TiO2-SnO2-SiO2 nanocomposite photocatalysts were prepared with Na2SiO3·9H2O, SnCl4·5H2O and TiCl4 as precursors by chemistry coating processes and supercritical fluid drying (SCFD) method. Characterizations ...TiO2-SnO2-SiO2 nanocomposite photocatalysts were prepared with Na2SiO3·9H2O, SnCl4·5H2O and TiCl4 as precursors by chemistry coating processes and supercritical fluid drying (SCFD) method. Characterizations with XRD, TEM, NMR and FTIR showed that in addition to anatase type TiO2, a new active phase(Ti,Sn)O2 was also formed in the range of the studied doping concentration, The catalytic activity was evaluated by photocatalytic degradation of phenol as model reaction. SiO2 remained amphorous at all samples. It could prevent from growth of the size of nanopaticle and transformation from anatase to rutile. Compared with pure TiO2, or TiO2-SnO2 catalyst prepared by Sol-gel method, Nano-composite photo-catalyst showed significant improvement in catalytic activity, the photo-catalytic degradation rate of phenol in 7 h reached 88.7%. Application of the composite catalysts for the photocatalytic decomposition of phenol not only gave the same activity relative to pure ultrafine TiO2, but also reduced cost. The experimental results also proved that the thermal stability of TiO2 was greatly enhanced after mixing with small amount of SiO2. The optimized doping of SiO2 was 20.3%. The photo-catalyst prepared by SCFD combination technology was characterized with smaller particle size, larger surface area and higher activity.展开更多
This study investigates the effect of injecting nanofluids containing nano-SiO_2 as drag reducing agents(DRA) at different concentrations on the pressure drop of air-water flow through horizontal pipe.The test fluid u...This study investigates the effect of injecting nanofluids containing nano-SiO_2 as drag reducing agents(DRA) at different concentrations on the pressure drop of air-water flow through horizontal pipe.The test fluid used in this study was air-water with nano-SiO_2 particles at 0.1%-1%mass concentration.The test sections of the experimental set-up were five pipes of the same length of 9 m with ID from 0.0127m-0.03175m(0.5 to 1.25 in).Airwater flow was run in slug flow regime under different volumetric flow rates.The results of drag reduction(η%)indicated that the addition of DRA could be efficient up to some dosage.Drag reduction performed much better for smaller pipe diameters than it did for larger ones.For various nanosilica concentrations,the maximum drag reduction was about 66.8%for 0.75%mass concentration of nanosilica.展开更多
文摘TiO2-SnO2-SiO2 nanocomposite photocatalysts were prepared with Na2SiO3·9H2O, SnCl4·5H2O and TiCl4 as precursors by chemistry coating processes and supercritical fluid drying (SCFD) method. Characterizations with XRD, TEM, NMR and FTIR showed that in addition to anatase type TiO2, a new active phase(Ti,Sn)O2 was also formed in the range of the studied doping concentration, The catalytic activity was evaluated by photocatalytic degradation of phenol as model reaction. SiO2 remained amphorous at all samples. It could prevent from growth of the size of nanopaticle and transformation from anatase to rutile. Compared with pure TiO2, or TiO2-SnO2 catalyst prepared by Sol-gel method, Nano-composite photo-catalyst showed significant improvement in catalytic activity, the photo-catalytic degradation rate of phenol in 7 h reached 88.7%. Application of the composite catalysts for the photocatalytic decomposition of phenol not only gave the same activity relative to pure ultrafine TiO2, but also reduced cost. The experimental results also proved that the thermal stability of TiO2 was greatly enhanced after mixing with small amount of SiO2. The optimized doping of SiO2 was 20.3%. The photo-catalyst prepared by SCFD combination technology was characterized with smaller particle size, larger surface area and higher activity.
文摘This study investigates the effect of injecting nanofluids containing nano-SiO_2 as drag reducing agents(DRA) at different concentrations on the pressure drop of air-water flow through horizontal pipe.The test fluid used in this study was air-water with nano-SiO_2 particles at 0.1%-1%mass concentration.The test sections of the experimental set-up were five pipes of the same length of 9 m with ID from 0.0127m-0.03175m(0.5 to 1.25 in).Airwater flow was run in slug flow regime under different volumetric flow rates.The results of drag reduction(η%)indicated that the addition of DRA could be efficient up to some dosage.Drag reduction performed much better for smaller pipe diameters than it did for larger ones.For various nanosilica concentrations,the maximum drag reduction was about 66.8%for 0.75%mass concentration of nanosilica.
