and the plasma sputtering source on the properties of the junction (silicon wafer-carbon nanotubes). The silicon wafer is fixed at (near, medium and far distances from the plasma source which is in the form of high purity graphite rod heated electrically). For the three cases, thickness of the sample is constant (20 nm). The samples were studied by scanning electron (SEM) and atomic force microscopes (AFM), X-ray and Raman spectra. For optimum distances the carbon layer is in the form of multi wall carbon nanotube (MWCNT). SEM images shows no formation of CNT on the Si wafer for near distance, which is consistent with the AFM images, X-ray and Raman spectrograms and no existence of characteristics (002) peaks whereas it appears for medium and longer distances, and by experience the optimum distance was found. This means that at closer distance high energy and high intensity plasma particles prevent the formation of CNT. This effect decreases with increasing distance of substrate from the graphite rod.展开更多
由于碳包覆能有效抑制硅材料在循环过程中的体积变化,减缓颗粒粉碎和无法形成稳定SEI膜的问题,提升原材料的电化学性能,因此我们制备了一种形貌均匀的Si/C/CNT负极材料。多巴胺热解形成的碳层能有效抑制硅的体积膨胀,而在外部的碳纳米...由于碳包覆能有效抑制硅材料在循环过程中的体积变化,减缓颗粒粉碎和无法形成稳定SEI膜的问题,提升原材料的电化学性能,因此我们制备了一种形貌均匀的Si/C/CNT负极材料。多巴胺热解形成的碳层能有效抑制硅的体积膨胀,而在外部的碳纳米管不仅协助抑制硅体积膨胀,而且提供了电子传导的通道,从而使材料表现出优异的电化学性能。测试产物的电化学性能结果显示:在0.42 A g-1倍率下,首次放电比容量分别为1500 m Ah g-1,经过100次循环后放电比容量为978 m Ah g-1,其容量保持率为65.2%。展开更多
Multi-walled carbon nanotubes (CNTs) were grown on silicon nanoporous pillar array (Si-NPA) by thermal chemical vapor deposition method, and the structural and capacitive humidity sensing properties of CNT/Si-NPA were...Multi-walled carbon nanotubes (CNTs) were grown on silicon nanoporous pillar array (Si-NPA) by thermal chemical vapor deposition method, and the structural and capacitive humidity sensing properties of CNT/Si-NPA were studied. It was found that with the relative humidity (RH) changing from 11% to 95%, a device re-sponse of ~480% was achieved at the frequency of 50000 Hz, and a linear device response curve could be obtained by adopting longitudinal logarithmic coordinate. The response/recovery times were measured to be ~20 s and ~10 s, respectively, which indicated a rather fast response/recovery rate. The adsorption-desorption dynamic cycle experiments demonstrated the high measurement reproducibility of CNT/Si-NPA sensors. These excellent performances were attributed to the unique surface structure, morphology and chemical inertness of CNT/Si-NPA.展开更多
文摘The research studies the effect of the distance between the sample and the plasma sputtering source on the properties of the junction (silicon wafer-carbon nanotubes). The silicon wafer is fixed at (near, medium and far distances from the plasma source which is in the form of high purity graphite rod heated electrically). For the three cases, thickness of the sample is constant (20 nm). The samples were studied by scanning electron (SEM) and atomic force microscopes (AFM), X-ray and Raman spectra. For optimum distances the carbon layer is in the form of multi wall carbon nanotube (MWCNT). SEM images shows no formation of CNT on the Si wafer for near distance, which is consistent with the AFM images, X-ray and Raman spectrograms and no existence of characteristics (002) peaks whereas it appears for medium and longer distances, and by experience the optimum distance was found. This means that at closer distance high energy and high intensity plasma particles prevent the formation of CNT. This effect decreases with increasing distance of substrate from the graphite rod.
文摘由于碳包覆能有效抑制硅材料在循环过程中的体积变化,减缓颗粒粉碎和无法形成稳定SEI膜的问题,提升原材料的电化学性能,因此我们制备了一种形貌均匀的Si/C/CNT负极材料。多巴胺热解形成的碳层能有效抑制硅的体积膨胀,而在外部的碳纳米管不仅协助抑制硅体积膨胀,而且提供了电子传导的通道,从而使材料表现出优异的电化学性能。测试产物的电化学性能结果显示:在0.42 A g-1倍率下,首次放电比容量分别为1500 m Ah g-1,经过100次循环后放电比容量为978 m Ah g-1,其容量保持率为65.2%。
基金Supported by the National Natural Science Foundation of China (Grant No. 10574112)
文摘Multi-walled carbon nanotubes (CNTs) were grown on silicon nanoporous pillar array (Si-NPA) by thermal chemical vapor deposition method, and the structural and capacitive humidity sensing properties of CNT/Si-NPA were studied. It was found that with the relative humidity (RH) changing from 11% to 95%, a device re-sponse of ~480% was achieved at the frequency of 50000 Hz, and a linear device response curve could be obtained by adopting longitudinal logarithmic coordinate. The response/recovery times were measured to be ~20 s and ~10 s, respectively, which indicated a rather fast response/recovery rate. The adsorption-desorption dynamic cycle experiments demonstrated the high measurement reproducibility of CNT/Si-NPA sensors. These excellent performances were attributed to the unique surface structure, morphology and chemical inertness of CNT/Si-NPA.
