将碳化硅(SiC)粉体与一定量的聚乙二醇(PEG)、四甲基氢氧化铵(TMAH)、羧甲基纤维素钠(CMC-Na)及去离子水和乙醇混合并球磨3 h制备出低浓度SiC浆料,研究了SiC浆料p H值与其Zeta电位对应关系和添加组分变化对浆料分散稳定性的影响。结果表...将碳化硅(SiC)粉体与一定量的聚乙二醇(PEG)、四甲基氢氧化铵(TMAH)、羧甲基纤维素钠(CMC-Na)及去离子水和乙醇混合并球磨3 h制备出低浓度SiC浆料,研究了SiC浆料p H值与其Zeta电位对应关系和添加组分变化对浆料分散稳定性的影响。结果表明,当p H=8.5时,浆料有最大动电位-37.76 m V,当m(TMAH)∶m(SiC)=1.5%、m(CMC-Na)∶m(SiC)=0.4%时,浆料的表观黏度最小为4.31 m Pa·s,浆料的相对沉降高度最小,浆料的分散稳定性能较佳。利用该浆料在多孔碳化硅陶瓷表面进行涂膜并高温烧成后制备了碳化硅膜并对碳化硅膜的显微结构与其孔径进行了分析表征,结果表明该浆料成膜性能良好,SiC膜晶粒周边圆润、堆积均匀,物相单一,膜孔径分布较窄,平均孔径约为1μm。展开更多
To improve the ablation resistance of carbon/carbon(C/C)composites,a SiC/ZrC-ZrB2 double layer coating was fabricated by pack cementation and slurry-sintering method.The ablation resistance of the SiC/ZrC-ZrB2 coating...To improve the ablation resistance of carbon/carbon(C/C)composites,a SiC/ZrC-ZrB2 double layer coating was fabricated by pack cementation and slurry-sintering method.The ablation resistance of the SiC/ZrC-ZrB2 coating was tested under plasma flame above 2300°C.The results indicate that the SiC/ZrC-ZrB2 double layer coating exhibits superior ablation resistance than the ZrC-ZrB2 single layer coating.After being ablated under the plasma flame for 20 s,the mass and linear ablation rates of the ZrC-ZrB2 coating are 0.89 mg/s and 15.3μm/s,while those for SiC/ZrC-ZrB2 coating are 0.09 mg/s and 24.15μm/s,respectively.During ablation,the SiC inner layer can generate SiO2 glass and result in the formation of ZrO2-SiO2 molten film.Compared with the ZrO2 molten film formed on the ZrC-ZrB2 coating surface,the ZrO2-SiO2 molten film with lower oxygen diffusion rate and viscosity enables the SiC/ZrC-ZrB2 coating to have better self-healing ability.Therefore,the enhanced ablation resistance of the SiC/ZrC-ZrB2 coating can be attributed to the formation of dense ZrO2-SiO2 molten film under the plasma flame.展开更多
文摘将碳化硅(SiC)粉体与一定量的聚乙二醇(PEG)、四甲基氢氧化铵(TMAH)、羧甲基纤维素钠(CMC-Na)及去离子水和乙醇混合并球磨3 h制备出低浓度SiC浆料,研究了SiC浆料p H值与其Zeta电位对应关系和添加组分变化对浆料分散稳定性的影响。结果表明,当p H=8.5时,浆料有最大动电位-37.76 m V,当m(TMAH)∶m(SiC)=1.5%、m(CMC-Na)∶m(SiC)=0.4%时,浆料的表观黏度最小为4.31 m Pa·s,浆料的相对沉降高度最小,浆料的分散稳定性能较佳。利用该浆料在多孔碳化硅陶瓷表面进行涂膜并高温烧成后制备了碳化硅膜并对碳化硅膜的显微结构与其孔径进行了分析表征,结果表明该浆料成膜性能良好,SiC膜晶粒周边圆润、堆积均匀,物相单一,膜孔径分布较窄,平均孔径约为1μm。
基金Project(51304249)supported by the National Natural Science Foundation of ChinaProject(14JJ3023)supported by the Science Foundation of Hunan Province,China。
文摘To improve the ablation resistance of carbon/carbon(C/C)composites,a SiC/ZrC-ZrB2 double layer coating was fabricated by pack cementation and slurry-sintering method.The ablation resistance of the SiC/ZrC-ZrB2 coating was tested under plasma flame above 2300°C.The results indicate that the SiC/ZrC-ZrB2 double layer coating exhibits superior ablation resistance than the ZrC-ZrB2 single layer coating.After being ablated under the plasma flame for 20 s,the mass and linear ablation rates of the ZrC-ZrB2 coating are 0.89 mg/s and 15.3μm/s,while those for SiC/ZrC-ZrB2 coating are 0.09 mg/s and 24.15μm/s,respectively.During ablation,the SiC inner layer can generate SiO2 glass and result in the formation of ZrO2-SiO2 molten film.Compared with the ZrO2 molten film formed on the ZrC-ZrB2 coating surface,the ZrO2-SiO2 molten film with lower oxygen diffusion rate and viscosity enables the SiC/ZrC-ZrB2 coating to have better self-healing ability.Therefore,the enhanced ablation resistance of the SiC/ZrC-ZrB2 coating can be attributed to the formation of dense ZrO2-SiO2 molten film under the plasma flame.
