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SiH_4、N_2二元混合气在低O_2态下的潜在危险性 被引量:1
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作者 沃银花 王少楠 余京松 《低温与特气》 CAS 2004年第1期32-34,共3页
通常硅烷与氧很难共存,人们也决不会贸然在硅烷气体中作掺氧试验。一次偶然的机会,我们做配制SiH4与N2二元混合气的实验,事后发现所用N2中含氧量为4 2%(体积分数)。由此我们知道这种处于亚稳状态的硅烷混合气其潜在的危险非常之大。
关键词 二元混合气 硅烷 氮气 sih4 n2 低O2 爆炸行为 亚稳状态 潜在危险性
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One-Dimensional Fluid Model of Pulse Modulated Radio-Frequency SiH_4 /N_2 /O_2 Discharge
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作者 王燕 刘相梅 +1 位作者 宋远红 王友年 《Plasma Science and Technology》 SCIE EI CAS CSCD 2012年第2期107-110,共4页
Driven by pulse modulated radio-frequency plasma in capacitively coupled discharge are studied by source, the behavior of SiH4/N2/02 using a one-dimensional fluid model. Totally, 48 different species (electrons, ions... Driven by pulse modulated radio-frequency plasma in capacitively coupled discharge are studied by source, the behavior of SiH4/N2/02 using a one-dimensional fluid model. Totally, 48 different species (electrons, ions, neutrals, radicals and excited species) are involved in this simulation. Time evolution of the particle densities and electron temperature with different duty cycles are obtained, as well as the electronegativity nsiH-3 /ne of the main negative ion (Sill3 ). The results show that, by reducing the duty cycle, higher electron temperature and particle density can be achieved for the same average dissipated power, and the ion energy can also be effectively reduced, which will offer evident improvement in plasma deposition processes compared with the case of continuous wave discharge. 展开更多
关键词 pulsed modulation sih4/n2/02 discharge capacitively coupled plasma fluidmodel
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The effects of process conditions on the plasma characteristic in radio-frequency capacitively coupled SiH_4/NH_3/N_2 plasmas: Two-dimensional simulations
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作者 刘相梅 宋远红 +1 位作者 姜巍 易林 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第4期338-343,共6页
A two-dimensional (2D) fluid model is presented to study the behavior of silicon plasma mixed with SiH4 , N2 , and NH3 in a radio-frequency capacitively coupled plasma (CCP) reactor. The plasma–wall interaction ... A two-dimensional (2D) fluid model is presented to study the behavior of silicon plasma mixed with SiH4 , N2 , and NH3 in a radio-frequency capacitively coupled plasma (CCP) reactor. The plasma–wall interaction (including the deposition) is modeled by using surface reaction coefficients. In the present paper we try to identify, by numerical simulations, the effect of variations of the process parameters on the plasma properties. It is found from our simulations that by increasing the gas pressure and the discharge gap, the electron density profile shape changes continuously from an edge-high to a center-high, thus the thin films become more uniform. Moreover, as the N2 /NH3 ratio increases from 6/13 to 10/9, the hydrogen content can be significantly decreased, without decreasing the electron density significantly. 展开更多
关键词 capacitively coupled plasma process conditions effects sih4/nH3/n2 discharges
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The Synthesis and Crystal Structure of [(n-Bu)4N]2 (C20H1402)2M02O7
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作者 LuXiaoming GengZhe TuShujie LiuShuneheng 《首都师范大学学报(自然科学版)》 1997年第2期52-56,共5页
The title eompplex:
关键词 [(n-Bu)4n]2(C20H1402)2M02O7 合成方法 结构研究 晶体
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硅烷及其杂质的气相色谱分析 被引量:2
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作者 陈澄清 《低温与特气》 CAS 1985年第2期40-42,共3页
制备多晶硅时,用液氨法在低温下产生的硅烷,除主成份SiH4外,尚含H2、微量NH3、Si2H6、CH4、H2O、O2、N2、PH3,以及痕量的B2H8和AsH3等杂质,而其中有些杂质,如CH4、H2O、N2等,主要由液氨带入。因此,要加强原材料的分析,严格监... 制备多晶硅时,用液氨法在低温下产生的硅烷,除主成份SiH4外,尚含H2、微量NH3、Si2H6、CH4、H2O、O2、N2、PH3,以及痕量的B2H8和AsH3等杂质,而其中有些杂质,如CH4、H2O、N2等,主要由液氨带入。因此,要加强原材料的分析,严格监控工艺过程中硅烷气内的有害杂质,采取必要的纯化措施。这样,将大大提高由分解炉中析出的多晶硅质量。 展开更多
关键词 气相色谱分析 硅烷 sih4 AsH3 有害杂质 工艺过程 多晶硅 CH4 H2O 液氨法 主成份 nH3 PH3 原材料 分解炉 n2 低温
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